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By G. G. Brown

Enthalpy-entropy diagrams are presented for natural gases of 0.6, 0.7, 0.8, 0.9, and 1.0 gravity over the pressure range of 5 to 10,000 Ib. per sq. in. and temperature range of 32º to 700°F. The charts indicate directly the work requirement and temperature rise for adiabatic compression or temperature change for free emansion of natural eases. Computation and Uses of Charts The Mollier diagram (Fig. 4), in which the enthalpy (heat content) is plotted against the entropy with lines of constant temperature, pressure,, and in some cases volume, has been found most convenient when dealing with the compression, expansion, and flow of fluids. In dealing with the flow of fluids, the sum of the increase in the enthalpy, AH, plus the increase in kinetic energy, AM —, plus the increase in potential energy, ?MZ, representing the total increase in energy of the fluid in flow, is equal to the sum of the heat q, and work added, —w, to the fluid while flowing between the entrance and exit of the flow system. AH + AM— + ?MZ = q-w [1] In cases where there is no significant change in potential energy or in kinetic energy (velocity), it follows that the increase in enthalpy is equal to the total energy supplied to the fluid. Under such conditions' the changes in the property of the fluid as it flows through a throttling valve, choke, or any other similar arrangement, may be read directly from the enthalpy-entropy diagram by following a horizolltal line between the known pressures' When compressing Or expanding a gas by means of a Or or engine in which no heat is added to or subtracted from the gas, but only work done, the changes in the properties of the gas may be determined along a vertical line of constant entropy between the entering and exit pressures. The power required for the compression of the gas may be readily determined by converting the increase in enthalpy into the desired units. The enthalpy-entropy diagram for natural gases is to the gas engineer what the steam diagram is to the steam-power engineer. For this reason it would be extremely convenient if a reasonably satisfactory enthalpy-entropy diagram could be prepared as a function of the gravity of the gas. A careful study of the known properties of natural gas indicate that this is possible. The effect of temperature upon the enthalpy at constant pressure is expressed as the "heat capacity" or "specific heat" of the gas. The best available data for natural and petroleum refinery gases indicates the relationship shown in Fig. I. From this it is clear that the specific heat of natural gases is a function only of the gas gravity and the temperature at atmospheric pressure. The effect of pressure on the enthalpy of natural gases is dependent upon the pressure-volume-temperature relationships,

Jan 1, 1945

By Clarence Hall, Spencer P. Howell

Among the more important factors involved in the use of high explosives in blasting operations is the means employed to bring about the detonation of the charge. When flame is applied to high explosives many of them may burn if not confined; but all of them when burning under certain conditions of confinement may detonate. Detonation may also be effected by mechanical means, such as frictional impact caused by a blow or by rubbing between surfaces. By this means, however, the full effect of the explosive charge may not be developed, so that a partial detonation, often accompanied by the burning of the explosive, results. When nitroglycerin was first used it was fired by the application of flame, but considerable difficulty was experienced in exploding it with certainty and in obtaining uniform resl'llts. In 1864 Allred Noble, a Swedish engineer, discovered that nitroglycerin could be surely and completely detonated by exploding in contact with it a small quantity of an initiatory explosive. Mercury fulminate was the substance then found capable of producing the best results There are many other fulminates and other substances that will produce complete detonation of commercial" high" explosives, but detonators or electric detonators containing mercury fulminate as the characteristic ingredient are still almost exclusively used in this country. The term" detonator" is used in the publications of the Bureau of Mines to designate what the miner calls a "blasting cap "-a copper capsule containing a small quantity of some detonating compound that is ignited by a fuse. The term" electric detonator" is applied to a blasting cap that is similar except for being ignited by means of a small wire which is heated to incandescence or fused by the passage of an electric current. One of the conditions prescribed by the Bureau of Mines for a permissible explosive a is that it shall be :fired by a detonator, or preferably an electric detonator, having a charge equivalent to that of the standard detonator used at the Pittsburgh testing station. A further requirement is that this charge shall consist by weight of 90 parts of mercury fulminate and 10 parts of potassium chlorate (or their equivalents). At the request of a manufacturer of permissible explosives, an investigation was undertaken by the bureau to determine the relative strength of detonators and electric detonators having different compositions. The tests of electric detonators herein reported were conducted by H. F. Braddock, junior chemist; J. W. Koster, J. E. Tiffany, junior mining engineers; and A. S. Crossfield, junior explosives chemist, at the Pittsburgh testing station of the bureau. Similar tests of detonators were not conducted because it was believed that the results would not show sufficient variation to warrant such tests. It is hoped that the conclusions drawn from the tests made will be of service to those using explosives by enabling them to select the grade of detonator or electric detonator that will insure the most effective results. The conclusions are given in this bulletin, which is published by the Bureau of Mines as one of a series of publications dealing with the testing of explosives and the precautions that should be taken to increase safety and efficiency in the use of explosives in mining operations. The results of tho experiments described in this bulletin show that the average percentage of failures of explosives to detonate was increased more than 20 per cent when the lower grades of electric detonators were used instead of No. 6 electric detonators, and was increased more than 50 per cent when these lower grades were used instead of No. 8 electric detonators. It is noteworthy, however, that when sensitive explosives, such as 40 per cent strength ammonia dynamite (p. 33), were tested under conditions ideal for detonation, the same energy was developed irrespective of the electric detonator used. When tests were made with a less sensitive explosive, such as a 40 per cent strength ammonia dynamite containing nitrosubstitution compounds (p. 32), the energy developed increased with the grade of the electric detonator used. For example, the average efficiency of four different explosives was increased 10.4 per cent when a No.6 electric detonator was used instead of a No.4 electric detonator, and 14.9 per cent when aN 0.8 electric detonator was used (see tabulation onp.45). The results of the tests emphasize the importance of using explosives in a fresh condition, but as fresh explosives can not always be had in mining work, strong detonators should be used in order to offset any deterioration of explosives from age.

Jan 1, 1913

By C. E. Sims, C. A. Zapffe

MANY hundreds of publications have appeared during the past 78 years that treat the subject of hydrogen in iron and steel,105 but conclusions regarding the functions of hydrogen in causing some important defects in steel are still unsatisfactory to many; and other hydrogen-caused phenomena yet remain to be identified with this gas. The most widely discussed of these defects is hydrogen embrittlement, but the conception, perhaps the popular one, that embrittlement is due to hydride formation does not conform to the known facts.104 The true identity of hydrogen embrittlement seems instead to lie in a mosaic nature of metal crystals, which is a concept not yet accepted by most metallurgists. A study of hydrogen embrittlement therefore provides new viewpoints in regard to the crystalline substructure of steel. A second widely discussed hydrogen-caused defect is the "flake" or "shatter crack." Although it is generally agreed that the presence of hydrogen is a prerequisite for their appearance, it is also realized that internal stress plays a decisive part. The relationship of hydrogen to internal stress has not been explained very clearly; nor is it always clear what the relationship is between a "flake" and a "snowflake," or between a "fish eye" and a "shatter crack." More importantly, the relationships among hydrogen embrittlement, hydrogen-caused fissures such as "flakes" and the ultramicroscopic structure of steel have scarcely been recognized. The present investigation attempts to provide an explanation for the embrittlement of steel by hydrogen by showing cause for accepting the "block" concept of metal crystals, and then to show how the numerous hydrogen-caused defects are interrelated in the light of this concept. EVIDENCE OF SUBSTRUCTURE IN METAL CRYSTALS It appears that the concept of a crystal as an aggregate of smaller multi-atom units must be accepted in some form if the behavior of metals is to be understood. The abundant literature on the evidence of an ultramicroscopic "mosaic" structure in metals and other crystalline substances suggests that the physicist has provided the metallurgist with an invaluable new insight. The exact picturization that any one physicist provides may be open to question, but the fact that there is some such fundamental substructure seems undeniable. The present work makes no pretense of comprehensively treating the imperfection structure theories. Nor will conclusions be drawn here regarding the exact nature of the substructure of crystals. However, the acceptance of some imperfection theory of fundamental attributes seems so necessary to an understanding of the behavior of hydrogen in steel that the following brief

Jan 1, 1941

By Robert G. Woolery

Union Carbide_ began looking seriously at heap leaching in 1971. At that time some 1.6 million tons of mineral averaging 0.040% U308 were stockpiled at various sites around the Gas Hills, Wyoming, uranium facility. Several alternatives for economically exploiting these reserves were considered and heap leaching seemed the most attractive. At the time, Western Nuclear Inc. was operating a heap leach project nearby in which the low-grade ore was leached with sulfuric acid, the product liquor treated in an on-site solvent extraction circuit, and the stripped product liquor re-acidified and recycled. They were most generous in allowing us to visit their site, answering our questions, and were helpful in discussing the problems associated with heap leaching. They confirmed our belief that, it was possible to operate a heap leach profitably on material too low grade for. conventional milling. Based largely on what we had learned from Western Nuclear's experience, a program was set up involving a laboratory study to determine the characteristics of the mineral stockpiles as related to heap leaching and to conduct a pilot heap leach adjoining our Gas Hills mill. Basically, the pilot heap construction and leach procedure were similar to those described in the literature(1,2) with certain modifications to permit detailed monitoring of the operation. In May, '1972, the decision was made to construct a test heap. The UCC plant at Gas Hills, Wyoming was selected as the most appropriate site for the follow¬ing reasons:

Jan 1, 1977

By D. Leppert

Clinoptilolite zeolite may offer attractive, cost-effective alternatives for remedial cleanup of old minesites, smelters and other sites with heavy metal contamination. Previous research demonstrates the relatively strong affinity of clinoptilolite for numerous metals and clinoptilolite displays a particularly strong affinity for lead (Loizidou and Townsend, 1987), one of the most toxic and problematic heavy metals. Since clinoptilolite can also selectively absorb some radionuclides and organic compounds, it may offer practical solutions to a wide variety of environmental problems.

Jan 1, 1989

By Keith E. Forrester

This paper presents results of bench scale laboratory evaluation of a processes developed by FESI and Brookhaven National Laboratories for the extraction and recovery of Pb and other heavy metals from incinerator ash which was subsequently modified by FESI for the extraction and recovery of Pb from soils excavated from a FESI client scrap yard and battery breaking operation facility. The specific waste matrix presented within the paper is a battery acid contaminated surficial soil at 0" to 12" depth. The extraction method was found to be highly successful on the bench scale in generating a final post-extracted soil matrix which passed TCLP Pb regulatory limits and retained minimal Pb after aggressive extraction application. The paper findings at this time are brief, as a majority of the research results are currently being compiled and additional efforts are underway based upon initial screening findings.

Jan 1, 1995

By K. O. Johnson

Contaminant transport of mine and mill tailings is controlled by the hydrologic flow regime and the geochemical mobility of the contaminants. Contaminant' mobility is primarily determined by chemical reactions occurring within an interface zone between the tailings and soil The large geochemical differences between tailings and groundwater create a disequilibrium in the groundwater with respect to the soils when seepage from tailings enters the groundwater. Precipitation and dissolution reactions involving the major chemistry occur to return the perturbed system to chemical equilibrium between groundwater and minerals. Retardation of trace elements depends upon the chemical character of the groundwater and the adsorption substrates. In the case of uranium mill tailings, the mobility of contaminants is controlled primarily by precipitation/dissolution reactions which neutralize the pH, modify the Eh (redox potential), and produce highly adsorptive substrate for retardation of trace elements.

Jan 1, 1988

By M. L. Clark

Advances in the recovery of gold from heap leaching are being made daily, but of all the systems vital to the maximum recovery of gold from a leach pile, none is more important than the methods used to construct the pile in preparation for the leaching operation. The technology described in this paper illustrates the latest systems developed to minimize compaction in the pile during its construction and reduce the cost of placement of ore on the pile. The Florida Canyon Mine of Pegasus is evaluated in detail to show reasons for its high degree of success to date.

Jan 1, 1988

By Frank Rausche

Introduction and Background Testing -Pile Preparation -Data Processing -Data Interpretation/Case Studies Case Studies - Existing Piles Stories from around the world

Jan 1, 2001

By R. R. Klimpel

The process of froth flotation as a means of upgrading the quality of coal by removing ash/pyrite and of separating selected mineral(s) from undesired gangue materials is certainly one of the most common unit engineering operations in use today. Flotation has been successfully practiced at the industrial scale for well over 50 years, and if anything, its use is increasing due to the ever decreasing feed grades of the coals and minerals being processed. Flotation, as a process, has also shown itself to be an extremely flexible process that lends itself well to a wide variety of solid/solid separations. Thus separations can involve very different particle sizes, particle densities, relative weight ratios of materials to be separated, etc., with surprisingly little modification in equipment and operating philosophy required.

Jan 1, 1988

By Det Juridiske Fakultet, Maria Madalena das Neves

The ocean is increasingly seen as the answer for a myriad of challenges facing humankind. In effect, in addition to being vital for transportation and communication, the oceans contain living and non-living resources that are essential to meet the demand for food, and to the development of pharmaceutical products, energy resources, and high-technology products. This entails that the oceans are under pressure by different activities: navigation, fishing, oil and gas exploration and production, renewable energy development, laying of cables and pipelines, marine scientific research, bioprospecting, and deep-sea mining for minerals and metals. The growing demand for essential minerals and metals such as cobalt, nickel, zinc, copper, and manganese, seen in tandem with technological advances in deep-sea mining, makes the latter an increasingly attractive activity, both in areas within and beyond national jurisdiction. At the same time, the further development of deep-sea mining adds to the problem of the competing uses of maritime space and accentuates the need to balance and articulate the interests of the different users of the seas (States, sponsored deep-sea mining investors, oil and gas investors, fishermen, shippers, etc.). Furthermore, as deep-sea mining activities increase and move on to an exploitation phase so does the possibility of new disputes (for instance during deep-sea mining exploitation a communication’s cable is severed, a vessel conducting deep-sea bottom fisheries damages deep-sea mining equipment, etc.).

Jan 1, 2018

By T. Zoltai

Asbestos is a generic term for industrially useful fibers recovered from exploitable deposits of the asbestiform varieties of five silicate minerals: chrysotile, anthophyl-lite, actinolite-tremolite, cummingtorute-grunerite, and rie-beekite. Asbestos and asbestiform fibers of some other minerals are known to be carcinogenic. Minerals crystallized in the asbestiform habit-are characterized by unique properties (morphology, strength and flexibility, physical and chemical durability, and defect-free surface structures). The key to the unusual properties, and health effects, of asbestiform fibers appears to be in their unusual surface structure. In contrast, non-asbestiform crystals of the same minerals, including the five so called asbestos minerals, do not have these properties and are not carcinogenic.

Jan 1, 1989

By David Cole

AT the time flotation appeared upon the metallurgical horizon in Arizona, the writer, under the direction of Dr. Ricketts, was engaged in remodeling and enlarging the No. 6 Concentration Plant of the Arizona Copper Co. at Morenci, and the work had been in progress nearly a year before the Inspiration experiments with flotation had disclosed the revolution in concentration that was at that timè impending. The simplified flowsheet worked out for the remodeling of the Morenci plant had been based upon the removal of the freed metal in a minimum number of stages by treatment upon tables equipped with Butchart riffles, the latter being adapted to accomplish both classification of feed and removal of the metal at one operation, substantially as described in my previous paper.1 The scheme of treatment for the slime was based upon the well-known fact that after copper sulphides, such as chalcocite and chalcopyrite, etc., are reduced to a certain extremely fine state of comminution they are definitely beyond the reach of separation upon any of the concentrating devices then known. By using drag-belt classifiers (which served as conveyors as well as separators), the overflow would be of the usual "slimes" class. Experiment had shown that when these drag-belt overflows were, properly diluted (that is, to about 5 to 7 per cent. solids in the feed under treatment) . the very fine sand, and especially the very fine but still granular sulphide particle's, would, if given a short distance to fall, quickly settle out in prime condition to yield an excellent recovery on vanners; a further valuable feature would be that the very fine non-separable final overflow tonnage might be discharged direct to tailing, thus conserving space requirements so as to permit within the old building, without embarrass-ment, the increase of capacity required.

Jan 9, 1916

By Angus W. Davis

The case of the P. G. E. railway is a peculiar one. Traversing, as it does, to a large extent, a mineralized country there are as yet no producing mines along its route although I am convinced that mines will be developed in the region tributary to the railway. The Fitzimmons group of claims, a copper property near Mons station, 37 miles from Squamish is now (unless recently relinquished) under bond to the Granby Company. On Cadwallader creek, in the upper Bridge river country, certain gold properties, referred to later, are being developed. Prospectors are fairly active in the Pemberton meadows area. There are also a large number in the Bridge river, Gun creek, and Whitewater districts. East of Marguerite station some development work is being prosecuted on some copper claims located there. In addition here and there throughout the entire route of the railway prospecting is being undertaken. At Hat creek, 15 miles from Pavilion station there is an enormous deposit of lignite. It is by no means certain that this coal can be profitably mined and hauled to the railway, but as a cheap fuel it offers possibilities in the recovery of by-products by destructive distillation. Logical procedure would ? indicate the expenditure of considerable money on development and, if results justify, the construction of a spur from the main line to the deposit.

Jan 1, 1925

By M. P. Juszli

During the 1980's, a revolution has been taking place in industrial minerals marketing. Transportation deregulation and a handful of creative marketing and distribution managers have completely changed the rules for marketing many industrial minerals. Minerals are being trans-ported much farther than in prior decades and at much less cost. Bulk and package terminals are becoming increasingly common as a means to take advantage of freight rate savings and to provide enhanced service to far-away customers. Water and rail transportation are being used increasingly to penetrate markets considered unreachable Just a few years ago.

Jan 1, 1989

By R Valenta, A Littleboy

Geological heterogeneity is one dimension of complexity in mining. Significant effort is put into developing an understanding of this complexity so it can be used in resource estimation, mine planning and economic modelling. However, over the decadal lifespan of a mining venture, many other dimensions add to the complexity of a mining operation. These include: technological evolution, market fluctuations; investor confidence; social norms; local expectations; and ecosystem functionality. As with geology, these factors are all heterogeneous, uncertain, time varying and represented through sparse and incomplete datasets. Recent work (Valenta et al) is beginning to show us how these risks correlate in different global settings. By analysing data relating to known, but as yet undeveloped copper deposits, this work (the complex ore body database) is demonstrating that it is the combination of issues (both price sensitive and non price-sensitive) that determine the viability of a deposit for extraction in the 21st century.CITATION: Littleboy, A, Plint, N and Valenta, R, 2018. Mining as a complex system: do we need a new model?, in Proceedings Complex Orebodies Conference 2018, pp 41–43 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By A. S. Ibrado

The adsorption of silver on activated carbon from cyanide solutions was studied as a function of concentration, ionic strength and pH. In cyanide solutions, silver exists mainly as the linear Ag(CN)2 complex and adsorbs on activated carbon following the Freundlich isotherm. The uptake and rate of adsorption increase with the addition of KC1 and KNO3 but changes only slightly with pH. In contrast, the adsorption of Cu(I), Zn(II), Cd(II), and Hg(II) shows marked changes with pH, closely following the predominance profiles of their neutral and singly-charged cyano complexes. Clearly, multicharged negative complexes are repelled by the negatively-charged carbon surface. This sensitivity of activated carbon to the charge of the adsorbing species indicates that silver adsorbs as an anion, not chemically bound to the co-adsorbing counterions. For the same reason, activated carbon is selective to metals that form neutral and Singly-charged cyano complexes, namely gold and silver.

Jan 1, 1988

By R. J. Roman

During the refining of primary magnesium metal: a spent flux (sludge) is produced which is considered a dangerous waste by the Washington State Department of Ecology. Four years of research, testing and marketing has identified two beneficial markets for the spent flux: 1) as a fertilizer and soil admendment as a result of the material's high potash and nitrogen content and its high lime equivalence and 2), as a roadway deicing agent to clear roads of ice and snow as a result of both the salt content and the flux containing chemical compounds which exothermically react with water.

Jan 1, 1988

By J. D. Lowell

The gold content of prophyry copper deposits ranges from less than .05 gmt (ppm) to more than 1.0 got, and most deposits contain on the order of 0.05 gmt Au. Perhaps the highest grade mineralization which has been found in close proximity to a porphyry copper is the Ok Tedi Gold Cap orebody whose grade falls in the 2-3 gmt Au range.

Jan 1, 1988

By D. A. Robbins

The application of remote sensing for environmental measurements is already being utilized. Aircraft mounted imaging spectroscopy has been utilized to evaluate areas of historical mining operations as well as active mine sites. To the extent that remote sensing can provide more sensitive, cost effective, and timely monitoring potential, the technology is of interest to the industry. Questions remain about the application and validation of the data and the availability of the technology in the private sector. This presentation will discuss some of the potential uses, benefits, and concerns related to remote sensing and efforts to monitor the technology's development.

Jan 1, 1999