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By l. Bokányi

The Tóth adsorption isotherm-model was derived and has been widely used for the inhomogeneous solid surfaces. The three-parameter isotherm incorporates the effect of the interaction between the adsorbed substances as well. All classic isotherms can be clearly derived from this one. Bio sorption is the sequestering of dissolved components, i.e. metals from aqueous environment by living or dead biomass. The mechanism of the bio sorption is rather complex and predominantly refers to the affinity of the chemical functional groups: acetoamido groups of chitin, structural polysaccharides, amino and phosphate groups in nucleic acids, amino, amido sulfhydryl and carboxyl groups in proteins, hydroxyls in polysaccharides, sulphates, etc. towards the soluted substances, i.e. heavy metal ions. The physisorption, as well as the micro precipitation also play a role in the bio sorption mechanism. The description of such a complex process can be done by a model reflecting this complexity. According to our experimental results obtained using algae and immobilised algae for the sorption of heavy metal cations, the most appropriate model for such a description is the Tóth-isotherm, the parameters of which can be interpreted. Flotation process is also a very complex one, the overall result of which depends on the partial results of many micro processes and parameters. The particle interaction which very often takes place in the flotation systems makes the phenomenon even more complex. The flotation kinetic model with particle interaction was already introduced by author in 1994 and further developed in 2000. In this paper based on the experimental results obtained with metallic particles in case of recycling flotation the applicability of the Tóth-equation as an alternative flotation kinetic model for the systems with particle interaction is proved. The applicability of Tóth-model in mineral processing demonstrates again its universal character and the great talent of the late József Tóth, great Hungarian chemist. Keywords : Toth isotherm, biosorption, Langmuir, Freundlich

Sep 1, 2012

By Troy Boisjoli

Since its discovery in February 2014, the Arrow Uranium Deposit has undergone rapid development through aggressive and systematic drilling programs and is now being progressed through advanced engineering and permitting. Based on the 2018 NI 43-101 Technical Report, the Probable Mineral Reserve estimate totals 234.1 million (“M”) pounds (“lbs”) triuranium octoxide (“U3O8”), contained in 3.43 M tonnes at an average grade of 3.09% U3O8. The proposed processing plant at the Rook I Project (the “Project”) will be capable of producing up to 31 M lbs of U3O8 per year, with a projected mine life of nine years based on the Probable Mineral Reserve estimate, although NexGen is permitting a 24-year operating life at the Project assuming the majority of Inferred Mineral Resources are upgraded to Indicated Mineral Resources with continued mineral resource development drilling. The Project will be developed through transverse and longitudinal longhole mining methods, pairing primary and secondary stoping techniques with a high degree of equipment mechanization which will provide a combination of good productivity, high extraction, and stable back support. This next generation of uranium operations combines the use of advanced tele-remote equipment and instrumentation with a low-cost bulk mining method and a best-in-class tailings management practice, effectively reducing operating costs and setting a new standard for elite environmental and social practices.

Jan 1, 2020

By A. Valenzuela

During the last years, Chile has been the largest copper producer, either as concentrates or cathodes. Copper obtained via pyrometallurgy is produced by seven smelters, which have carried out modernization plans to increase smelting capacity or to achieve environmental regulations established in the Chilean legislation. Thus, the present work updates technological innovations in smelters, environmental regulations and presents solutions for S02 handling, particulate matter and arsenic. Also, the authors emphasize the important role of CODELCO Chile, the most important state-owned copper company, in developing technologies such as El Teniente Converter and El Teniente Slag Cleaning Furnace.

Jan 1, 2003

By Jacob A. Jordan, Rachel M. Garrett, W. Robert Thompson III, James C. Pegues

"Environmental control structures for an existing fossil-fuel power generating plant near Pascagoula, Mississippi faced several design and construction challenges due to space limitations. Conceptual design calculations indicated drilled shaft foundations would likely be needed to accommodate the higher lateral and compressive loads expected under some structures. A maximum drilled shaft diameter of 60-in was preferred due to various space constraints. Smaller diameter drilled shafts were deemed acceptable under structures with more moderate loading conditions. Furthermore, augercast piles were considered where lateral loading was not a governing design criterion.A series of SPT borings and CPT soundings revealed a subsurface profile consisting of soft to firm clays to depths of about 25 feet, underlain by fine to coarse sands. The apparent relative density of the sands was loose just below the clay, with increasing density noted with an increase in depth.Analysis of conventional drilled shafts indicated needed capacities could not be achieved unless shaft lengths exceeded 100 feet. Post-grouted drilled shafts were therefore evaluated to decrease shaft lengths by taking advantage of increased base capacity. Analyses showed the higher predicted capacities needed for some structures could be achieved with this approach. Final design for the project incorporated 90-ft long, 60-in diameter post-grouted drilled shafts; 60-ft long, 48-in diameter post-grouted drilled shafts; and 60-ft long, 48-in diameter conventional shafts. Both post-grouted and conventional trial shafts were installed as part of the detailed design phase of the project. Each trial shaft included CSL integrity testing and Osterberg-cell bi-directional load testing. Load test results revealed that additional base capacity was, in fact, achieved through the post grouting process. The 60-in diameter post-grouted production shafts and the 48-in diameter conventional production shafts have been installed at the site, with the project that would utilize the 48-in diameter post-grouted shafts deferred at this time."

Jan 1, 2015

By S. Castro, L. Gutierrez

"Mining operations are often located in remote arid environments with limited access to fresh water. Shortage of fresh water in such cases makes it necessary to use seawater in mineral processing plants. Such plants treating Cu- Mo sulfide ores in seawater have been fully operational in Chile (e.g. Las Luces, Centinela). In many cases process waters used in commercial flotation plants (e.g. Mt Keith in Western Australia) are even more concentrated electrolyte solutions than seawater. This paper is an attempt at classification of the flotation operations carried out in process waters that are concentrated electrolyte solutions.INTRODUCTIONAccording to Gleick (1966), of the total Earth’ water resources 97.5% is in the oceans and ice caps, and thus only about 2.5% is fresh water. Shortage of fresh water in many parts of the world makes it necessary to use seawater in mineral processing operations. The existing commercial operations using seawater as well as recent research projects that deal not only with sulfide ores but also with apatite ores provide a lot of information that can now be generalized. The progress that has been made in this area is reviewed and based on this information an attempt is being made at classifying the flotation operations carried out in highly concentrated electrolyte process waters.SALT FLOTATIONFlotation in highly concentrated electrolyte solutions was studied by Klassen (Klassen, 1963). He reported that hydrophobic, bituminous coals, could float in salt solutions without addition of any other flotation agents. The process is referred to as salt flotation. Other inherently hyhrophobic minerals (e.g. talc, graphite, sulfur, etc.) were shown to behave similarly (Klassen and Mokrousov, 1963)As Figure 1 shows, some coals float quite well in solutions of Na2SO4, NaCl and NaNO3 (Klassen, 1963). While there are differences between the tested salts (explained by different foamabilities of these solutions) all the tests indicate that only bituminous coals float well in concentrated electrolyte solutions. 0.3 M solutions are quite sufficient to initiate a good and very fast flotation. If wettability of various coals is compared it becomes obvious that these well floating coals are very hydrophobic bituminous coals (Figure 2)."

Jan 1, 2018

By R. M. Von Storch

Most coal mining areas of the Western United States are characterized either by thick beds, steep pitches or heavy cover. Individually, each of these may present inherent safety hazards that influence miring. When all are met at one location, the combined effect is to make the safe operation of the mining property a challenge to management. These combined, conditions are met in most coal mines in southeastern Utah including those of the United States Steel Corporation. This coal bed measures up to 16 feet in thickness, the pitch is as much as 25% and mining is under a cover approaching 2, 000 feet. The Sunnyside coal bed is found in the Book Cliff Mountains, a great escarpment extending from west of Castle Gate, Utah, some 180 miles to Grand Junction, Colorado. West of Green River, Utah, the Book Cliffs swing sharply to the north because of the domelike uplift of the San Rafael Swell to the southwest..It is in this northerly extension of the Book Cliffs that the Sunnyside coal in the Blackhawk Formation of the Mesa Verde Group, Upper Cretaceous Age is found. The strata are transected by numerous faults with from a few inches to as much as a hundred feet of displacement. All of these faults have had some effect on the mining operation, either in roof control or, in the case of major faulting, the pattern of mine development.

Jan 1, 1967

By P B. Hills, R J. Walton

Geotechnical instrumentation has been implemented as a key step for monitoring and optimising an engineered mine design for managing seismicity at the Beaconsfield Gold Mine. Measurements of displacement, stress change, ground control element load and seismic response of the rock mass allow for back analysis and calibration of critical parameters for feedback into the engineering design loop. Instrument clusters are installed in strategic locations prior to the commencement of stoping in order to determine the nature of the response of the rock mass to stoping. A selection of instruments including instrumented cable bolts and rod extensometers, resistance wire extensometers, hollow inclusion stress cells, vibrating wire stress meters and resistance wire extensometers are used to gather data through a data logging system. The rate at which data is recorded is adjusted to provide more information during periods of anticipated rapid change such as around stope firings or during periods of high seismic activity, and less information during periods of anticipated quiescence. The twofold purpose of the instrumentation is to calibrate the numerical modelling output which forms the basis of the engineered mine design, and to provide an alert mechanism where the behaviour of the rock mass is not what was anticipated, or where the impact of that behaviour may compromise the integrity of the engineered ground control system. The paper describes the location of instrument clusters with respect to stoping, the type of instruments employed and the method of data acquisition. It provides examples of results obtained and illustrates the way in which that information is used to optimise the mine design and manage seismicity.

Jan 1, 2008

Miners and mineral explorers are concerned at the increasingly hostile environment being generated towards their industry and their profession. There is little official or public recognition that the mining industry is essential for the maintenance of the country's standard of living; a large part of this hostile feeling is caused by the assumption that mining destroys large tracts of our attractive countryside. This paper presents a historic review of the impact on the countryside of the major land using groups commencing with the Polynesian migration. European farming practices, subsequent expansion of the urban dweller and the land management practices of the two Government Departments, Lands and Survey and New Zealand Forest Service who between them control half of the total land area, are discussed. Estimates of total land area to date, directly and indirectly affected by mining have been calculated and a broad estimate of 18 000 ha or 1/1500 of total land area is indicated; current annual mineral production requires some 240 ha. These gross areas take no account of subsequent land rehabilitation, its improvement upon the original in some cases and the recreational, historic and aesthetic areas gained. Comparisons are then drawn with some current land practices in New Zealand.

Jan 1, 1977

By G. G. Richards, D. J. Rioux, R. L. Stephens

Teck Cominco Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. The year 2007 marks ten years of operation of KIVCETTM flash smelting technology for the treatment of zinc plant residues and lead concentrates. Since start-up in 1997, the furnace throughput has been increased to exceed its design rate and other metallurgical performance targets while continuing to meet its environmental objectives. This was achieved through resolution of key mechanical issues, improved understanding to stabilize the reaction shaft operation and control furnace accretions, significantly reduced boiler corrosion by molten chloride salts through the extensive application of weld overlay, a suite of projects to improve furnace integrity, and some debottlenecking of the surrounding unit operations in the lead smelter. The combination of increased feed rate and improved on-line time allowed the KIVCETTM furnace to set a new quarterly feed throughput record of 129,300 tonnes in the first quarter of 2008.

Jan 1, 2008

By B. T. Darnton

Gravity concentration at the Pegasus Gold Montana Tunnels Mine was initiated in late June, 1991 with the commissioning of a coarse gold scalping circuit that processes a small portion of the ball mill circulating load. The primary objective for the circuit was to reduce the risk of gold particles advancing to flotation that are too coarse to float. The secondary objective was to enhance overall gold recovery and payable gold ounces in a cost effective manner. The gravity circuit has proven itself to be a major success. The above mentioned goals have been achieved, and they have been maintained at record throughput rates that are 30% higher than when the circuit was commissioned. A number of modifications and improvements were made over the last three years which allowed the gravity circuit to keep pace with the higher tonnage, these are discussed in detail in the body of this paper. The overall approach to gravity concentration at Montana Tunnels has always been to optimize production rather than maximize the gold ounces produced. This philosophy has now yielded a circuit expansion and relocation project which will allow for an estimated 50% increase in gravity gold production, while reducing the overall unit costs of production significantly. This paper will review historical gravity circuit performance, improvements, and the current relocation and expansion project.

Jan 1, 1995

By Mark Rebagliati, John Payne, Jim Oliver

The Campo Morado precious-metal-bearing, volcanogenic massive sul?de deposits occurin a lower Cretaceous, bimodal, calc-alkaline volcanic sequence in a major northerly trending belt inthe Guerrero Terrane in northeastern Guerrero, Mexico. During upper Cretaceous to Early Tertiary greenschist-facies regional metamorphism, the rocks were deformed strongly into a northeast-verging fold-and-thrust belt. Three later stages of weak deformation were dominated, respectively, by kink folds, broad warps, and extensional faults. Most deposits occur in the upper part of a sequence of felsic ?ows and heterolithic volcanoclastic rocks or at its contact with overlying chert and argillite-sand-stone. The Reforma and El Rey massive sul?de deposits are on the overturned limb of a major, thrusted anticline, and the Naranjo and El Largo massive sul?de deposits are to the south on the upright limb of the same major fold. The La Lucha and San Rafael massive sul?de occurrences are in an upper plate to the southwest which was thrusted over the plate containing the Naranjo and El Largo deposits. In several of the deposits, Au, Ag, Zn, and Pb are concentrated near the stratigraphic top, andCu is concentrated near the stratigraphic base. Major minerals are pyrite, quartz, ankerite, sphalerite,chalcopyrite, and galena. Minor minerals are tennantite-freibergite, arsenopyrite, and pyrrhotite. Goldand Ag occur in argentian gold, and Ag also occurs in tennantite-freibergite. The cumulative inferred resource of massive sul?de for the Reforma, Naranjo, El Rey, and El Largo deposits exceeds 30 Mt, with the latter two deposits incompletely delineated. Underlying pyrite-quartz stockwork zones contain chalcopyrite, chlorite, and sphalerite. Hydrothermal alteration minerals in the stratigraphic foot-wall are pyrite, quartz, chlorite, ferroan dolomite, and ankerite. In the stratigraphic hangingwall, hydrothermal alteration minerals are sericite, calcite-dolomite, and lesser clay minerals and quartz. The deposits belong to a low-sul?dation, volcanogenic massive sul?de system formed in a subaqueous environment, and are of the bimodal, siliciclastic type.

Jan 1, 1997

By L. R. Mabson, F. M. Russell

INRODUCTION Roan Consolidated Mines Limited (RCM) operates five underground mines - Mufulira, Luanshya, Baluba, Chambeshi and Chibuluma (figure 1) . Associated metallurgical plants provide for the operations of milling, smelting two refineries for copper and a cobalt plant. Primarily a producer of high quality copper (242,000 tonnes during 1980) the Company is also the world's second largest producer of cobalt metal. RCM's remaining ore reserves at 31st March 1980 were 275 million tonnes at 2.84% copper. Monthly ore production is in excess of 1.2 million tonnes. Sublevel open stoping was the choice of mining method for the first underground operations on the Copperbelt for ore with dips steeper than 30 degrees. This was for use at the Roan Antelope mine, subsequently to be called Luanshya mine. The sublevel open stoping system was planned based on the methods used in many of the iron mines of Michigan and New York and in the copper mines of Tennessee. Peterson (Ref. 1) gave the following reasons for employing sublevel stoping, reasons which are still valid today: (1) the working place could always be barred and made safe, and the sublevel exit was always at hand; (2) the working conditions were similar day by day and drilling operations were repetitive; (3) pillar spacing can be varied as conditions demand; and (4) stoping operations could be shut down completely or opened up to full capacity at short notice, without affecting grade or causing wastage of reserves. Such was the success of the method that it was adopted as the basic mining method at all the RCM mines in their initial stages. Although cut and fill, block caving, and sub- level caving methods have been used, sublevel open stoping in its many variants still accounts for nearly 90% of total ore production in the Company. The following descriptions outline some of the applications of sublevel open stoping within RCM. LUANSHYA Geology There are two main ore deposits at Luanshya: the Roan (Luanshya Mining Area), in which mining began in 1930, and Baluba, in which mining production started in 1973 (figure 2). Both orebodies occur in synclinal and variably folded basins. These basins are underlain and completely surrounded by much older schists and granites. The ore formation, an argillite, lies near the base of the sediments and is underlain by conglomerates, quartzites and arkoses. Copper mineralisation is mainly found in two well defined zones, separated by a varying thickness of pyrite mineralisation. In the eastern part of the Roan deposit only the upper orebody is present, but west of 18 shaft and at Baluba the lower orebody predominates. Locally the subjacent quartzites of the footwall formation are also mineralised with copper. The copper mineralisation is found princi- pally as disseminated sulphides, mainly chalcocite, bornite and chalcopyrite. Near the surface the sulphides have been changed to oxides. At Baluba the cobalt mineral carrollite is found with the sulphides. Mining methods Sublevel open stoping is the basic mining method. In its standard form this method is best suited to steeply inclined orebodies, with simple structures and with a strong foot- wall and hangingwall. In recent years, as more complex folding and flatter dipping orebodies have been encountered, considerable variations have been introduced. Stope drilling is effected with drifters and extension steel.

Jan 1, 1981

By J. D. McLenegan

The purpose of this investigation was to prepare a market survey of the refractories industry in California and Nevada (referred to in subsequent paragraphs as the region), and to determine the degree of self-sufficiency and the potential capacity for anticipated growth. The report includes estimates of the total annual refractories consumption, the quantity of refractories imported into the region, the tonnage of raw materials required for their manufacture, and the resources of fire clay and high-alumina minerals in the region.

Jan 1, 1956

By Earl Cook

A high-energy economy based on fossil fuels is in fundamental conflict with an ideal of clean air, clean water, undisturbed scenery, and maintenance of fragile ecosystems. There is an inevitable trade-off between the material standard of living of a modern society and the conservation of its environment. During the past four years, some of the costs of environmental protection have been internalized in the energy-flow system of the United States. The cost of bituminous coal and fuel oil usable under new air-quality standards has doubled or more. The cost of mining coal underground has risen because of a 20-30 percent reduction in productivity resulting from new environmental health and safety legislation; the economic impact of proposed surface-mine regulation may be equally severe. The cost of producing electric power has been rising at a 12 percent annual rate because of environmental costs, and would be climbing still more steeply were it not for the continued forced subsidy of natural-gas consumers by natural-gas producers. The efficiency of the automobile, already a monument to the triumph of self- indulgence over economy, is being further decreased by addition of anti-pollution devices. Part of the recent sharp rise in agricultural costs stems from the fact that five energy units of fossil fuel go into U.S. agriculture for every energy unit of raw food that leaves the farm; further large injections of fossil-fuel energy occur in the transport, processing, and refrigeration of farm products.

Jan 1, 1974

By M. G. Zabetakis

This publication describes an investigation conducted by the Federal Bureau of Mines regarding the cause of an explosion of a dephlegmator or fractionating column at the Cities Service Oil Company Refinery, Ponca City, Okla., January 22, 1959. The column was that used with the refinery's No.1 Dubbs Coker. The explosion caused the death of an employee of the refinery and resulted in extensive damage to the refinery and to nearby property. The Bureau's study of the explosion began January 26.

Jan 1, 1960

By David M. Spatz

Ore deposit models are defined largely by physical geologic features that relate conveniently to remote sensing. New Landsat, SPOT, RADARSAT and other multispectral and hyperspectral sensors with improved spatial resolution are currently in development. Near-infrared and thermal airborne hyperspectral scanners hold outstanding promise for both mineral exploration and feasibility stage mapping at potential new mining projects. These scanners are capable of identifying silicification, differentiating silicate alteration types, and mapping compositional variations within igneous and metamorphic complexes. Research in 'mineral and rock spectrometry is helping to advance applications of remote sensing. Hyperspectral scanners are capable of differentiating compositional variations within individual mineral species. Innovative data processing techniques continue to enhance computer software applications and facilitate imagery analysis by the geologist. Today, . remote sensing imagery is commonly integrated with multiple data sets in GIS format to form the core data base for regional exploration programs.

Jan 1, 1995

By M Grigorescu, J H. Hodgkinson

The expansive, open cut iron-ore mines in Western Australia typically experience few days of rain per annum, often amounting to less than 250 mm. Unlike mines where rainfall is frequent, they may be less prepared for extreme rainfall events. Such events can cause erosion, flooding and sedimentation, drainage alteration, spoil and stock heaps wetting and effect slope stability. Such impacts may threaten personnel safety, infrastructure, and production. The CRATER (‘Climate Related Adaptation from Terrain Evaluation Results’) framework collates and interprets a mine’s pre-existing data and semi-quantitative information to assess vulnerability to, and ultimately plan to avoid or minimise, flood-related hazard to infrastructure, people, downtime, environment and revenue. Outputs assist decision makers to design investment strategies for minimising mining operations’ vulnerability to climate. Previously developed for smaller, wetter mines in Queensland’s coal region, the outputs provide a hot-spot map, fault tree analysis and an assessment of the mine’s capacity to adapt. The multicriteria evaluation (MCE) within a geographic information system (GIS), equally suits iron-ore mines’ siteconditions (elevation, slope, drainage, soil and vegetation) to identify critical inundation areas. Hotspot results provide target zones for in-depth fault-tree analysis that, in turn, present a range of sitespecific adaptation options. Rainfall-intensity and the number of rain days since the 1970s have increased over central and eastern parts of the Pilbara Region. While tropical cyclones may become less frequent, they are projected to increase in intensity. Although some parts of the Hamersley Ranges receive more than 500 mm per annum, rainfall in the Pilbara is generally very low. Therefore, experience of the impacts of extreme rainfall events in the constantly changing topography of Western Australia’s iron ore region may be sparse. Minimising potential effects can be proactively assisted using CRATER.

Nov 8, 2021

By S. M. Hsiung

This paper presents the results of an extensive study concerning a series of roof falls in a room-and-pillar coal mine located in West Virginia. Three dimensional finite element modeling was employed to identify the possible causes for the roof falls. The effectiveness of possible roof control measures for alleviating or eliminating the adverse roof conditions is analyzed, discussed, and compared. The best mining alternatives are recommended. It has been found that large overburden depth and typical roof geology are the major reasons for the roof falls. Angle bolting may not solve the problem encountered in the mine studied. Changing the mine layout currently used in the mine appears to be the best alternative. The recommended pillar size and entry width which will eliminate the problem completely are 90 ft. x 90 ft. and 14 it., respectively.

Jan 1, 1985

By Akira Yazawa

In the field of pyrometallurgy, the equilibrium evaluation has recently become easy by use of thermodynamic software, but it is strongly desired to estimate the amounts of non-equilibrium minor components to simulate practical processes. However, simple physico-chemical technique can not be applied to evaluate practical non-equilibrium components for many reasons. As an engineering solution for postulated equilibrium system, the activity coefficient is modified and introduced as the simulation parameter referred to as the "adjustment coefficient." This modified thermodynamic calculations were adopted to various sulfide roasting processes where many solid phases are participating and the system is not necessarily in equilibrium. Successful simulation was realized by assigning suitable adjustment coefficients for minor components which form a pseudo solid solution in the calcine. Some examples from sulfation roasting and dearsenizing roasting were discussed. In the smelting system, the loss of copper in slag is caused by equilibrium and non- equilibrium reasons, that is, chemical dissolution and entrainment of copper in slag. The total copper content of slag was simulated by use of the adjustment coefficient for entrained copper.

Jan 1, 1998

By G B. Smith

Barrick (Australia Pacific) Limited initiated a trial of Caterpillar’s Minegem autonomous loader technology in 2009 at the Kanowna Belle mine in Kalgoorlie. Autonomous loader technology offers the potential to improve loader productivity, reduce operating costs and improve safety through removing personnel from the mine operating environment. This paper discusses the implementation of the technology at the mine site, the data collected during the trial and quantifies the benefits of using automated loader technology in comparison with teleremote loader operation. The lessons learned from the trial and work planned for the future in respect of this technology is also discussed.

Mar 21, 2011