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By A. D. Davis

The Gilt Edge Superfund Site is a former heap-leach gold mine that currently is being remediated in the Black Hills of South Dakota. Mine runoff water is treated before release from the site. The field pH, before treatment, is about 3, and the water contains arsenic and some heavy metals, in addition to sulfate concentrations of about 1400 to 1500 mg/L. In the Keystone area of the Black Hills, naturally occurring arsenic has been detected in ground-water samples from wells. Keystone City Well #4, which is not used currently, showed arsenic concentrations of 36 parts per billion (ppb) and sulfate concentrations of about 19 mg/L. With field samples of water from these sites, a limestone-based method was successful in reducing arsenic and heavy metals concentrations. The results are significant because previous research with the limestone-based method mainly had involved samples prepared with distilled water in the laboratory, in which interference of other ions such as sulfate did not occur. The research indicates the potential for broader field applications of the limestone-based removal method.

Jan 1, 2011

By H. Takamoto, M. Ichinose

"The basic objectives of mine roadways are to provide sufficient cross sections in order to meet the needs of accommodation of equipment, transport, personnel travel and ventilation. However, many roadways become damaged to the extent of needing maintenance, generally dinting, and in some cases requiring re-ripping. The damaging of a roadway is a result of several factors including geological properties of surrounding strata, method of roadway formation, support systems and so on. Among these factors, strata conditions play important effects on the stability of roadways and other mining activities. Weak rocks cause excessive roadway closures, and water softens some rocks and worsens the closure problem. In Indonesia, over 250 Mt of coal is now produced from almost surface mines. In the near future, some coal must be mined from underground. Unfortunately, the mechanical properties of coal measures rocks are not so good to open underground mines. In this paper, a scientific discussion on the effect of water on the stability of roadways is given on the basis of results obtained by means of in-situ investigation and laboratory tests both in Japan and Indonesia."

Jan 1, 2011

By R. C. D. Phillis

Conventional stoping in hard rock mining is largely considered an operational environment. This paper suggests that stoping falls within the realm of a project management environment typified by uncertainty, variation, and large numbers of interdependencies. Stoping was then equated to a micro-project with many simultaneous activities that had to be executed accurately using finite resources within limited shift durations in order to reach specific goals. Critical chain project management (CCPM) principles were applied to the stoping activities, and the results showed that the number of blasts per panel can be significantly increased by successfully moving the distribution of work as close as possible to the start of shift. Critical chain principles also assisted in facilitating re-focusing and teamwork among stoping crews as well as between day- and night-shift crews. The main recorded success was in managing inherent protective capacities/local contingencies/fat/buffers that are found in all projects. The impact on mine health and safety (MHS) was significant as individual operators and crews became convinced that they could perform all stoping tasks (activities) without compromising accuracy or speed.

Jan 1, 2011

By Tapan Goswami, Stephen Jeric, Geoff Brent

Highwall failures in large deep open cut mines have very significant safety and commercial implications. There are many factors influencing the stability of highwalls. The major influence is the interaction of the local geology with the shape of the pit wall. This factor is in the realm of the geotechnical engineer and is beyond the control of the blasting engineer. However, a secondary influence is the blastinduced damage to the wall. In most open cut metal mines the blasting strategy to control this damage involves the use of separate production and trim blasts bounded by presplits at the final wall.

Jan 1, 2011

By T. R. Ellis

Many appraisers/valuers believe that the only valuation method available within the Cost Approach category for Real Property appraisal is the depreciated replacement cost method. Some valuation and financial reporting standards setters also believe the same. This paper introduces the minerals appraiser to a number of useful methods for mineral property appraisal that are based primarily on the principle of contribution to value, the predominant economic principle in the cost approach. Most of these cost approach methods discussed are primarily for use in valuation of exploration tracts and resource properties that have no defined reserves. However, the powerful rural cost method can be used to calculate the contribution of categories of resources, reserves, and other property components to the value of a mineral property. This method can be applied to mineral properties at all stages of development, including producing properties.

Jan 1, 2011

By Saeid Pournaderi, Ahmet Geveci, Ender Keskinkilic, Yavuz A. Topkaya

"This study investigated calcination behavior of one of the Turkish laterite deposits, which was recently found in Sivrihisar region. Representative limonitic laterite samples (1.26% Ni) taken from Yunusemre Karasivritepe and Kucuksivritepe location were first subjected to drying. Removal of chemically bound water and other volatiles were then studied, in detail. In the calcination experiments, temperature and time were the main experimental variables. Thermal treatment was conducted at the specific temperatures in 250 °C - 800 °C range. The weight losses due to elimination of chemically bound water and other volatiles were reported to be approximately 10 per cent of the weight of the ore. For the particle size used in the current work, 700 °C and 40 minutes were determined to be the optimum calcination temperature and time, respectively.IntroductionThe nickel ores that are economically valuable can be grouped into two categories: sulphide type nickel ores and oxide type nickel ores, namely laterites. Over all reserves in the world, 40% are sulphide nickel ores and the remaining 60% are laterites [1]. Pyrometallurgical nickel extraction from sulphide type nickel ores is conducted via matte smelting. More recently, laterite ore bodies have been subjected to nickel extraction. Depending mainly on the chemical composition of the laterite and the process economics, various extraction techniques have been implemented: pyrometallurgical route involves ferronickel smelting. High pressure acid leaching (HPAL) is the commercial method for hydrometallurgical nickel extraction, while ammonia leaching (CARON Process) is a combination of pyrometallurgical and hydrometallurgical processes [2]. With the improvements in these processes, it is predicted that laterite’s share in the world nickel production will rise to 50% in 2012, while it was reported to be 42% in 1,200,000 tons of annual production in 2003 [3]."

Jan 1, 2011

By Behdeen Oraee-Mirzamani

Since the advent of New Austrian Tunneling Method (NATM), shotcrete as a primary means of support in tunnels has been widely applied. It?s most important features are durability, speed of application and cost effectiveness. This paper introduces some tables that provide guidelines for the thickness of shotcrete required in some common situations of mine roadways. In order to devise such tables, two different arch sections, together with three different overburden types, were considered. Geotechnical parameters such as apparent cohesion and angle of internal friction of surrounding rocks were chosen, based on the five-category classification of Bieniawski. Two K0 factors (the ratio of horizontal stress to vertical stress) and an average rock density were utilized. Using numerical methods, 60 models were then devised in this way. By applying interaction diagrams of axial force and the bending moment for different thicknesses of shotcrete, appropriate shotcrete thickness for these models were calculated. The results of this research, as well as the methodology applied, can be used in mining roadway support design and all types of civil engineering tunnels.

Jan 1, 2011

By L. Becze, S. J. Hock, G. P. Demopoulos

"Regeneration of HCl from chloride solutions is commercially practiced by high temperature (800-900 °C) pyrohydrolysis associated with high energy consumption and capital cost. As an alternative to pyrohydrolysis a novel low temperature ( <200 °C) non-autoclave hydrolytic process has been studied in this research work, which comprises two steps. In the first step, ferrous chloride is oxidized by oxygen at 1;150 °C, followed by hydrolytic decomposition of ferric chloride to coarse hematite particles and superazeotropic hydrochloric acid (8-9M) operated at approximately 180 °C. This paper provides a summary of the laboratory results related to both oxidation and hydrolysis and presents a newly designed conceptual process flowsheet.IntroductionRecovery of base, noble and rare metals from ores and secondary materials (slags, dusts, residues) by chloride-based hydrometallurgical processes holds a lot of promise if a low cost HCl process becomes available. This is particularly so due to the high activity of HCl or more accurately activity of hydrogen ion [1] in concentrated chloride media and the formation of chlorocomplexes allowing for effective leaching under atmospheric leaching conditions and simultaneous ease of metal separation. However, during leaching significant amount of iron, which is associated with most of ores and secondary materials, goes into the solution. Hence, the obtained leach solution has to be treated to convert iron chlorides into easily filterable iron oxide and simultaneously produce concentrated hydrochloric acid. Apparently the critical operation of these processes is the regeneration of the lixiviant (HCl). Currently in the industry, its regeneration is accomplished by high capital and intensive pyrohydrolysis which operates at 700- 900 °C. Aimed at lowering the operational cost of pyrohydrolysis a process called PORI [2] was developed and tested in pilot plant scale in the 1970s for the purpose of treatment of pickle liquors without, however, resulting in industrial application."

Jan 1, 2011

By Peter Zhang

As simpler and easier reserves are exploited to depletion, underground coal mining continues in more complex geologic settings and conditions. Roof bolting for long-term entry stability is always a challenge. For long-term entries of a mine such as belt, track entries and return airways, roof could be under-supported if one uses the same bolting plan as in short-term entries or even seem over-supported with increasing use of longer, stronger bolts along with mesh, pans, straps or trusses. In most underground coal mines, roof deteriorates over time with cutters developing deeper in entry corners; roof sagging and popping out between bolts; entry width increasing due to rib sloughage; and separations developing deeper up into the roof. In deteriorated long-term entries, roof falls could occur at certain locations and re-bolting could be costly or sometimes unfeasible. Therefore, it is important to choose an appropriate bolting plan during development based on mining and geologic conditions if the entries will be used for the long-term. In both short-term and long-term entries, primary roof bolting is critical in building a strong and effective beam. But in long-term entries, supplementary bolting is necessary in certain cases to ensure roof stability can still be maintained even if a roof failure develops beyond the primary bolted horizon. This paper deals with roof bolting for long-term entries based on studying the progressive roof failure and roof falls under different geologic conditions. The paper presents bolting considerations in terms of bolt type, length, diameter and spacing as well as bolting strategy to minimize the risk of roof falls in long-term entries.

Jan 1, 2011

By D. T. Hristopulos, A. Pavlides, C. Roumpos

In many of the lignite mines in Greece that supply the nearby power plants, the lignite deposits are multilayered and faults destroy the spatial continuity. This fact complicates lignite exploitation and the profitability evaluation of each layer. The location of a lignite layer could be so deep compared to other layers, that its exploitation would not be profitable. The purpose of this paper is the development of a suitable profitability index to help with the evaluation of the profitability of separate lignite layers. The definition of the profitability index is given and an algorithm is formulated that calculates the profitability index and evaluates whether each layer should be mined by comparison with a critical threshold value. The profitability index algorithm is applied to the multilayered lignite deposit of Amyndeo mine. It should be noted that the proposed index could be used in any kind of multilayered deposit, not just lignite.

Jan 1, 2011

The only significant iron ore deposit in Hungary could be found in Rudabánya. The mine was closed in 1986. The area of Rudabánya was always the home of heavy mining activity. In former times, mainly silver and other non -ferrous metals were excavated.

Jan 1, 2011

By S-J. Park

When evaluating mining investment opportunities, one should consider the risks associated with mineral exploration and development. These are commonly classified as technical, economic, and political risks, and are accounted for in the investment decision by changing the discount rate. Thus, a company may use different discount rates associated with varying risks in order to compensate for the variability of success. The discount rate has a tremendous effect on the economic evaluation of mineral projects. Even when all other factors used as inputs for calculating the NPV (net present value) are equal, the project under consideration may be accepted or rejected depending upon the discount rate. Determining a realistic discount rate for a given project is therefore the most difficult and important aspect of cash flow analysis. It should be determined with the consideration of proper technical, economic, and political conditions surrounding the specific project undergoing economic evaluation. One key problem for determining the appropriate discount rate is that it typically depends more on subjective perception of the degree of risk or other experience factors than on a systematic approach. Thus, this study aims to identify, analyse, and document the type, role, and impact of risk factors influencing the determination of discount rates, and then to determine discount rate by using the aforementioned factors.

Jan 1, 2011

By Timothy C. Siegel

A piled raft refers to a shallow foundation that is structurally connected to the piles, while composite ground refers to a soil-pile matrix where the piles are not structurally connected. The design objectives for both a piled raft and composite ground are (excluding special considerations such as expansive soil): (1) to provide a sufficient ultimate resistance and (2) to distribute the load into the soil-pile matrix so that the settlement experienced by the shallow foundation is within tolerable limits. A simplified model is proposed for a shallow foundation on composite ground where the foundation settlement is estimated as the sum of the downward movement of the piles plus the downward movement of the shallow foundation relative to the pile head. The proposed simplified model is applied using conventional geotechnical analyses for two hypothetical examples of shallow foundations undergoing compression settlement.

Jan 1, 2011

By B. Wasmund, K. Adham, K. O'Keefe, C. Lee

"Metal chlorides (e.g. iron and nickel) can be pyrohydrolysed at elevated temperatures to yield an HCl rich off-gas and a metal oxide product. Typically, the high energy requirement for pyrohydrolysis is provided by the combustion of a hydrocarbon fuel with air. Here, it is demonstrated that the use of oxygen-enriched combustion can result in lower fuel requirements and higher HCl concentrations. In addition, the oxygen enrichment can result in a smaller volume of off-gas and thus, smaller and less expensive process equipment. This new concept can be applied to both the spray roaster (SR) and the fluidized bed reactor (FBR). Similar to the aircombustion case, the oxygen-enriched process can use a direct contact venturi scrubber, to recover energy from the roaster off gas, but at a higher efficiency. The new process also uses an absorption tower for capturing HCl from the roaster off-gas, but generates a stronger HCl solution than is possible with pyrohydrolysis in air.BackgroundIn recent years, the metallurgical industry has become increasingly involved with developing methods for extracting metals, upgrading products or cleaning metallic products by using hydrochloric acid. These applications of chloride metallurgy often result in metal chloride solutions, which should be processed to regenerate HCl for reuse, and to recover the metal value as a product or by-product oxide [2, 3, 4].The pyrohydrolysis of metal chloride solutions has been done in two types of air roasters: spray and fluidized bed. The existing roasters burn a hydrocarbon fuel in air, to provide the required energy for evaporating the feed solution and to provide an elevated temperature for the chloride pyrohydrolysis to occur, according to the following reactions:"

Jan 1, 2011

By Isabela Leao Amaral da Silva, Felipe Perisse Duarte Lopes, Alice Barreto Bevitori, Sergio Neves Monteiro, Ruben Sanchez Rodriguez

"The fibers extracted from the stem of the ramie plant are among the strongest natural lignocellulosic fibers with a potential to be used as reinforcement of polymer matrix composites. Characterization of the ramie fiber has recently been conducted for its physical and mechanical properties. However, the effect of increasing temperature on the ramie fiber behavior has not yet been fully investigated. Therefore, the objective of this work was to perform a thermal analysis on ramie fibers with different diameters within the naturally found range of practical interest. The analysis was conducted by thermo-gravimetric, TGA and DTG, as well as differential scanning calorimetric, DSC, techniques. It was found that the ramie fibers present thermal stability up to 200°C and then suffer a sharp deterioration between 300 and 500°C, resulting in characteristic peaks.IntroductionSince the middle of last century, polymer composites have substituted many conventional monolithic materials in applications ranging from aerospace to sport [l]. The main advantages of these composites are the low density and flexible properties specially using fiber as reinforcement to suit the mechanical performance requirements [2]. These are usually high strength and stiffness requirements that could be reached with synthetic fibers such as glass, carbon and aramid fibers. In recent years, however, the use of synthetic fibers is being questioned in terms of problems caused to the environment. In fact, as non degradable material, synthetic fibers are associated with long term pollution when discarded. Moreover, the expended energy for fabrication and processing can be related to relatively large amounts of C02 emissions and represents a contribution to global warming [3]. Glass fiber, in addition, is toxic and cannot be incinerated as a waste in thermal power plants [ 4]. Possible substitutes for glass fiber are the natural fibers. Many natural fibers are today being considered as viable alternatives to replace glass fiber as reinforcement of polymer composites. In particular, some natural lignocellulosic fiber extracted from plants present a real potential for this replacement [2-8]. Their comparative advantages are lower density and reduced cost as well as renewability, biodegradability, recyclability and neutrality with respect to C02 emission [3]."

Jan 1, 2011

By N. Z. Fotoyi

Keywords: MgO-MgR2O3 refractory, SO2-containing gases, chemical attack The reaction mechanisms occurring when MgO-MgR2O3 refractories are exposed to SO2-containing gas atmospheres were examined. The study examined the characteristic structures of magnesite-chrome, chrome-magnesite and magnesite refractories exposed to SO2-O2 gas mixture at temperatures of 700°C to 1350°C. The phase characterization was conducted with scanning electron microscopy (SEM) and powder X-ray diffractometry (XRD). The results show that the physical characteristics of the refractory matrix along the grain boundaries are important refractory features during chemical attack from SO2-containing gas. Upon heating in SO2-containing gas, the changes in phase-chemical compositions and accompanying grain growth causes loosening of the structure and the pore volume promotes gas diffusion. The chemical reactions that occur form stable sulfate compounds identified as MgSO4, CaSO4 and CaMg3(SO4)4, and lead to disintegration of various phase structures and consequently erosion of the refractory. In conclusion, the reaction mechanisms in MgO-MgR2O3 refractories exposed to SO2-containing gases progress through a combination of structural disintegration and chemical attack.

Jan 1, 2011

By A. Tikhonov, D. Kipper, V. Korovin, A. Olifirenko, Yu. Shestak

The present paper deals with vanadium and molybdenum sorption from industrial wastes and intermediate processing products using Cybber macroporous strong- and weak-base anionites. Vanadium and molybdenum recovery by Cybber anion-exchange resins as well as desorption processes were studied in static and dynamic modes; their efficiency was demonstrated for that purpose. The results of the work may be used to design technologies for complex processing of both ores and industrial wastes containing vanadium and molybdenum.

Jan 1, 2011

In a gravity separation device, particle shape, size and density all play a role. The combination of these determines where each individual particle reports to in the viscous fluid, where particle crowding (solids to water ratio) also plays a role. To understand the performance of gravity separation devices in the heavy mineral industry, these particle characteristics need to be measured. There are various challenges in analysing particle density and particle size simultaneously for the purpose of quantifying gravity separator performance, not to mention particle shape. These analytical challenges include the high cost of high-density sink-float fractionation, toxicity of high-density sink-float media, inability of sink-float media to fractionate at densities greater than 4.0 g/cm3, and the time-intensive nature of these fractionations. The use of the detailed particle-by-particle output from Qemscan® particle mineral analyses (PMA) as a fast and cost-effective alternative is evaluated. The size and density outputs from the Qemscan® were employed to characterize the performance of a heavy mineral spiral concentrator as an example. Critical analytical requirements are to be addressed before the Qemscan® output data can be utilized. Keywords Gravity separator, performance, heavy minerals, Qemscan® particle mineral analysis

Jan 1, 2011

By T. J. Goff

Keywords: accurate control, matte level, smelting operations, process control, tapping, sounding bar, electromagnetic measurement [ ] Accurate control of matte levels during primary matte smelting operations is desirable in order to improve process decision-making. High matte levels in the vessel could have to disastrous consequences, particularly in the new generation of intensive smelting furnace with deep-cooled copper coolers. Knowing when to commence tapping and a better understanding of melt times can only be improved if the furnace levels are monitored correctly. At Lonmin Marikana Smelter Division it has long been understood that the matte level information being provided by the manual sounding bar is only as good as the operators? following of measurement procedure, their skill in assessing what the sounding bar is displaying, and their individual interpretation of what they are looking at. This paper sets out to show how this problem was identified as an area of major concern to the plant, how a solution was sought and how an electromagnetic measurement system was installed as an alternative measurement to the matte sounding bar system. Other areas discussed in the paper are the difficulties to be overcome when first installing new equipment and how these teething problems were solved by close co-operation between Lonmin and equipment suppliers, which led to some design modifications to the delivery system. In conclusion the paper discusses the results between the electromagnetic measurement and the manual sounding measurement and how best to integrate the generated data into the plant?s process control system for improved decision making.

Jan 1, 2011

By Zong-Xian Zhang

In sublevel caving mines, serious eyebrow break usually gives rise to lower ore recovery, higher dilution, and worse safety for the people working in the field. For example, chargers must go near the caving region and stand under the damaged eyebrow where a hanging stone may suddenly fall down or rock fragments may quickly roll down.

Jan 1, 2011