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By Xiaorong Liu

Interfacial emulsion generated in copper solvent extraction is an inhomogeneous O/W emulsion that consists of organic phase, aqueous phase and solid particles. In order to determine what kind of components in organic phase promotes the emulsion, the organic phase separated from the interfacial crud provided by Dexing Copper Mine in Jiangxi, China was analyzed for its components by combined gas chromatography-mass spectroscopy. It was found that many kinds of emphiphiles containing such hydrophilic groups as carbonyl, carboxyl, or acylamine existed in organic phase, most of which were originated from the reagent degradation. Conclusively, Lix984N would degrade gradually during a long-term contact with the acidic aqueous feed and strip reagents. Lix84 and nonylphenol, as effective components of Lix984N, degraded almost completely after long-term recycling. As a result, the effective components of Lix984N were far lower in concentration than the dense-aromatic impurities derived from the diluent and the degradation products in total. The degradation of Lix984N would deteriorate solvent extraction, disengagement performance and result in more serious interfacial emulsion.

Jan 1, 2006

By J C. Macintosh

Capcoal Mine has modified its water use practices over the past 15 years. Two issues have changed the way water was managed:an economic review of water supply options for a planned expansion of the coal handling and preparation plant (CHPP) in the early 1990s, and increasing neighbour concerns about discharge of worked water from the mine into the local streams. These issues resulted in commitment by the site General Manager to cease discharge of worked water from site and to convert from using raw water to worked water in the CHPP. Operational needs, societal demands and continuing dry weather are again demanding change to the siteÆs water management strategy. This paper outlines the drivers for past and future operational change.

Jan 1, 2006

By Z. Kowalski

In the non-operational ?Górka? quarry, there are situated both a waste disposal site of an area of 6.7 ha, containing approximately 1 million ton wastes from high aluminium content materials (incl. about 400000 t of wastes from aluminum hydroxide production), and a pond of an area of roughly 3 ha, up to 15 m deep, with about 400000 m3 of polluted water and infiltrates from the disposal site mentioned. The basic problem related to the effluents in the Górka pond is both their high alkalinity (pH 12-13.4) and a variable analysis of pollutants whose level increases appreciably with the pond?s depth. The solution offered provides, first of all, remedial pumping and a treatment of effluents retained in the Górka reservoir. Effluents would be treated in a reverse osmosis plant according to a process verified so far on a quarter-commercial scale. The treatment process by-product, a brine solution (containing about 25% NaCl) whose amount may reach up to 100000 m3 might be supplied to the Debiensko Mine, which produces technological salt from salt-bearing mine waters. In parallel, an intake of underflows of infiltrates would be provided (previous geochemical identification) in order to take them away from the high aluminum site (by means of deep wells, and possibly girdling ditches). Such effluents would be subject to treatment. The successive stage is the utilization of approx. 50000 m3 of bottom slurry, left in the emptied reservoir, in the production of self-solidifying mixtures, which would be then used for sealing the bottom and the banks of the Górka reservoir. The empty and sealed reservoir would be filled up with a volume of approx. 600000 t of ashes, coming from coal burning in the thermal-electric power station. For the last stage, instead, is scheduled the rehabilitation of the entire waste disposal site in the Górka quarry. The site will be drained, covered with a leveling, sealing and rehabilitating layer, which will allow to introduce plants on the rehabilitated waste site. Later on, the area could be turned into a town park

Jan 1, 2006

By I. Yarita

Magnesium alloys have the lowest density among the metals in practical use, and have properties such high specific strength, electromagnetic interference shielding and good vibration damping. Thus, there are many applications of these materials in automotive and electric parts. However, there is a little use of the products of metal forming of these materials because of poor plastic deformability in the normal temperature range and their high cost of production. To expand the range of application of products manufactured by metal forming, rolling technology for producing thin sheets having good mechanical and surface qualities is required. In this study, hot-rolled Mg-alloy sheets are experimentally rolled with or without lubrication in the temperature range from 293 K to 523 K. Rolling force, plastic deformability and surface quality are investigated, and the grain structures and their uniformity are observed. The effect of friction between the roll and the deforming material on the uniformity of the grain structure is discussed. Moreover, rolled materials are annealed and their mechanical properties are investigated by the tensile test and compared with those of as-rolled materials. The effects of the rolling conditions on the mechanical properties are discussed.

Jan 1, 2006

By D Clarke, R Simpson

The Main lode in the Anwia Gold deposit is difficult to interpret due partly to the fact that three separate grid and drill hole orientations exist over the area and partly due to a lack of understanding of the controls on the high-grade mineralisation. Scattered high gold grades and multiple veining orientations add to the confusion. Sectional interpretations of the lode are often misleading due to the multiple orientations of drilling. Initial attempts to define a high-grade constrained geological model were not successful due to the inability to establish any geological continuity that would hold together in three dimensions. As a consequence the initial geostatistical domaining for the Main lode at Anwia comprised a simple broad mineralised envelope split by the weathering profiles. Subsequently an analysis correlating subjective qualitative logging information with grade plus utilisation of LeapfrogTM software, together with extensive geological re-interpretation resulted in the definition of a coherent high-grade shoot within the Main lode. The resource was re-estimated including this new domain as a high-grade hard boundary. Estimations on both models were carried out using uniform conditioning, which is a recoverable resource estimation methodology that estimates tonnages and metal above a series of cut-offs for SMU (selective mining unit) sized blocks. This paper compares the tonnages and metal contents that are calculated from the two estimation runs, both at a zero cut-off and a series of higher cut-offs. The results confirm that the estimation methodology has been implemented correctly as the tonnage and metal content at zero cut-off is the same for both models. The resource tabulations and grade tonnage curves predicted by the two models highlight the differences that can occur at higher cut-offs when realistic high-grade domaining is implemented. The results also reinforce the point that recoverable resource models are intended to address selectivity issues and are not substitutes for good geological modelling. Recoverable resource techniques, such as uniform conditioning, will not correctly estimate high-grade zones that have not been explicitly modelled.

Jan 1, 2006

By Chen Yongming

In order to eliminate the serious environmental pollution caused by low concentration of sulfur dioxide smoke in antimony smelters, a new smelting process, named as reducing-matting smelting, is proposed in this paper. The effects of technical conditions such as smelting temperature, smelting time, Pyrite cinder addition and the amount of additive on the smelting of stibnite concentrate have been investigated by the method of single-factor experiment. The results show that the optimum conditions are as follow: The amount of pyrite cinder is 1.2 times of its theoretical amount. The addition of soda and sodium sulfate is 15% and 72.6%, respectively, to the amount of stibnite concentrate when the total amount of sodium is 30%. The reducing-matting smelting is conducted at 1100°C for 2h then the smelting temperature is raised to 1200°C for 50min. Under the optimum conditions, the direct and total recovery ratio of antimony can gain 90.99% and 98.87%, respectively, and the fixed ratio of sulfur is higher than 99%.

Jan 1, 2006

By Chai Li-yuan

The anodic behavior of AZ31 magnesium alloy in NaOH alkaline solution was investigated in this paper. The effects of anodizing parameters, such as applied current density, concentration of NaOH and temperature of the solution on the formation, structure and surface morphology of the anodic films were also studied. The formation of the anodic film was analyzed by analyzing the anodic polarization curves, the potential-time curves and XRD, SEM graphs of samples obtained at different anodizing time. The results of corrosion resistance tests, XRD and SEM observation showed that the temperature greatly affected the formation and anti-corrosion property of the anodic film, but the concentration of NaOH not. The film with best anti-corrosion resistance was obtained at applied current density of 10mA/cm2, 353k in 1mol/l NaOH solution.

Jan 1, 2006

By John P. Davis

The use of conventional, circulatory air rotary and fluid rotary, cased and uncased drilling methods in the vicinity of sensitive infrastructure can have deleterious effects on the ground conditions surrounding and supporting structures and the structure itself. Furthermore, the use of these conventional methods offers the engineer or contractor little information about the condition of the subsurface during geotechnical applications. Conversely, sonic drilling measurements and samples can be used to evaluate actual conditions during the progress of exploration and construction across a given site. This paper will discuss the history and properties of sonic drilling and explore case histories of geotechnical applications for the advancement of boreholes within vulnerable structures and on sensitive sites for several recent infrastructure projects ? a tunnel and railroad project, a dam grout curtain project, a bridge micropile exploration project and a tunnel instrumentation project. Project summaries will discuss the advantages realized when the application of sonic drilling techniques demonstrated superior accuracy, quality control, efficiency, productivity, penetrability, waste minimization and adaptability when drilling adjacent to or within existing infrastructure. Finally, the discussion will address the current testing and application of sonic drilling to the installation of micropiles, earth retention anchors, grout injection and instrumentation installation where the quality control benefits provided by the inherent soil cores, measurement while drilling systems, accuracy and non-destructive production drilling features will be advantageous.

Jan 1, 2006

By S. Kamado

Development of new SF6 alternative cover gas with low global warming potential is strongly desired for melting and casting of magnesium alloys. We have tried to apply several kinds of HFC and HFE gases with low potential from 30 to 950 as protection gases to AZ91D alloy melt in the temperature range of 650 to 800°C. As a result, protective film consisted of MgF2 and MgO is formed on the melt surface and ignition-proof effect is sufficiently obtained at all the temperature ranges even when flow rates of mixed gases containing CO2 as a carrier gas are almost the same as those using SF6 gas. Reduction of global warming potential exceeds 98% at 650°C and 89% at 800°C in comparison with a mixed gas of CO2 and SF6.

Jan 1, 2006

By Fatma Arslan

The lateritic nickel ore sample subjected to this experimental study was taken from Çalda ore deposit (Turkey) and contains 1.43% Ni and 0.105% Co. Mineralogical investigations showed that the ore sample contains asbolane, chromite, limonite, hematite, goethite, lepidocrocite, magnetite, serpentine, and clay type minerals together with chalcedon, quartz, calcite, and chlorite. In the acidic leaching experiments, the effects of temperature, acid (H2SO4) concentration, and leaching time on nickel leaching recoveries were investigated. Leaching recovery versus time curves showed a parabolic trend and increasing the temperature shifted that curves to the higher values. The dissolution of nickel from lateritic ore can be explained by a shrinking core model and the apparent activation energy was found as 47.34 kJ/mol in the range given by the literature. The highest Ni and Co leaching efficiencies as 90.2% and 96.8% respectively were obtained at 80°C temperature, 200 g/L H2SO4 concentration, and 8 hours of leaching time.

Jan 1, 2006

By L. A. Cornish, S. N. Prins, R. Süss

The work is being done using the Thermo-CalcTM software, and the database is being built up by obtaining good thermodynamic descriptions of all of the possible phases in the system. The database supplied did not cover all of the phases, and these had to be gleaned from literature, or modelled using experimental data. Similarly, not all of the experimental data were known, and where there were gaps or inconsistencies, experiments had to be undertaken. A preliminary version of the database was constructed from assessed thermodynamic data-sets for the binary systems only. The binary descriptions were combined allowing extrapolation into the ternary systems, and experimental phase equilibrium data were compared with calculated results. Very good agreement was obtained for the Pt-Al-Ru and Pt-Cr-Ru systems, which was encouraging and confirmed that the higher-order systems could be calculated from the binary systems with confidence. Since some of the phase models in databases were different, these phases had to be remodelled. However, more work is ongoing for information concerning the ternary phases present in the Al-Cr-Ru, Pt-Al-Ru (two ternary compounds in each) and Pt-Al-Cr (possibly more than three ternary compounds) systems. At later stage of the work, problems with the thermodynamic descriptions of the Cr-Ru and Pt-Cr binary systems were found. A programme of experimental work to overcome these has been devised, and is being undertaken. Keywords: Pt-based alloys, phase diagram calculations.

Jan 1, 2006

By John M. Rapkoch

In the continuing search for copper matte converting methods, commercially available and feasible choices remain Peirce-Smith Converters, Hoboken Converters, Mitsubishi Converting, Ausmelt converting, and Outokumpu/Kennecott Solid Matte Oxygen Converting (?Flash Converting?). While each alternative improves on Peirce-Smith Converters? limited fugitive gas capturing capability, the Peirce-Smith Converter is relatively easy and economic to operate and has an unmatched ability to accept valuable but difficult-to-handle material such as scrap anodes and purchased scrap copper. Recent experience with designing, building, and starting up an ISASMELT facility, applied in primary smelting of copper concentrates, has led the authors to speculate on how suitable the ISASMELT process would be for copper converting, given its low fugitive gas release and its ability to accept a variety of feed types. This paper reviews the potential metallurgical challenges posed by converting copper matte in an ISASMELT vessel and considers possible engineering and design challenges posed by the inclusion of this technology into a new or refurbished copper smelter.

Jan 1, 2006

By R. M. Lamya

The leaching behaviour of nickel?copper matte in an acidic?copper sulphate solution during the repulping stage at Impala Platinum Refineries has been studied. The base metal recovery process consists of a matte repulping stage prior to a series of pressure leach stages. Therefore, the repulping stage is basically an atmospheric leach stage in which the matte containing mostly Niand Cu is leached in copper-spent electrolyte from the tank house, resulting in dissolution of nickel and precipitation of almost all the copper. To understand the nature of the leaching process during this stage of the operation, the effects of temperature stirring rate and matte particle size on the rate and extent of base metal dissolution and copper rejection from the solution have been investigated. The leaching mechanism of the matte in the investigated system is alsoproposed.

Jan 1, 2006

By L Chaffey, M Buckland

The minerals industry has enormous potential to positively contribute to sustainable development and many leading companies have concluded that their long-term success is directly linked to their ability to leave a lasting positive legacy. While there are many examples of success, there have been failures as well and much work has been done in recent years to define the role of the minerals industry in sustainable development and identify the key elements for success. In the past, our sector could point to the taxes and royalties it paid, the exports it generated and employment it created and felt confident that its contribution would be recognised and duly acknowledged. This is no longer the case. Critics of the industry have highlighted resource-rich countries that have failed to capitalise on their resource wealth and have arguably lower standards of living than their resource-poor peers û the æresource curseÆ hypothesis. Recent research has done much to clarify the factors that contribute to a countryÆs success or failure and all stakeholders in the industry now need to include these learnings in their approaches going forward. We know that our long-term success relies on embedding a company- wide approach to sustainable development into all aspects of our business operations. In this paper we highlight BHP BillitonÆs experience in the development and implementation of policies and systems designed to enhance our contribution to sustainable development. We detail the business drivers for excellence in this area and the key external codes and initiatives that have shaped our approach. The values-based BHP Billiton Charter, Sustainable Development Policy and associated Health, Safety, Environment and Community (HSEC) Management Standards are central to our approach. Implementation is reviewed through our HSEC audit program. One area in which we have placed particular emphasis is our approach to community development. BHP Billiton has a corporate target to contribute one per cent of its pre-tax profit on a three year rolling average to voluntary community programs. As our profit stream has increased with the minerals boom this is approaching an A$100 million commitment. In our paper we detail how we are working to ensure we maximise the value of this contribution for our communities and our shareholders.

Jan 1, 2006

By K. L. C. Gonçalves, V. K. Alves

"CVRD’s Department of Development and Technology – GETEK has been developing and perfecting a general methodology for scaling up flotation and grinding circuits over several years. This methodology has been applied in several prospective CVRD mining projects. It encompasses a procedure for variability analysis based on bench scale tests, pilot scale grinding and flotation tests and modeling and simulation for scaling up the industrial flowsheet.The bench scale tests include the determination of the Work Index, simplified DWT tests, rougher flotation and locked-cycle tests with samples that are representative of the ore body variability. After completion of these studies, continuous, pilot-scale flotation tests are carried out at a Mini Pilot Plant with drill core samples representative of different stages of the mine life. Finally, studies are carried out with large volume samples using a conventional grinding and flotation pilot plant. This sample is also used for liberation characterization, grinding kinetics, flotation kinetics and industrial circuit scale up. This methodology has been successfully employed in the development of CVRD’s new mining projectINTRODUCTIONCVRD has been developing and perfecting a general methodology for scaling up flotation and grinding circuits over several years. The definition of the processing route and the sizing and scale up of the processing system are some of the products generated during the pre-feasibility of a greenfield project. This paper is focused on the scale up of grinding and flotation circuits, operations known to be of the most importance in a mineral processing plant.The methodology for the definition of the flotation and grinding circuits is divided in the following stages: bench scale ore variability studies, pilot plant operation and modeling followed by simulation. The product of this work is a calibrated simulator that can be utilized for plant operation as well as mine planning, looking to achieve optimal operational conditions.The current models used for scale up of the grinding circuits are aimed at the generating information about the size distribution of the circuit product. However, it is well known that the liberation state of these products may be of critical importance for the performance of the concentration processes downstream. Nevertheless, CVRD has been developing a methodology for liberation kinetics during grinding, aimed at optimizing grinding circuit throughput together with downstream flotation recovery."

Jan 1, 2006

By Fernando Guevara

Many smelting and slag-cleaning furnaces operate with cooling systems designed to freeze a slag layer over the refractory to protect it. The fluid flow and heat transfer conditions associated with the freeze layer and mushy zones are poorly understood. These phenomena were simulated with a small-scale room temperature, 2-dimensional model, using an aqueous solution of calcium chloride to simulate the slag. Reasonable similarity with conditions encountered with copper and nickel smelting systems was achieved (Pr 50 and Ra 108, in the laminar-turbulent transition). Measurements of the freeze layer development and velocities were made with the Particle Image Velocimetry (PIV) technique. Direct Numerical Simulations (DNS) were also made of the unsteady fluid flow and heat transfer problem. It was found that the solidification process is well described using an improved model for high molecular viscosity in the mushy zone. Solid front growth, isothermal profiles, velocity profiles and heat transfer through the walls showed good agreement between the PIV and DNS results. Experimental and numerical velocity profiles close to the freeze layer show a parabolic behaviour in the vertical velocity profile which is completely different from the calculation of heat transfer using a sharp interface model. The reason for this is attributed to the effects of the mushy zone with a high viscosity and high shear stresses acting on that area.

Jan 1, 2006

By Ken Dyck Sr.

"Construction of the Cigar Lake uranium mine in northern Saskatchewan is well under way. Production is anticipated to begin in the first half of 2007. When in full production, the mine is projected to produce a net 18,000,000 pounds of U3O8 per annum from a high grade ore averaging approximately 20% U3O8.Water management was a major issue that required substantial effort in the Cigar Lake design. Not only is effluent quality controlled, a tight water balance to minimize effluent volume is also designed into processes in order to minimize environmental impact. This paper focuses on the water treatment process and water handling equipment, as well as the operating philosophies that will reduce fresh water consumption to a minimum. An overview of the mining and ore handling systems, as well as aspects of controlling water production from the ore formation and the mine development areas will also be discussed.INTRODUCTIONThe Cigar Lake ore body has proven and probable reserves that total 232 million pounds U3O8. Cigar Lake is the world’s largest undeveloped high-grade deposit. It is the second largest highgrade deposit surpassed only by the McArthur River deposit another Cameco - operated mine in the Saskatchewan Athabasca Basin. Cigar Lake is owned 50% by Cameco Corporation, 37% by AREVA (COGEMA Resources Inc.), 8% by Idemitsu Uranium Exploration Canada Ltd. and 5% by TEPCO Resources Inc. When production starts in 2007, ground ore slurry from Cigar Lake will be shipped to the McClean Lake mill (owned by AREVA) some 80 km away. All of the Cigar Lake uranium will be leached from the ore at McClean Lake. During initial production ramp up, all uranium will be processed at McClean Lake to yellow cake (uranium oxide). After the average production has exceeded a 10 million pound per year rate, Cigar Lake uranium will begin to flow from the McClean Lake Mill to the Rabbit Lake Mill. At this point, subject to regulatory approval, 57% of the Cigar Lake uranium, in a uranium rich solution, will be transported to Rabbit Lake mill (owned by Cameco) for purification to yellow cake. A complete summary of the flow of uranium from the Cigar Lake ore body through to product at both McClean Lake and Rabbit Lake can be found in a recent paper titled “The Cigar Lake Project – Mining, Ore Handling and Milling” in the March 2004 issue of the CIM Bulletin. The paper was written by C.R. Edwards."

Jan 1, 2006

By Sergio N. Monteiro

Polymeric composites reinforced with natural fibers are increasingly been used in several engineering applications, from automotive parts to building construction elements. In addition to the relatively low cost, the natural fibers are also appraised by their renewable and biodegradable characteristics. Fibers extracted from the crust of coconut fruits, also known as coir fibers have been investigated for a possible use in composite materials. In the present work, the coirfiber/polyester matrix interfacial strength was evaluated by means of pullout tests. The variation of the pullout tensile stress vs. the embedded coir fiber length permitted to determine the critical fiber length and, thus, to calculate the interfacial strength. Observations by SEM complemented the results from pullout tests, indicating that coir fibers have a potential for application aspolymeric composites that could replace conventional materials such as wooden and gypsumpanels.

Jan 1, 2006

By G. Velarde

This paper presents the metallurgical results of column and stockpile leach tests with forced aeration to determine the usefulness of this process in the operational leaching at Sociedad Minera Cerro Verde S.A.A. The evolution of the aeration system is presented and also an innovative solution developed to overcome forced aeration’s main problem, which is the early obstruction of the aeration pipes located at the base of the stockpile, causing a decrease in air and oxygen levels and therefore a reduction in the metallurgical benefits.

Jan 1, 2006

By F. Azgomi

A possible way to characterize (classify) frothers using gas holdup as a surrogate for bubble size was explored. Nine surfactants with a range in chemical structures were selected and tested in a bubble column instrumented to measure gas holdup and superficial gas velocity. A correlation between frother type and gas holdup was observed: for alcohols, gas holdup increases with hydrocarbon chain length and the effect is the same whether the chain is branched or straight; for polyglycols, gas holdup increased with number of propoxy groups. The ranking by gas holdup gave the same result as other frother characterization techniques.

Jan 1, 2006