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By Yuanyuan Zhang, Patrick J. Masset

"The reduction of FexO in slag is one of the fundamental reactions in iron and steelmaking technology, including the blast furnace process (BF). Experiments on the reduction reaction of iron oxide using CaO-SiO2-Al2O3-FexO-C mixtures were carried out using thermogravimetric analysis (TGA) under reducing conditions at temperatures up to 1100°C. The composition of the primary slag was chosen so that the FexO concentration varied between 0 and 75 wt % and the CaO/SiO2 ratio being kept constant to 0.90. From the TGA curves recorded isothermally at different temperatures the kinetic parameters of the iron oxide reduction were determined.IntroductionIn blast furnace the iron ores and coke are charged in layers from the top. The reduction of iron oxide by coke is one of the fundamental reactions in the blast furnace process. Although a great amount of work has been done on the topic of reduction of composites [1, 2, 3], gasification of carbon [4, 5] and reduction of iron oxides by CO [4, 5, 6], the mechanism of reduction in iron oxide - carbon powder mixtures is not fully understood. Fruehan [1] and Rao [2] studied the reaction rate of the reduction of iron oxide by different types of carbon and concluded that the reaction mechanism is controlled by the oxidation of carbon at temperatures up to 1200°C. Rao [2] studied the reaction of hematite with graphite as carbon source up to 1080°C. An activation energy close to 300 kJ/mol was calculated within the temperature range of 950°C to 1087°C. In his study, Fruehan [1] determined the rate of reduction of Fe2O3 and FeO by coal, coke and coconut charcoal as carbon sources within the 900°C to 1200°C temperature range. He found that the reduction of Fe2O3 by carbon occurs in two stages and that the reduction of Fe2O3 to FeO is faster than that of FeO to Fe. This is due to the fact that the CO2/CO equilibrium ratio is higher, and hence, the rate of oxidation of carbon is faster. Fortini and Fruehan [3] have studied the reduction reaction of wustite by graphite and wood charcoal. They found that the wustite reduction can have a significant effect on the overall rate of reduction in composites at high temperatures or in the presence of a large excess of carbon. The calculated activation energy of the reduction reaction by wood charcoal was close to 368 kJ/mol, while the activation energy of the reduction reaction by graphite was 444 kJ/mol."

Jan 1, 2011

By J. Kouam

Al-Si-Cu and Al-Si-Mg alloys are widely used in several applications. Although they can be produced near-net-shapes, products made of these alloys very often require some machining. The purpose of this study is to evaluate the machinability of A319 and A356 under TO and T6 conditions. The machinability was assessed using during dry drilling machining process and the machinability indexes used are the chip form, the chip breakability and the cutting forces. It is found that 319 and 356 exhibit different machinability behaviors, especially in the T6-condition in terms of forces requirements, chip breakability and chip segmentation. It is also found that both the microstructure of the workpiece materials and the machining conditions significantly affect the chip formation mechanism, and therefore, the machining parameters could be selected to promote a chip form that is easily manageable in production.

Jan 1, 2011

By P. J. Sylvester, S. J. Piercey, S. Maloney, S. M. Brueckner, L. Pilgrim, D. Hyde, G. Ogilvie

The 1806 zone is part of a Au-rich volcanogenic massive sulfide deposit at the Rambler Camp on the Baie \/erte Peninsula, northwestern Newfoundland, and is characterized by high Au grades (3.97 g/t), relatively low Cu and Zn grades (0.60 wt% Cu, 1.17 wt% Zn), and moderate Ag grades (27.83 g/t) at ca. 0.37 Mt ore. Gold and Ag occur as electrum and different Ag varieties including Ag-Hg ± Au alloys, miargyrite, and pyrargyrite that occur often in close proximity to electrum. Additionally, Ag-, As-, Sb-, and Sn-bearing sulfosalts are frequently observed and usually close to electrum. These textural relations strongly favor a syngenetic/magmatic origin for the 1806 zone, despite having a metamorphic overprint.

Jan 1, 2011

Existing geological structures such as faults or shear zones can greatly influence the interpretations of amplitude or energy attenuations of measured blasting vibrations along both affected and unaffected orientations. Mineralisation in conjunction with large faults or shears is commonplace in the geology of steeply dipping metalliferous deposits, such as those found in the goldfields of Western Australia. Better understanding of the influence of faults or shear zones on blast-induced seismic waves can lead to more effective blast vibration monitoring programs and interpretation of the results measured along affected orientations.

Jan 1, 2011

By Mark H. Balfe

Over the last decade, Fenway Park has undergone annual improvements to modernize the facility for players and fans. These renovations include the Monster Seats, the Right Field Roof expansion, a new pavilion behind home plate, expansion of the Red Sox clubhouse, additional roof seating, and concourse improvements. Retrofitting the historic ballpark to bring it up to current standards required installation of foundations to support the new structural loads for each of the alteration projects. This required evaluation of existing conditions, and in many cases augmentation of the foundations at existing columns to accommodate the structural changes to the park. New foundations, generally consisting of drilled-in micropiles, were installed in numerous configurations and conditions. Since 2003, a total of 215 drilled-in micropiles have been installed to augment various columns around the park. The micropiles range in capacity between 40 and 70 tons and are installed through Fill and Organic Soils and embedded into the dense Glaciofluvial Sand and Gravel layer. Issues and learning related to the foundation augmentation include schedule constraints (work is typically conducted during the off-season and schedule is very aggressive), encountering old/abandoned utilities or foundations, ventilation of equipment, and management of spoils during micropile installation.

Jan 1, 2011

By T. J. Cox

The Red River is located within the Sangre De Cristo Mountain Range in northern New Mexico. An approximate 12-mile segment of the river from the town of Red River to the village of Questa (Questa) includes several hydrothermal alteration zones. Alteration ?scars? formed as a result of rapid chemical weathering and physical erosion of pyrite-rich hydrothermally altered rocks. Storm water runoff from the scar drainages contributes metal-laden, acidic water to the river and creates a visible plume of discolored water in the river. Acidic runoff reduces the river pH from 7 to the mid 3s for at least 2 hours during large storms and the low pH water continues downstream. Runoff from scar drainages increases some metal concentrations in the river from below chronic ecological criteria to as much as two orders of magnitude greater than acute ecological criteria, and results in acutely toxic conditions for macro-invertebrates. A general improvement in the river?s water quality occurs downstream due to dilution from tributary inflow from non-mineralized watersheds, the natural buffering capacity of the river, and storm water controls at the Chevron Mining Inc. Questa mine.

Jan 1, 2011

By K. Hawboldt, J. E. Halfyard, C. Bottaro

The removal of sulfur from leach residues has been practised in the zinc industry using a combination of flotation and hot melt filtration. The process is highly dependent on the nature of the concentrate and the subsequent residue. When the mineral constituency of the residue alters, the process can encounter significant operational challenges. An alternate method of converting elemental sulfur to water-soluble polysulfides was applied to leach residue from Vale's nickel demonstration plant in Argentia, Newfoundland. Reaction parameters, sulfur purity and other key indicators are discussed as is the potential commercial application.

Jan 1, 2011

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011

By A. Mboma

Keywords: Furnace, decommissioning, care and maintenance, re-start, funding, nickel Bindura Nickel Corporation (BNC) operates two nickel mines, and treats concentrates from these mines as well as toll concentrates from the region around its Bindura Smelter and Refinery (BSR) complex. At the smelter, concentrates of at least 5% nickel content are blended and dried to 4% moisture in a coal-fired rotary kiln. Matte smelting of concentrate is carried out in a six-in-line electric arc furnace, where the furnace slag is granulated and discarded. Furnace matte is transferred via ladles into Peirce-Smith converters, where, after granulation, a leach alloy containing 68%Ni, 20%Cu, and 6%S is produced. Converter slag is recycled via the matte-smelting furnace. The onset of the global economic recession towards the end of 2008 resulted in a collapse of metal prices, worsening the local situation that was already marred by unfavourable macro-economic conditions in Zimbabwe. As a result, BNC mines were put on care and maintenance in November 2008, followed by Bindura Smelter and Refinery in February and March 2009 respectively. The business environment has since changed, and BNC is getting ready to re-start the plant. This paper describes the decommissioning of the Bindura furnace, asset preservation during the care and maintenance programme in the past two years, and preparation for starting up of the Bindura smelter in the near future.

Jan 1, 2011

By Ezzeddin Bakhtavar

There are several geotechnical challenges and risks inherent in the interaction between the open-pit and block cave mining environments. This is especially true when they have to work simultaneously for a short time, as well as when only the caving operation is continued. Some of these challenges and risks include the induced zones of stress due to the large and deep open-pit, instability of the slope, instability of the crown pillar and water inflows, subsidence, and sometimes instability of the main accesses to the block cave portion of the mine. These challenges usually occur due to cave propagation. In this paper, these geotechnical challenges and associated risks have been studied and discussed. It was concluded that the majority of the mentioned geotechnical risks could be decreased, and often eliminated, by considering the appropriate dimensions of a stable crown pillar, especially in simultaneously working open-pit and block caving operations.

Jan 1, 2011

By D. R. Wilburn

This summary of international mineral exploration activities for the year 2010 draws upon available information from industry sources, published literature and U.S. Geological Survey (USGS) specialists. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry and presents analyses of exploration activities performed by the mineral industry. Three sources of information are reported and analyzed in this annual review of international exploration for the year 2010: 1) budgetary statistics expressed in U.S. nominal dollars provided by Metals Economics Group (MEG) of Halifax, Nova Scotia; 2) regional and site-specific exploration activities that took place in 2010, as compiled by the USGS, and 3) regional events including economic, social and political conditions that affected exploration activities. These were derived from published sources and unpublished discussions with USGS and industry specialists.

Jan 1, 2011

? The U.S. depends on minerals for economic growth and development, and for national security and defense. ? Public lands are an important, long-term source of essential minerals. ? Access to public lands for mineral exploration and development has become more difficult as large tracts of land have been designated for other uses. ? Mineral-bearing areas on public lands are routinely withdrawn or restricted from development before comprehensive resource inventories and economic assessments have been made.

Jan 1, 2011

By R. J. Hundermark

Keywords: Anglo American, Anglo Platinum Ltd, Waterval, Mortimer, Polokwane, ACP, pyrometallurgy, platinum, PGMs Anglo Platinum Ltd is the largest primary platinum producer in the world and operates three smelters in South Africa: Waterval, Mortimer and Polokwane. The operational details of the smelters are covered in previous reviews, thus only unit operations that have been upgraded are discussed. The most significant of the upgrades include the installation of a second ACP converter at Waterval Smelter in 2006 and the anticipated upgrade of Mortimer Smelter to 38MW in 2011. Several advances have been made in the smelting operations to improve the furnace stability and longevity. Control of the chromium input to each of the smelters has substantially allowed continued operations at levels below the spinel saturation point in slag, which results in lowered matte and slag temperatures. Mogalakwena concentrate, arising from the Platreef ore, is used to dilute high chromium-containing concentrates. In addition, furnace controls have improved in terms of crucible temperature and condition monitoring, improved feeding control, management of alarms and trips and having the quality of instrumentation and operational rigour required to support this. Advances have been made on the ACP converter in terms of good converter matte quality, and increased intensity and efficiency of operation. Combined with improvements to both the conventional and tower sulfuric acid plants, the emissions from Waterval Smelter have been reduced substantially since the introduction of the ACP. This is in spite of increasing metal throughput. The Anglo Platinum Ltd smelting operations have made significant progress since 2006 and further advances are envisaged to further improve on safety, reduce costs, increase efficiencies and throughput, while reducing emissions.

Jan 1, 2011

By E. P. Wiechrnann, C. M. Castro, G. A. Vidal, F. A. Muñoz

Different authors and publications indicate that Optibar Segmented Intercell Bars cause a remarkable distortion in the distribution of the current in a cell group. However, these results were based in inaccurate computer based models and do not represent the technology. During the last trimester of 2010, a 92 cells circuit from Barrick Zaldívar EW plant was implemented with Optibar Segmented Intercell Bars. The technology was incorporated progressively without disrupting the plant production. Depending on operational conditions, this led to a 2 to 4% current efficiency increase and 3 to 5% specific energy consumption reduction. By October 2011, 40,000 tons of copper will be produced with the technology.

Jan 1, 2011

By N. Shi, T. G. Joseph

ABSTRACT: An interactive cable shovel simulation has been developed to mimic any shovel dipper geometry for a given cable shovel operating in any homogeneous face material. This interactive cable allows the user to predict shovel performance in any face material encountered and track both its ground stability and the dipper-ground interaction. An embedded Microsoft® Visual Basic spreadsheet was used as the platform for developing an interactive simulation that allows for maximum user-defined parameter input and interactive visual output. The result is an analytical dipper-ground interaction solution that yields crowd, hoist, and digging effort as a function of face activity position.

Jan 1, 2011

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Jan 1, 2011

By K. J. R. Ford, Botz. M. M.

Porphyry copper ores are frequently a source of low-grade gold ore, but gold in these ores is often associated with significant levels of cyanide-soluble copper. Cyanide leaching of such ores increases flowsheet complexity and operating costs, and requires thorough planning to satisfy environmental requirements for tailings disposal and mine closure. This paper presents a review of the chemistry of cyanide leaching of gold-copper porphyry ores, carbon adsorption phenomena and means of removing base metals from leach solution. The primary economic drivers behind the processing of such complex ores are also analyzed.

Jan 1, 2011

Filtration systems with disposable filter elements (DFEs) are used in the underground coal mining industry to control particulate matter emissions from diesel-powered permissible and nonpermissible coal mining equipment. This study was conducted in underground mine conditions to evaluate three types of high-temperature DFEs used in those filtration systems. The DFEs were evaluated for their effects on the concentrations and size distributions of diesel aerosols and concentrations of nitric oxide (NO) and nitrogen dioxide (NO2). Those effects were compared with the effects of a standard muffler. The experimental work was conducted directly in an underground environment using a unique diesel laboratory developed in an underground experimental mine. After an initial DFE degreening period, the filtration system with all three DFEs was found to be very effective at reducing total mass concentrations of aerosols in the mine air. The effectiveness of DFEs in filtering aerosol mass was found to be a function of the engine operating conditions. The efficiency of the new DFEs significantly increased with accumulation of operating time and buildup of diesel particulate matter in the porous structure of the filter elements. A single laundering process did not exhibit substantial effects on performance of the DFE elements. The effectiveness of DFEs in removing aerosols by number was strongly influenced by engine operating mode. The concentrations of nucleation mode aerosols in the mine air were found to be substantially higher for both DPFs and DFEs when the engine was operated at high-load modes than at low-load modes. Initial heating of certain DFEs resulted in visible white smoke and substantially elevated aerosol number concentrations. The effects of the DFEs on total nitrogen oxides (NOX) concentrations were found to be minor. The NO2 fraction was found to be generally lower for the DFEs than for the muffler. The engine-out NO2 fraction of the total NOX was found to be substantially higher for low-load modes than for high-load modes.

Jan 1, 2011

By Jinxia Nie, Yunnen Chen, Dachao Zhang

"Rare earth resources are strategic and non-renewable resources. But disordered exploitation on rare earth metals leads to resources waste, environmental pollution and ecosystem destroyed. In this paper, soil collected from garden was cultured in thermostated incubator. Adding exogenous rare earth to the soil and the effects of recombination action of rare earth lanthanum, cerium and yttrium on soil enzymatic activities were studied. The results showed that single metal La and Ce can increase urease activity, but Y inhibits its. Coexist La/Y or La/Ce in soil inhibit the urease activity, coexist Y /Ce or coexist three metals promote its. Single metal La, Y and Ce can promote catalase activity, and that of coexist three metals. Pairwise coexist La, Y, Ce in soil inhibit catalase activity. With certain concentration of rare earth recombination action, urease activity in soil has been very significant direct proportion to ionic impulse, but catalase activity been insignificant inverse proportion to its.1. IntroductionThe increase of rare earth element content due to anthropogenic inputs frequently takes place in agro-industrial areas, leading to soil pollution episodes that may cause serious environmental problems because of their potential toxicity to microorganisms, plants, animals and human beings [ 1]. China is abundant in lanthanides resources. Rare earth metals are used in many frontier technologies such as photic devices, magnetic materials, and fine ceramics, and the amount of the rare earth metals used in these industries has been increasing. In addition to their use in industry, rare earth metals are more widely applied to cropland as microelement fertilizers due to their ability to promote growth and productivity of some crops [2]. As a result, more and more rare earth metals are moving into the ecosystems. While a permanent contamination of soils results in populations of micro-organisms with high resistance to rare earth metals, a short-term burden of contaminants at high concentrations could exert inhibitory effects on microbial carbon [3]. They accumulate in soils, bioaccumulate in crops, and enter the food chain, causing a potential problem of rare earth metals environmental pollution in China [4]. This contamination may also severely influence organisms and soil activities [5]."

Jan 1, 2011

By Paul D. Tomlingson

The difficult and often harsh working environment of the mining industry can stress both personnel and equipment to the extreme. Often, the unintended consequences of this environment lead to confrontations between departments, as each goes about its tasks of mining, maintaining or supporting these activities. On occasion, the confrontations may result in criticism of other departments for perceived or real sins or omissions. The offended department may not be able to change the circumstances, but can only complain while frustration persists. The most effective solutions are the actions of the mine manager. By establishing mutually supporting roles of each department and specifying conditions for the interactive conduct of maintenance, the mine manager can better assure that the inherent problems of the mining environment are neutralized.

Jan 1, 2011