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By Timo Niitti, Antti Rinne, Janne Turunen, Klaus Schommarz, Sami Grönstrand

This paper captures the essential steps employed in developing Outotec?s new FloatForceTM mechanism. The development of a flotation mechanism essentially revolves around the efficient transfer of installed power, or capital cost, to optimum flotation performance. Optimum flotation performance will be achieved if a balance between metallurgical results, operating and capital costs is maintained. The development of the FloatForceTM mechanism was done by careful evaluation of each of these three areas. This paper focuses on how experience, CFD and laboratory equipment, pilot and plant tests are used to test and evaluate a new flotation mechanism. Validated variables include mixing profile, power draw and local air hold-up. Metallurgical and mechanical design considerations are not covered in this paper. Besides using the FloatForceTM mechanism in new flotation equipment, the FloatForceTM mechanism can be used in existing flotation cell installations, thus enabling improvements in the mixing profiles, solids suspension and metallurgical performance of operating flotation circuits. Results of several tests carried out in existing plant operations are presented.

Jan 1, 2007

By J. O. Marsden

Over the past decade, the copper industry has been through an extended downturn followed by several years of sustained high copper price. A number of new technologies have been developed over the past 10 years aimed at reducing costs by decreasing energy, labor, and materials requirements, or by increasing metal recovery. The energy intensity of different copper extraction routes and different technologies varies considerably and this has a significant impact on the economics of extraction. Based on average ore grade materials, the total energy for the extraction of copper typically varies from about 24-26 MJ/lb (6.7-7.2 kWh/lb) for the mining, crushing, milling, flotation, smelting and refining route to about 14¬16 MJ/lb (3.9-4.5 kWh/lb) for the mining, crushing, heap leaching, solution extraction and electrowinning route. New technology developments are providing opportunities for significant reductions in energy consumption for copper extraction, representing energy savings up to 20-25% in some cases. In addition, in many cases, these new technologies have introduced environmental, safety and health benefits over the incumbent technology. Some of these technology developments have been more successful than others, and many hold great promise for application in the coming decade. This paper provides an overview of the technology developments that have occurred, and explores the underlying reasons behind successful implementation.

Jan 1, 2007

By Aly M. Mohammad

Croton Point Avenue Bridge carries Croton Avenue over Metro-North main tracks at Harmon Rail Yard in Westchester County, New York. The new bridge is 1100 foot long and 36 foot wide nine span structure with three spans continuous units. The spans are steel multi-stringers, composite with concrete deck. The piers are solid wall piers and the foundations are spread footings. During the design of the bridge foundations it was determined that the relatively loose to medium dense sand layer is susceptible to liquefaction under a design earthquake with a seismic coefficient of 0.15g. Several foundation options were considered for the new bridge including both shallow and deep foundations. It was determined that the most cost effective alternative is to use spread footing foundations supported on densified soils. Vibratory probes were utilized to densify the loose to medium dense sand layer and reduce the risk of liquefaction. Densification test sections were performed to determine the optimum spacing for the vibro probes. The test sections included performing piezocone tests before and after the densification to compare the increase in relative density of the sand. In addition, ground surface settlement due to the vibro probes was measured and correlated to the increase of soil relative density. The paper will present the results of the ground improvement method utilized and correlate the spacing of the vibro probes and the increase in relative density and the results of the piezocone tests performed before and after the densification. It was found that the vibro probes are not as effective as thought at shallow depth below the ground surface. It is believed that the results and finding presented in this paper will benefit both the design and construction industries by providing a relatively cost effective means to improve the soils

Jan 1, 2007

By P. G. West-Sells

At Barrick's Zaldivar Copper Mine in Chile, the addition of sulfuric acid to the ore going to heap leaching is a major expense. A process in which a portion of this acid is replaced by elemental sulfur added to the heap has been developed by Barrick and Westcoast Biotech that has the potential for significant cost savings. Initial shake flask tests with plant raffinate solution indicated that oxidation of elemental sulfur by a culture of sulfur-oxidizing bacteria, some indigenous to the Zaldivar heap, showed a significant lag period. This lag period could be reduced by dilution of the raffinate, but dilution would not be economical to implement at Zaldivar. Short (0.75 m) column tests indicated that after the initial lag period, sulfur biooxidation occurred steadily and the acid requirement for obtaining the same copper recovery as the control without sulfur was reduced by as much as 13 kg/t. These tests were followed by taller (5.1 m) column tests that confirmed the reduction in acid consumption, with no negative effect on copper extraction.

Jan 1, 2007

By J. M. Shneerson

Gipronickel Institute, Saint-Petersburg will The copper concentrate was extracted from copper and nickel matte after its hydrometallurgical treatment and nickel removal. The concentrate containing 60-74% of copper was represented by two principal copper minerals, digenite and covellite. The oxidising leaching of this kind of concentrate was studied at the Gipronickel Institute. The effect of key parameters, such as temperature, oxygen partial pressure and initial solution compound, on the rate of copper dissolution and transfer of sulphur from sulphide to elemental form was investigated. It was shown that at temperatures about 90DC, the sulphur content of covellite converts to elemental form. Under autoclave conditions at 11ODC, the elemental sulphur dissolves as a sulphate-ion. At the temperature range from 50 to 90DC, the copper dissolution rate is in direct relation with temperature. By increasing the temperature to 130DC, this effect is reversed. Based on the research work, a technological flow sheet for the leaching of the copper concentrate was developed.

Jan 1, 2007

By S. A. Ziebold

There is often a need to increase capacity through existing mist eliminator installations without significant tower modifications. Often there is not enough extra space outside existing vessels unless more expensive changes can be justified. Also, plant downtime must be considered. The challenge in retrofitting is to overcome velocity limitations inherent in the design while at the same time extend performance capability. The solution most often is to create new ways to add extra filter area while remaining constrained to the existing space. This strategy, however, can dangerously backfire if basic design principles are not followed. Mist eliminator design is a complex integration of many conflicting performance parameters. Often the objective is to increase scrubbing capacity while maximizing collection efficiency and service life and minimizing operating pressure drop (energy cost), particle regeneration (re-entrainment) and overall maintenance costs. Results of plant retrofitting using mesh pads, impaction fibre beds and diffusion fibre beds are presented based on actual plant projects. Often the retrofit project can be more effective by increasing the scope and combining other new plant equipment with the upgrade such as new tower components. In some cases, the type of mist eliminators can be upgraded from impaction type (velocity dependent) to Brownian diffusion type (velocity independent) if additional downstream protection or reduced emissions are desirable, especially at turndown rates. Trade-offs between different fibre bed types and styles are discussed as they relate to performance and maintenance.

Jan 1, 2007

By T. Prietl

Metallurgical vessel linings are multilayered, consisting of refractory bodies, insulation materials, joints, and additional space to control for thermal expansion. A unique biaxial hot testing press (BHTP) was installed at the RHI Refractories Technology Center Leoben, Austria to enable the three-dimensional behaviour of complex vessel lining segments to be investigated under simulated service conditions. Using the BHTP, the heat up and thermo-mechanical behaviour of magnesia chromite brick lining segments with and without mortar filled joints were examined. The results obtained during the initial heat up provided validation of CFD modelling of the lining system. In addition, after the heat up and under steady state conditions, the lining behaviour during deformation-controlled compression and relaxation was examined. These analyses generated important data regarding the stiffness, joint compressibility, and brick damage of the lining segments after cyclic loading and unloading as well as the benefits of using mortar joints in the lining. These investigations were performed in collaboration with the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals, University of Leoben, Austria. The BHTP has been operational since November 2004 and is providing information regarding the thermo-mechanical behaviour of different lining segments.

Jan 1, 2007

By Axel Studeny

Geomechanical-numerical methods are an established tool for planning of underground excavations worldwide. By describing the interaction between heterogeneous layered strata and support elements it is possible to determine their suitability. The German hard coal mining industry has more than twenty years experience in investigation and using these parameters to carry out numerical calculations. Today, nearly all excavations (shafts, pit bottoms areas, bunkers, coal faces, development drivages, gate roads etc.) are calculated by geomechanical-numerical tools in combination with empirical planning methods. A high accuracy of planning results, which is a special requirement in the German coal industry with its deep-level longwalls, bedded and weak surrounding strata and multiple seam mining layouts, depends on the extensive calibration of the numerical models, which is achieved by: 1) Taking a large number of underground measurements with empirical evaluation. 2) Carrying out physical modeling. 3) Using the characteristic features of the installed support elements. This paper compares the planning approach used for multiple and single seam mining and presents the advantages of this planning tool. The main focus is on the feasibility of rockbolting as the sole means of roadway support for multiple seam mining operations, though the paper will also look at how the costs can be improved by using a low bolting density in single seam layouts.

Jan 1, 2007

By Stefan Basista, Janusz Tomala

Modern constructions of electric ferroalloy furnaces are still based on applying in the lower "liquid" areas the standard carbon materials. What can be illustrated by the experience from several years, in the part of tap hole, hearth walls and bottom, is that so-called carbon or semigraphite microporous materials are successfully being applied. These materials, compared to the standard carbon, give better resistance to the attack by liquid metal and other wear factors. Generally this group includes materials characterised by considerable share of pores of diameters below1µm (significantly exceeding 90% of total porosity). The microporosity increases the resistance to the infiltration of the liquid metal. The effect of microporosity can be obtained by introducing silicon (or its compound) additive to materials based on electrically (or gas) calcined anthracites, electrographite and binder. Moreover, by introducing other ceramic additives, the microporous materials are more resistant to dissolution by the liquid metal. Observing the trends of "improving the materials" in the last years, it is clearly seen that the share of non-carbon additives is bigger and bigger, so we can reasonably speak of rather carbon-ceramic materials. In this paper, the survey of the most important quality criteria, which must be met by the carbon furnace linings, as well as the new testing methods will be presented.

Jan 1, 2007

By Thomas P. Kwiatkowski, Joginder S. Bhore, Christopher D. Orlandi, Jose Velez

Three case histories of successful TBM tunneling for New York City Water Tunnel No. 3 are presented. The tunnels, costing about one billion dollars total, are the 5-milelong, 18'-11" OD Brooklyn Tunnel; the 5-mile long, 23'-2" OD Queens Tunnel, and the9-mile long, 12'-4" OD Manhattan Tunnel. The three tunnels are the first major tunnels constructed in New York City rock utilizing the TBM method of construction. This paper describes and compares the three tunnel projects in terms of geology, construction methods, TBM’s, rock and groundwater behavior, rates of advance and other performance data, and challenges and solutions encountered during the projects.

Jan 1, 2007

By G. Markopoulos

Thracean Gold Mining is a Greek Company specialized in gold exploration and exploitation. It is focused on the development of the advanced Perama Hill gold project, which is currently waiting approval of the environmental terms of reference from the Ministry of Environment. We have designed a mine operation that is completely safe environmentally. The mine design exceeds all the standards environmental safety set by the European Union. We are currently negotiating lasting relationships with the communities which surround the mine by creating sustainable projects within the area that will provide sources of income to the region long after the mine is exhausted.

Jan 1, 2007

By M I. Jeffrey, J A. Rumbal, D M. Hewitt

Ion chromatography utilising an anion exchange column and UV detection has facilitated an improved understanding of sulfide mineral leaching in cyanide solutions. By analysing for sulfide, sulfite, thiocyanate, thiosulfate and metal cyanides it is possible to show that chalcocite dissolution is a non-oxidative process in which copper cyanide and sulfide ions are formed in solution. Further, the homogeneous oxidation of the sulfide ions by dissolved oxygen is slow, but catalysed by a surface of lead sulfide or pyrite. Polysulfides may also be formed as an intermediate oxidation product and these undergo further reaction to produce thiocyanate, thiosulfate and sulfite. The leaching of copper from a pyrite concentrate sample is shown to be rapid, and accompanied by significant iron dissolution; however, the iron is not believed to be from pyrite, pyrrhotite or chalcopyrite. The rate of iron leaching and cyanide consumption is reduced by maintaining low cyanide and high oxygen concentrations. Preoxidation or the addition of lead(II) ions does not reduce the iron dissolution from this pyrite concentrate.

Jan 1, 2007

By Z. H. Zhou

It is difficult to remove cadmium from raw indium using only electrolytic refining because their standard potentials are similar. In this paper, physical and chemical methods were used to remove Cd from raw indium. Indium metal is vacuum refined for two hours at 400°C with a vacuum pressure of 20 Pa. In this process, 99.70% of the Cd can be removed. The removal rate of Cd reaches 90% to 95% when indium is further smelted for 10 minutes in a 20% glycerin solution of KI and I2 at 180°C. When pre-indium is electrolytic refined in an In2(SO4)3-H2SO4 system, in which the indium content is 80 to 100 g/L, the pH is 2.0-3.0 and the current density is 80 to 100 A/m2, the contents of the impurities decrease and the purity of the indium product reaches 99.99%.

Jan 1, 2007

The effect of superficial gas rate distribution (Jg profile) on down-the-bank metallurgical response was tested in the rougher-scavenger bank (eight 10-m3 tank cells, 4 roughers and 4 scavengers) at Highland Valley Copper Mine's Cu/Mo separation circuit. Three Jg profiles were tested: (a) as found (i.e., typical practice), (b) increasing decreasing (i.e., increasing from cell 1 to 4 and decreasing from cell 5 to 8), and (c) decreasing-increasing (i.e., decreasing from cell 1 to 4 and increasing from cell 5 to 8). The Jg profile approach proved to be of considerable value. Profile (b) gave the best metallurgical results, i.e., the highest down-the-bank grade/recovery (increase in grade at constant recovery was approx. 3-4% compared to the as found case) and the most efficient Cu/Mo separation (cumulative Cu recovery was reduced by almost half - approx. from 20% to 12%, at 99% Mo recovery). The success of the evaluation prompted the implementation of profile (b). Detailed gas dispersion characterization tests (Jg and Db (bubble size)) showed significant discrepancies between the Jg measured directly (using the McGill University sensor) and the Jg calculated from field instrument readings (volumetric gas flowmeter) and machine dimensions (cell cross-sectional area). Tests were designed to reveal the source of disagreement. It was observed that a significant number of bubbles were not able to float (i.e., they were entrained with the tailings), the evidence appearing to be a significant number of very small bubbles (approx. 200-300 µm) which did not have sufficient buoyancy to rise. Consequently, rather than relying on the field instrument, the evaluation depended on the McGill University Jg sensor, which collects bubbles in a tube near the pulp-froth interface, thus providing significance to the data as the measurements were obtained from bubbles that almost certainly floated.

Jan 1, 2007

Explosive manufacture, handling and transportation is hazardous and special precautions should be taken while manufacture, handling and transportation. Various regulations and rules defined in explosive act and factories act of India are discussed in this communication. General process control measures during the manufacturing of different types of explosives are also dealt in detail. Various processes hazardous in manufacture of various explosives like slurry explosives, PETN, detonators, styphnic acid, lead azide and lead styphnate and special precautions to be taken during the manufacture of the above explosives are also discussed.

Jan 1, 2007

By Dick Minnitt

Large-scale variability in process plants and process control can be identified and controlled through disaggregating the overall variability in a process stream. Conventional statistics and Statistical Process Control (SPC) fail to address the concept of stream heterogeneity, therefore fail to identify and distinguish between the various sources of variability in a process stream. A modified set of 445 data from a process plant is used as an example to explain the benefits of variography in process control. Large-scale variability, usually in the form of product composition cycles and chemical cyclic variations may be manifest throughout a sampling system or a process plant, but this type of variability is most easily discernable in one-dimensional process streams. The Moving Average is a powerful tool for identifying large and small scale variability and cyclical behaviour in process streams, while the variogram is a custom built tool that allows the components of variability to be identified and resolved. The positions in the variogram at which the different variance can be read and the nomenclature of these types of variability is described. The transfer of variances converted to standard deviations to the Control Charts, allows an operator to appreciate the appropriateness of Upper and Lower control and specification limits. The overall contribution of the various sources of variability is represented in a pie diagram.

Jan 1, 2007

By M. D. Lionnet

The Bafokeng Rasimone Platinum Mine (BRPM) is a joint venture between Rustenburg Platinum Mines Limited and Royal Bafokeng Resources (Pty) Ltd (Bafokeng). The mining lease has been granted over Boschkoppie 104JQ and is located approximately 10 km south of the Pilanesberg Alkaline Complex. The Merensky Reef, which constitutes the principal orebody, is geologically complex. A relationship between its geological variability and the associated mineralization has been established by defining a number of facies types. The Merensky Reef has been subdivided into seven distinct facies types: the pegmatoidal facies, contact facies, FW1 potholefacies, FW3 pothole facies, FW6 pothole facies, and FW7 pothole facies. The Merensky Reef, which does not form part of the potholed reef, has a large component of footwall mineralization. The pothole facies, in contrast, has mineralization located in the hangingwall. Statistical analysis of the facies types indicates that they are unique populations and hence need to be evaluated independently. The mining lease has distinct structural domains that have added additional complications to evaluation of the Merensky Reef. The Merensky facies on BRPM exhibit unique geological and statistical characteristics within well-defined structural blocks. Due to the extreme variability of the Merensky Reef on BRPM a unique approach has been developed, within Anglo Platinum, to evaluate the deposit. Mining cuts are defined and composited for the individual facies types, and then modelled individually by applying known geological controls. The resultant grade models are weighted based on statistical and local geological knowledge. The object of weighting the facies is to replicate the variability observed in the orebody. The introduction of stringent geological controls to the evaluation process has resulted in increased confidence in the in situ grades estimated as an input to the mine planning process.

Jan 1, 2007

By A. Krause

Shovel-truck systems for loading and hauling material in open pit mines are now routinely analysed using simulation models or off-the-shelf simulation software packages, which can be very expensive for once-off or occasional use. The simulation models invariably produce different estimations of fleet sizes due to their differing estimations of cycle time. No single model or package can accurately estimate the required fleet size because the fleet operating parameters are characteristically random and dynamic. In order to improve confidence in sizing the fleet for a mining project, at least two estimation models should be used. This paper demonstrates that the Machine Repair Model can be modified and used as a model for estimating truck fleet size in an open pit shovel-truck system. The modified Machine Repair Model is first applied to a virtual open pit mine case study. The results compare favourably to output from other estimation models using the same input parameters for the virtual mine. The modified Machine Repair Model is further applied to an existing open pit coal operation, the Kwagga Section of Optimum Colliery as a case study. Again the results confirm those obtained from the virtual mine case study. It is concluded that the Machine Repair Model can be an affordable model compared to off-the-shelf generic software because it is easily modelled in Microsoft Excel, a software platform that most mines already use. This paper reports part of the work of a MSc research study submitted to the University of Witwatersrand, Johannesburg, South Africa. Keywords: simulation, bunching, probability distributions, cycle time, queuing, matching, shovel-truck, OEM.

Jan 1, 2007

By M Bannear, J-F Wilhelmy, R Jones

Mineralogical study of the interactions between fluxes and iron-oxides helps to understand how magnetite oxidises to haematite during pellet firing. Samples of OneSteel magnetite pellets tested at COREM pilot plant were collected after three firing steps and were studied mineralogically. Preheated pellets revealed no particular microstructures related to the composition of fluxes but were more affected by their bed position. After kiln firing, the impacts of lime and magnesia became more apparent. Magnetite oxidation is complete in the cooling stage. The position and the microstructure of the residual magnetite can bring useful information that could æcompleteÆ the view of the firing cycle.

Jan 1, 2007

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter has been developed to predict the molten temperature. The primary assumption of the model was that all matte, slag and gaseous phases in the converter were in thermal and chemical equilibrium. In this model, the matte components were considered only as copper, iron and sulfur elements. In the slag making stage, all the reacted iron was converted to fayalite. The reaction rate of iron and oxygen in this stage was considered to be constant. The converter temperature was calculated by heat balance over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depends on process parameters such as oxygen efficiency and molten emissivity.

Jan 1, 2007