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By S. H. Castro

In 1997 Chile was the world's largest copper mine producer with around 3.4 million metric tomes of copper. Conventional technology (conminution-flotation- smelting-converting-electrorefining) for copper sulfide ores was used. For copper oxidized ores hydrometallurgical processes (heap leaching-solvent extraction- electrowinning) were employed. Consequently, the most important waste effluents include flotation tailings, gaseous emissions, smelter slags, acidic and alkaline wastewater, electrolytic sludges, solid residues from leaching, etc. The introduction of stricter environmental regulations are forcing the Chilean industry to minimise the generation of waste and promote cleaner production. Gas emissions such as SO2 and arsenic from smelters and process wastewater are the major problems at this stage. The environmental impact assessment of gas emissions in all six largest smelters namely Chuquicamata, Caletones, Potrenllos, Ventanas, Paipote and Chagres led to design a "decontamination plan." The implementation of this plan resulted in (i) the installation of sulfuric acid plants for SO2 abatement and (ii) the installation of electrostatic precipitators to remove arsenic oxides condensed from cooling gases. The aim of this paper is (i) to describe the type of waste associated to the various stages of the metallurgical processes and (ii) review the main abatement technologies used in medium and large size companies.

Jan 1, 1999

By S. D. Hill

State-of-the art precious metal recovery practice uses cyanide leach solutions to extract the valuable constituents from ores, wastes, and tailings. Activated carbon is then used as an adsorbent in either a carbon-in-pulp system or counter-current flow columns to concentrate and recover the precious metals. Existing techniques for recovering precious metals from carbon prior to the precipitation or electrowinning of the metal involve either the use of dilute aqueous hydroxide solutions at elevated temperature and pressure or, as in a more recent method, the use of a strong cyanide soak followed by a water strip solution at an elevated temperature. Despite past Bureau efforts in the area of precious metal recovery, the ex- traction of gold from pregnant leach solutions remains the most serious drawback in carbon-in- pulp and heap leach processing of low-grade ores containing precious metal values. A second disadvantage in the current practice is the interference in adsorption and desorption that occurs due to the presence of other heavy metal cations in cyanide leach solutions. Specific objectives of current Salt Lake City Research Center precious metals research are to develop less energy intensive and more economic methods for recovering gold, silver, and by- product metals from low-grade resources. To meet these objectives, we are investigating noncyanide leaching reagents, ion exchange resins, solvent extractants, and novel electrowinnlng procedures.

Jan 1, 1984

By E. A. Devuyst

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by Borberly et al. (1984). The process uses S0, (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst that can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops waste waters. The S02/Air process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore, alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful byproducts species exist. Consequently, final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By A. V. Tarasov

The natural resources of lead and zinc are primarily constituted by polymetallic and lead-zinc ores. Beneficiation of these types of ores to produce standard nonmetallic concentrates inevitably results in an increase in the loss of base and precious metals with tailings. An improvement in the grades of lead and zinc concentrates can be achieved by re-cleaner flotation, but it results in production of intermediate products (middlings) to which substantial amounts of lead, zinc, copper and precious metals report. Without an appropriate technology for treating such intermediate products, the recoveries of valuable constituents from lead-zinc ores would remain unsatisfactory. A process has been developed in the Gintsvetmet Institute for processing of polymetallic intermediate products produced at the ore beneficiation plants. This process is based on electrothermic smelting to produce lead bullion containing precious metals, commercial-grade copper-lead matte and high-zinc slags (up to 15-20% Zn) from which zinc can be extracted by slag-fuming or Waelz process. Tests have indicated that the recovery of lead from intermediate products into lead bullion and matte is about 83-85% and 13-14% respectively (the total recovery is 97-98%), while copper recovery into the matte and zinc recovery into the slag is 90-92% and 95-96% respectively. Precious metals (about 96-97%) report into the lead bullion.

Jan 1, 2006

By Larry M. Southwick

Processing of ores to recover metals usually generates large amounts of waste materials, such as rejects from concentrating operations, tailings from leaching and slags from smelting. These wastes often contain substantial amounts of iron and other metals, recovery of which are often considered to be of commercial value. Earlier versions of this paper investigated a number of processes built to recover iron from a variety of copper processing residues. This paper will extend that coverage to residues from nickel/cobalt, aluminum, asbestos and oil shale processing and coal plant fly ash. Products of interest are iron, ferroalloys, magnesium and aluminum. While none of these processes achieved long-term commercial success, their efforts cover the gamut of problems that must be addressed in treating dirty and difficult materials to recover generally low-value products. An Adept is an alchemist who can create a Philosopher's Stone, which could transmute base metals into gold. In 1701 in Berlin one Johann-Freidrich Böttger, a nineteen year old apothecary's apprentice, told King Frederick I that he could discover how to make the Stone. He failed and fled Frederick's wrath to Poland. He failed again, and King Augustus II threw him in jail. Then, in 1709, he discovered instead the secret of making Dresden china, certainly a more practical search. His failures in alchemy led to the nickname Adeptus Ineptus.

Jan 1, 2004

Eliminate accidental tramming of a cleanup tractor. Approach A switch was installed in the operator's seat cushion to pre-vent the cleanup tractor from tramming without an operator in the driver's seat. How It Works The operator must be seated, and the Forward/Reverse Switch (that controls tramming direction) must pass through the NEUTRAL position before the vehicle will tram. See Figure 1. A pressure-sensitive seat cushion switch, a solid-state relay, and a double-contact relay were added to the control circuitry of an S & S BMUAT -88 cleanup tractor to create this tramming interlock. The weight of the operator on the cushion closes the seat cushion switch (Figure 2, A). This activates the solid-state relay (B), which completes the initial circuitry. Moving the For- ward/Reverse Switch (C) to NEUTRAL energizes the coil in the double-contact relay (D) and closes both contacts. One contact completes a sustaining circuit which keeps the double-contact relay energized. The second contact transfers power to the remaining contacts within the Forward/ Reverse Switch. These circuits are shown in greater de- tail in Figure 2.

Jan 1, 1978

By Sheila E. Daniel

"Since 1989, the Mine Environmental Neutral Drainage Program (MEND) has sponsored research into ways of reducing the environmental impact and financial liabilities associated with Acid Mine Drainage from tailings and waste rock. Toward this overall objective, Kilborn was contracted to review the use and applicability of passive treatment systems for acid mine drainage.Experimentation using passive systems to treat acid mine drainage has been ongoing since the early 1980's in North America. Passive treatments are generally considered an attractive alternative to active lime treatment, since they require minimal human involvement, no power, and only seasonal or periodic care and maintenance after establishment. Most attractive is that initial capital cost to implement a passive treatement system is generally low to moderate. Ongoing operating costs are similarly low when compared to active treatment systems.Passive treatment systems currently used, or under investigation to treat acid mine drainage include: anoxic limestone drains, aerobic wetlands, reed bed wetlands, compost wetlands, microbial systems and bioabsorption systems. These wastewater treatment systems utilize the chemical, biological and physical removal processes that occur naturally in the environment to improve wastewater quality, including: oxidation, reduction, coagulation, adsorption, absorption and precipitation; microbial activity; and, gravity aeration and dilution. The rates at which these processes occur determines the loading which can be treated and the effectiveness of the system.The results of our literature review will be summarized, and insight provided into the applicability of passive systems to treat acid mine drainage from Canadian Mines."

Jan 1, 1995

By Kostas Fytas

Canada still remains today a strong resource nation with a huge geological potential. Canada ranks among the top five leading countries in the production of 15 major minerals. Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian Mining Industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage production. It is estimated that across Canada there are a few thousand abandoned mine sites as a result of the last fifty years of mining. Most of these sites are acid producing presenting a serious threat to the environment. It has been estimated that the cost of stabilizing and reclaiming these sites across Canada will be over $5 billion over the next twenty years. Current practices for decommissioning acid producing sites are water covers (flooding), dry covers, revegetation and treatment of the acid effluents. This paper presents the technical and legal issues of mine closure and reclamation in Canada. The methods used in the revegetation of acid producing mine sites is also presented This paper also reviews the financial guarantee requirements for mine closure by the provincial legislations in Canada. A case study of stabilizing and reclaiming a sulphide tailings area in the Sudbury region is presented. It illustrates the challenges facing the Canadian Government and the mining companies in restoring and revegetating the closed and abandoned mine sites across Canada.

Jan 1, 2002

By Abbas Zaidi, Betty L. W. Ou

Wastewaters generated during the extraction of gold from the ore can contain a variety of contaminants such as cyanide, heavy metals and arsenic. Proper management of these wastewaters is therefore necessary to minimize the negative impact of gold mining and milling operations on the environment. The Wastewater Technology Centre (WTC),located in Burlington, Ontario, Canada, has been involved in several studies related to the evaluation of various effluent treatment technologies which are relevant to the treatment and proper management of gold mill effluents. These studies have included bench and pilot scale tests, and the evaluation offull-scale systems. Furthermore, the WTC staff developed protocols for cyanide analysis in gold mill effluents, and a mathematical model for predicting the degradation of cyanide in tailings ponds. The information generated by the WTC staff has been referenced in several reports and papers published over the last ten years (Schmidt et.al. 1982, Simovic & Snodgrass 1989, Whittle et.al. 1989, Zaidi et.al. 1989, Zaidi et.al. 1991). Recently, the WTC has started to develop a micro­computer based expert system for use by decision makers in the gold mining industry and relevant government agencies who are involved in process design, process evaluation, costing, evaluation of the best practicable technology, approval of suggested effluent management systems, and so on. This paper presents some relevant background information and a discussion of the latest version of the expert system being developed by the WTC.

Jan 1, 1992

By G. Deschenes, M. Fulton

The New Britannia Mine processes a qumtz-carbonate gold ore containing 4.63 git Au at a rate of 2,200 tpd. The ore contains approximately 3 .0% arsenopyrite, 2. 7% pyrite and the rest is gangue minerals. Eight to ten percent of the gold is refractory to leaching. Two years ago, New Britannia Mine experienced cyanidation problems. Gold extraction was not stable and occasionally decreased significantly. Preliminary test work, at laboratory scale and in the plant, indicated that lead nitrate addition was beneficial. A laboratory study was initiated to evaluate the level of control of the parmneters (grinding size, dissolved oxygen, pH, free cyanide and lead nitrate) to optimize the efficiency of the process. It was found that lead nitrate addition is required to alleviate the effect of metallic sulphides. This addition causes a significant increase in the gold leaching kinetics and a reduction in the cyanide consumption. The optimum system appeared to be: leaching for 24-30 hours at pH 11.8, 50 git lead nitrate, 250 ppm NaCN and 8 ppm 02. The gold extraction was 89.8% with grinding at 89%-74Fm (leached tail at 0.48 git). Cyanide and lime consumption are 0.40 kglt NaCN and 1.9 kglt respectively. Following the incorporation of lead nitrate, overall gold extraction was increased from 89.2% to 91.1 % but no change was noticed in cyanide consumption. The gross profit is $CDN 988,000 per year.

Jan 1, 1999

By S. K. Pan, M. P. Srivastava, N. Prasad

"Dalli mines of Bhilai Steel Plant, India is fully mechanized iron ore mine having wet processing system. It has a capacity to treat 5 Mt of ROM. In processing circuit of Dalli mines, scrubbing, wet screening and classification operation is being carried out. Average slime generation for the last five years is about 14% of ROM. As the mining has reached to the lower benches, fines generation is more. As a result, very fine and heavy particles, which settle fast, are being discarded with the slime to tailing pond. These heavy and faster settling particles were causing jamming in the thickeners.Laboratory investigations were carried out at Research and Development Centre for Iron and Steel (RDCIS) to suggest a suitable scheme to recover high quality fines so that the availability of thickener can improve. The slime samples were first treated in a floatex density separator. The concentrate obtained from the floatex density separator was treated in hydrocyclone. Laboratory investigations indicated that the slime with 49% Fe, 12.7% silica and 10.7% alumina can be upgraded to 62.1% Fe, 3.3% silica and 2% alumina with 36% material recovery. Based on the laboratory studies ,a system was installed at Dalli minesThe general arrangement of the system is shown in Fig. below."

Jan 1, 2003

By Frank Firmstone

THE indicator cards shown herewith were taken by the writer in June, 1877, from the water-pressure blowing engine of the Longdale Iron Co., at Lucy Selina Furnace, Longdale, Virginia. A description of this engine with figures, and some indicator cards, was published by Washington Jones, Esq., Superintendent of the I. P. Morris Co.,* in the Journal of the Franklin Institute for May, 1877, to which those desiring a full account are referred, but for convenience the principal dimensions, etc., are given below. The machine consists of a pair of horizontal directacting blowing engines, connected at right angles to a common fly-wheel shaft. The blowing cylinders are 4 ft. diameter by 5 ft. stroke; the water cylinders were 18 in. diameter by 5 ft. stroke as built. Both water and blowing cylinders are double acting. The water valves are balanced piston valves, 18 in. diameter, moved directly by eccentrics on the fly-wheel- shaft. Great care was taken to have the areas of the ports and passages at least equal to the area of the working piston. The engine is set about 14 ft. above the tail-race, and the * The engine was built by the I. P. Morris Go., from drawings made by Messrs. Tuws and Hartman.

Jan 1, 1879

During the past decade geopolymer technology has emerged as a possible solution for the effective stabilisation and solidification of waste materials. Amorphous to semi-crystalline geopolymers form by the co-polymerisation of individual alumino and silicate species, which originate from the dissolution of silicon and aluminium containing source materials at a high pH in the presence of soluble alkali metal silicates. It has been shown previously that geopolymerisation can transform a wide range of waste alumino-silicate materials such as fly ash and blast furnace slag into building and mining products with excellent chemical and physical properties, including high compressive strength as well as fire and acid resistance. These chemical and physical properties suggest that geopolymeric matrices derived from waste materials are well suited for environmental and other applications such as the encapsulation of mine tails, the immobilisation of heavy metals and also the fabrication of structural products. The current challenge is to demonstrate that a wide variety of natural Al-Si minerals could serve as potential source materials for the synthesis of geopolymers. Moreover, it should be shown on a large commercial scale that it is possible to encapsulate waste materials into the geopolymeric structure without compromising the chemical and physical properties of the final product for the desired application.

Jan 1, 2000

The efficient development and exploitation of an orebody relies on an understanding of the mineral characteristics of the deposit. This information is valuable throughout the mining cycle - during exploration, assessment, testing, design, operation and rehabilitation. Problems can arise at each stage if there is an inadequate appreciation of the mineralogy involved and its effects on the treatment process. Modern image analysis systems now permit a more quantitative understanding of the mineralogy of an ore to be gathered. Where previously the metallurgist had to rely on qualitative information to guide technical decisions, it is now possible to give numerical estimates to the compositional and textural properties which govern the mineral concentration processes. Ore samples can be characterised according to modal abundances, mineral grain size parameters and mineral associations, all of which affect the liberation and concentration of the values. The paper will discuss the application of quantitative process mineralogy by considering a number of case studies. These include: ore characterisation to assist in exploration, assessment and mine planning; modal analysis of complex mineral suites to assist in the evaluation of ores, the deportment of values between products and the recovery or loss of these values; liberation analysis for ore testing, plant optimisation and performance monitoring; and characterisation of tailing to guide estimates of leachability, stability and rehabilitation options.

Jan 1, 1998

By De Cuyper J

Laboratory testwork has been performed on ancient residues from the cyanidation of a previously roasted gold-containing pyrite and arsenopyrite ore. By grinding to 95 per cent minus 60 microns, and after a strong aeration conditioning of the pulp, a gold recovery of approximately 67 per cent was obtained by cyanidation. This recovery was brought up to 80 per cent by leaching with thiourea, after a preleaching step with sulphuric acid under severe conditions of acidity and temperature. To avoid excessive capital costs bound to such processes, it was decided to investigate the possibility of applying flotation after grinding at a size similar or finer than the one used for the leaching tests. The method turned out to give interesting results because of the natural flotability observed at pH values lower than two for particles rich in gold present in the residue. After two cleaning steps, a final concentrate, representing around one weight per cent of the feed, was obtained with an approximate gold content of 350 g/t, representing a batch recovery of gold of about 50 per cent. Apart from sulphuric acid, whose addition was very high (flotation slurries at 25 g/l H2SO4), other reagents were not found necessary. Additional flotation tests were carried out to examine whether the recycling of the cleaner tails was justified but the gain observed appeared insufficient.

Jan 1, 1993

By E. V. Manlapig, M. C. Harris

"The complexity of the flotation process has made the identification of an appropriate model structure for the predictive simulation of flotation circuits far from obvious. Work performed under the auspices of the AMIRA P9 flotation program has indicated that the metallurgical performance achieved from a flotation cell arises from the interaction of two essentially independent property classes, namely the cell operating conditions and the properties of the cell feed stream. These observations have led to the development of a model structure that associates a constant set of flotation parameters to the streams of the circuit, which are transformed into a flotation response depending on the operating conditions within the flotation cell.A variety of alternative model structures exist within the literature which do not make this distinction between cell and stream flotation properties, and many of these models are in widespread use for flotation optimisation and design studies, both in industry and academia.In this paper, circuit survey and laboratory batch flotation data collected from an industrial flotation circuit are analysed. The data demonstrate that streams in an industrial flotation circuit exhibit varying particle floatability – concentrate streams typically float faster than tailing streams (Figure 1(a)). This floatability, however, is generally conserved around the various units within the flotation process (i.e. the effective floatability of the combined feed and product streams of a unit is equivalent (Figure 1(b)))."

Jan 1, 2003

The high-grade orebody at Miami was mined successively by top-slicing, shrinkage, stoping and under caving. The method described in this paper was developed to enable the low-grade orebody (36,000,000 tons assaying 1.06 per cent copper) to be mined at a low cost without further dilution of the grade. The method is clearly described and illustrated by drawings and photographs, and the original paper should be consulted as it is impracticable to abstract it, beyond noting that the mining cost is just under 40 cents per ton and the average grade of ore now being produced yields less copper than the mill tailing of 1915, the tons mined per day having increased from 4000 to 18,000 in the same period. Vertical and Incline Shaft Sinking at North Star Mine By Arthur B. Foote, Grass Valley, Calif. (Tech. Pub. No. 324: Class A. Metal Mining, No. 36) THE main shaft of the North Star mine is an inclined one following the main vein at an average dip of 26 deg., a vertical shaft intersects it at the 4000-ft. (incline) level, the incline continuing to the 6300-ft. level. At this point the vein was found to give out and a new vein, called the No. 1, was found to dip in exactly the opposite direction.

Jan 1, 1930

By James Malcolmson

(New York Meeting, February, 1913.) THE Tigre Mining Co. of Mexico, owned by the Lucky Tiger Combination Gold Mining Co. of Kansas City, decided early in 1910 to enlarge its mill, which consisted of a concentrator milling 3,000 tons of ore per month. The enlarged plant was designed to crush and concentrate 6,000 of ore and to cyanide 7,500 tons per mouth. The extra tonnage cyanided was to be obtained from tailings which were stored below the old mill. Power was supplied to the old mill from four boilers; a 150-h-p.. Corliss engine and two Weber 60-h-p. gas-engines using producer-gas made from charcoal. The total horse-power required, including 60 h-p. used for machine-drills in the mine, was approximately 275. Cord-wood cost $4.32 per cord, 8 by 4 by 3 ft., and charcoal $15 per ton. The fuel supply in the surrounding country was approaching exhaustion; more than 150 mules and 50 men were engaged in cutting and transporting this fuel, and the unsettled political, conditions in Sonora were such that it would be practically impossible to keep an organization of this kind together. The price of fuel was steadily rising and at times it became almost impossible to get sufficient fuel to operate.

Jan 4, 1913

By Walter E. Heinrichs

This case history really started during the tail end of WWII when two Navy men, both Colorado School of Mines graduates, got together in Washington, DC, while they were assigned to the Office of Navy Petroleum Reserves doing some of the first aerial magnetometer work ever done on a practical oil exploration basis over the offshore area of the Gulf Coast. When separated from Naval Service active duty in 1946, the two men, Walter E. Heinrichs, Jr., and Robert E. Thurmond, tried, unsuccessfully, to form a commercial air magnetometer business. Later they got together again in Jerome, AZ, with Newmont Mining's early geophysical exploration endeavors from 1947 to 1949. Subsequent to the Newmont experience, they jointly proposed a specific mining geophysical exploration and development program to Herbert Hoover, Jr., then president of United Geophysical Co. of Pasadena, CA. Mr. Hoover, in consultation with his father Herbert Hoover and others of his staff at United, particularly Edwin G. Schempf, executive vice president, and Raymond A. Peterson, vice president of research, agreed to establish the proposed program under United's auspices, to be headquartered at Tucson, AZ. The primary objective would be to practically test and develop various mining geophysical methods and techniques while exploring particularly for base metals in the general area of southeast Arizona and southwest New Mexico.

Jan 1, 1991

By A Crawford, P Manton

Telfer is a gold/copper operation, currently operating one open pit mine and one underground mine. The ore processing plant consists of two parallel trains involving semi-autogenous mill, ball mill and crusher (SABC) grinding, flotation and leaching. Due to receiving relatively high grade underground ore for over half of its total feed, Train 1 frequently experienced cleaning circuit overloading during high production periods. This resulted in losses in recovery and ineffective concentrate upgrade. As a quick and simple solution, the Train 1 copper flotation circuit was reconfigured to send concentrate from the first two rougher cells directly to the final concentrate and return the cleaner scavenger tailings to the third rougher cell. These modifications have resulted in a 1.4 per cent increase in plant copper recovery with no change in final concentrate grade. Preliminary results also indicate gold recovery has increased by more than 1 per cent since the circuit reconfiguration. Other benefits include less spillage, more friendly circuit to operate and a more consistent metallurgical performance. Focus for the next phase of optimisation is on concentrate upgrade. A number of opportunities have been identified and are currently being investigated, including staged reagent addition, single stage cleaning of the first two copper rougher concentrates, regrinding of the remaining copper rougher concentrate prior to cleaning and process control based on a machine vision system.

Jan 1, 2009