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By Eustathios S. Kikkinides

This work presents an integrated approach for the optimal design and control of hydrogen storage beds. A detailed 2-D mathematical model is developed for metal hydride beds and validated against experimental and theoretical literature results. Based on recent advances in dynamic optimization, the model is used to find the optimal process design and operating strategy in order to minimize the storing time, while satisfying, a number of operating constraints (such as pressure drop limitations, cooling fluid availability and maximum tank temperature). Trade-offs between various objectives, alternative design options and optimal cooling control policies are revealed illustrating the potential of the approach. In a further step the model is used to exploit the benefits between material and process design. Systematic simulation and optimization studies are performed at two different length scales (tank and adsorbent pore level) for carbon based materials. The macroscopic approach determines the optimal values of the sorption parameters while, based on these results molecular simulation techniques are employed to determine the pore size distribution of the adsorbents.

Jan 1, 2006

By J. Defreyne

CESL has developed a proprietary hydrometallurgical process for base metal concentrates, notably those of copper and nickel. The process is based on pressure oxidation (PO) of the sulphide minerals, which is done at elevated temperatures in mixed sulphate-chloride liquor at about pH 2 ? 3. The process achieves maximum oxidation of the metals whilst minimizing sulphur oxidation to sulphate. Almost all base metal sulphide minerals are efficiently treated under these conditions. In the case of copper minerals, pressure oxidation does not generally put the copper into solution, because of the relatively high pH prevailing in this process. Therefore, PO is followed by an acidic leaching stage, which specifically aims at maximum copper dissolution with minimal leaching of iron. The overall copper recovery is largely determined by the efficiency of this stage. The process has low capital and operating costs, partly because there is minimal use of acid or neutralizing agents for iron dissolution or precipitation, respectively; this is achieved by minimizing iron leaching during both the oxidation and leaching stages. Iron sulphides in the feed concentrate deport almost entirely to the solid leach residue as hematite, which has superior handling characteristics for filtering and washing. Iron minerals play a key role in the process, with pyrrhotite and pyrite having very different responses to the oxidation process. Acid management for the whole process is affected by the iron mineralogy, and the flowsheet is therefore tuned to the specific concentrate.

Jan 1, 2006

A three?stages countercurrent fluidized bed prototipe reactor to neutralize the SO2from smelter gases has been developed. For gases with 8 vol-%SO2, at 800°C and for 4 h mean reaction time of the limestone, the capture of SO2 is 99%, with off gases with 0.07 vol-%. For 2 vol-%SO2, the total capture of SO2 can be obtained at 750°C and 4 h reaction time. The calcine obtained contain a blend of unreacted limestone and calcium sulphatewith minor amounts of residual lime.

Jan 1, 2006

By D. Moraetis

The present study examines the nutrients and micronutrients availability of uncultivated soils originated from different parent rocks. The study areas include four types of parent rocks with different geological origin, from acidic to ultramafic. The parent rock mineralogy and the nutrients available in soils are in strong relation-ship. Mineralogy, particle size distribution and chemical composition of the soil samples were studied jointly with the nutrient content of soil solution. High magnesium availability in soils of Anogia area is related with the alteration products of the ultramafic rocks. Potassium content of the soils exhibits no relation with the geology of the area. Micronutrients, iron and manganese, shows strong dependence to the bulk chemistry and mineralogy of the parent rock material. In contrast no interrelation detected between zinc and copper availability in soil and parent material.

Jan 1, 2006

By Robert Hopler

Earthquakes, ground vibrations, seisms, or whatever you want to call the shaking of the earth, have been a fact of life throughout time. In spite of this, most people (except those unfortunate enough to live in seismicallyactive areas) have probably never felt this phenomenon, or if they have, only a very few times in their entire lifetime. However, when it does happen, nothing is more frightening than the sudden shaking of the earth beneath us - after all, we think of the ground we walk on as the unyielding, solid underpinning of our existence.

Jan 1, 2006

By Z. Kowalski

Landfilling of waste causes the degradation of natural environment, not only due to land occupation, but also due to pollution of air, water and soil. The flotation waste from zinc-lead industry also poses such problem. There is a need to find the way to utilise substantial amount of these wastes and backfilling seems to be a good solution. Recently, in Poland only sand was used for backfilling. However, it will be more beneficial to substitute the sand with the industrial solid waste, especially flotation waste. The tests were performed in the laboratory to examine the use of flotation waste as a main ingredient for backfilling. The use of flotation waste is possible only when it is combined with other waste with specific bonding properties, especially regarding the prevention of leakage. The outcome of tests shows that flotation waste combined with cement and fly ashes can be used as a backfilling material. This paper presents the preparation of flotation waste for using it for backfilling.

Jan 1, 2006

By R. Poulin, M. R. Samis

Real options valuation is an alternative net present value framework that is able to incorporate both management flexibility and dynamic project risks. In this paper, management is considering the development of a satellite low-grade zone while operations in a developed high-grade zone continue. If the lowgrade zone is developed prior to high-grade zone exhaustion, mine capacity must be expanded before additional production from the low-grade zone can be processed. This expansion can be avoided only if low-grade zone development is delayed until the high-grade zone is exhausted. The real option model presented here allows the development and capacity expansion decisions to be reconsidered on a discrete half-year basis. It delineates price regions, for given levels of high-grade zone reserves, in which it is optimal to develop the low-grade zone, defer low-grade zone development and abandon the mine irrevocably.

Jan 1, 2006

By D. Triantis

This paper presents the results of laboratory experiments for the detection of electric signals from Fiber Reinforced Polymer (FRP) sheet samples which have undergone a temporally increasing loading of bending type up to fracture. Electric signals that were recorded while the sample was subjected to bending are referred from now on as Bending Stimulated Currents (BSC), in order to differentiate them from the relevant signals emitted by materials that suffer uniaxial compressional stress. The latter signals are referenced as Pressure Stimulated Currents (PSC). BSC emitted from FRP sheet samples presented here, were recorded after applying three successive load steps to samples. The increase rate of applied stress was about 0.15kN/s. Initially starting from low load values to higher load values until the FRP sheet reaches at a state just before its failure. The BSC records from FRP samples are compared to equivalent recordings from cement mortar beam and distinguishable differences are discussed.

Jan 1, 2006

By Oliver Zach

To know as much as possible about the condition of the refractory material (lining thickness, slag layer, build ups, ...) in an high temperature furnace is very important due to the safety and economic impacts. The new CONSCAN system offers the possibility to measure the inner surface of an furnace, and based on this results to calculate the thickness of the refractory lining, slag layer, build ups,.... The CONSCAN System provides this results as figures and graphics. This system is also working under hot conditions so it is not necessary to cool down the furnace. Based on these results the process control and the refractory lining concept could be optimized for maximum campaign life of the furnace.

Jan 1, 2006

By A. Fahr, T. Byczkowski, M. Genest, C. Mandache

"Layered aluminum structures assembled with rivets are often found in aircraft fuselage. These structures are exposed to various mechanical loads and a range of environmental conditions that contribute to their ""aging"". The rivet holes are the source of stress concentrations and the location of crack nucleation and growth. Detection and sizing of second and third layer cracks under fasteners represent a major challenge for non-destructive evaluation (NDE) technicians. Electromagnetic methods are currently the most feasible NDE techniques that are capable of successfully inspecting such structures. However, different probe lift-offs, due to protruding rivets and paint coatings, or interlayer separations, due to sealant or air gaps, pose difficulties in detecting and sizing cracks. In addition, the use of conventional eddy current technique is limited due to the inverse relationship between the probe spatial resolution and its field penetrability. In this paper, we present an alternative approach that overcomes the previously mentioned shortcomings by using pulsed eddy current excitation and magnetoresistive sensor pick-up. Various signal manipulations are employed for defect detection and quantification."

Jan 1, 2006

By L. Cornish, P. A. Olubambi, J. H. Potgieter

Four 22%Cr series duplex stainless steels alloys containing varying nickel contents of approximately 5, 7, 9 and 13% were melted in a vacuum induction furnace, hot rolled, solution annealed and water quenched. Their corrosion behaviour was investigated in sulphuric acid and sodium chloride solutions using a potentiodynamic polarization technique. Increasing nickel contents have appreciable influence on their corrosion behaviour. Polarization curves show similarities in the uniform corrosion behaviour of the alloys in the solutions and a significant difference in their pitting behaviour in chloride environments. Alloy 2209 generally exhibited highest resistance to uniform corrosion while 2213 displayed distinct and best pitting corrosion resistance. Their corrosion behaviour were attributed to the influence of nickel on phase modification, microstructural refinement, and the probably types of films formed in different environments. Keywords: Duplex stainless steel; Nickel; Microstructure; Phase modification; Corrosion

Jan 1, 2006

By C. Kasatuka

Globalization creates investment opportunities for enterprises around the world. Attracting foreign investment has been a key challenge for economic growth in developing countries. Corruption, political instability, armed conflict, and other internal problems affect foreign direct investment (FDI) inflows negatively. A framework of criteria provides a basis for comparing non-commercial risk (NCR) among twenty-three mineral economies. Countries competing for foreign direct investment inflows are ranked from least to most risky. This study compares Inward FDI Performance Index (IND) with NCR ratings in developing countries and shows that risk is increasingly mitigated by means of appropriately structured insurance. Given the option for countries with similar mineral potential, investors will generally invest in the country that offers lower non-commercial risk. Keywords: foreign direct investment, non-commercial risk, developing countries.

Jan 1, 2006

By Marshall Khan

The Goodfellow Expert Furnace System Optimization Process (Goodfellow EFSOP?) is a proprietary process that uses real-time and continuous off-gas analysis, along with process monitoring to optimize the operation of electric arc furnaces (EAF) for steelmaking. With the exception of off-gas composition, dynamic process measurements within the EAF are not possible due to the harsh operating environment. The Goodfellow EFSOP? system provides a dynamic indication of the operating conditions within the EAF. Continuous measurement of furnace off-gas composition, along with other furnace operating parameters is used to elucidate the fate of chemical energy usage within the EAF including: the evolution of carbon from the molten steel bath; the in-leakage of air into the furnace; the extent of combustion above the molten steel bath and the occurrence of dangerous water-leaks from the furnace cooling system. The ability to measure the process reliably and continuously enables Techint Goodfellow Technologies Inc (TGTI) to implement dynamic process control of combustion within the electric arc furnace and to optimize the overall operation through adjustments to the EAF process based on off-gas measurement. This paper discusses the methodology and results achieved from several recent Goodfellow EFSOP? installations in South East Asia.

Jan 1, 2006

By J Parmenter

Issues around water û its quality, use, availability and environmental value û can be a major point of tension between mineral projects and local communities. Failure to manage these issues appropriately can jeopardise the obtaining of regulatory approvals for new projects and place at risk the æsocial licence to operateÆ of existing operations. Conversely, there may also be significant opportunities for companies to engage constructively with communities over water issues and to make a positive contribution to the sustainable development of these communities. Using case studies, this paper will explore the various types of social risks and opportunities associated with water and mineral resource development and identify key learnings relating to the management of these issues.

Jan 1, 2006

By Russell Frith

For many years, underground rock mechanics and in particular, roadway/tunnel roof stability has been underpinned by the often unchallenged assumption that roof strength (as defined by the UCS) and stiffness (E) are key stability controls. This has logically led to the proliferation of laboratory testing of rock specimens and the development of indirect geophysical methods to gain estimates of these two rock parameters. Furthermore, many design methods are significantly focussed on replicating rock mass behaviour through either intact or failed constitutive models. Demonstrably the strength and stiffness of the host rock material is commonly used as one of the key indicators of excavation roof stability and it finds either direct or indirect use in just about every rock mass rating system in use today. In more recent times there has been a common move to consider and apply (even if only conceptually at the current time) structural engineering type principles (e.g. buckling) to coal mine roadway roof (and rib) stability. Similarly our knowledge of the in situ stress environment and its likely origins has improved significantly, largely through stress measurements and subsequent analysis. This paper combines knowledge in both of these fundamental areas through a deterministic model for roadway roof stability and in combination with field examples, reaches the almost certainly controversial conclusion that UCS and E are commonly irrelevant, albeit that the former may provide an indication of other relevant geotechnical parameters (e.g. bedding cohesion). As with all hypotheses or rules, there are naturally exceptions and in this case, the most obvious is the tailgate of the longwall panel (with adjacent goaf). Due to the significant change in the strata loading environment of a longwall tailgate as compared to first workings for example, the stability equation materially changes so that UCS and E become critical controls. The point of the paper is to present a different perspective on a traditional mining problem and to challenge geotechnical professionals to keep thinking ?outside of the square? in the never-ending endeavour to improve our understanding of the engineering problems we regularly face. Such an understanding impacts upon such issues as geotechnical data collection from borecore, support hardware requirements and design capabilities. Therefore making the assumption that our understanding is always fundamentally correct could in fact be limiting the development of new and improved engineering in the future.

Jan 1, 2006

By A Jha, R Merz

The substantial growth in world demand for Queensland coking coal has seen a number of new coal mine developments in the Bowen Basin in recent times. The Bowen-Broken Water Supply Scheme (BBWSS) is presently based on water supplied from Eungella Dam and storages at Collinsville to two major pipelines. In early 2004, three successive years of well-below average rainfall had left Eungella Dam at critical levels, threatening the regionÆs mines, which rely on it for their essential water supply. SunWater noted that without significant inflows into Eungella Dam, or the development of a new water supply to the region, existing mines would be severely restricted in water supply, and downstream economic impacts to the region would follow. SunWater investigated the opportunities for additional supply capabilities, including combinations of off-stream storages, additional pipelines, and raising Eungella Dam. An off-stream storage (OSS) was selected as being the preferred option to improve the reliability of the system and head off impending falls in announced allocation for the system. The integrated quantity quality model (IQQM) is the Queensland GovernmentÆs preferred model to define and assess total catchment performance against water security and environmental objectives. Modelling of the performance of the water supply system, with and without the proposed OSS, was required to provide justification to the customers of the system that the OSS was in fact required, and also to optimise the configuration of the OSS within time and budgetary constraints. In the case of the BBWSS, no environmental base flows are dictated by the Department of Natural Resources, Mines and Water (NRM&W) at present and the primary reason for applying IQQM was therefore to investigate the trade-offs between supply options and reliability. SunWater produced IQQM outputs for a range of scenarios for the proposed off-stream storage, and these IQQM outputs were then used as input to a decision-support tool based on the GoldSim modelling package. The GoldSim model was then applied to investigate the water supply reliability for high priority users resulting from various existing and/or proposed water supply infrastructure configurations coupled to the hydrologic system. The GoldSim model included the ability to assess the long-term water supply reliability impacts for each of the water supply end-users for a wide range of user-defined scenarios. Non-technical model users were able to change the size of the off-stream storage, pipeline capacities and assumed climatic conditions and test for themselves the relative benefits (in terms of water supply reliability) of different infrastructure configurations under consideration. The decision tool was of significant benefit in assisting the decision process to SunWaterÆs mining customers. These customers needed to decide if they felt that the increased reliability in their water supplies from the system that would be created warranted the estimated increased charges that would require to be levied to recover costs of the new infrastructure with appropriate profit margins. The conjunctive use of IQQM and GoldSim was successful in demonstrating the impact of both hydrological and non-hydrological issues on the future water supply reliability in the BBWSS and resulted in a decision to proceed with the construction of a new OSS.

Jan 1, 2006

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale (MD/FE) method has been used to study dislocation generation and plastic deformation during a nanoindentation process which is physically associated with the generation of heat within the specimen and as a consequence with a temperature rise. Two different techniques are applied to study the temperature effect on the nanoindention process. In the first technique, a global Nose-Hoover thermostat is applied to the entire atomistic region to keep temperature constant during simulation (finite temperature approach). In the second method, the thermostat is applied only on a damping region along the MD/FE interface. Both techniques are able to effectively and efficiently absorb high frequency reflected waves from atomistic/continuum interface. The temperature profile of the atomistic region beneath the indenter is reported and discussed at four different initial substrate temperatures for both techniques. The loaddisplacement (load/unload) curves for different temperature-controlling techniques are compared and discussed. The nucleation and propagation of dislocations in the atomistic region are investigated for both techniques. Correlations between the observed features in the load-displacement curves with the motion and pile-up of dislocations are reported as a function of temperature.

Jan 1, 2006

By Kazuya Koyama

We are studying the hydrometallurgical recycling process of indium from an Indium-Tin-Oxide(ITO) target. For this process, it is necessary to remove Sn(IV) ions from the aqueous hydrochloric acid solutions containing In(III). In this study, the removal of Sn(IV) ions by a potentiostatic electrolysis method was examined. The polarization measurements and potentiostatic electrolyses were carried out under a nitrogen atmosphere. In the Sn(IV) solution, current begins to rise at the cathode potential of -0.26 V vs. SHE, and increases with a reduction in the cathode potential. In the In(III) solution, current begins to rise at a cathode potential of -0.43 V vs. SHE. Metallic tin was electrodeposited without indium electrodeposition at the cathode potentials of -0.30 and -0.40V vs. SHE. More than 98% of the Sn(IV) was removed at the cathode potential of -0.40 V after the electrolysis for 3hrs. Both tin and indium were electrodeposited at the cathode potential of -0.50V vs. SHE.

Jan 1, 2006

By Francis Vanbellen

Umicore Precious Metals Refining operates an integrated precious metals smelting and refining plant in Hoboken, Belgium. Once a smelter and refiner of complex concentrates, the plant today?s feed consists exclusively of industrial and consumer recycled products, making it the world?s largest recycling facility for precious metals. Unlike the fairy tale of the Frog Prince, it took much more than a princess? kiss to successfully realize this makeover. A completely renewed plant has been built over the past decade. The most visible technological innovation was the commissioning of the Pb-Cu smelter. Its flexibility towards very different types of feed makes it perfectly suited as main entry to the Hoboken flow sheet. A new Cu-leaching & electro winning plant and precious metals refinery make up the Precious Metals Operations (PMO) whose targets are fast throughput and maximized yields for gold, silver and the platinum group metals. The Base Metals Operations (BMO), flexibly process the by-products from the PMO, valorizing ?impurities? like indium, tellurium, selenium and others. Off gas and waste water treatments ensure compliance with strict environmental standards. Precious metals recycling is an art that goes beyond mastering a unique flow sheet. Umicore Precious Metals Refining offers a complete recycling service, taking care of sampling and assaying, metals management and logistics. The quality of this integral service is recognized through the attribution of ISO certifications for our operational activities, sampling and the environmental care. And it?s an art that follows Michelangelo?s experience: ?Art is 5% of inspiration and 95% of transpiration.?

Jan 1, 2006

By D. C. Oldroyd

Western Coalfield?s Tandsi Mine, has difficult support conditions and a history of roof falls, resulting in mining roadway widths and depths being restricted for safety reasons. Rock Mechanics Technology Ltd was contracted to improve the support system to allow the introduction of mechanised room and pillar mining. The introduction of a ?world best practice? bolting system resulted in major improvement in roof stability, allowing mining restrictions to be lifted and Tandsi to become one of the first two Indian mines to introduce a mechanised continuous miner system. The first year?s production was some six times previous levels. Because of the improvement in the support system, RMT was also able to design a partial de-pillaring system suitable for the Tandsi continuous miner districts together with the introduction of monitoring procedures and guidelines to maintain safe roof support conditions. In situ monitoring of pillar and roof behaviour was undertaken as the first pillars were extracted to confirm the design. De-pillaring operations have also proved highly productive, and to date there has been no associated support related major injury or dangerous occurrence. The success of this project demonstrates the potential for mechanised room and pillar mining in India.

Jan 1, 2006