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By R. J. Davidson

Arguments are presented in favour of a new interpretation of the chemistry pertaining to the dissolution of gold, when this takes place in typical gold plant leach circuits where calcium is present in solution. It is suggested that under these conditions the standard chemistry, as it applies in the absence of calcium, is no longer valid. Thus the concept of very soluble sodium and aurocyanide ionic species in solution is replaced by the presence of weakly soluble calcium aurocyanide, which is a covalent coordination complex that is non-ionic. Supporting evidence for this is provided and the implications that the presence of calcium in gold plant circuits may have for operational efficiency are discussed. In particular, because of the formation of this weakly soluble calcium complex, the addition of lime to the leach circuit is questioned. Arguments for the use of a sodium hydroxide/sodium carbonate/sodium bicarbonate buffer solution as a means of controlling pH and of increasing ionic strength in a so-called ?soft? leach are presented. Such a lime-free system, besides benefiting the leaching of gold, would have many downstream benefits in existing CIP circuits. Furthermore, the direct electrowinning of gold from the leach now becomes potentially feasible.

Jan 1, 2007

Introduction The science of geometallurgy requires that ore characterization be performed holistically, that is, with consideration of ore quality on plant performance and product quality. Geometallurgy, by definition, requires knowledge of geology, mineralogy, extractive metallurgy and pyrometallurgy. Examples of the ore characterization challenges for the geometallurgist in the production of iron ore pellets from low-grade Proterozoic iron formation are presented here. Ore Characterization Ore characterization, the quantifying of mineralogy, grain size and the texture of ores, is an often overlooked tool in improving process efficiency. Some mineral related problems are not unique to the production of iron ore pellets; e.g. the problems caused by expanding clays in flotation. The negative impact of carbonate minerals in the ore on pellet productivity and pellet quality are unique. The long and complex geologic history of Precambrian iron formations contribute to modifications of grain size and the introduction of complex textures.

Jan 1, 2007

By D. Bessinger, N. Rughubir

Exxaro Sands KZN produces?among other heavy mineral products?high titania slag, which is used as feedstock to the pigment industry. The titania slag is produced from the smelting of ilmenite in two 36 MW DC furnaces. In this smelting process carbon monoxide gas is produced. This gas is cooled, scrubbed and washed to remove entrained dust. This paper provides details on the gas cleaning plant system and the chemistry, mineralogy and size distribution of the particulate material contained in the off-gas stream. Characterization of the dust shows that is consists mainly of ilmenite, but with relatively high levels of SiO2and MnO. Smelting of the dust in a 500 kW DC furnace was carried out to investigate the potential for recovering valuable elements from the dust.

Jan 1, 2007

By M. Kirsten, W. H. Botha, M. H. Fox, J. A. Moolman, A. J. Lathwood

Water is a valuable and in many areas a scarce resource. Governmental legislation regulates the environmental impact of water usage and wastewater disposal through the issue of licenses. These requirements mean that hydrometallurgical refineries must ensure that water consumption and water disposal is managed on a continuous basis in order to prevent the repeal of their operating license. Water balances are often overlooked during the design of a hydrometallurgical refinery. Recent changes in environmental legislation have forced both design engineers and operational management to review water use and disposal within these processes. Unlike concentrators where water can easily be recovered by recycling from tailing dams, water introduced into hydrometallurgical refineries becomes contaminated with soluble metals and thus requires pre-treatment prior to disposal. This paper discusses the various concerns that need to be considered during design and operation of hydrometallurgical refineries with respect to the water balance.

Jan 1, 2007

The VoD of non-ideal explosives depends on the charge diameter and the thickness, strength and sound velocity of the confiner. VoD measurements are made to evaluate explosives for development, quality control and prediction of field performance. In testing, the container is part of the explosive system and affects the measured VoD. Pipe testing in cardboard tubes delivers the best guide to unconfined critical diameter and minimum VoD range, but the thickness of the pipes affects the result close to critical diameter, even in emulsions. PVC pipes are not good for unconfined test work because they provide relatively strong confinement. Care must be taken to select pipes with constant relative pipe area across the range of diameters. Where pipes are used to evaluate the effect of confinement, the ratio of the wall thickness relative to the thickness of the detonation driving zone in the explosive needs to exceed 0.5 to create full confinement and the ratio of the detonation velocity to the confiner wave speed must be considered. Estimates for critical thicknesses are provided from Non-Ideal detonation models. The relationship between confinement modulus and VoD is discussed and indexes are suggested for quantifying the explosive performance.

Jan 1, 2007

By M. Gruber-Pretzler

Technical Sn- bronzes tend to form both macrosegregations and microsegrega¬tions during DC-casting due to the particular thermodynamic properties and kinetics of phase transformation. As a result a heterogeneous cast microstructure forms that is some¬times a reason for a decrease in workability. The extent of macrosegregations in DC-casting can effectively be influenced by casting parameters like casting velocity, primary cooling or inlet geometry which in fact change the relative flow between the melt and the forming solid. In order to understand the influence and interaction of the related phenom¬ena, simulation methods are applied. The solidification of the strand as well as the forma¬tion of macrosegregation are simulated with a two phase volume averaging model. The velocity field of the melt flow is explicitly calculated by solving the corresponding mo¬mentum conservation equations. Within the mushy zone the local formation of microseg¬regations in the presence of feeding flow is estimated. The thermodynamics of the Cu-Sn system is accounted for and it is distinguished explicitly between interface and average concentrations. To investigate the influence of feeding flow on the formation of mac-rosegregations, a study has been performed. Based on this result, the phenomena of mac¬rosegregations are described in a detailed discussion.

Jan 1, 2007

By J. Engel

The talc deposit in Gemerská Poloma lies 350 to 400 m under the surface; the whole deposit is located at the highest-level drinking-water-source protection zone, therefore, opening in this mining area (a well, a ramp) requires higher investment, operational and water protection costs. The adit, outside the mining area, with a length of 4200 m, rising with a gradient of 3? and a diameter of 10.3 m2, allows free passage/runoff of mining-water through the adit, and guarantees low costs for transporting produced material and equipment. This solution is in total less demanding from both investment and operational point of view.

Jan 1, 2007

By A. Haldar

This study focuses on the flow characteristics of hypereutectic Al-Si alloys in thin sections. The pattern assembly consisted of spiral horizontal patterns, 6.25 mm (0.25 inch) and 12.50 mm (0.50 inch) in thickness with a common sprue. Al-Si alloys with silicon levels of 14%, 18% and 22% were poured with superheats of 60°C, 115°C and 170°C. It was observed that metal fluidity (in terms of flow length and metal velocity) increased with increase in silicon levels and superheat for both section thicknesses. It was also observed that, for a section thickness of 6.25 mm (0.25 inch), silicon level had more pronounced effect on the metal fluidity. For 12.50 mm (0.50 inch) thickness, both silicon level and superheat affected the metal fluidity. The surface hardness of the castings increased with an increase in silicon level of the alloys at the gate and the flow tip. Detailed study of the flow tip was also carried out with a view to understanding the effect of silicon level and superheat on undulated flow length, surface hardness and microstructure.

Jan 1, 2007

By Issa S. Oweis

Two Towers are currently under construction in Central Moscow in the Russian Federation. Building A is a 96 story tower and Building B is a 65 story tower. The columns in both structures bear on a thick concrete mat that is supported on drilled shafts, 1.5 m in diameter. The shafts derive their capacity from weak limestone with layers of marl. Assigned allowable shaft loads were initially based on rock strengths that were later verified by load tests using the Osterberg Cell. One of the load tests was carried to near failure which allowed refining socket friction values that were later used in the design of Building A. All shafts were advanced using an auger and concrete placed in the dry. Grout tubes were placed with the reinforcing cage which allowed grouting of the limestone in contact with the shaft. Load sharing between the shafts and the mat was approximated using published methods as well as site specific finite element analysis. This paper covers the methodology of design, analysis of the Osterberg results to derive non-linear stiffness of the rock and differences between finite element analyses and results by approximate methods.

Jan 1, 2007

By R. E. Wilmot

This paper is based on the experiences, over many years, of numerous authors in the South African mining industry and of the hot dip galvanizing process and its application as a corrosion protection system. The paper sets out the extensive development, financial resources and stringent operating requirements of the South African mining industry. After many years of research and operational experiences, hot dip galvanizing and, when necessary, duplex systems, have been found to meet the demanding requirements of this particular industry. The paper sets out the requirements from the standpoint of corrosion criteria and is followed with a case where the corrosion protection properties of hot dip galvanizing are demonstrated. This case history traces the early investigation of the expected corrosive conditions in a new mining operation and concludes with two follow-up visits to the mine in order to examine actual performance of the corrosion protection system after ten years in service.

Jan 1, 2007

Having worked as a consultant for most of his 40-year working life, mostly as a mineral property valuer, the author has seen many poor valuations. Most were valuations of exploration tenements where the selection of the rather subjective, but necessary, geological inputs raised the main concerns. Those valuations involving iron ore prospects raise particular problems due to the special characteristics of such deposits. Iron ore is more like an industrial mineral rather than precious or base metals and Reserves are determined not by a traditional cut-off grade but by customer specifications. This is intended to be an overview/keynote paper on the current state of the growing (yet consolidating) Australian Iron Ore industry. It has now moved beyond Western AustraliaÆs æPilbara Big TwoÆ of Rio/BHPB (with the emergence of the irrepressible FMG and Hancock Prospecting) to include the YilgarnÆs æMidwest ManyÆ (including US re-entrant Cleveland Cliffs through Portman) and projects in other States. Ore types have moved from haematite Brockman to martite-goethite Marra Mamba (including the RobeÆs mesas and below water table Yandicoogina CIDs) and magnetite ore types. There are DSOs and secondary process feed. Mineral valuers have to reflect today upon these and many other determinants of value when choosing the most appropriate methodologies to adopt when technically assessing and valuing exploration tenements containing iron ore. Set against a frame work of the JORC Code (2004) and VALMIN Code (2005), the general valuation issues involved in using the cost methods (eg multiple of exploration expenditure), market methods (eg comparable sales, rules-of-thumb and joint venture terms) and income methods (eg synthetic discounted cash flow (DCF)/net present value (NPV) modelling) are discussed. Relevant factors when valuing iron ore properties are discussed, eg ore type, lump/fines ratio, stripping ratio, water table, impurities and grade, particularly the JORC confidence category of the identified mineralisation. Remoteness and access to existing rail infrastructure is a key consideration.

Jan 1, 2007

By J. Contreras

In the period 2003-2004, the situation of the copper concentrate market was unfavourable for smelters and refineries, with low TC/RC values and euro-dollar parity affecting European companies negatively. Within this scenario, Atlantic Copper decided to develop a plan to increase its competitiveness and to improve its results in these market circumstances. The plan affected all departments in the Company and was based mainly on cost reduction in energy and manpower. A general analysis of the Complex's overall efficiency was carried out and, based on this analysis, two major Projects emerged, "Primavera" and "KF". Each Project consisted of smaller sub-projects which aimed at improving the areas which could perform better according to our general analysis. The paper describes how this entire project developed and the final results obtained by the Company.

Jan 1, 2007

By John Gamble

This paper summarizes the weight of epidemiological evidence to evaluate the hypothesis that asbestos exposure is causally associated with increased risk of gastrointestinal (GI) cancers as suggested by Selikoff in an early study of insulation workers. This review looks at populations that develop GI cancers, namely stomach, colorectal, colon and rectal. Guidelines for assessing causality are strength of association, biological gradient and consistency of the associations. Exposure?response (E?R) was evaluated using three methods to estimate exposure. Rate Ratios (RRs) for lung cancer and percent of mesothelioma are used as surrogate measures of asbestos exposure for all the cohorts of exposed workers. Quantitative or semi-quantitative estimates of cumulative exposure to asbestos were also used to assess E?R trends and were compared to E?R trends for lung cancer and mesothelioma in individual studies. Surrogate measures are important since there are few individual studies that have assessed E?R. None of the various methods to estimate asbestos exposure yielded consistent E?R trends and the strength of the associations were consistently weak or non-existent for the four types of GI cancers. The epidemiological evidence detracts from the hypothesis that occupational asbestos exposure increases the risk of stomach, colorectal, colon, and rectal cancer. Findings are briefly summarized below. © 2007 Elsevier Inc. All rights reserved. Keywords: Asbestos; Colon cancer; Colorectal cancer; Gastrointestinal cancers; Ingestion; Lung cancer; Mesothelioma; Rectal cancer; Review; Stomach cancer

Jan 1, 2007

By R Shaw, R Williamson

Global iron ore demand, sparked by ChinaÆs rapid industrialisation and emergence as the worldÆs newest steel market, has seen iron ore groups investing heavily in production capacity as well as infrastructure. The success of these new projects depends heavily on reliability, competitiveness and quality control in an increasingly demanding trading environment. Furthermore, the iron ore industry continues to improve its competitiveness in mining practices, technology innovation and management processes. The continued fine tuning of these sectors will be critical to the success of the industry in the years ahead, and this mining sector will continue to demand process improvements from their service suppliers to maintain competitiveness. Automation offers a real solution to these demands. A crucial quality control element in mining, beneficiation, stockpiling and shipping stages is ensuring representative samples of ore are taken along each step of the process. When these samples reach the laboratory it is imperative that the sample is representative of the entire stream and that no induced errors occur. Examples of automation start with mechanical primary and secondary samplers in the run-of-mine processes through to sample tower and laboratory crushers, dividers and collectors. Automation is widely used in many forms to provide reliable and repeatable samples for analysis whilst providing a safer working environment. Laboratory automation systems in use today vary from simple linear systems to sophisticated robotic cells. Sample automation in the iron ore industry has resulted in many benefits for both producers and their customers. The most significant benefits have come in the form of higher safety standards whilst reducing sample error, sample handling and sample contamination during collection. These benefits have been further augmented by reliability and repeatability of automating the final sample preparation and analysis stage. Today these benefits are reflected in reduced costs of sampling and improvement in both turnaround time and quality of results, whilst complying with Australian safety and ISO sampling standards.

Jan 1, 2007

By R. Gurung, S. Asokan, Ch. V. G. K. Murty, R. Upadhyay

Tata Steel Limited which is Asia?s first and India?s largest integrated private sector steel company, as part of its vision to grow in related industries is also undertaking the Titania project. The project will involve mining, separation of ilmenite and other valuable minerals from the inland heavy mineral sands deposit in the Indian state of Tamil Nadu. The raw material will be beneficiated to synthetic rutile, titanium dioxide pigment and ultimately to titanium metal. The recently concluded feasibility study revealed that the deposit under consideration has 10.4%of total heavy mineral content and 15.2% slimes of the size below 63 µm, over an average sand thickness of 6.9 metres. The presence of about 15% slimes in ROM sand coupled with scarcity of water at the project site complicates the slimes handling/disposal system, requiring the development of an innovative, efficient and effective system for disposal of slimes. Mineral characteristics of slimes revealed the presence of kaolinite clay, which poses its own challenges in thickening/dewatering of slimes. This paper outlines the detailed studies conducted, including slime characterization, settling and thickening characteristics, and ge-technical studies to arrive at an efficient and effective slime handling/disposal system, with a view to plant saplings on the mined-out reclaimed land with species typically suitable to that environment.

Jan 1, 2007

By R Farnf, M Pegden, S Hosein, T White

A number of theoretical papers have been published outlining the use of electronic detonators to limit peak particle vibrations levels, but few empirical studies have been undertaken and even fewer examples have been published of the use of such technology in the aggregates industry. This paper gives a summary of the research work carried out at two limestone quarries in the North of England, where a series of blasts were used to compare and contrast the use of electronic and non-electric detonators. The majority of blasts were carried out using the same burden, spacing and decked charge weight loadings. A methodology was established that could be used to reduce the peak particle velocities (PPVs) at two or more specific locations by using single-hole blast vibration signatures in conjunction with specific electronic detonator timing intervals. The initial study concluded that this was only possible if single-hole signature blasts were periodically recorded to establish the shape of the correct vibration envelopes as properties were approached. These wave envelopes could then be used as the basis for choosing the specific electronic detonator timing intervals to give the lowest PPV for the properties or locations concerned. This methodology was then used in the second study to access a large volume of aggregates adjacent to a working railway tunnel. The financial benefit for the company was to convert these additional tonnages of rock from being a resource to an exploitable reserve. The project involved careful blast design and the instrumentation of a number of boreholes to enable the results of blast monitoring exercises to be compared with predicted PPV results. The iterative process involved the vibration results being uploaded into æBlast LogÆ (an expert blasting database system developed by the Blasting and Environmental Research Group at the University of Leeds) and analysed to produce predictions ready for the next blast.

Jan 1, 2007

Knelson concentrators are commonly used to recover fine liberated gold in gold processing plants. The decision to employ a gravity gold circuit consisting of centrifugal devices such as Knelsons is primarily taken on the results of GRG tests, among other considerations. While the GRG test is considered a material characterisation test, which is useful in the design stages, its use in evaluating the performance of an existing unit is questionable. The problem is exacerbated by the fact that it is time consuming and costly. This paper examines the validity of the GRG test for performance evaluation and discusses alternative test work that can be performed to evaluate the performance characteristics of an operating machine. Principles that are useful in selecting optimal operating parameters, such as optimal fluidising water flow rate for a given ore/machine combination, are also discussed and illustrated with laboratory and plant data.

Jan 1, 2007

By Vince Luongo

PROJECT DESCRIPTION The York Durham Sanitary System (YDSS) Interceptor in the Town of Richmond Hill located just north of Toronto, Ontario, Canada will see the construction of a tunnel extending along 19th Avenue for a length of approximately 3.8 Km from Yonge Street, east to Leslie Street and will have a minimum internal diameter of 2.1 m. t to Leslie Street and will have a minimum internal diameter of 2.1 m. The tunnel will connect into four shafts, for which two of the shafts will be constructed using the slurry wall construction method given the high water table and difficult ground conditions encountered at these locations. The two shafts noted as Access Shaft No. 2 and No. 3 were designed and constructed to meet regulatory conditions, which required a sealed shaft construction method. GEOGRAPHICAL PROFILE The ground conditions in the Toronto region consist predominately of glacial till, glaciolacustrine and glaciofluvial sand, silt and clay deposits, and beach sands and gravels. The shallow geological formation found in the project area consists of four types of deposits: Oak Ridge Morain deposits, Halton Till, Glacial lake deposits and Organic soils. The Oak Ridge Morain is the dominant deposit encountered along the tunnel alignment. This formation consists of three deposits: The Upper Till, Middle Sand and the Lower Till. Standard penetration tests (SPT) carried out in these deposits measured N-values ranging from 2 to more than 100 blows/300mm which indicate very loose to very dense soil conditions. The Middle Sand deposit will be the dominant feature within the slurry wall construction at access shafts 2 and 3. Access Shaft 3 The base of the slurry wall will be 20.5 M below the ground surface. Slurry wall excavation will be within peat and organic soils found at the upper 3 M, followed by 5 M of the Upper Till. The remainder of the excavation will be within the Middle Sand. The piezometric head elevation is found at the ground surface. Access Shaft 2 The base of the slurry wall will be 22.5 M below the ground surface. Slurry wall excavation will be entirely within the Middle Sand 2.The piezometric head elevation is found at 7 M below the ground surface.

Jan 1, 2007

By G. Bulut

The recovery of copper and cobalt from ancient copper slags from the Küre region of Turkey was investigated. A fayalitic-type of ancient copper slag containing 1.24% Cu, 0.53% Co and 53.16% Fe were subjected to an experimental study. Two different routes were followed to recover the metal values. The first route was roasting the slag with pyrite followed by leaching. The second route was flotation of the slags, roasting of the flotation tailings with pyrite and leaching. The second route was found to be suitable for the treatment of the copper slag studied. In the flotation step, a copper concentrate containing approximately 11% Cu was produced with a 77% recovery while 93% of the cobalt stayed in the tailings. In the roasting experiments, the effects of roasting time, pyrite: slag ratio and roasting temperature on the dissolution efficiencies of Cu and Co were investigated, and the optimum conditions were determined. In the tests, 87% of the cobalt dissolution was observed after one hour of roasting at 500°C with a pyrite: slag ratio of 3:1. The copper dissolution in the tests was 31%. Based on the results of this study, a process flowsheet is proposed for the evaluation of these slags.

Jan 1, 2007

By E. L. Thyse, P. Bepswa

The Western Cape Mineral Processing Facility (WCMPF) is a collaborative educational initiative between the Department of Process Engineering at the University of Stellenbosch and the Chemical Engineering Departments at the University of Cape Town and the Cape Peninsula University of Technology. The primary objective of the WCMPF is to facilitate the education, development and graduation of suitably qualified engineering graduates and diplomats for the mining and mineral processing industries. In recent years the WCMPF has embarked on a number of initiatives aimed at improving the quality of mineral processing education which include, more importantly the introduction of novel ?end to end? or ?integrated? practicals. The practicals are developed around a specific mineral theme or route, which more than often includes the development of several new pilot plant practicals demonstrating key unit operations or processes in the selected mineral theme or route. The most recent mineral processing pilot plant practical programme is developed around the beneficiation of heavy mineral sands. The programme consist of the following developed pilotplant practicals: the online electrostatic separation of free flowing mineral sands using a Roche Mining Carrara high tension roll separator incorporating a Blue Cube Systems MQi in-line mineral quantifier; the production of titania-rich slag and pig iron from the smelting of ilmenite and anthracite in a 60 kW direct current (DC) plasma arc furnace as well as the mineralogical characterization of the feed and products; the continuous closed-circuit ball milling and screen classification of titania-rich slag. This paper illustrates the important role of a well-designed heavy mineral sands beneficiation pilot plant practical programme in facilitating the education and development of suitably qualified personnel for the mining and mineral process industries.

Jan 1, 2007