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By J Boshoff

The management and operation of tailings storage facilities (TSFs) are often neglected until the process plant has to shut down as a result of this negligence or as a result of a catastrophic failure as was the case during the recent TSF failure in North America.TSFs are often regarded as non-assets and do not receive the attention they deserve in terms of technical expertise and financial provision. A TSF is not a simple structure but a complex and dynamic structure that changes throughout its operational life. The operational life of a TSF is the period in which there is the greatest opportunity for risks to occur. The failure of a TSF is normally not as a result of a single event but as a result of a consequence of events. These events are often not recognised in time due to a number of factors.Process plants and slurry pumping systems are operated at suboptimal conditions in order to maintain throughput. At the same time, the tailings properties are compromised in terms of slurry density and particle size distribution amongst other things. Tailings deposition cycles and drying cycles are not well understood and the tailings management strategy is not well tuned in terms of maximising consolidation and improving in situ densities. Pond control is also neglected. These are aspects that form the keystone to the effective utilisation of available deposition area as well as the frequency and cost of future embankment raises.Apart from operational issues, forward planning in terms of budget requirements, increases in tailings throughput, embankment raises, pipe replacements, etc are normally put on the back burner. Available deposition space at the time seems to render this planning obsolete.The bottom line is that responsible tailings management and proper forward planning can limit liability and reduce the bottom line in terms of cents per ton if correctly implemented by suitably qualified tailings managers and engineers.The aspects that need to be considered as part of responsible tailings management are highlighted in this paper.CITATION:Boshoff, J, 2015. Responsible tailings management, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 317–322 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By W. A. MacWilliams, R. G. Reynolds

"This paper describes, for the first time, a patented method of extracting sodium sulphate from a natural deposit in Western Canada. The method resembles, but is not, strictly speaking, solution mining. The fact that a plant based on this method has been in successful operation since late 1969 will be of added interest. The deposit in question is located near Metiskow, Alberta, and conventional surface recovery methods could not be applied because of heavy concentrations of mud. Considerable pilot work went into the separation and recovery process on which the plant operation is based. The history of the industry is covered briefly as background to this development. Today it is clear that the method has broader application within the industry and, in concept, may generate interest in many other applications."

Jan 1, 1973

In the estimation of recoverable resources, geostatistical techniques such as Multiple Indicator Kriging require a change of support correction to derive theoretical recoveries based on an assumed level of mining selectivity. The change of support models most widely used in practice entail model based generalized corrections either on a global or local basis. Examples include the affine and indirect lognormal methods. Change of support corrections derived empirically through short-scale conditional simulation realizations often show notable differences compared with theoretical corrections determined using model variogram parameters. The existing changes of support models are reviewed and an alternative method is proposed.

Jan 1, 1999

By V. Gregoire

THE DEVELOPMENT by the Iron Ore Company of Canada of the Quebec-Labrador mining project, which eventually led to 'Iron Ore in 1954', involved, from the start, several distinct undertakings. Among them, the most important were: The construction of a 360-mile railway, linking Knob Lake with Seven Islands. The erection of a railway terminal, and harbour facilities, at Seven Islands itself. The building of an entire townsite at Schefferville (formerly Knob Lake) The construction of two hydroelectric plants; and, finally, The development of a sufficient number of orebodies to enable a production of 10 to 15 million tons of ore a year. Since these phases of the project have already been the subject of previous discussions, this paper will not elaborate further on them but will rather concern itself with a brief outline of the Company's current mining practices.

Jan 1, 1958

By J. F. Magee

THERE is nothing new about drag-line dredging for placer gold. The use of the separate unit for excavating preceded the large barge with bucket-line excavator mounted upon it, which has developed to a high state of perfection through use in every part of the world. But at present there is a vogue for a small, inexpensive plant to work economically the shallower gold gravel deposits that the bucket-line dredges do not work. The dragline dredge consists of the drag-line excavator, on caterpillar mounting on the edge of the dredging pond, which feeds the gravel to the washing plant, mounted on a floating barge in the pond. There have been more than twenty-five such plants built and operated in central and northern California and an unknown number in other States. There have been variations in details of design but the essentials are similar in all. I wish to describe the operation of a typical drag-line dredging plant, that of the Wyandotte Gold Dredging Company on the Farnan Ranch in the Oroville district. This organization of six active partners built their first plant on Wyandotte creek in the autumn of 1933. The operation was successful due to wise management, which was based upon good plant design and proper principles of operation. The partners elected one of their number, H. F. England, as manager with full control and responsibility. This plant and operation furnished the pattern for many subsequent ones.

Jan 1, 1937

By Markus Papst, Denise Millier, Daniel Beckers, Axel Preusse

"At an open-pit lignite extraction mine in Germany, groundwater has to be pumped over a large area, which leads to subsidence at the surface. As long as the geology of the area of influence is homogeneous, the subsidence is uniform and has marginal influence on buildings.Since the geology of many regions is characterized by faults, there are different rates of subsidence along those faults, which can lead to considerable consequences. Those different rates of subsidence on both sides of a geological fault are associated with the structure of the geology and soil mechanical properties. Horizons with various thicknesses and types of soil are affected differently by the groundwater pumping because of the offset of the faults, and thus react dissimilarly to dewatering.The smaller the grain of the geological horizon, the stronger the chance of shrinking, which leads to a stronger effect at the surface; therefore, dewatering impacts on clayey soil are different to those on sand and gravel. Regions consisting of meadows with turf inclusions are endangered as well; compared to the surrounding geology, those areas react in an entirely different way to water removal, which leads to immense differences in subsidence.The differences in area and respective subsidence impacts, as well as if it is possible to localize those areas, is an issue which needs to be analyzed. Furthermore, detailed mapping can help in the development of future forecasts about those subsidence differences and can also help with monitoring geological faults. In the context of subsurface spatial planning, this mapping has to be kept under review medium- to long-term.INTRODUCTIONThe utilization of underground mining is of increasing significance and of high interest, both for the common good and for future generations. For decades, humanity has been extracting resources from the subsurface, and salt, coal, lignite and water - just to mention a few resources - have been extracted from underground (Sailer, 2013)."

Jan 1, 2016

By G. A. Irons, D. Guo

"The average spout height and width produced by bottom gas injection in a water model of a steel ladle were measured with an image processing technique. It was revealed that the spout height could be described by a Gaussian curve. A combined SIMPLE -VOF model was developed to simulate the liquid surface and flow. The results showed that, though the model produced reasonable velocity distributions and free surface positions, the spout height due to the dynamic head of the rising liquid was substantially lower than observed, indicating that the bubble dynamics at the bath surface play an important role in spout height.IntroductionDue to the enormous importance of gas injection and stirring in metallurgical processes, there have been numerous publications on water and numerical modeling of such vessels. The free surface of the bath has received considerably less attention, despite its importance. At the free surface there are often important chemical phenomena occurring that require a good understanding of the fluid flow; these would include reoxidation of steel, metal splash and fume formation. Furthermore, to understand the details of slag-metal interactions such as slag entrainment, metal losses to slag and the transport phenomena associated with refining reactions, it is necessary to understand the plume and spout interactions first.There have been few experimental studies of the free surface of liquid in gas-injected ladles [1- 3], and even fewer on numerical modeling. Brimacombe and co-workers [1] studied the gas void fraction in the spout region, using a double-tip electrical resistance probe. This sensor cannot distinguish between gas in bubbles about to break and gas in the freeboard. Thus, it is a matter of judgement as to the position of the free surface. Schwerdtfeger and co-workers [2] used a single probe configuration with a wire and a counter electrode in the liquid, so that the height of the continuous liquid phase was unambiguously determined. Irons and co-workers [3] measured the spout height by ultrasonic and electrical capacitance techniques. These techniques were as reliable as the resistance techniques, but were restricted to low flow rates."

Jan 1, 2001

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By J Seppelt, G S. Lane, E Wang

Newcrest’s Cadia concentrator operated from 1998 to 2012 with a traditional SABC grinding circuit treating Cadia open pit ore. The Cadia comminution circuit was well characterised through surveys and data that are available in the public domain, and became a benchmark standard for the industry and practitioners modelling large SAG mill based circuits. In 2012, the HPGR-based crushing circuit was introduced in front of the SAG mill to increase throughput when treating the Cadia East ore that was derived from an underground block cave. This ore was expected to be more competent and have a coarser run-of-mine size distribution.Numerous previous papers have described the design and commissioning of the Cadia HPGR-based circuit.This paper describes the improvement in comminution energy consumption resulting from the introduction of the HPGR, including identifying the impact of process complexity and an increase in ancillary energy consumption for conveyors, screening, and crushing.CITATION:Lane, G S, Seppelt, J and Wang, E, 2018. Quantifying the energy efficiency transformation at Cadia due to HPGR crushing, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 141–152 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Maurice Hall Haycock

ONE result of the higher price of gold has been the exploitation of many low-grade deposits, the successful treatment of which depends upon obtaining high recovery of the contained gold. Modern methods have made it possible to recover gold from many ores formerly regarded as impossible to treat economically, but in order to apply these methods efficiently it has become desirable, and indeed in many cases indispensable, to gain precise information concerning their mineralogical and physical character. The most successful means of doing this is the use of the reflecting microscope. Reflecting microscopes had long been employed by metallurgists for studying polished surfaces of iron and steel when, thirty years ago, Dr. W. Campbell, of Columbia University, advanced the idea of using similar methods for studying opaque minerals (1). The immediate result was the completion of two microscopic studies, the first on Cobalt silver ores (2) and the second on Sudbury nickel ores (3). The idea was surprisingly slow in being adopted, and not until 1911 did it begin to spread through the universities of this continent. From then on, ore microscopy, or 'mineragraphy', made rapid progress, and, during the next fifteen years, research in universities of North America and Europe led to the development of somewhat specialized apparatus and technique. This phase of development, which resulted largely in contributions of a descriptive nature, furnished a mass of data from which the possibility of economic applications was soon recognized. Ore microscopy became an aid to the mining geologist in solving many problems of ore deposition. This soon led to its application in the study of ores and mill products in connection with their treatment. Its usefulness in this latter field has been very marked and has led to its widespread adoption by the mining industry.

Jan 1, 1937

By R. Perlo

"INTRODUCTION Peoples’ and operators’ safety in construction are tightly linked to the engineering choices, as much as the necessity of reducing time and costs of realization. Therefore, it is of paramount importance to address them properly from the earliest stage of the design, identifying the risks connected to the work and the variability of such during the different phases of the project. Risk is often measured as the expected value of an undesirable outcome. Regarding to occupational safety and health, the risk is the likelihood that a person may be harmed of suffers adverse health effects if exposed to a hazard. This combines the probabilities of various possible events and the assessment of the corresponding harm into a single value. However, the actual occurrences are often more complex than a single binary possibility case. In a real case scenario, with several possible accidents, the total risk is the sum of the risks for each different accident, provided that the outcomes are comparable. The semi-automatic tunnel support system along with its erector machine proved to be a solution with improved structural performance, able to reduce the time and yet to deliver an enhanced, quality-aware and safer working environment for the operators. The implementation of the system provides the engineers, the contractors and the owners with an effective alternative option shortlisted in 2015 for the ITA Award for the Safety Innovation of the Year. In a market industry driven by safety and time constrains the efficiency shall be the ultimate goal, in order to provide solutions able to negotiate with the most challenging ground conditions. In this paper, the authors describe the recent developments on regard of this whole new tunnel support system, including design approach and presenting related case histories OFFSETTING THE RISKS Considering the above factors, from the manufacturers’ point of view, an effective way to limit the construction risks is to focus on the material and technological characteristics, their application and the risks related to them including any residual risks. Finally addressing the construction needs also involves time and cost-effective solutions. The path to follow is an integrated approach where the efficient management of the risk is supported by a flexible, user-friendly, and time effective product that is able to provide a safe, reliable and viable solution to address the construction requirements. Therefore, in a market sector driven by safety and time constraints, the efficiency is a key goal, in order to avoid redundancy and yet to deliver a safe working environment able to meet the construction schedule. The safety of all the parties involved is given by stable working conditions, either for the workers, or the operators and eventually the public. Therefore, the solutions provided should ‘strengthen’ the overall condition and such “to limit or to reduce the deformations within acceptable designed limits and to prevent [the tunnel] to collapse” [1: Clause 207.1.4]."

Jan 1, 2018

By David Verrelli, Melissa Kistner, Leanne Smith, Chris Aldrich, Lidia Auret, Warren Bruckard

In this investigation, different mixtures of realgar and orpiment particles were floated in a laboratory batch flotation cell and multivariate image analysis was used to estimate the arsenic content in the froths. The analysis was based on the froth colour, as well as extraction of three groups of textural features, namely those based on grey level co-occurrence matrices (GLCMs), wavelets and local binary patterns (LBPs). Collectively, these features provided better information on the arsenic content of the froths than any one of the individual groups of features. Partial least squares models could explain approximately 78% of the variance in the arsenic by using all the features combined. The colour content, particularly the green component in the red-green-blue (RGB) features, provided almost as much information as each of the three sets of texture-base features individually.

Jan 1, 2014

By C. Liley

Open cut blasting at the Ernest Henry mine has the potential to cause damage to nearby underground workings. This paper is a case study of the blast vibration management project which was conducted to ensure pit blasting did not adversely affect the stability of upper production levels or cause damage to the underground primary fan units.

Jan 1, 2012

By J. H. van Laar, L. J. van der Walt, P. L. Crouse, H. Bissett, G. J. Puts

"SynopsisSilicon carbide nanopowders were produced using a microwave-induced plasma process operating at 15 kPa absolute and at atmospheric pressure. Methyltrichlorosilane (MTS) served as precursor, due to its advantageous stoichiometric silicon-to-carbon ratio of unity, allowing it to act as both carbon and silicon source. Argon served as carrier gas, and an additional hydrogen feed helped ensure a fully reducing reaction environment. The parameters under investigation were the H2:MTS molar ratio and the total enthalpy. The particle size distribution ranged from 20 nm upwards, as determined by SEM and TEM micrographs. It was found that an increase in enthalpy and a higher H2:MTS ratio resulted in smaller SiC particle sizes. The adhesion of particles was a common occurrence during the process, resulting in larger agglomerate sizes. SiC layers were deposited at 15 kPa with thicknesses ranging from 5.8 to 15 µm.IntroductionIt is well known that methyltrichlorosilane (CH3SiCl3 or MTS) decomposes to form silicon carbide (SiC) and hydrogen chloride (HCl) as shown in Equation [1]. The reaction kinetics and mechanisms for this reaction are thoroughly reported in the literature (Sone et al., 2000; Papasouliotis and Sotirchos, 1999; Kaneko et al., 2002; Wang et al., 2011)."

Jan 1, 2015

By D Carroll

Mining of the zinc, lead and silver deposit at the Broken Hill Southern Operations site has been occurring for over 100 years. As a result of this, a significant amount of high-grade ore is now taken from narrow remnant pillars left between old stopes and zones of previously mined ground. Stopes have been filled with either hydraulic fill (also known as ‘sandfill’), cemented hydraulic fill (cemented sandfill), waste rock backfill or a mixture of these fill types.In the last ten years, there has been considerable success mining through narrow pillars where sandfill is exposed in the development face and/or walls using a ‘shell’ support regime, wherein a layer of bolted mesh is sandwiched between two layers of sprayed fibrecrete (25 mm fibrecrete, then mesh and bolt, followed by a final 50 mm layer of fibrecrete). Shell support is also used in very poor, broken, relaxed ground conditions and in areas filled with cemented fill (sandfill with a minimum four per cent cement content).The next stage of innovation has been to develop a technique for mining through old stope voids filled with uncemented sandfill, known locally as ‘contours’ (old cut-and-fill working), an activity where unconsolidated sandfill can run at the face and from the backs. The challenge is to prevent exposed sandfill in the face and the backs from failing before it can be supported.To achieve this, the Southern Operations mine has implemented a technique in which 6 m long spiling bars are used to strengthen and stabilise the sandfill in front of the face. The hollow steel bars are driven in around the heading perimeter in a closely spaced pattern then pumped full of grout. The bars and the grout stabilise the sandfill in front of the face, preventing it from failing into the drive during excavation and prior to further support being installed.A final support system consisting of shotcrete, mesh, bolts and steel girders is installed as excavation progresses. Both the initial and final support systems are essentially passive support systems designed for a low-stress environment (as the stress originates mostly from the mass of unconsolidated sandfill).This process is slow and labour intensive. Fifteen separate cycles of people/machinery are needed to progress one equivalent heading cut (compared to six for a standard fibrecrete- and bolt pattern-supported rock face heading). This slow pace introduces scheduling challenges, but the process opens up parts of the orebody that were previously uneconomical to mine.CITATION:Carroll, D, 2014. Mining through sandfill using spiling bars, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 95–100 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

"Cast blasting is the primary means of overburden displacement in a surface coal mine. It serves two purposes; fragmenting the rock and throwing it directly to its spoil pile using explosive energy. Increased throw minimizes costs by reducing the amount of material that needs to be re-handled. Prior studies have shown that by only changing blast hole timing with the same blast design, fragmentation and throw alters. It is necessary in cast blasting to optimize both fragmentation and throw, since larger fragments will require more wasted energy to throw the same distance. In an operating mine in Georgia, an optimum inter-hole delay for fragmentation has been found by studying timings from 0ms to 45ms. Instantaneous timing between holes increased the throw by over 100 ft, but fragmentation was poor. Shock and detonation wave collision is a potential reason for this increased throw. This paper investigates this optimized inter-hole timing while altering top and bottom column primer time to potentially improve throw while maintaining optimum fragmentation. Timings studied are top initiation, bottom initiation, and top and bottom simultaneously. INTRODUCTION Explosives are utilized extensively by the mining industry in order to break rock, as either ore or overburden, for hauling, loading, and crushing. An effective production blast strives to achieve optimum rock fragmentation in order to increase the efficiency and reduce the costs of those downstream operations, while simultaneously meeting environmental regulations. The goal of blasting with respect to fragmentation is, according to Hettinger (2015), “to decrease the average particle size of the fragmented rock without overly increasing fines or, in other words, improve fragmentation.” Additionally, the distance the rock is transported by the explosive energy from the blast, also known as throw, can increase efficiency by reducing the amount of material that is re-handled by mine equipment. The primary situation in which this is desirable is the cast blasting of overburden across the narrow pit of a surface coal mine. A key variable in a blast design pattern that can be manipulated to optimize both fragmentation and throw is delay timing between detonations. The invention and increased utilization of electronic detonators has allowed for precise delay timings to be used between rows, holes, and even multiple primers within the same hole. These recent developments in the blasting community have also provided an opportunity to investigate whether or not the mechanism of shock or detonation wave collisions caused by short timing delays are responsible for any increased fragmentation or throw. This experiment attempts to demonstrate if an increase in throw can be achieved while maintaining optimum fragmentation. This study consisted of 3 full scale bench blasts at a granite quarry in Talbotton, GA. Each blast was characterized by the timing delay between the top and bottom primer in the blast column of each hole; one simultaneous blast with a 0 ms delay, a bottom-initiated blast with a 1 ms delay, and a top-initiated blast with a 1 ms delay. Fragmentation analysis of the resultant muckpiles was performed using a combination of the PortaMetrics handheld point-and-shoot rugged tablet from Motion Metrics and the software WipFrag from WipWare. Throw was measured by placing strategic distance markers on the floor of the bench and then taking overhead photographs of the muckpiles after each blast. High-speed video footage was captured of each blast using an MREL Blaster’s Ranger II camera."

Jan 1, 2017

By P. G. Dunn, J. Fitzgerald

ABSTRACT The scheduling of underground mining activities is a complex task that must simultaneously satisfy a large number of constraints. A schedule optimization tool (SOT) for underground mine planning is described, and its use for investigating strategic decisions is illustrated through a case study. The maincomponents of the SOT include (a) a genetic algorithm that searches for optimal schedules, (b) guidance for the application of heuristic rules, and (c) sliding, which implements just-in-time development. Findings indicated that preliminary scheduling performed before invoking the SOT, intended to provide a good starting point for the search, did not ultimately lead to higher value schedules.

Jan 1, 2010

By C. L. Pillar

In the capitalistic system the success of a mining enterprise is measured by the rate of return on the investment and the speed by which its redemption is achieved. Exploration in search of ore deposits often results in the emergence of the lean orebody which does not meet basic company requisites. At this point a decision must be made whether to place the orebody into production or postpone production pending more favourable market conditions. The wisdom of this decision, borne out by future results, demonstrates the quality of a company's management and is instrumental in the degree of financial success it achieves. The project feasibility report must show a rate of return on the capital invested that is attractive to the company, plus its full redemption in the desired period of time, in order to bring the property into production on a sound economic basis. Mining companies have demonstrated their ability to bring the profitability of a marginal property from a point that says "no go" to a point of "go" by substantial reduction of expenditure without adversely affecting production rate or cost. Here is where the real challenge exists for today's mining engineers and plant designers; they will have to develop better ideas and concepts: ideas that will still allow maximum production at reduced capital expenditure, This is the sound way marginal orebodies can be brought into production without inflationary increases in the price of their product.

Jan 1, 1969

By E. J. Mayhew

Bentonite and newly discovered deposits of sepiolite, saponite, and hectorite are now being processed and marketed from the Amargosa Valley of Nevada. All of these deposits are large. The bentonite has been known for decades and is the whitest known. The only other sepiolite deposit is in Spain. The only other commercial hectorite deposit is at Hector, California. No other saponite deposit is known. All the components except bentonite are hydrous magnesium silicates. The bentonite is mixed layer Na-Ca. All the materials have characteristics unique to their locale and type, such as high yield point for drilling muds and liquid suspending agents. The sepiolite has geothermal stability. Figure 1.

Jan 1, 1979

By F. Crundwell, N. Steenekamp

"The leaching of sulphide minerals generates a significant amount of energy. There are three systems that might be used to remove this energy. These are: cooling coils, quench water, and flash recycle. Flash recycle is the recycling of slurry from the autoclave to the feed tank. Heat is removed in this arrangement when the slurry at elevated temperature and pressure is flashed to atmosphere, releasing steam. The slurry is returned to the autoclave at lower temperature, resulting in cooling. The cooling is directly proportional to the steam released from the recycled slurry. Design equations and results for the flash recycle system are presented. A fourth proposal for removing heat is to recycle slurry from the back of the autoclave. These four alternatives not only remove the heat, but also have an effect on the leaching efficiency. Amongst the four alternatives, design calculations indicate that the flash recycle option is the optimal solution in terms of leaching efficiency and heat removal, and recycling product from the back of the autoclave is the worst. In spite of its efficiency in terms of heat removal and leaching, the implementation of the flash recycle system is limited to a few operations in the platinum industry.INTRODUCTIONIn considering ways to improve leaching operations, focus is placed on the chemistry, on the kinetics, the agitation and perhaps even on the gas mass transfer conditions. Attention is less frequently placed on the removal of energy from these reactors and how this might limit performance.The pressure leaching of sulphides releases a significant amount of heat. For example, the reaction for the leaching of chalcocite, Cu2S, given by"

Jan 1, 2012