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By Masaki Imamura

A novel hydrometallurgical process for copper concentrate treatment has been developed by Niihama Research Laboratories of Sumitomo Metal Mining Co., Ltd. The process has numerous advantages with respect to the operational and environmental aspects. For example, copper is leached effectively from chalcopyrite concentrates by chlorine gas under atmospheric pressure. The copper in the leach solution is then separated from iron and silver by solvent extraction and undergoes electrowinning for its recovery as a highly pure copper metal; this does not require any further purification. Moreover, iron metal can be produced from the purified raffinate by electrowinning without generating a large volume of goethite or hematite, which are solid wastes generated due to iron rejection in common hydrometallurgical processes. This process can also realize the efficient recovery of precious metals. The results of batch testing and continuous-operation testing are presented in this paper.

Jan 1, 2006

By I. P. Giannopoulou

Flotation tailings resulted from the mineral pro-cessing of mixed sulfides ores represent the main source of the generation of acid mine drainage (AMD). These solid wastes remain un-utilized in the disposal areas (tailing dams), while for their stabilization and the immobilization of the contained heavy metals highly costly management techniques are required. In the present paper the geopolymerization of the flotation tailings resulted from copper sulfide ores dressing process is investigated, as an alternative method for their treatment aiming at immobilize the contained heavy metals and utilize the produced materials as raw materials in the construction materials industry.

Jan 1, 2006

By Xi Dai

The LiFe1-xNixPO4(x=0, 0.05, 0.10) cathode materials for Li-ion battery were synthesized with Fe1xNixC2O4?2H2O(x=0, 0.05, 0.10) as Fe sources by high temperature solid-state reaction method. The Fe1xNixC2O4?2H2O(x=0, 0.05, 0.10) materials were produced by liquid co-precipitation method and crystal structure and morphology of cathode materials were characterized by X-ray diffraction and scanning electron microscopy. The composition contents and charge-discharge performances were measured by chemistry analysis and charge-discharge apparatus. The XRD patterns showed that LiFe1-xNixPO4(x=0, 0.05, 0.10) cathode material samples were well-crystallized homogeneous olivine-type phase, with only tiny trivalent iron impurities according to chemistry analysis results. Charge-discharge test showed that cathode materials possessed excellent charge/discharge capacities, about 150mAh/g at 0.1C rate and more than 120mAh/g at 0.4C rate. The polarization of cathode in charge-discharge process can be restrained effectively, for the potential offset between oxidative peak and reductive peak of doped LiFePO4 material was only 0.079V, lower than pure LiFePO4 markedly.

Jan 1, 2006

By J Knoblauch, D, P J. J Strobos, C Foggo

The Sally Malay Project is located 120 km north of Halls Creek in the eastern Kimberley region. Since commissioning, ongoing improvements on the plant have resulted in recoveries now greatly exceeding the initial design targets. The continual optimisation endeavours of the Sally Malay metallurgy department included an automation project that was done in close collaboration with Mintek. In this team effort, several problem areas were addressed and the FloatStar advance control system was successfully commissioned to stabilise and optimise the flotation circuit. The remote location of the Kimberley Nickel Mines operation, fly-in, fly-out roster and the current mining boom makes the acquisition of experienced flotation staff difficult. The implementation of an automated flotation control system reduces this burden and contributes to the training of inexperienced staff. This paper illustrates not only the process control improvements achieved as a result of the installation of the FloatStarÖ advanced control system, but also how it has assisted operational personnel with their understanding of the process.

Jan 1, 2006

By Ch. Arvanitidis

This work concentrates on investigating the development of a geotechnical classification method for the Greek soils, which can readily provide a rough but usable estimate of the main strength parameters of the soil. It is expected that such a system will be useful to the structural engineer for either checking the laboratory results or for providing a direct estimate in cases where no tests have been conducted. The method provides strength parameter values by relating classification or physical parameters of various types of soils and/or in situ observations of geological and physiographical nature to the strength parameters, such as, cohesion, angle of internal friction, compressibility, modulus of elasticity, etc, by means of a statistical approach and the extraction of empirical formulae.

Jan 1, 2006

By D. Bouchard, M. Forté, A. Charette

A transparent replica of a casting die was built to achieve a better understanding of the filling mechanisms of aluminum in high pressure die casting. Water and tomato paste were respectively used as analogues for the Newtonian liquid aluminum and the non-Newtonian semi-solid aluminum. The transparent die was installed on an industrial casting press and filling was filmed with a high-speed camera. Differences between the Newtonian and non-Newtonian fluids are presented and discussed.

Jan 1, 2006

By N. Sauret-Szczepanski, G. Patry, S. Gauthier, G. Potvin, C. Munger

Adsorption/thermal desorption with sorbent cartridges and analytical method using gas chromatography coupled to mass spectrometry (GC/MS) was developed for the determination of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) emitted from primary aluminum smelters. A customized cartridge was built like a packed column with a stainless steel tube filled with a specific resin. The optimization of adsorption and desorption parameters was carried out to support the PFC sampling for all aluminum production technologies. The proposed method showed good linearity for concentrations ranging from 10 to 500 ppbv for CF4 and from 5 to 500 ppbv for C2F6 with correlation coefficients above 0.999. In certain conditions, the detection limits of the analytical method reached 0.3 ppbv for CF4 and 0.15 ppbv for C2F6- Using this methodology, a field campaign was carried out using a sequential sampler allowing the simultaneous sampling of PFC with cartridges and sampling bags. The results showed no significant difference (t-test) between the two sampling technologies and no breakthrough was observed from the cartridges .

Jan 1, 2006

By Robert W. Hyers

Electromagnetic levitation has proven important in a wide range of experiments, all affected by fluid flow. For some experiments such as viscosity measurements, only whether the flow is laminar or turbulent must be established. For other experiments, however, quantitative assessments of velocity, shear stress, or shear strain rate are required. In most cases it is difficult or impossible to measure the internal flow in levitated droplets directly. The samples are usually small, opaque, reactive, high-temperature, metastable, or all of these. Furthermore, recirculating flow limits the utility of tracking surface particles, since they collect in stagnation points ratherthan following the flow. Most research groups have chosen mathematical modeling to assess the internal flow in levitated droplets. A variety of analytical and numerical methods have been applied, including both laminar flow and various turbulence models. A number of these models are reviewed and their impact on different containerless experiments is assessed. Much of the research reviewed here was performed by alumni of Professor Julian Szekely, and by others using similar methods.

Jan 1, 2006

By Mark E. Schlesinger

A substantial database exists for the thermodynamic properties of many antimonide compounds, but these have rarely been compiled or critically discussed. An abbreviated version of a full?scale review of the thermodynamic properties of binary antimonide compounds is presented, focusing on the choice of experimental techniques.

Jan 1, 2006

By C. Boudreault, M. Fortier, S. Fafard

In the forging industry, the increasing trend is to use DC cast billets as forging stock to replace extruded stock. However, there is little technical information available in open literature. In order to gain a better understanding of the behaviour of cast stock during deformation, a study was initiated to evaluate the impact of an homogenisation treatment on the billet prior to cold forging. Axisymmetric upsettings of cylindrical samples machined from DC billets were achieved in order to evaluate and compare flow stresses, crack initiation and propagation. Results show a 30% decrease in flow stress after homogenisation. Observations of the deformed samples show major cracking for the as-cast material. Optical microscopy and SEM observations have related the crack initiation to decohesion around ß -AlFeSi particles and subsequent growth along the constituent path. Homogenisation effectively breaks up and transforms the ß phase, present as platelets in the cast product, into smaller spherodised a-AlFeSi particles. This has the effect of preventing crack growth in the forged product. The homogenisation treatment also resulted in the reduction of Mg and Si in solid solution. The softer matrix generated 29% less die wear when compared to the as-cast structure. Based on the results of this study, it is thus recommended to homogenise cast billets prior to cold forging.

Jan 1, 2006

By Yuhua Pan

Generic mathematical models have been developed for simulating heat transfer in two types of slag resistance heating electric furnaces for sulphide smelting: i) six-electrode-in-line rectangular furnaces and ii) three-electrode circular furnaces. The models are based on three-dimensional steady-state heat transfer of conduction, convection and radiation. Solidification of liquid slag into solid slag by water-cooling units, for use as freeze lining of furnace walls, is also considered in the models. The developed models are capable of providing predictions with reasonable accuracy for electric furnaces on 1) temperatures in slag, matte, cooling water, freeze lining and other solid regions as well as temperatures at various fluid/solid interfaces, 2) freeze lining thickness, 3) furnace smelting rate and 4) furnace heat loss rate. These computer models are built into executable application programs that are very efficient, with execution time less than one second, and can be easily portable to most computing platforms. This paper describes, as an example, the modelling results on heat transfer in six-electrode furnaces. The major modelling results show that in six-electrode furnaces uniform electric power inputs to the electrodes likely lead to low temperature regions close to slag and matte tapping ends of the furnaces, and the power input and the formation of air gaps between freeze lining and cooling units have significant influences on the thickness of freeze lining maintained by the cooling units.

Jan 1, 2006

By Garth Howlett

In 1998 the Matanuska-Susitna Borough formed the new port district at Point MacKenzie, known as Port MacKenzie, located directly across the Knik Arm from Anchorage. In 1991 PND Engineers Inc. (PND), working with the Matanuska-Susitna Borough manager and port director, envisioned a fill structure at Port MacKenzie with a 500-foot-long Open Cell? sheet-pile bulkhead face extending to EL -20 feet Mean Lower Low Water (MLLW) at the face. Now under operation the fill created 5.5 acres of tideland property using local materials for fill. The fill is protected from 2- to-3 foot-thick ice pans and 9 feet per second (fps) tidal currents by an envelope of armor rock. Construction required working in water with 30 to 40 feet of tidal variation. Construction required placement of frozen fill in water depths possibly exceeding 50 feet, creating real concerns about soil consolidation and long-term maintenance issues. A plan was prepared to consolidate the soils using Vibracompaction. Soil Density and consolidation were monitored during the work. In 2003 the port district and NPI, a wood chip export company, formalized an agreement to construct a deep water port facility at Port MacKenzie for cape-class bulk carriers. PND provided planning, studies, geotechnical investigation, design documents and construction inspection for a 500-foot-long trestle with a platform dockhead and dolphins providing 1,100 feet of dock face in EL -70 MLLW as shown in Figure 1. Design included installation of large-diameter spin-fin piles driven on a 2V:1H batter. Also included was a 300-ton tension test of smaller spin-fin piles.

Jan 1, 2006

By Ross McClelland

This paper provides a technical overview on the installation and commissioning of the Ausmelt lead smelting, slag reduction and slag cleaning operations at the HZL Chanderiya site in India. It also discusses theoretical concepts behind the process practices currently in place at HZL.

Jan 1, 2006

By L. A. Cornish, R. Süss, M. Sephton, N. B. Maledi, J. H. Potgieter, L. Chown

The gas turbine industry is faced with a challenge to improve the performance of engines, while simultaneously adhering to stringent environmental legislation. One way of addressing the problem is by further increasing the recipient working temperatures. Unfortunately, the use of nickel based superalloys (NBSAs) in the gas turbine industry has reached its limitations. Although coatings can be used for small increases, and air cooling is also incorporated by design, attention is towards developing stronger metallurgical materials having higher melting points, with acceptable creep and corrosion resistance. A series of ternary and quaternary Platinum-based superalloys were developed. Platinum was selected because of its higher melting points compared to nickel, similar fcc structure and better corrosion properties. Mechanical characterisation studies of Platinum-based superalloys alloys, which included oxidation, creep and hardness, demonstrated reasonable results, outperforming an oxide dispersed strengthening (ODS) Fe-based superalloy (PM2000) and a nickel based superalloy (MAR-M200). During any materials development where high temperatures are concerned, high strength is the primary property of interest. However, during the development of gas turbines, component life and reliability, which are influenced by temperature, need to be taken into consideration, and therefore creep as well as corrosion (both temperature dependant properties), are important. These properties become significant with increasing temperatures. With increasing demand for higher temperatures, it is becoming increasingly important to include hot corrosion properties of the alloy during the material selection process. A short description on hot corrosion and its degradation mechanisms are given in this paper. Coatings are currently dominating as the best practical solution to address temperature increases. This paper looks at benefits and shortcomings of coatings over Pt-based superalloys as candidates for applications under extreme conditions. Key words: Hot corrosion, Pt-based superalloys, Ni-based superalloys, Coatings

Jan 1, 2006

This paper gives a first-hand account of what a graduate mining engineer can learn by visiting Atlas Copco in Sweden and gives reasons why all mining engineering students should apply for this excellent scholarship. It will also (attempt to) refute the authorÆs mine managerÆs claim that the trip was a huge junket.

Jan 1, 2006

By R. D. Hagni

Introduction The ore deposits of the Viburnum Trend in the Southeast Missouri Lead District constitute the world's largest lead producing district. Six or seven mines currently are in production in the Viburnum Trend. The principal minerals are few in number, simple in composition, and form simple superposition and replacement textures. The economically valuable minerals in the typical lead-zinc ores of the Viburnum Trend are the sulfides, galena, sphalerite, chalcopyrite, and siegenite. The most abundant gangue minerals are dolomite, marcasite, pyrite, calcite, quartz, and dickite. Four concentrates, lead, zinc, copper, and cobalt are produced from the ores, and they contain an interesting suite of trace elements, of which silver and cadmium are recovered at the smelter and refinery.1 Emphasis is given here to the variations in directions of ore fluid flow based upon interpretations of the positions of orebodies due to the ore fluids being impeded by Precambrian basement relief and upon patterns of ore mineral/metal zoning. The Precambrian basement relief and Lamotte Formation pinchout has exerted an important control upon the specific locations of orebodies in the Southeast Missouri Lead District. The locations of some orebodies along one side of Precambrian knobs or ridges strongly suggests that they are positioned on the side from which the ore fluids flowed. Other orebodies are located in positions that suggest that they formed where the ore fluids passed around or between Precambrian knobs. Patterns of mineral and/or metal zoning have been used in many mineral districts to interpret the directions of ore fluid flow. The mineral/metal zoning pattern correlates closely with that of the mineral paragenesis. The earliest deposited minerals tend to be deposited nearest to the source, the later deposited minerals next closest to the source, and the latest deposited minerals furthest from the source. In the Southeast Missouri Lead District, it is interpreted here that the early-deposited copper-rich ores are closest to the source of the ore fluids, the subsequently-deposited zinc-rich ores are next closest to the source, and iron-rich ores are furthest from the source.

Jan 1, 2006

By C Adams

Reports of delays and cost blowouts in major study and construction projects are becoming increasingly prevalent in the resources industry. This is mainly being attributed to an escalating cost environment associated with the increased number of projects in the development to construction pipeline and a scarcity of competent skilled resources to deliver these projects. However, not all this effect can be directly attributed to the current environment. Historically the mining industry has not performed well in its ability to deliver projects according to the financial and physical parameters forecast in the feasibility study process. To manage the risks associated with delivery of major projects, resource companies need to ensure they use a standardised approach to management of their project development to satisfy project objectives and enable more efficient use of the increasingly limited available resources. Each discrete step in advancing the project from scoping study to operations needs to be integrated, reducing the amount of rework and duplication. This paper is primarily a consolidation of existing ideas on project management systems but also introduces new concepts to solve current issues. It describes the basic components of a typical mining project, the issues that commonly arise, the key attributes, and critical steps required for an effective integrated project management system covering projects from initial scoping studies through to project commissioning and operation. This paper focuses on technical study components of the mine development project with allowance for transitioning to design and construction and operation phases.

Jan 1, 2006

By Jiann-Yang Hwang

Hydrogen storage is a critical issue for the hydrogen economy. Current storage technologies are not able to meet the combined gravimetric, volumetric, and system cost targets set by the Department of Energy. To solve the problem, the development of a new material - perhydride ? is proposed. Perhydrides are defined as materials that contain more hydrogen atoms in their molecules than conventional hydrides do based on the valence. This concept is supported by the versatile bonding capability of hydrogen and the recent discoveries in the chemistry of hydrogen clusters.

Jan 1, 2006

By M J. Nugus

A substantial cost is invested into the data collection phase of any exploration or development program; notwithstanding, it is impractical to expect a database of information can be collated to ensure a perfect geological interpretation. The question then becomes, is there a possible alternative interpretation and what is the likely impact of the variations? Modelling in 2005, of the Cosmo lode at Sunrise Dam Gold Mine, Western Australia led to consideration of the philosophical implications associated with resource management. It was concluded that several plausible geological models could be constructed from the known geological database. To varying degrees, this predicament is common to all geological reconstructions, as several alternative geological models can be generated at almost any stage that will impact on the resultant resource estimation and mine plan. The significance of that variation and the associated risk of multiple geological models (MGMs) requires due consideration. What is being suggested is that using plausible multiple geological models advances the holistic understanding of a mineral deposit within the bounds of the data collected, providing fluidity for updating geological knowledge and building inherent variability into the design and planning departments where variations of the geological models may materially impact on the resource performance.

Jan 1, 2006

The development and distribution of gold placers in Otago û Southland is related primarily to the evolution and architecture of three distinctly different drainage networks that developed during and since Gondwana breakup: +        Late-Gondwana û Pre-marine; +        Middle Tertiary Post-marine; and +        Modern. Late Gondwana û Pre-marine drainage was dominantly recti-linear and controlled by normal faults and sedimentary basins formed before or during Gondwana breakup. Placers formed dominantly in 2nd order transverse drainages with primary sources in their catchments. This drainage network was progressively destroyed by inundation and burial by marine strata during Late Cretaceous û Middle Tertiary marine transgression that ultimately covered most of New Zealand. Middle Tertiary Post-marine drainage evolved on and incised the newly emergent low-relief landscape during regional marine regression driven by development of the present plate boundary through South Island. Most of Central Otago was drained into Southland and to the southern coast via a large braided river system with an extensive network of tributaries in its Central Otago reach. East Otago was drained by several smaller systems. Placers formed dominantly in proximal and medial reaches of 1st and 2nd order drainages with primary or pre-existing placers in their catchments. This drainage network was destroyed by inundation and burial of the Central Otago reach of the major system by lacustrine strata following tectonic damning of its middle reach by range uplift and development of a lake complex that covered >5000km2 of Central Otago. The Modern drainage network evolved from the Middle Tertiary network through complex response, firstly to uplift of NW-trending and NE-trending ranges throughout the region since the Late Miocene, and secondly to the effects of major Pleistocene glacial advances in West Otago. Placers formed in alluvial fans at range margins, proximal and medial pre-glacial fluvial systems and glacial outwash sequences. Evolution of each of these drainage networks has been accompanied by widespread sedimentary recycling of alluvial gold from older to younger placers, augmented locally by input of first-cycle gold derived from erosion of primary sources in the repeatedly exhumed basement rocks.

Jan 1, 2006