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By Luo Yang

It has been known that after initial pile driving, pile capacity gain over time (set-up) could constitute a significant portion of the total pile capacity. In the past, there has been very little guidance for incorporating pile set-up capacity in design. This may be due to large uncertainties involved in predicting the pile set-up. A comprehensive statistical database is developed to describe the increase of pile axial capacity with time, known as set-up, when piles are driven into sand. Based on the collected pile testing data, pile set-up is significant and continues to develop for a long time after pile installation. The statistical database shows that a lognormal distribution can be used to describe the probabilistic characteristics of the predicted set-up capacity using Skov and Denver?s equation. The main objective of this paper is to incorporate the set-up effect into a reliability-based Load and Resistance Factor Design (LRFD) of driven piles in sand. A First Order Reliability Method (FORM) is used to derive separate resistance factors that would account for different degrees of uncertainties associated with the measured short-term capacity and the predicted set-up capacity from the proposed semi-empirical equations. The incorporation of set-up effects in the LRFD helps improve the prediction of the total capacity of driven piles, resulting in more economical design. A practical design procedure within LRFD framework to incorporate the pile set-up effect is outlined at the end of the paper.

Jan 1, 2006

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By Chia-Fu Chang

We revise the applicability of the theory of self-organized criticality (SOC) to the process of magnetic relaxation in type-II superconductors. It is demonstrated that the driving parameter of self-organization of vortices is the energy barrier for flux creep and not the current density. Power spectrum of the magnetic noise due to vortex avalanches is calculated and is predicted to vary with time during relaxation.

Jan 1, 2006

By Chang-hong Peng

Solubility phase equilibrium in the ternary system of Me2+-NH4+-SO42--H2O (Me2+ represented Mn2+, Zn2+ and Fe2+) was studied by the isothermal method at 298K and physicochemical properties of the saturated solution such as density, refractive index and pH were also investigated. The experimental results show that the solubility isothermal phase diagrams of these systems consist of three invariant branches, two invariant points and three crystallization fields. Corresponding to the three crystallization fields, there have three phases of solid, that is MeSO4?nH2O, (NH4)2SO4 and (NH4)2Me(SO4)2?6H2O, respectively. At the eutectic point, the concentration and the refractive indexes of the saturated solution change evidently. Otherwise, the pH value change slowly in all the systems. The calculated results of the density and refractive index agree with the experimental results.

Jan 1, 2006

By Daojin Cao

Aiming at many controversial reports on Raman spectral pattern of heptamolybdate ion in aqueous solution appearing in the literature and the absence of its standard pattern, the comparative investigations on Raman spectral pattern of saturated solution of ammonium heptamolybdate tetra hydrate were done. The results showed that the main vibrant frequencies of Raman spectral pattern of the saturated solution were in good agreement with those introduced in the literature, and that the intensity ratio (4.4) of the strongest peak to the second strongest peak recorded in Raman spectrum of the saturated solution had three obvious characteristics: it was greater than each of the results (ranging from 3.7 to 1.3) reported in the literature, much closer to that (4.7) of crystal and well conformed to the change rule of Raman spectra occurring in the process of the first-step polymerization of acidified molybdate solution. It was found that Raman spectrum of heptamolybdate ion in aqueous solution was determined by not only the main vibrant frequencies but also the intensity ratio, which is also the crucial result in this study. The comparative investigations indicate that the pattern of Raman spectrum of the saturated solution is the standard pattern of Raman spectrum of heptamolybdate ion in aqueous solution essentially. The affirmed standard pattern is reliable and can be used to the identification of heptamolybdate ion in aqueous solution, applied in the research of the equilibrium of acidified molybdate solution and the exploration of the best technologic condition for the production of high quality heptamolybdates.

Jan 1, 2006

By Yanxia Lu

Porous silicon carbide (SiC) has been the top selection for diesel particular filters (DPFs) since 2000 because of its high thermal diffusivity and strong body, which help it to survive in the harsh environment of a diesel exhaust system. However, the process to produce SiC DPFs is a costly one. The work presented herein describes more cost effective composite materials for this application, namely Si-SiC and Si₃N₄-SiC. Both composites have shown excellent filtration efficiency, low back pressure and outstanding survivability of regeneration at high soot loadings. Since the composites are batched from silicon metal, they can be prepared by a low temperature process that is impossible in the production of pure SiC PDFs. In fact, fabrication of SiC composites simply involves reactions between nitrogen gas and silicon metal, or silicon metal bonded with SiC, and as such uses a much less costly process when compared to the one employed to make SiC. In addition, the pore structure of the composites can easily be tuned by selecting raw materials and changing the ratio of two components. A typical pore structure consists of well connected pores with a median pore size of 5-20 µm and a porosity of 40-55%. This talk will describe the exothermic behavior as well as the mechanical and thermal properties of SiC composites in comparison to those of SiC filters. It will also show the superior thermal shock resistance of Si₃N₄ bonded SiC which is due to the unique combination of these phases that lowers the thermal expansion and elastic modulus relative to pure SiC.

Jan 1, 2006

By R L. Langak, R A. Heins

The use of differences in specific gravity between minerals to separate them has long been utilized in the extractive industries. The environmental and cost benefits of the commercialized forms of these processes are well understood and widely used. Gravity concentration is used inter alia in the primary beneficiation of gold, diamonds, coal, tin, ferrous metal ores and andalusite. The potential for economic loss due to poor performance of these gravity processes is significant, but diverse in manifestation and regular process monitoring can prevent or at least reduce these losses. The measurement of performance of gravity processes has always presented a challenge, due primarily to the masses of material involved and the physical nature of the processes, generally typified by long reporting time, and hazardous materials (such as Tetrabromoethane) for float and sink type tests. The development of density tracers has improved this situation, however recovery of these tracers from the process streams created the next set of challenges, requiring significant manpower to physically remove tracers from product dewatering screens. Additions to these tracers (magnetic or x-ray fluorescent) eased the recovery mechanism issues but made them much more expensive to produce, hence operators became concerned about losses during process testing. In addition, magnetic recovery of smaller size tracers by a magnet suspended above a loaded screen panel is still problematic. The development of new low cost magnetic tracers has improved statistical significance of tracer tests, as the tracers themselves can be bought and used in much larger quantities, whilst still remaining economically viable. Coupled with the development of effective magnetic recovery technology, such as the Gekko MagScreen, for even fine sized tracers, on-line, continuous tracer testing is now becoming a reality. Whilst the development of high technology radio frequency detection tracer systems continues, enabling the real time measurement of the process and interpretation of results, miniaturization and recovery of these tracers, which is critical given their costs at present, remains an issue. Keywords: Gravity, process measurement, tracers, magnetic recovery

Jan 1, 2006

By Joo Hyun Park

A history of the research regarding the spinel in the community of the stainless steels has simply been reviewed, followed by the recent studies for the formation mechanism of the spinel in the ferritic stainless steel melts equilibrated with the highly basic slags and the crystallization behavior of spinel phase in the calcium aluminosilicate melts containing MgO and CaF2 during slow cooling cycles. It has been proposed that the content of aluminum and calcium in the steel melts as well as the basicity and the content of MgO and Al2O3 in the slags are quite important factors affecting the spinel formation in view of the formation mechanism based on the reduction of MgO (or CaO) and Al2O3 in the slags by the aluminum and silicon added to deoxidize the molten steel. The use of magnesia refractory was also recommended. The formation mechanism of spinel from the MgO inclusions readily formed in the steel melts equilibrated with the highly basic slags has newly been proposed on the basis of the ionic exchange reactions at the inclusion/metal interface and the crystal chemistry of oxides. The crystallization behavior of the spinel phase in the calcium aluminosilicate melts was enhanced by the Al2O3 based on the ionic reaction of spinel formation in the oxide melts, while the size of the spinel crystals in the oxide melts decreased by addition of CaF2.

Jan 1, 2006

By E. F. Schnitzer, D. R. Haight, G. T. Krogman

The 1997 New Year’s Day Rogue River flood near Medford, Oregon, USA, entered historic channels, eroded a 150-foot-wide buffer, and captured an inactive gravel pond located within the channel migration zone. Channel redirection caused by pit captures threatened adjacent inactive gravel ponds. In response to this capture, a stakeholders group of concerned individuals and organizations was formed. This group ultimately developed a rehabilitation plan, which conformed to the Rogue River’s geomorphic trends. A two-dimensional model, FLO-2D, was used to evaluate channel splits, flood storage, backwater, and future conditions. Modeling results coupled with trend analysis were used to create a stable design where stream barbs, gravel redistribution, a channel outfall spillway, bendway weirs, bank reshaping, and revegetation were integrated into a single plan for a three-mile reach. The quick action by the stakeholders group averted further damage to the Rogue River system and surrounding environment. The project has preserved three miles of mainstem habitat, one mile of side channel habitat, and protected ten gravel ponds from pit capture.

Jan 1, 2006

By G. A. Harrison

The introduction of extra low profile (XLP) mechanized equipment within Anglo Platinum is aligned with the overall New Mining Technologies strategy to focus on continuing modernization of our mining operations` incorporating injury-free production and cost-effective mining technologies. The method allows for the introduction of a suite of ultra-low profile equipment in narrow reef (1.2 m) stoping operations. For the first time it is now possible to achieve total trackless mechanization at these widths and indications are that XLP mining has the potential to add more value when benchmarked with conventional mining and low profile (1.8 m) room and pillar methods. Various mine layouts were tested at different sites within Anglo Platinum and the XLP breast mining layout proved to be the most effective. This paper describes the results of the trials at Waterval Shaft and concludes with recommendations on our future strategy on implementation of XLP technology within Anglo Platinum.

Jan 1, 2006

By David R. Sadedin

The highly negative Gibbs free energies of hydrogen atom reactions suggest that refractory oxides such as titanium dioxide should be easily reduced by hydrogen atoms. These reactions appear to be most favourable at low temperatures; oxides should be reducible even at room temperature. Since hydrogen atoms are produced in plasmas containing hydrogen a number of investigators have used hydrogen plasmas of various sorts to test these possibilities for reducing refractory oxides, in particular TiO2. None of these attempts has succeeded, a small degree of reduction being achieved in only a thin layer near the surface. A deeper consideration shows that several factors complicate the reactions expected on the basis of the negative Gibbs free energy. One factor is that the back reaction by water molecules produces molecular hydrogen, not hydrogen atoms, and the metal atoms that have been reduced may be immediately re-oxidised. In plasmas there are complications due to diffusion, thermal and charge boundary layers and charged particle reactions. Interpreting the results of hydrogen atom reactions is difficult. Hydrogen is not detectable by electron dispersive spectroscopy and amorphous products are not determinable by x-ray diffraction. Another consideration is economics. The cost of producing hydrogen atoms has a large bearing on the metals for which hydrogen atom reduction may be competitive. In this paper these factors are discussed, some necessary basic studies are highlighted and the general principles of a laboratory reactor are given, together with the results of tests using ZnFe2O4, ZnO and TiO2 as test oxides.

Jan 1, 2006

One of the most frequently asked questions at the feasibility study stage of a project is, æhow big can one go?Æ This important question effects costing and efficiency of metallurgical equipment, the real estate required and the operating plant strategy.The presentation covers both engineering and process considerations and explains the limits that exist today and explores future trends.The paper is specific about large slurry application usually found in gold applications; however, it could apply to silver and uranium or other dense media leach duties.Agitator drive sizes are examined as well as process risks associated with large tank agitation. New technology has increased the maximum tank size and designers are now experienced in tank volumes in excess of 5000 m3. Tanks of 6000 m3 have been agitated and 10 000 m3 tanks are within present engineering know-how and scale-up.Fabrication techniques for shaft and impeller designs exceed the existing standards and new specifications will be needed to cover large mixer design. The paper covers certain aspects of mechanical design and proposes alternative standards that are more appropriate. Process considerations such as fluid natural frequency as well as typical superficial velocities for efficient operations are examined. Scale-up techniques based on existing and new technology are also examined to ensure a successful installation.The presentation therefore covers the majority of large mixer design questions that are frequently asked.

Jan 1, 2006

By Moo Eob Choi

The reduction of iron oxide particles by hydrogen is one of the most widely investigated gas-solid reactions. The search for new methods for producing iron by the direct reduction of iron oxide has resulted in a large number of exhaustive studies of the various aspects of this reaction. However, previous studies have largely been done with either pellets or lump ores. Little has been published on the hydrogen reduction of very fine concentrate particles smaller than 37 µm (-400 mesh). The kinetics of hydrogen reduction of fine iron oxide concentrates were investigated in the temperature range of 900 - 1300°C.

Jan 1, 2006

By R Norris, M Dunne

Mining and mineral processing is expected by society and obliged by law to operate in an environmentally friendly fashion, minimising the impact on and avoiding damage to the environment. Substantial efforts by the industry, as well as by process and equipment designers have resulted in many innovative developments, which show that operating in an environmentally responsible manner can be achieved in a cost-effective way. This paper showcases five emerging equipment best practices in industry including installation examples. Flip-flow screening machines are proven worldwide in the dry classification of coal and other minerals, reducing the size of beneficiation plants whilst reducing energy, water demand and media consumption. They also allow the screening of wet/sticky materials not able to be sized using conventional screens. The belt press filter is a small fraction of the operating and capital cost of alternative dry tailings technologies. This gives operators who must dry their tailings a competitive advantage and makes such ægreenÆ operations much more sustainable. The filtercake is disposed with other plant rejects, eliminating the need for tailings dams to be constructed and thus also often increasing mine reserves. Mining applications include coal tailings, sand tailings, sinter plant waste and power station fly ash. Screen-scroll and vibrating centrifuges are widely used in the coal, potash and salt industries to dewater the product to low surface moistures. Inclined plate Lamella separators are used for toxic water clarification and/or sludge thickening in many downstream metal industries with the underflow often dewatered in a belt filter press. Such low cost, high capacity thickeners could also be used instead of conventional thickeners at smaller mines. The simple and reliable continuous washing upward flow (CWUF) sand filters have been used for treatment of waste water from coal preparation plants and steel works as well as in the worldwide production of potable water. The filtered waste water from mining processes can then either be reused or discharged from site. Other installations include cleaning mine water to prevent the blocking of dust suppression spray nozzles.

Jan 1, 2006

By Art Cooper

Granulation systems are customarily viewed as problem areas in metallurgical operations. The inherent risk of explosion when combining a high temperature melt with water creates a safety hazard. Separation of the granulated material from the quenching medium generally involves equipment that can have significant maintenance and operating costs. Granulation systems' reliability and availability can negatively affect the plant production. Against this background, granulation systems have been treated by design firms and producers as an add-on and a necessary evil. The technology is becoming better understood and solutions to common problems are being found. This paper will discuss typical problems in common systems, and some of the improvements that have been made, with particular reference to non-ferrous applications.

Jan 1, 2006

By Du Sichen

The present paper presents the modeling of gas-solid reactions in the case of the decomposition of CaCO3, describing the reaction kinetics on the basis of heat-transfer concepts which could be compared with thermogravimetric results. In the case of solid-solid reactions, the present paper describes the model developed for describing solid-solid reactions from dynamic X-ray diffraction technique, developed by the present team. The model has been successful in explaining the formation of spinel from MgO and Al2O3.

Jan 1, 2006

By O. Naiker, T. Riley

Keywords: Pyrometallurgy, furnace, Xstrata, ferrochromium, Premus Technology The presentation will give a basic overview of Xstrata Alloys. Included will be a brief history of the Alloys division as well as of each plant within the division. The Xstrata chrome plants utilise a wide variety of production processes, including Xstrata's Premus process, the Outokumpu process, and the conventional process. Xstrata?s Lion Project is underway, with commissioning expected in the third quarter of 2006. The new smelter will utilize Xstrata?s patented Premus process, and the competitiveness of the Premus process is discussed.

Jan 1, 2006

By Charlie Adcock, Rob Farnfield, Andy Wetherelt

The ISEE Blasters Handbook gives guidance on the level of air overpressure likely to cause occasional window breakage (151dB) and general window breakage (171dB). A long-term safe level of 140dB is also suggested. This guidance is widely used by demolition and other contractors to assess damage zones in the region of explosive applications employing unconfined charges. Other reference material gives more detailed guidance relating to window area, aspect ratio and glass thickness. Despite the guidance given in these references, complaints by members of the public regarding window breakage continue to be received by explosives engineers from air overpressure levels well below the longterm safe limit. Such complaints are not limited to the use of unconfined charges but can even be generated from the highly confined use of explosives in quarry blasting. This paper describes a series of experiments with explosive charges fired in unconfined conditions close to various window configurations. The aim of the work was to test the existing guidance levels and to extend the knowledge base in this area. Topics covered include the role of differential pressure across windows in the walls of an enclosed space such as a room.

Jan 1, 2006

By Joachim Lemke

The stainless steel sheets of permanent cathodes at Norddeutsche Affinerie (NA) were damaged by corrosion after nearly 11 years in operation. The necessary raising of the strength for stripping the copper had increased the deformation of the stainless steel blades. Current efficiency declined. After investigating the possibilities, like buying new cathodes or treating the steel surface, i.e. by sliding, a repair process was developed whereby the stainless steel sheet was exchanged. Special laser technology for cutting used blades und welding new stainless steel sheets underneath the used hanger bar was applied because the energy input into steel is the lowest of all welding methods. The new stainless steel sheet was welded with the rolling line in a horizontal direction. The achieved flatness of the repaired cathode blades amounted to less than 4mm per meter. During 11 months NA repaired nearly 36,000 permanent cathodes and put them back into operation. Repair costs were much lower than the costs of buying new ones and current efficiency increased again to more than 96% with a current density of 340 A/m².

Jan 1, 2006

By James F. Kvitkovich, George V. Weisdack

Editor’s note: This is the second part of a two-part series on longwall mining in the United States. Part one was published in the December 2005 issue of ME (pp. 21-26). It provided a history of longwall coal mining in the United States. It also discussed the technology involved in the productivity gains and operational improvements. Boyd anticipates that U.S. coal production will increase by 61 Mt (67 million st) (6 percent) from 2004 to 2010. A combination of higher surface and underground mine production will be required to meet the projected market demand. Boyd’s projections of coal production by major mining methods are shown in Table 1.

Jan 1, 2006