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By S. Theobald

Semi-finished copper and copper-alloy products are typically produced by casting, subsequent hot rolling or extruding and further cold working by rolling and drawing. The technological properties of the products depend not only on the chemical composition of the alloys but also on process parameters such as annealing conditions and degree of deformation. In each production step, measuring and control technology is an important tool for optimizing processes and ensuring constant high quality. This paper follows the product all the way from testing incoming scrap packages, chemical analysis of melts, mould level control in casting, non-destructive testing technologies in cold forming processes, controlling geometrical properties in the production process, to the final tests of technological properties. All test methods are focused on the applications and requirements of our customers, as the examples show.

Jan 1, 2007

The key functions of project evaluation are to assess potential profitability and to develop an effective operational design. For mining projects, design aspects include mining methodology, ore treatment methodology and production rates. All of these characteristics impact on project economics and overall value. Resource models, which form the ultimate basis of project evaluation, typically consist of tonnes above cut-off, grade above cut-off and the spatial distribution (connectivity) of tonnes/grade above cut-off, for one or more variables. Dilution, ore loss and metallurgical recovery are all modifying factors applied to the resource model during evaluation and determination of profitability. A key issue is: how is the value determined? In addition to traditional combination of in situ tonnes/grade, the following merit serious consideration: the concentration of deleterious elements, throughput rates, mining/processing costs and - importantly - metallurgical recovery. Geometallurgy is an emerging field targeted at integrating these issues by identifying either direct measures or proxies for throughput (hardness, grindability), recovery (liberation, mineral shape/texture, etc) and concentrate quality from easily collected macro-, meso- and microscopic data. These 'geometallurgical variables' drive project costs and revenues in a fundamental way. For geometallurgical characterisation to have a real impact on business design, it must enable improved mine planning. When creating spatial estimates for such variables, it is preferable to find proxies that can be measured as close to the intact rock mass as possible. However, spatial estimation of proxies for geometallurgical properties and responses is complex and requires special consideration. Unlike grades, both proxies and absolute measures of geometallurgical variables are not necessarily linear or additive and therefore require very careful geostatistical consideration. In some cases, models must predict extreme values of geometallurgical attributes rather than averages. Incorrect characterisation of metallurgical recovery/throughput can (and has) led to misspecification of the scale of projects, and thus can be seriously value destructive. Aspects of geometallurgy have long been important in iron, bauxite, manganese and coal deposits and are increasingly on the radar for base and precious metal miners. However, as more metallurgically complex deposits are developed and mining of large-scale, low-grade deposits becomes more commonplace, the importance of characterising the metallurgical response in order to generate properly optimised projects will rapidly increase. It is possible that in many `traditional' (ie grades and tonnes) reserve models, the variables that drive the project are missing!

Jan 1, 2007

By F. Freme

For the second time in four years, the coal industry was brought to the forefront of the nation’s consciousness in 2006, as two separate events unfolded which involved coal miners trapped underground. Unfortunately, the tragic results of the 2006 incidents were not the same as in 2002 when the trapped miners were all successfully rescued. In January, two different incidents, both in West Virginia, focused the public’s attention on the dangers that miners face on a daily basis. As a result of these unfortunate events new legislation requiring improvement in safety in underground mines passed both at the federal and state level. In 2006, a total of 47 miners died on the job, matching the total number that occurred in 1995, and more than double the 22 killed in 2005. Notwithstanding those tragic events, coal production in the United States reached another record level in 2006, ending the year at 1.05 Gt (1,161.4 million st) according to preliminary data from the U.S. Energy Information Administration (Table 1). Production in 2006 was 27.1 Mt (29.9 million st) higher than the prior record set in 2005 of 1.03 Gt (1,131.5 million st). Although coal production rose in 2006, U.S. total coal consumption actually declined for the year. Coal consumption decreased in the electric power sector by 1.1 percent, while coking coal consumption decreased slightly. Only the other industrial sector had higher coal consumption in 2006, increasing by 0.3 percent. (Note: All percentage change calculations are done at the short tons level.) U.S. coal exports declined slightly in 2006, while coal imports again reached a record level. The excess production over consumption allowed total coal stocks to increase significantly during the year, as electric generators rebuilt their stockpiles that had fallen substantially in 2005 because of missed shipments in the second half of that year.

Jan 1, 2007

By A. A. Bilgin

The prevention of acid mine drainage (AMD) in situ is more attractive than down-gradient treatment alternatives that do not involve source control. AMD source control can be achieved by shifting the microbial activity in the sulfidic rock from pyrite oxidation to anaerobic heterotrophic activity. This is achieved by adding biodegradable organic carbon amendments to the sulfidic rock. This technique was applied to an abandoned coal mine pool in Pennsylvania. The pool had a pH of 3.0 to 3.5. Following treatment, near-neutral pH and decreased effluent heavy metal concentrations were achieved. In situ bioremediation by the enhancement of bacterial iron and sulfate reduction is a promising technology for AMD prevention.

Jan 1, 2007

By W G. Szymczak, Leslie C. Taylor

The University of Maryland (UMD) has conducted a series of small-scale tests using explosive charges buried in saturated sand. Twelve different combinations of depth of burial of the charge and height of the target plate above the soil were tested. The target plates did not deform plastically. High-speed video was used to track the motion of the plate. The video data are analyzed to determine the position and velocity of the plate as a function of time. The results of this analysis are compared with computations performed at NRL using the BUB2D computer code. This code treats the saturated sand as an incompressible visco-plastic fluid which yields according to a Drucker-Prager (frictional-cohesive) yield surface. Comparisons of simulations with experiments are presented. In the cases examined so far, the velocity grows very quickly to a peak and then slows, first with a deceleration greater than one “g,” which then transitions to an approximately one “g” deceleration. An analysis of air drag on the plates has shown that its effect is negligible in the time span of interest. In all cases in which the BUB2D code can be applied, the computations compare favorably with the results of the data analysis. This suggests that the code and model used in the computation are properly capturing the physics of the interaction between the soil and a non-deforming plate.

Jan 1, 2007

By E. Herrera Alarcón, L. Mariscal Samaniego

The Teniente Converter (wet charge type) was commissioned in august 1995 and was designed to smelt 744 tpd (metric tons per day) of dry copper concentrates. Its products are white metal (73% Cu) that is sent to the Peirce Smith converters, slag that is cleaned in Reverberatory Furnaces and the process gases that are sent to the Sulfuric Acid Plant. Since its start up, the Teniente Converter smelting capacity was increased 1.6 times, from 800 tpd to 1,280 tpd using 33% oxygen-enriched air, and reaching an operative availability of 97%. By the other hand its campaigns have reached a record duration of 530 days without hot patching tuyeres and a partial refractory lining repair in the last four campaigns. This paper describes the most relevant improvements, as well as the strategies that had been used to reach these achievements.

Jan 1, 2007

By S. Ganguly, R. Kononov

Carbothermal reduction of manganese oxides and manganese ores in the solid state was studied in hydrogen, helium and argon at different temperatures, ore compositions and carbon to manganese oxide ratios. Wesselsore (South Africa) and two grades of the Groote Eylandt ore (Australia) with different level of impurities were examined. Ores were characterised by XRD, X-ray fluorescence, optical microscopy and scanning electronmicroscopy. Isothermal and temperature programmed carbothermal reduction experiments were conducted in a fixed bed reactor in a vertical tube furnace, with on-line monitoring of gas composition by the CO-CO2 infrared sensor. The reduced samples were characterised by XRD, SEM and LECO analyses. Extent of reduction was calculated using data on the off-gas composition, and LECO carbon and oxygen contents in the reduced sample. Manganese oxides in the ore were reduced to a-Mn and carbides Mn23C6 and Mn7C3 depending on the carbon to ore ratio. The reduction rate of manganese ores in hydrogen was higher than in helium and argon. Key words: Manganese, Carbothermal Reduction, Hydrogen, Argon, Carbon Monoxide, Helium, Kinetics.

Jan 1, 2007

By J. T. Hollow

The Fort Knox Mine is located in Alaska?s interior, where the average ambient air temperatures range from -24°C (-11°F) in January to 16°C (61°F) in July. The mill processes a free-milling gold ore utilizing both a gravity recovery circuit and conventional cyanide leach/carbon-in-pulp circuits. Mathematical models have been developed to accurately predict the impact of leach circuit slurry temperature on gold leaching, carbon adsorption and cyanide destruction kinetics. Additionally, an energy-balance approach has been used to model the seasonal variations in slurry temperatures throughout the Fort Knox mill. The energy-balance model, combined with the kinetics models previously developed to predict plant performance, was used to justify a tailing thickener installation at the Fort Knox Mine. This paper describes the development of the energy-balance model and its prediction of plant performance assuming a tailings wash thickener to reduce heat loss from the mill. Also presented is an analysis of the post-project plant performance that validates the model and shows that the mine produced an additional 596 kg (19,155 oz) of gold while reducing mill reagent costs by $6,302,000 during the first 38 months of operation.

Jan 1, 2007

Laboratory and pilot plant investigations aimed at recovering gold as an electroformed sheet from gold eluate and gold leach solutions and slurries are discussed. The electrolytic test work undertaken makes use of high surface area electrodes, in particular nickel-chrome foam metal and activated carbon, as well as ultrasonic activation. The process involves initial gold electrowinning (or adsorption onto activated carbon), followed by gold electroforming, both operations being carried out in a specially designed reactor. The pilot plant work mainly involved the treatment of gold eluate solutions from a South African gold mine containing 600 mg/L Au: some tests were also carried out on gold leach solutions containing 6 mg/L Au. In the former case, very efficient gold extraction onto the foam metal cathode was achieved using electrolysis combined with ultrasonics. The polarity of the gold-loaded cathode was then reversed and, using a replacement electroforming electrolyte, gold was electroformed in situ onto a polished stainless steel mandrel, from which gold sheet was subsequently removed. In the case of leach solutions, pilot plant tests confirmed laboratory findings that in the presence of calcium (resulting from the lime used during the leaching process) no electrowinning is possible. Laboratory tests showed, however, that when sodium (in the form of NaOH or Na2CO3) is added to the leach solution, electrowinning can indeed take place. Alternatively, if a special activated carbon electrode is used (without current), the non-ionic calcium aurocyanide complex is adsorbed on to the activated carbon. When a gold-loaded activated carbon electrode is made anodic in a gold electroforming electrolyte, gold electroforming is feasible, although the efficiency is very low. The possible implications of these developments for gold recovery are further examined.

Jan 1, 2007

By J. C. M. De Souza

The Samarco pipeline, the longest in the world for iron ore slurry transportation, started operation in 1977 to transport concentrate from the Germano facilities, in the state of Minas Gerais, to the pelletizing plant, located 396 km away, in the state of Espirito Santo, on the south-east coast of Brazil. Designed for a nominal capacity of 12 million tons per year, the pipeline reached 15.5 million/year due to operational improvement and, in late 2005, it was resized to transport 16.5 million tons per year, with the installation of a booster station. In order to ensure the accurate performance of the system, a pipeline cleaning programme was carried out and, since it has been29 years from the operation start-up, precise knowledge of the pipe condition would be fundamental to guarantee the success of the project. The cleaning programme demonstrated the potential of operational gains from this initiative, and its effect on the corrosion control and future measures, which should be permanently adopted to maintain the improved capacity. The intelligent pig runs provided essential data used to establish a pipeline integrity programme that allowed Samarco to develop a pipe repair plan based on the severity and significance of the features and to implement a future pipe replacement plan.

Jan 1, 2007

By S. W. Marcuson

In the late 1960's concerns about the natural environment reached high levels within North America and provided activists with suitable platforms for exerting influence over the general public and politicians. In response a host of regulatory mechanisms were developed, statutes, voluntary measures, land grants, codes of practices etc. Emerging environmental awareness from the era provided impetus for rapid technological change that encompassed all industries, especially the base metal business. The resulting clean up impacted all aspects of copper production, dealing with issues such as waste disposal, water and air quality with specific impact on emissions of sulfur dioxide and particulate. This paper provides a perspective of these changes reviewing the macro-economic impact of environmental movement in mining with its specific implications to the copper smelting industry. The fundamental challenges that were faced by the old, but capital-intensive North American plants and the approaches taken to deal with the changing times are reviewed with special emphasis on the conceptual approach to smelter S02 abatement and different paths taken in the USA and Canada. The role of economics, sustainable R&D and presence of technical infrastructure that facilitated the change process is elucidated, and speculations are made about the future state of pyrometallurgy and the natural environment. Cu2007 -

Jan 1, 2007

By M. Dobbins

Magnetic separation has long been used to upgrade and beneficiate a wide variety of industrial minerals. Advances in both wet and dry magnetic separators over the years has broadened their use, and questions are often raised about which separation technique or equipment type is most appropriate for a particular operation. This paper will provide a brief look at existing magnetic separation technologies, and discuss their potential advantages and disadvantages when applied to heavy mineral applications. Relevant case studies for the separation of ilmenite and chromite are then presented. The process development efforts undertaken for each case are described, and the rationale for selecting appropriate magnetic separation technology is explained. The nature of the material being treated must clearly be understood, knowledge and access to testing the best separation technologies is required, and careful process development and economic evaluations are a must. As is shown in the case study discussions, it is imperative that these principles drive the separation technology selection and placement, rather than looking at typical or existing similar flowsheets as rules. As examples, the ilmenite tailings case study presented in this paper shows how advances in technology have allowed for increased recovery of -45 µm ilmenite by utilizing a multi-stage SLon® wet magnetic separator circuit equating to an additional 30 000 tons of ilmenite produced per year. The virgin chromite case study presented shows that through careful testing and circuit design efforts using RED technology, a 20% increase in overall chromite recovery was achieved over previous demonstration work.

Jan 1, 2007

By N. ?peh

The purpose of the paper is to present a way of assessing nonrenewable lignite resources by means of sustainability indicators. An introductory presentation of the origin and characteristics of the discussed nonrenewable natural resources is followed by the study and analysis of separate sustainability indicators. Out of many, only the ones that would directly relate to the explored coal deposit were studied. Some different viewpoints such as economic, social and environmental were assessed inside the studied landscape structure and in relation to other provincial resources using the indicators that are closely linked with the explored lignite reserves. Exploitation of coal as an underground nonrenewable natural resource, has been taking place in the ?alek valley for more than 120 years. However, about 60% of the coal will still be left underground since not all coal will have been extracted when the mine closes. According to the regional and wider national strategic goals concerning the use of natural resources and electricity production in the future, the sustainable aspect of the exploitation of the geologically well explored reserves is emphasized in the paper. Finally, we have tried to evaluate the role and the meaning of the studied underground natural resources for further sustainable development of the ?alek valley and placed stress on the most questionable spheres that should be considered preferentially.

Jan 1, 2007

By T. Arthur Palm, Stephen L. Bessinger

San Juan Coal Co. (SJCC) operates an underground coal mine near Farmington, NM. Continuous miners and a longwall produce 6.3 to 7.2 Mt/a (7 million to 8 million stpy). SJCC is owned and operated by BHP Billiton. The coal seam at SJCC has been shown to have a propensity for spontaneous combustion. As such, during the feasibility study for this project, it was elected to use a bleederless ventilation system on the longwall. Due to the combination of spontaneous combustion, methane liberation and, to a lesser extent, hydrogen sulfide, a typical wraparound ventilation system would not be appropriate. Three-entry gate roads are developed, and the longwall gob is sealed as mining progresses. SJCC uses a nitrogen injection system to continuously inertize the gob.

Jan 1, 2007

By R L. Brathwaite, R Carver

The REGCHEM (Regional Exploration Geochemistry) database of open file mining company data, managed by GNS Science, has recently been upgraded with the compilation of additional data, especially for the Otago region (see http://maps.gns.cri.nz/website/minmap). In June 2007, data compiled for the Otago region included more than 2000 stream sediment samples from 19 surveys, more than 800 BLEG (bulk leach extractible gold) samples from 12 surveys and a few pan concentrate samples. The stream sediment samples were typically analysed for Au and As, and in many cases for other elements including Cu, Pb, Zn, Sb, W and Mo. The BLEG samples were analysed for Au and in some cases also for As. The main exploration target was mesothermal gold deposits in the Otago Schist, although one survey of the Otago Peninsula targeted potential gold deposits associated with the Dunedin volcanic complex. Geochemically, the mesothermal gold deposits are characterised by anomalous As and Au, with some also characterised by anomalous W and Sb, and these four elements are the best pathfinders in stream sediment geochemical surveys. The introduction of lower detection limits in Au analyses in the more recent stream sediment surveys and in the BLEG surveys enables the use of this element as the primary pathfinder for mesothermal gold deposits.

Jan 1, 2007

By P. M. Prasad

Off-grade molybdenite concentrates, mainly derived from secondary sources as by-products of the processing of copper, uranium and tungsten ores, do not satisfy the purity requirements (percent MoS2) for the production of molybdenum bearing products. This investigation is a continuation of a successful effort to refine a low-grade molybdenite concentrate to prepare a high-grade MoS2 using a mixed acid (HF + HCl) leach procedure. Specifically, this investigation is concerned with an understanding of the separation chemistry underlying the removal of the oxide/silicate gangue and the base-metal sulfide associations present in the low-grade molybdenite by their selective dissolution in the two acids. Experiments were conducted on an off-grade concentrate containing 42.6% Mo. Results of the controlled dissolution tests indicate that both HCl and HF are suitable for the removal of the associated alumina and both work well for iron, nickel and copper. However, HF was found to be the most effective for dissolving silica/silicate and magnesia. An attempt was made to rank the leaching efficiencies of the acids used singly, sequentially or in a mixed mode. Scale-up (300 to 2,000 g) experiments were conducted to validate this approach. Excellent purification of the concentrate was possible by processing the off-grade concentrate with 10% HCl plus 15% HF at 363 K for 7.2 ks in open polypropylene reactors with internal stirring. These conditions leached practically all of the oxide and silicate gangue and 96% of the metallic impurities. Starting from the low-grade molybdenite concentrate (42.6% Mo; 71.1% MoS2) it was found feasible to obtain a refined product containing 97.8% MoS2, which is suitable for industrial use.

Jan 1, 2007

By P. A. Riveros

This paper describes the leaching of the common copper minerals tennantite (Cu12As4S13), tetrahedrite (Cu12Sb4S13) and enargite (Cu3AsS4) in acidic media using Fe(SO4)1.5, FeC13 or 02 as oxidizing agents. At temperatures <100°C, tennantite dissolves slowly in Fe(SO4)1.5-H2SO4 media, and the rate is directly proportional to the area of the sized tennantite. The rate increases sharply with increasing temperature and the apparent activation energy is 69 kJ/mol. Increasing Fe(SO4)1.5 concentrations slightly increase the tennantite leaching rate. The kinetics of dissolution of disks of synthetic iron-bearing tetrahedrite in Fe(SO4)1.5-H2SO4 media are linear; the leaching rates are slow but increase significantly with increasing temperature, with an apparent activation energy of 120 kJ/mol. The dissolution of sized particles of natural Ag-bearing tetrahedrite in FeC13- HC1 solutions proceeds according to the shrinking core model, and both Cu and Ag dissolve at about the same rate, provided that the total chloride concentration of the solution is sufficiently high to solubilize the AgC1 reaction product. The leaching rates are slow, and the apparent activation energy is 116 kJ/mol. The addition of sulphate ions to the FeC13-HC1 system reduces the tetrahedrite leaching rate to values similar to those realized in the Fe(SO4)1.5-H2SO4 system. At <100°C, enargite dissolves slowly in either Fe(SO4)1.5 or FeC13 media, and the dissolution rate obeys the shrinking core model. The rate increases with increasing temperature and the apparent activation energies are 50-64 kJ/mol. The rate increases slightly with increasing FeC13 concentrations in 0.3 M HC1 media. The leaching of enargite at elevated temperatures and pressures was also investigated. Potentially useful leaching rates are achieved above 170°C, at which temperature sulphate, rather than sulphur, is produced. Lower temperatures (130-160°C) lead to fast initial leaching rates, but the dissolution of the enargite is incomplete because of the coating of the enargite particles by elemental sulphur.

Jan 1, 2007

By C. Ringas

Pipelines are used extensively in industry to convey various products. Internal corrosion of pipelines can lead to perforation and leakage of the product. A growing problem, not often accurately recognized, is internal corrosion of pipelines caused by bacteria. Microbiologically-induced corrosion (MIC) refers to corrosion caused by a variety of micro-organisms. This form of corrosion is not widely recognized in many industries, although it is widespread and causes many corrosion problems in pipelines, both internal and external. Sulphate-reducing bacteria (SRB) are responsible for the bulk of the corrosion problems caused by MIC. Corrosion caused by SRB is found extensively in water pipelines conveying raw, potable and waste water, as well as in pipelines conveying slurries. This problem also occurs in pipelines conveying crude oil. This paper describes internal corrosion problems of slurry pipelines caused by bacteria and outlines mitigation methods to improve slurry pipeline integrity, thereby extending the life of such pipelines.

Jan 1, 2007

By S. Moutsatsos

The impact that societal issues can have on mineral resource projects has proven to be a critical component of feasibility studies around the world during the past ten years. The recently signed Impact Benefits Agreement (?IBA?) for the Victor Project in Northern Ontario between De Beers Canada Inc. (?De Beers?) and the Attawapiskat First Nation provides an opportunity to capture the interactive process followed, the controlling parameters and the implications for the future. The uncertainty about the time required to complete an IBA makes it one of the key intangibles in risk assessment of a feasibility study. This paper considers items related to the significance of engaging communities at the early stages of exploration in a project and the catalytic effect that alignment of interests and interaction in a pre-IBA period can have. Furthermore, the de facto link between permitting and the successful conclusion of the IBA and the role of external advisors in the project are discussed. The paradox of empowering and supporting communities through the negotiation process, and the implications of the IBA to maintaining good relations throughout the life cycle of a project are also explored.

Jan 1, 2007

If an orebody has been drilled to achieve some level of regulatory compliance, then a number of associated geological databases will exist, representing 10 000 to 100 000 m plus of core intervals. The databases usually contain data about assays, lithology, mineralisation and geophysical attributes. They will also include location information such as collar positions and downhole surveys. Obviously this data is collected by geologists for, predominantly, geologists and mining engineers. However, from a process design viewpoint process engineers usually ignore the geology where possible and rely on a small number of metallurgical test samples. Typically these test samples are sourced from convenient and available cores or from a small number of specially drilled metallurgical holes. One of the worst instances known to the author was the design of a SAG mill using only two SAG specific test results (one for each of the major ore types) while, geologically, the orebody was defined by more than 30 000 m of drilling. This paper sets out a philosophy to maximise the use of the geological data, both for process design and in preparation for the commissioning phase of projects. Geological data is used in the identification of preferred locations for metallurgical test samples, for checking the metallurgical validity of the geological ore-type definitions, where necessary developing new ore-type definitions (geometallurgical domains) and developing mathematical relationships for the estimation of important metallurgical factors across the geological database. If the estimation of factors (for example ore competence) is considered reliable enough then there is also the possibility of feeding calculated data back into the block modelling process to allow the generation of metallurgically relevant outputs in the mine plans.

Jan 1, 2007