Search Documents

By John J. McClelland

The U.S. Bureau of Mines formed a team in 1991 to begin developing a long-range research plan for computer-assisted mining that would benefit the metal-nonmetal mining industry. This report details the team's accomplishments, specifically, the development of a model that identifies metal-nonmetal mining research needs that could be addressed by the application of automation technology. The report also provides a summary of automation needs and applications based on visits with mining company representatives. The status and future direction of this work is also presented.

Jan 1, 1994

By J. E. Gillespie

Introduction Mineral wool may be defined as "rock, slag, or glass fibres made by a process of melting and blowing by steam or air, containing a minimum of oil and unfiberized material" (U.S. Bureau of Standards CS 117-44). The earliest production of the material was in Wales, about one hundred years ago. In the United States, the industry daces from 1870 when a plant, using slag as raw material, was established in Greenfield, New Jersey. It was not until 1897, however, that large-scale production was commenced on this continent at a plant in Alexandria, Indiana, which utilized rock from nearby deposits. Today, mineral wool is manufactured in many parts of the United States and Canada, the plants for the most part being in close proximity to deposits of suitable rock or to sources of slag. In the United States there are some seventy-five producers with a total annual capacity of nearly one million tons of wool. In Canada, in 1946, eleven manufacturers produced about fifty million square feet of batt-type mineral wool insulation material. Mineral wool is, perhaps, the most efficient of all heat-insulating materials and, moreover, it is fireproof, extremely durable, and insect- proof. Its high efficiency is due to the very low thermal conductivity of the fibres themselves and to the fact that the produce as marketed contains up to 90 per cent non-conducting air space. Depending on the degree of compression of the fibres in the manufactured product, the specific gravity ranges from 2 lb. to 10 lb. per cubic foot. Products Marketed Following are the principal forms in which mineral wool is marketed: Blanket. - Mineral wool with or without reinforcing on one or both sides, with various types of confining media, all suitably bound together.

Jan 1, 1948

By B Lumsden, R Smiles

Independence Group’s Jaguar Mine treats a polymetallic ore producing a copper concentrate and zinc concentrate. Effective separation of the sulfides requires relatively fine grinding with flotation feed P80 of about 75µm. Zn losses to final tails are greater than 60 per cent and <32 µm. When magnetic conditioning was first installed in 2010 it showed about an 8 per cent reduction of zinc in final tail and on some ores a similar benefit for silver as well. Current testwork is showing about a 12 per cent reduction in zinc and silver in final tail, consistent with the original testwork. Sizing of the final tail during the tests showed that the reduction of zinc and silver losses were only in the <32 µm fraction, as would be expected from an aggregation process. However, the most surprising result was about a 4 per cent reduction in zinc and silver in the plant feed with a >99 per cent statistical certainty. The reduction in zinc and silver in the feed is also only in the <32 µm fraction. Therefore, because the magnetic conditioning of Zn flotation feed cannot impact plant ore feed grade the hypothesis is that the magnetic conditioning is reducing the fine mineral from downstream processes, like filtering and thickening, returning to the plant feed in the recycled process water. This hypothesis is consistent with plant observation of dirty concentrate thickener overflow and measurements of solids in the overflow, as well as the average % Zn grade in cyclone overflow that correlates with the magnetic conditioning ON and OFF days. This paper presents these plant test results.CITATION:Smiles, R and Lumsden, B, 2018. Improving fine sulfide mineral recovery in Independence Group’s Jaguar Mine zinc circuit, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 433–440 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Zuhair A. Munir

"The use of self-propagating combustion reactions to synthesize metallic, ceramic, and composite materials is described. The limitation of this process because of the porous nature of its products is discussed. The formation of dense bodies through the simultaneous application of pressure is shown for a metal-matrix composite. The effect of an external electric field on the synthesis of ceramic and composites is described. The nature of the effect of the field on the mechanism of synthesis is analyzed theoretically and experimentally. The use of the self-propagating combustion to synthesize intermetallic thin films is presented for the Ni-Al and Ti-Al cases. The formation of functionally gradient materials (FGM) by centrifugally-assisted self-propagating high-temperature synthesis is described.IntroductionThe use of self-propagating combustion reactions for the synthesis of a large number of simple and complex materials has been described in numerous publications. These have been amply discussed in several review articles [1-4]. The many benefits of this method of materials synthesis are commonly examined in light of its most significant limitation: the porous nature of its products. The porosity in the products of self-propagating high-temperature synthesis (SHS) is an intrinsic characteristic of the process and its elimination has been the focus of numerous attempts. Various experimental methods have been used to accomplish this goal."

Jan 1, 1994

By George S. Dulikravich

An advanced semi-stochastic algorithm for constrained multi-objective optimization has been adapted and combined with experimental testing and verification to determine optimum concentrations of alloying elements in heat-resistant and corrosion-resistant H-Series austenitic stainless steel alloys. The objective was to simultaneously maximize a number of alloy's mechanical properties. This research will result in a rigorous tool for the design of high-strength H-Series steels and other types of alloys unattainable by any means existing at the present time. Such a material-by-design tool will also be able to reduce or minimize the need for the addition of expensive elements such as Cr, Ni, Co, Nb, Ti, V, etc. and still obtain the optimum properties of an alloy.

Jan 1, 2003

By J. E. Gray

Before specifications are discussed it may be well to define the term "Mineral Aggregates." Professor K. B. Woods (1) defined "Mineral Aggregate--An aggregation of sand, gravel, crushed stone, slag, or other material of mineral composition used in combination with a binding medium to form bituminous and portland cement concrete, macadam, mastic, mortar, plaster, etc., or alone as in railroad ballast, filter beds, and various manufacturing processes, such as fluxing, etc. " This definition is too all inclusive for the purposes of this paper; therefore, this discussion will be confined to specifications for natural aggregates which means sand and gravel and crushed stone, and limited primarily to coarse aggregate which is aggregate larger than one-quarter inch in size. To the uninitiated, this may seem to be a very limited subject on an unimportant material. However, aggregates are essential in all types of construction. The tonnage and value of these two aggregates produced in the United States during 1959 as reported by the Bureau of Mines were as follows: Sand and Gravel 729,895,000 tons valued at $728,527,000 Crushed stone 581,721,000 tons valued at $824,411,000

Jan 1, 1961

By Hong Ouyang

A unified computational model has been developed for the Bridgman growth processes of B-NiAI and CdTe crystals. To handle the geometrical and physical complexities, a two-level approach has been developed. At the gtobatlevel, conjugate heat transfer, phase change dynamics, and variable material properties along with the realistic geometries and thermal boundary conditions are accounted for inside the entire crystal growth system. Refined calculations are then made within the ampoule, with the boundary conditions supplied by the global simulations. This model can optimize the use of computational source, help understand solidification behaviors, and improve designs of crystal growth system.

Jan 1, 1996

By D Genge, E Martin, T Goswami, M Rothery

Rio Tinto’s Hunter Valley Operations is a large open pit coalmine situated in the heart of the Hunter Valley in Australia. The Riverview West Pit has faced increasing production challenges in recent times due to decreasing dragline strike lengths and increasing environmental constraints on vibration, overpressure and fume generation. Conventional mining techniques would involve five to six production blasts per strip to recover multiple coal seams. Each blast event carries the risk of exceeding the strict environmental requirements. By working collaboratively with Orica, it was realised that the blasting method known as Stratablast™, in conjunction with advanced computer modelling techniques, could provide productivity gains whilst simultaneously providing more control over the environmental effects and the impact on nearby infrastructure.As a result of this change, the number of blasts per strip was reduced to one, with the implication that a great deal of care and forethought was needed to manage the increased challenge posed by multiple constraints in the proposed mining area. This innovative approach of combining throw and stand-up blasts allowed the extraction of all major coal seams in a single pass blast event. The blasts were initially designed with a large factor of safety to stay within environmental limits as they were over 1.1 km in strike length, with more than 800 holes and with a total charge weight of about 1000 t of bulk explosives. Furthermore, there were conflicting priorities around the desired blast outcomes. So far, 11 such blasts have been designed and successfully fired. After each blast, innovative design changes have been iteratively implemented to provide further control over environmental impacts, whilst continuing to improve productivity. As a result of these changes, blasts have progressively increased in complexity with the inclusion of features such as damage zones, mid-splitting, time gaps and different directions of firing. The consequence of this complexity is that the blast duration can be as long as 28 seconds to accommodate all components of the blast.This project has increased the productivity of the Riverview West Pit through blast design improvements and allowed the environmental impacts to be managed with far more control and predictability than would have been possible under a conventional blasting regime. There still remains room for further optimisation of mine productivity and this is being addressed through a process of continuous improvement.CITATION:Goswami, T, Martin, E, Rothery, M and Genge, D, 2015. A holistic approach to managing blast outcomes, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 645–654 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By J. Organiscak

A majority of continuous mining machines employ a water spray system and a machine-mounted flooded-bed scrubber to suppress and capture dust during coal mining. These machine-mounted dust control systems must be designed to function within the localized face ventilation system at the mining section to control both dust and methane. Spray systems can impede or improve the scrubber effectiveness in controlling dust or methane at the mining face. Laboratory experiments were conducted to examine the effect of spray type, spray pressure, machine body blocking sprays and scrubber airflow on dust and gas levels, while using a 12.2-m (40-ft) exhaust ventilation curtain setback from the face. These experiments were conducted with the mining machine positioned at the end of a simulated 6.1-m (20-ft) sump and slab cut. Results indicate that the hollow cone nozzles with blocking sprays best complement the flooded-bed scrubber performance in an exhaust ventilation system. This external spray system notably reduced dust and gas levels on the off-curtain side of the mining machine for both the sump and slab cut compared to the flat spray nozzles. Higher scrubber airflows reduced dust and gas levels on the curtain side and in the return of the continuous mining machine. The remote operator position, located on the off-curtain side and parallel to the inlet end of the exhaust curtain, sustained the most stable and lowest dust levels around the mining machine.

Jan 1, 2010

By N. A. Warner

To filly secure the environmental and social acceptability benefits of making a sulphide smelting facility and its ancillary sulphuric acid plant or other means for fixing sulphur, a virtually zero gas emission operation, it will be necessary to utilise exclusively technically pure oxygen. The strategy proposed for preventing the smelter from overheating involves highly efficient energy transfer by promoting sulphur trioxide formation at a relatively higher temperature than normal. A closed-loop gas circuit uses an eductor system actuated by the process oxygen to recirculate sulphur trioxide and unconverted sulphur dioxide back to the smelter, the endothermic dissociation of sulphur trioxide becoming a major contributor to the removal of excess heat. The only gases leaving the system relate to the bleed of nitrogen impurity introduced in the tonnage oxygen.

Jan 1, 1998

By M I. Pownceby, W J. Bruckard

A South African chromite sample was subjected to characterisation and physical beneficiation testwork in order to assess its suitability to produce an upgraded chromite product with a silica level of <1 per cent SiO2 and a chromite level of >46 per cent Cr2O3. Chemical analysis by XRF indicated that the bulk material had a Cr2O3 content of 40.5 per cent w/w and a SiO2 content of 7.5 per cent w/w. Combined XRF analysis with sizing data showed that the majority (~70 per cent) of the siliceous material was present in the +600 ¦m fraction while ~70 per cent of the Cr2O3 was in the -600 ¦m fraction. Qualitative mineral phase analysis by XRD indicated that the sample mineralogy was dominated by ferrian-magnesiochromite spinel ([Fe,Mg]Cr2O4) and aluminium-chromite spinel (Fe[Al,Cr]2O4), with enstatite (Mg2Si2O6), haematite (Fe2O3) and anorthite (CaAl2Si2O8) as minor phases. SEM and EMP characterisation showed that the silica was mainly present in discrete enstatite grains but lesser amounts were also present as the high silica phases plagioclase and enstatite on the edge of grains. Wet gravity separation performed on sized fractions (-600+106 ¦m size range) from the -2.0 mm (primary) ore as well as the ore that had been crushed to pass 0.6 mm (secondary) showed that stage crushing of the -2 mm +600 ¦m fraction followed by wet gravity separation upgraded the Cr2O3 grade at 70 per cent Cr2O3 recovery from ~44 per cent Cr2O3 in the primary material to 46 per cent Cr2O3 (the target grade specification) in the secondary sample. It also showed that the stage crushing of this +600 ¦m fraction at a cut-off level of one per cent SiO2 increased the cumulative Cr2O3 recovery from ~50 per cent in the primary material to ~63 per cent in the secondary sample in the same size range of -600+106 ¦m. The extent to which additional crushing could lead to improved chromite recoveries at the required chromite and silica grade target specifications was not determined. This experience demonstrates that prior to processing test work being conducted, a thorough understanding of the chemistry and mineralogy of the test sample promotes efficient and targeted processing research.

Jan 1, 2008

By Yogeshwar Sahai

Submerged gas injection into melts contained in furnaces, ladles, or similar transfer vessels is commonly used in industrial practice. In this review paper, conditions leading to gas bubble formation at the nozzle are first summarized. The increasing gas injection rates and other conditions, such as nozzle size, lead to regimes which are commonly known as "bubbling" and "jetting". These are explained. The gas/melt interactions result in energy transfer to the melt. In recent years, a large number of researchers have investigated the relationships between the energy density and the mixing times. Their work is reviewed, and the mixing mechanisms is described. Finally, computational approaches of modeling submerged gas injection are briefly presented.

Jan 1, 1993

By Liu Chun-Bao Sun, Hong-Jun, Wei Zhang, Tao Xu

SABC circuits have gained widespread attention within China, and are being gradually applied to many mines. However, the domestic knowledge of comminution process is still relatively basic, and the design and production management of the application of SABC technology lack guidance of scientific theories. This research project focuses on the Phase I SABC milling circuits of Wu Shan Porphyry copper mine. Targeting the design and operation problems of existing process and circuit, and without increased investment and alterations in equipment, the new technologies will combine ordinary crushing and grinding theories as theoretical guidance, and borrow JK Simulation Software (JKSimMet) for analysis in order to optimize the comminution process, efficiently allocate production output and energy consumption, eventually resulting in increased production and energy efficiency. Using JKSimMet Simulation Software, and combining theoretical optimizing and practical production techniques, as well as the on-site situation, the eventual SABC comminution process and circuit optimization plan is: increasing the grinding Ball charge from 8% to 10% v/v in the SAG mill; Setting the Ball charge in the Ball mill to 27% v/v and the maximum operating power draw to 5 800kW; replacing the HP Series crusher with a TRIO TC84 crusher, which is without a power controller, and adding a pebble bin. The final optimization result is: Maximum system processing capacity increased between 20%-26.7%, specific energy consumption reduced by more 2.0 kWh/t, creating an economic benefit of over 300 million RMB, thus achieving the goal of increased production, reduced energy consumption, and improved profitability.

Jan 1, 2014

By Frank McKinley

This paper discusses the basic requirements covering the area between the initial discovery of a deposit and a decision as to whether or not the deposit will support an economically sound mining venture. The procedure for gaining the necessary information and the sequence of steps is in .some respects parallel to gaining like information on deposits other than the sand type. For the sake of simplicity the stages and sequence are presented as follow: first, the initial reconnaissance drilling; second, the exploration drilling to permit initial ore body estimates; third, metallurgical testing; fourth, the estimate of plant and operating costs; and last, the economic balance. The objective of the reconnaissance drilling is to collect sufficient information to reach a decision as to the advisability of further exploration or the abandonment of the area. This initial phase will comprise, in addition to some drilling, a thorough reconnaissance of the area, a study of the best geological and topographic maps of the region, and a study of any literature available, all under the guidance of a geologist.

Jan 1, 1958

By G. Johnston, J. Greenly, R. G. Buchheit, D. C. McIntyre, R. Muenchausen, D. J. Rej, R W. Stinnett

"Rapid thermal treatment of materials using high energy, high flux, pulsed ion beams can produce modified surface layers with unique microstrutures and properties. High energy ions loose their energy during the slowing down process in the workpiece and thus deposit their energy continuously over a depth of a few microns. The deposition of energy can lead to melting and in some causes ablation of the heated layer. Because the pulse duration of the ion beams is typically only 50-200 ns, steep thermal gradients generated during heating facilitate rapid cooling (107K/sec-108K/sec) of the treated layer by thermal diffusion into the underlying material. Rapid heating and cooling of materials can generate surface layers with non-equilibrium amorphous or nano-crystalline microstructures that exhibit increased hardness, wear resistance, and corrosion resistance. Pulsed ion beam treatment can also lead to surface smoothening or can be used to mix thin « 1 11m thick) coatings into underlying substrates. Pulsed ion beams can be generated using existing ""flashover"" ion source technology which is capable of producing single shot, mixed C, H, and O ion beams with beam cross sections of approximately 100 cm2 and energy fluxes up to 100 J/ cm2. Recent advances in repetitive high energy pulsed power technology and development of magnetically confined anode plasma ion sources have facilitated the development of ion beam systems that generate single species beams that pulse continuously at 120 shots/second. These capabilities will allow rapid treatment of large surface area workpieces at low cost.IntroductionThe rapid solidification of liquid materials can create unique materials and material microstructures that often have properties that can lead to enhanced performance. Rapid solidification processing of the surfaces of materials using continuous and pulsed laser beams (laser glazing) has been explored for over 20 years (1-5). Advances in high energy, pulsed electron and ion beam technologies over the past decade have provided rapid thermal treatment techniques that may be less expensive to impliment than laser surface treatment for many surface modification applications (6). High energy pulsed ion beams have recently been used to harden aluminum(7), copper(8) and tool steel surfaces (6,9), increase corrosion resistance of Al alloys (6), mix coatings into underlying substrates (10), and create amorphous films (11,12)."

Jan 1, 1994

By L Blackwell

Strategic mine scheduling is an industry best practice for increasing the long-term value of mining operations and supply chains. The application of optimisation technology such as mixed integer linear programming (MILP) is able to achieve a mathematically optimal result for a given scheduling model. Such a model will typically define the available source material, processing options and desired constraints for accessing and processing the material. Most strategic scheduling models, however, do not include a sufficiently detailed model of capital expenditure options related to capacity expansion.Typical strategic schedule models do not include important capital expenditure features such as capacity decay or expiration (limited lifespan of trucks), precedence relationships over time (rail construction before a new plant or non-linear expansions due to economies of scale) or mutually exclusive option sets (choices of plant size). By not including these features, a strategic mine scheduling model for a capital-sensitive operation is unable to be optimised to deliver maximum value or profitability.This paper presents several results of MILP optimisation using advanced capital expenditure modelling for mining operations and supply chains. Results of the study demonstrate that optimising capital expenditure at the same time as optimising the mining schedule allows for minimisation of capital purchasing, optimal timing for those purchases and optimal scheduling around them. Overall, this results in an increase in net present value.CITATION:Blackwell, L, 2014. Capital expenditure modelling for strategic mine scheduling, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 315–322 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By Sharanappa Yalal, Rakesh Kumar Khali

"Himalayan geology poses the most challenging ground conditions almost anywhere in the world, one of the reasons thereof is their evolution as the youngest mountain chains. They are demonstratively rising faster than any mountain elsewhere. The composition is also younger, and consequently less well consolidated than the other older fold belts. This is consistent with the fact that they constitute one of the most active of the plate margin zones rising at a rate that is almost double the Andes, which is in turn three times that of the Alps. Thus, stress conditions (Magnitude and variations) can potentially be more extreme and adverse on a Himalayan tunneling project. Tunnel excavation under the Himalayan Mountains will pose significantly more challenges than an equal length and equal cover drive almost anywhere in the world. These in-depth-tunneling difficulties through high mountainous terrains have posed major challenges for application of traditional drill and blast (D&B) and NATM methods. Handling such adverse geology at any depth is always problematic and generally leads, if not adequately foreseen, to the significant tunneling delays. The author wants to highlight the challenges faced and on the spot solutions adopted while executing most prestigious 273Km long Udhampur –Srinagar- Baramula Rail Link Project (USBRL) in the Himalayas in the state of Jammu & Kashmir, India. The main focus of the paper is on main stretch of USBRL Project i.e. T-80 (India’s 2nd longest railway tunnel & 3rd longest in Asia) where the team of the author has recently completed a 11.2 Km long tunnel and where the train track has gone operational from Qazigund to Banihal. The construction of this stretch posed several challenges akin to highly adverse geological conditions. Executing on -the -spot solutions, the project has been completed successfully. 1.0 INTRODUCTION Construction of Udhampur-Srinagar-Baramulla Broad gauge railway line is one of the Mega projects undertaken by Indian Railways to establish a dependable transportation in the state of Jammu and Kashmir. In engineering terminology, it is a challenging project negotiating breakthroughs against the complex Himalayan geology. The Project which has been operational over last 12 years , stretch by stretch, is in advance stage of construction . The purpose of the prestigious project is to connect the Kashmir valley to the mainland of the state of the country. On the date owing to the hurdles of the tuff terrain, the transport of this part is totally dependent on the surface transport, i.e., through a road which connects NH-1A from Delhi to Srinagar. The altitude of the region varies from 500.00 to 1700.00, ranging through Udhampur to Katra - Reasi –Sangaldan- Banihal-Quazikund-Ananthnag-Srinagar-and Baramulla. The main features of this project are its Pirpanjal Tunnel and T-48 & 49 tunnels which cover the maximum length of tunneling through thick hostile geological conditions, the total length being 138km. Details of Pirpanjal tunnels are shown in Figure-1."

Jan 1, 2016

By Lloyd Buckingham

Barrick Gold Corporation (Barrick) has undertaken innovative methods of evaluating and improving the performance of grinding mills in several of its operations around the world. The results have been positive with some of the mines showing more than 20% net energy improvement leading to more than 43,000 tonnes per year reduction in CO2 emissions in four of the operations reviewed.

Jan 1, 2012

By Roy J. Greenfield

A highly undesirable side effect of the mining of coal is the release of acid forming chemicals into the ground water system. The disturbance of the ground during mining allows water to flow through the coal bearing strata and mine refuge where it absorbs iron and sulfide ions and thus becomes highly acidic. The highly acid mine water can then contaminate water supplies and can destroy many of the recreational uses of Pennsylvania's waterways. A great deal of effort has been expended to develop methods of controlling groundwater pollution from mine drainage. At the Pennsylvania State University there has been an ongoing effort to under- stand the chemistry of acid mine water formation and the hydrologic environment in which the acidic water migrates from the mine source into the ground water system. As a support to the hydrologic studies, geophysical studies have been used to help determine the geologic structure of the areas under study which are contaminated by acid water. In addition, the geophysical work has been used to define the type of information geophysical methods can give to determine which geophysical methods are most useful and to develop geophysical field procedures.

Jan 1, 1973

By H. Kasaini

Batch wise adsorption tests for platinum (Pt) on the surface of activated carbon pellets (Norit RO 0.8 BET surface area 1100 mg/g) were carried out in mixed chloride solution. The purpose of this study was to assess and compare the adsorption performance of amine-treated activated carbons (AACs) and native activated carbons (NACs) in terms of adsorption capacity and selectivity. The effect of pH and temperature on adsorption capacity and selectivity was established. The amine- treated ACs were prepared by anchoring the amino groups (butyl amines) on the surface of AC pellets in aqueous media and the UV-Vis was used to determine the amount of amine sequestered from solution by ACs. The dosage of butyl amine on the surface of ACs averaged 0.15 g/g, carbon. The adsorption mechanism was described by the ionization and complexation model whereby interaction between the protonated AAC surface and the anionic chlorocomplex ions (PtCl5 [H2O]-, PtCl62-) proceeded by either electrostatic attraction or/and by covalent bonding [(NH3)2PtCl6 or (CH2COO)2PtCl6]. By comparison, the adsorption capacities of Pt on amine-treated ACs and native ACs were 53.8 mg/g and 33.03 mg/g, respectively which highlight the benefits of anchoring functional molecules on ACs. The selectivity of AACs was influenced by solution pH. Pt adsorbed selectively on the surface of amine-treated ACs at pH<1.5. The highest separation factor that was recoded pertained to Pt and Fe species (ßPt/Fe = 90) then followed by Pt and Ni species (ßPt/Ni = 30) or Pt and Cu species (ßPt/Cu = 15). The lowest separation factor was recorded for Pt and Cr ions (ßPt/N= 5). Adsorption kinetics of Pt on amine-treated AC surfaces, according to the first and second order reactions, were investigated and results showed that rates were in the order 10= 5). -4 min-1 and 102 g?min/mg, respectively. The pseudo 1st order kinetics predicted the adsorption capacity of 51.81 mg/g which was almost similar to the experimental value (53.8 mg/g) while the second order rate equation predicted Pt adsorption capacity of 40.1 mg/g. Both The Langmuir and Toth isotherm fitted the Pt adsorption at pH < 1.0. The Freundlich isotherm tended to underestimate the adsorption capacity of AACs.

Jan 1, 2014