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By A. M. A. Mohamed, F. H. Samuel, S. Valtierra, H. W. Doty, A. M. Samuel

"The influence of Fe, Mn, Cu and Mg alloying additions, Sr modification and grain refinement on the microstructure of as-cast and solution heat-treated Al-10.8% Si alloys was investigated using optical microscopy and EPMA techniques. The results showed that the modification effect of Sr diminished with increasing Cu and Mg additions, due to Sr-Cu-Mg interactions. Strontium caused segregation of AlzCu in areas away from eutectic Si regions, and altered the precipitation sequence of the a-Ah5(Fe,Mn)3Siz iron intermetallic from post-dendritic to pre-dendritic, with the phase observed within the a-Al dendrites. Depending upon the alloy Fe and Mn content, a coarser variation (""sludge"") of the a-Fe phase occurred, in the form of polyhedral shaped particles. The AhCu phase dissolved almost completely during solution heat treatment, while Al5Cu2Mg8Si6, sludge, and a-Aln(Fe,Mn)3Siz phases persisted in all alloys, particularly at high Mg and Fe levels. The f3-Al5(Fe,Mn)Si phase dissolved partially in Sr-modified alloys, the dissolution becoming more pronounced after solution heat treatment."

Jan 1, 2006

By John D. Kinton

A patent is a right granted by the government to exclude others from making, using, selling, offering to sell, or importing a claimed invention. Once the right is granted, the patentee may use the U.S. Federal Courts to enforce that right. Reading a patent from a litigation perspective is quite different than reading it from a technical perspective. The Judge's interpretation of the claims will affect their scope, and likely the ultimate outcome of a patent case. Additionally, the patent right can be challenged. If done successfully, the patent can be rendered invalid or unenforceable. The likelihood of success, and well as the achievement of other litigation goals is often influenced by the forum where the litigation is initiated. Finally, patent litigation costs are significant, and will weigh heavily in the decision to file (or fight) a patent lawsuit.

Jan 1, 2006

By Kalathur S. Narasimhan

Powder metallurgy is a net shape process competing favorably with machining, stamping, forging and castings. The growth of ferrous powder metallurgy over the past four decades reflect the advancements in materials technology, compaction technology, sintering technologies and other related fields. This presentation gives a brief background on how materials technology evolved.

Jan 1, 2006

By Mike Onsager

Jan 1, 2006

The current boom in the mining sector has required mining operations to ramp up production to meet the international demand for minerals. This increase in production is putting enormous pressure on on-site professionals, and in particular the role of the on-site geotechnical engineer is ballooning. Mining engineers are focused on machinery and schedules; geologists concentrate on grade control and resources; everything else becomes the responsibility of the geotechnical engineer. Day to day geotechnical engineering is very different from geotechnical design work, and a practical understanding of both is required to successfully carry out either role. In addition, a successful geotechnical engineer has to have a good understanding of almost all technical aspects of mining. Even more important are good communications skills and the ability to problem solve on the fly. None of these skills are taught at tertiary institutions and therefore need to be learnt in the workplace. However, the shortage of geotechnical professionals means that young engineers do not always receive the mentorship and training they need to develop confidence and technical effectiveness. This paper outlines the changing role of on-site geotechnical engineers and presents some thoughts on how industry and young engineers can adjust to the changes.

Jan 1, 2006

Coal mining ceased at Strongman Mine this year after 70 years of production. Underground mining finished in 2003 and opencast methods began in 1998. During the life of the mine, 8 million tonnes of coal was extracted from two underground mines and 1.2 million tonnes removed through opencast methods. Strongman Mine is within the Grey Coal Fields; various seams have been extracted from the Rewanui Coal Measures. Coal extracted was predominantly of thermal or semi-soft specifications and characterised by low sulphur and low ash.   The area has steep topography, high rainfall (>3000 mm/yr) and is particularly exposed to westerly quarter winds. Strongman 1 and 2 underground mines are located in the steep, narrow valley which leads to the Strongman Opencast at the top of the valley. Subsidence from underground mining combined with spontaneous combustion, has resulted in an underground fire which has had substantial surface effects. Opencast mining in the steep topography resulted in several landslides at the perimeters of the site. These factors, along with water management, topsoil management and erosion control have added to the complexity of rehabilitating the site.   Rehabilitation of the site is well underway, including infrastructure removal, final landform creation and revegetation of the Strongman Opencast footprint (~45 hectares). Some innovative methods of rehabilitation have been trialled. Successful trials such as helicopter-seeding and moss hydro-seeding on highwalls are now routinely used along with traditional revegetation practices. 18 hectares disturbed land has been replanted with 88 000 seedlings, and another 200 000 seedlings are scheduled for planting over the three years. Fire management is an ongoing challenge; however thermal photography shows a steady decrease in hot areas which have been contained by grout curtains.   Mine closure is some time away and will occur after all standards set by Solid Energy and regulatory bodies are achieved.

Jan 1, 2006

This paper presents the development of a knowledge based integrated decision support system (E.X.I.S) for the extractive industries to provide information concerning the environmental impact of extractive operations on land quality, surface and ground waters, and the best solutions for the rehabilitation/revegetation of the waste disposal areas to the relevant target groups (extractive industries, regional authorities, national authorities, research institutes, public). GIS was integrated with the decision-making models for the rehabilitation and revegetation of mine spoil. The system design involves several steps including site selection ? mine type identification ? waste identification ? selection of rehabilitation (revegetation or other methods). The knowledge based model consists of two integral parts: the model base, in which the input data are processed and classified using special fuzzy algorithms and criteria and the knowledge model, which hosts the various decision algorithms concerning evaluation of vegetation covers, selection of trees and plant species, selection of rehabilitation and revegetation schemes and also economic analysis for each option. The system input will include parameters on site characteristics (climate, topography, geology, hydrology etc), waste type and properties (physical-geotechnical and geochemical data) as well as environmental parameters of the existing waste disposal area. Based on the values of the above parameters and the characteristics of the rehabilitation technologies developed worldwide, the system, using IF-THEN rules will define a list of appropriate techniques for the rehabilitation of the examined waste. Then, the model will involve the application of multi-criteria analysis (MCA), i.e. a structured system for ranking alternatives and making selections and decisions. Each technique shall be judged based on its behavior into four fields, i.e. financial, social, technical and environmental criteria. In turn these fields will be analyzed into a lower level of evaluation criteria.

Jan 1, 2006

By Ray Y. Lin

This study explores the formation of sodium pyrosulfate in molten sodium sulfate resulting from dissolution of SO3 at temperatures between 1160 and 1250 K. Solubility of SO3 in Na2SO4 melts at temperatures between 1160 and 1250 K under gas mixtures of SO2, O2 and argon was investigated applying a thermogravemetric analysis (TGA) technique. The activity of Na2O in the melt was determined with a high temperature electrochemical cell (ECC). Results showed that the SO3 solubility in molten Na2SO4 increases with decreasing temperatures and increasing SO3 partial pressures. Enthalpy of SO3 dissolution in molten Na2SO4 was calculated to be -119 kJ/mol for infinite dilute solutions. Thermochemistry of Na2SO4-Na2S2O7 melts was analyzed based on information obtained from both TGA and ECC techniques. Detailed examinations of the earlier low temperature measurements in the Na2SO4-Na2S2O7 system along with data from this study reveal that the solution behavior between Na2SO4 and Na2S2O7 can be satisfactorily treated as regular with the interaction parameter, , being 2.7 kJ/mol. The phase diagram and the field of SO3 partial pressure has been generated with the thermodynamic calculation using a regular solution approach.

Jan 1, 2006

By Alexey Lozhko

The technical-and-economic furnace exploitation indices are considerably influenced by the system of heat utilization. In the situation of total output decrease works are forced to exploit furnaces at the partial loading, sometimes even at the idle running for the sake of steam production. The furnace exploitation in this regeme is known to cause the increase of the heat portion, taken away together with waste flue gases. The losses can be partially compensated at the expense of heat exchange efficiency development in the recuperator or heat-exchanger. One of the well-known methods, characterised by high efficiency and low expenditures is the intencification of the heat exchange process by the means of pulsation method.

Jan 1, 2006

By John W. Lund

The Geo-Heat Center has been investigating the utilization of waste silica from the Cerro Prieto geothermal field for several years. The main objectives of the research were to com-bine silica with various additives to (1) form bricks for low cost housing, and (2) to produce a suitable road surfacing material. The various additives that were tested included hydrated lime, portland cement, plastic fibers, asphalt cement and emulsified asphalt. The silica-cement combination produced the strongest bricks and had the best weather resistance, whereas, the silica-lime combination produced the bricks with the lowest thermal conductivity and specific gravity density. The addition of plastic fibers to the silica-lime mixture improved both strength and weather resistance. The combination of asphalt and silica is not suitable as a road surfacing material, however, silica-cement appears promising.

Jan 1, 2006

The Daly-Judge Tunnel, begun in 1887 to drain mine workings, is now a source of potable water for the Municipality of Park City. The water is exceptionally clean; however, when roof falls occur, suspended solids levels become too high and water from the tunnel cannot be used in the treatment plant. In 2001, the tunnel was inspected and rehabilitated to ensure that the water supply for the 2002 Winter Olympic Games would be uninterrupted. Twenty-five timber tunnel sets were removed, and 86 steel sets were installed. Timber lagging was installed or replaced over about 230 m (750 ft) of tunnel length.

Jan 1, 2006

By Toshiki Kabutomori

In fuel cell powered automobiles, hydrogen is required to be stored in materials that have a hydrogen storage density of over 4 mass%; further, these materials should be capable of supplying hydrogen by using the waste heat from a fuel cell, which is at a temperature of 373 K, in order to match the mileage of gasoline-powered vehicles. A Ti-Cr-V alloy, which exhibits a BCC structure and forms a solid solution, is a promising candidate for onboard hydrogen storage materials. Although it has a large hydrogen storage capacity of over 3.9 mass%, the rechargeable hydrogen capacity is limited to approximately 2.6 mass%. In this study, the effects of fine pulverization of the alloy on PCT (hydrogen pressure-composition-isotherm) characteristics were investigated in order to improve the rechargeable hydrogen storage capacity of the alloy. From the PCT measurements of the finely pulverized samples of the alloy, a plateau in the absorption curve was observed to begin at a hydrogen concentration of 0.5 mass%; further, a rechargeable hydrogen storage capacity of 3.3 mass% was obtained. This was greater than that obtained from the sample that was not finely pulverized, i.e., 2.5 mass%. However, the plateau width in the desorption curve was 2.5 mass%, which was the same as that observed for the sample that was not finely pulverized. The increase in the rechargeable hydrogen capacity during absorption is attributed to the precipitation of the -hydride phase (MH~2) directly from the metal phase (phase). The precipitation of the phase (MH~0.5), which should be formed in low hydrogen concentrations, is suppressed as a result of a possible reduction in the internal defects such as dislocations, vacancies, and grain boundaries by fine pulverization and annealing of the alloy.

Jan 1, 2006

By R. G. Cawthorn

The earliest authenticated scientific report of the occurrence of platinum in rocks from the Bushveld Complex appears to be by William Bettel on 10th November 1906. Thereafter, prospecting of the chromite-rich rocks for platinum proved frustrating. I suggest that the resurgence of interest shown by Dr Hans Merensky in 1924 resulted from his realization that newly-panned platinum had a different grain size from that in the chromite layers and indicated a different source rock, which he located and it became known as the Merensky Reef.

Jan 1, 2006

By C. Vasilescu

Phytotechnologies use plants to remediate various media impacted with different types of contaminants. These technologies can be implemented either in situ or ex situ. The affected media in which phytotechnologies can be applied include soil, sediments, groundwater and surface water. They are best applied at sites with shallow contamination of organic, nutrient, or metal pollutants that are amenable to one of five treatment options: phytoextraction, phytotrans-formation, rhizosphere, bioremediation, phyto-stabilization or rhizofiltration. Phytoremediation can be used along or, in some cases, in place of mechanical cleanup methods. Phytoremediation can be used to clean up metals, pesticides, solvents, explosives, crude oil, polycyclic aromatic hydrocarbons and landfill leachates.

Jan 1, 2006

By K. Narayana Swamy

The traditional approach to improving the operating efficiency of a metallurgical plant has been to study individual unit operations and focus on improving the poor-performing unit operations. The complex nature of most metallurgical plants call for a holistic approach that will consider the whole rather than just focus on the individual units of a plant. This holistic approach is part of the systems thinking principles. Numerous case studies highlight the importance of the need to apply systems thinking principles in improving the effectiveness of metallurgical operations. Improving the efficiency of one unit operation without considering its effect on the performance of other unit operations has in many cases lead to lower overall operational efficiency. Modeling and simulation are key to the application of the systems thinking principles. Standard flowsheet models are very useful in scenario analyses though they have to be supplemented with other models for useful predictions.

Jan 1, 2006

By Ana Bohé

Nowadays, Gas-solid processes are widely used in the industry. The chloration and carbochlorination of metallic compounds are some of this kind of non catalitic heterogeneous reactions. In particular those related with extractive metallurgy of refractory elements (Zr, Ti, Nb, Ta, RE, etc). The development of materials to be used in reactors at elevated temperatures and with high corrosion performance, enhance the application of this kind of processes. Although they are currently carried out in the production of many comodities, the mechanism of most of them are yet not well understood. The present work is a deep discussion on the most important aspects to take into account for determining the mechanism of gas- solid reaction, and those criteria fulfil in this analysis were applied to chlorination and carbochlorination examples. The microstructural characteristic of solids, the mass and heat transfer phenomenon, the adsorption and desorption of gaseous species on active surface, surface diffusion processes and chemical elementary steps, which are the mainly contributions to the mechanism of these reactions were analysed. Furthermore, the effect of them on the reactivity of solids and the control step of the reactions were determined. The application of catalitic mathematical models to this kind of reaction and the modification for the better interpretation of experimental results is also undertaken. The most appropriate experimental procedures for following these reactions and the microstructural characterization techniques needed to be use in each case, there limits and applicability are also indicated.

Jan 1, 2006

By H. Somekawa

The fracture toughness and deformation structures an AZ31 magnesium alloy processed by equal-channel-angular extrusion (ECAE) were investigated. The average grain sizes of as-ECAE and annealed-ECAE alloys were 4.0 and 16.3 µm, respectively. The plane-strain fracture toughness, Kip, in as-ECAE and annealed-ECAE were estimated to be 27.3 and 23.5 MPam1/2, respectively, by stretched zone analysis. The fracture toughness indicated higher value with grain refinement. From optical microstructural observations in samples after fracture toughness tests, although deformation twins were observed in annealed-ECAE, no deformation twins were observed in as-ECAE. From TEM observations, the dislocations on basal and non-basal planes were activated in as-ECAE. With grain refinement, the activations of dislocations on both basal and non-basal planes were possibly related to the reduction in formation of deformation twins in as-ECAE. In addition, in comparison with direct extruded process, ECAE process was more effective method to improve the fracture toughness in magnesium alloys.

Jan 1, 2006

By P. M. Wiltcher

The construction of a deep structural slurry wall in a restricted city centre location is always a challenging prospect. However, when the city is London and the site is bounded on two sides by high level canals and a main traffic highway on the third, the challenges are greater than usual. The paper discusses the design considerations required by the principal contractor to accommodate a single high level lateral support, value-engineered, bottom-up construction technique and the impact this had on the design detailing and construction of the slurry wall panels. This paper discusses the logistical challenges successfully overcome during the construction of 65,000sq ft of 40inch thick, 80ft deep structural slurry wall in the City of London. The paper reviews the benefits gained from using the state-of-the-art hydraulic grab and rotator system. Technological advances in computer instrumentation and real time monitoring were utilised to assist the grab operators in consistently delivering deviational control during excavation better than 1:200. With working space always at a premium on construction sites, the need for high quality, pre-fabricated reinforcement cages has never been greater. This paper reviews the argument for off-site fabrication of reinforcement members.

Jan 1, 2006

By Ron Harper

Jan 1, 2006

By H Lehtonen, H Mansikkaviita

In primary copper smelters, the received copper concentrate and other materials contain a certain amount of moisture, ranging from six to 14 per cent. Moisture in wet concentrate has a negative effect on the performance of the smelting furnaces when it is fed directly to the furnaces, namely increasing the energy consumption and the off-gas flow. There are several drying technologies available for drying copper concentrate, varying from direct heated rotary dryers and flash dryers to indirect heated steam dryers. Application of steam dryers has changed the drying process for copper smelters. Produced from a waste heat boiler, steam as heating medium enables plant-wide heat utilisation. Fossil fuel used from outside sources to remove water is no longer required and the combustion chamber is not required. In addition special attention has been paid to overcome the known problems of pollution emissions, excessive wear, clogging and frequent maintenance. The Kumera steam dryer is featured with many advantages based on principal improvements in reducing tube element wear and increasing drying efficiency. Thus, it has been considered as the first choice for those smelters where steam is available.

Jan 1, 2006