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By John Watson

Overview: Intro and Product Use Trends ?? Packaged Explosives ?? Bulk Explosives ?? Initiation Systems – Conventional Initiation Systems – Electronic Detonators ??Q&A

Jan 1, 2006

By Song Ning

The main mineral constituents of phase-transformed chalcopyrite are CuS and FeS2. CuS is more soluble than FeS2 in an acidic CuCl2 solution with presence of excessive NaCl, so that FeS2 could be removed as solid residue from a leached solution. The experimental results showed that the efficiency of the copper leaching is heavily determined by the following two factors: a) The degree of the chalcopyrite phase transformation to CuS and FeS2 b)The concentration of Cl during the leaching, specifically whether there is enough excessive Cl existed. I t was found that when the Cl in the solution is not excessive, the slowest step of the leaching is the dissolution of Cu2Cl2.

Jan 1, 2006

By Thomas Passlick

By means of further developed machines and techniques and with growing experiences in jet grouting, the challenge of this building method becomes more and more complex. To keep the concerning risks as low as possible, the requirements on the quality assurance continuously in­crease. The construction of a 37.0m deep seated slab for the Amsterdam metro station Vijzelgracht in marine clay represents such a complex task. This paper summarises the required measures of quality assurance. In particular a new hydraulic measuring device is introduced with which it was possible to detect the column diameter of 2.6m at a depth of 37.0m during the production process and with a very high accuracy.

Jan 1, 2006

By A. A. Shirzadi, E. R. Wallach

"Liquid gallium has been used successfully to modify/remove the surface oxides prior to diffusion bonding similar and dissimilar nickel-base superalloys. Using this approach, bonds in nickel-base superalloys with ""virtually invisible interfaces"" were produced, and the compositions in the bond region were very close to those of the bulk alloys. Room temperature tensile and bend tests showed no preferentially failure at the bond lines. Creep tests on samples made between two different Inconel alloys also showed failure away from the joint, i.e. in the parent metal of the Inconel alloy with lower creep resistance. The high temperature lifetimes of these samples were as long as those of the unbounded Inconel, confirming that the joining approach has no adverse effect on the nickel-base superalloys being joined."

Jan 1, 2006

By H. Agnerian

"A survey of 925 mineral property transactions worldwide was carried out between 1987 and 2004. These mineral properties with reported Mineral Resources include 457 gold properties, 322 base metal properties, and five platinum group element (PGE) properties. Based on constant Canadian dollars, the results of the survey indicate that:• In general, unit metal values in the ground (e.g. $/oz Au or $/lb Cu) have kept pace with the changes in the respective metal prices during the period of the survey.• A general decrease in unit gold values in the ground has occurred from about $57/oz Au in 1987 to about $11/oz Au in 2002 for Canadian mineral properties, with the exception of a peak of $58/oz Au in 1996.• A similar trend for mineral properties has occurred in the United States, but with lower unit values, in the range from $1/oz Au to $10/oz Au during the last three years of the survey. • Unit metal values in the ground for gold properties in Canada were higher than for those in the rest of the world.• Unit metal values in the ground for copper properties in Canada were in the mid-range compared with other countries in the rest of the world; the United States and Australia were higher and Latin America, Asia, Africa, and Europe were lower than in Canada.• Unit metal values in the ground for zinc properties in Canada were also in the mid-range compared with other countries in the rest of the world; Latin America and Europe were higher and the United States, Australia, and Asia were lower than in Canada.• Unit metal values for nickel properties in Canada were highest compared with other countries in the rest of the world, followed by the United States, Australia, Africa, and Asia.• Gold values in the ground in Canada have ranged from 6% to 14% (with an average of approximately 10%) of the gold price.• The unit values of base metals in the ground have been in the order of 2% of the quoted metal price, during the period of the survey."

Jan 1, 2006

By D Craw

Oceana Gold as part of their environmental strategy are looking at various methods for cost-effective revegetation of their tailings dams. Under the concept of revegetating the tailings this study looked at several issues. These issues were; testing different methods of revegetation, arsenic (As) uptake in vegetation with respect to capping thickness, and background As levels in farmland areas above mineralised rocks. A number of plots were set up in a temporarily disused tailings dam to trial the direct sowing of ryecorn into the tailings.   Ryecorn was sown in sandy tailings (ca 1000 mg/kg As) and then covered with oxidised schist to anchor the seeds. This proved successful and ryecorn was established. Once the plots covered with oxidised schist were growing, 1 m and 2 m strips were sown on the sheltered side of the existing plots without the covering of oxidised schist. The uncovered plots also established successfully. From this set of trials a sowing plan can be developed that uses a minimum of resources to successfully establish vegetation. The maximum As content of the ryecorn was 80 mg/kg. Clover, Yorkshire fog and ryegrass plant matter was sampled from a pot trial that used different thicknesses of topsoil covering tailings material. As the thickness of topsoil increased, the amount of As taken up decreased. Soil samples were taken from farmland areas which were known to have elevated levels of As (up to 1000 mg/kg) in the top 10 cm. Vegetation samples were also taken from the same locations, and show the As levels in plants is <50 mg/kg.

Jan 1, 2006

By O. Leuangthong, E. Schnetzler

"The McMurray formation in the Athabasca oil sands deposits of northern Alberta is part of the world’s second largest proven crude oil reserves. The formation is characterized by stratigraphic layers that correspond to three different depositional environments: Marine, Estuarine, and Fluvial facies. Resource estimation for oil sands has traditionally relied on polygonal and inverse distance schemes. These techniques are simple and straightforward in practice, but they do not permit reliable uncertainty assessment. This paper describes the modelling of the McMurray formation using modern geostatistical techniques.Geostatistical modelling should be performed within homogeneous geological facies. The methodology for geostatistical simulation within each of the identified facies involves: 1) assessing the most appropriate stratigraphic transformation for optimization of the correlation structure; 2) determining representative distributions with declustering and debiasing techniques; 3) modelling spatial continuity of the bitumen grade, fines grade, water saturation, and other petrophysical variables; 4) performing estimation and cross validation as checks against simulation results; 5) performing simulation for uncertainty quantification of bitumen and fines grade; and 6) model checking of simulation results against the input data, and comparisons against the kriged models. These steps are described in detail. The application of these models for uncertainty quantification in support of resource classification is also discussed."

Jan 1, 2006

By H. Rosenberg

Haldor Topsoe A/S has developed its WSA technology to meet the demand in the market for a simple and reliable process that converts sulphurous emissions from off-gasses into high-grade sulphuric acid. With more than 50 references in 25 countries, the WSA technology has proven its ability to generate acid at 98% concentration, efficiently and economically. The wet gas sulphuric acid (WSA) technology treats the furnace off-gas directly from upstream gas cleaning plants. No further drying is required, since the humidity present in the off-gas is used to hydrate the SO3generated in the converter and produce sulphuric acid. The heat generated during the oxidation, hydration and condensation processes is principally reused in the process to preheat the off-gas to the required temperature level, and also to generate high pressure superheated steam for process use. This advantage of steam production, coupled with lower water and power consumption requirements, is particularly important in the African production environment. Having fewer process components than conventional acid plants, the WSA technology is a simple and compact operation, which makes it easier to retrofit into an existing smelter plant. Further, the WSA technology simultaneously offers the possibility to treat multiple gas streams arising within the production facility due to superior flexibility in terms of SO2concentration and turndown ratio.

Jan 1, 2006

By M Kuruppu

Large mining operations require a high percentage of the capital invested in mobile and fixed mining machinery. From an investment point of view this expenditure must be met by an equally high rate of return, thus the need for high plant and equipment reliability is of major importance. Equipment downtime is undesirable and very costly, resulting in lost production and revenue, which is of critical importance to successful mining operations. One of the solutions to this problem may be found in the form of competent computerised maintenance management software systems, which help to reduce the problem of breakdowns. These software assist the engineers for the management of service orders, resource allocation, progress monitoring as well as costing. They also facilitate the communication of targets and objectives among the service personnel. A computerised maintenance management software called MAINPAC was used to record and plan the activities of mobile equipment maintenance in a large mining operation in Western Australia. Among the details recorded were equipment data, service history, machine downtimes, previous maintenance, job planning and the resource required. This information further helped to analyse the maintenance efficiency, availability and the reliability of the equipment.

Jan 1, 2006

By J. Nowak

Polish power industry is based on brown and hard coal combustion and transferring the heat into electric power. Over 99% of lignite is used as a fuel in power plants. Lignite is mined on in open pits. Therefore very deep (for example 300 m in Belchatow open pit) excavations having great volume are formed. Thus such type of mining has the impact on land degradation. In order to reduce this effect, at the earliest possible moment the cap rocks are dumped in the pit but at the safe distance from the mining face. Due to the big amounts of lignite delivered to the power plant, there are shortages of solids for filling the pit after completing the mining operations. Geotechnical properties of dumped combustion by-products depend on the lignite type, combustion technology and ashes haulage methods. The paper presents lignite combustion methods used in Poland and their impact on properties of ashes and methods of their transport determining the parameters of dumped wastes. Geotechnical, physical and chemical test results concerning transport and deposition of hydraulically active ashes from the Belchatów power plant are presented. The critical role of geotechnical properties in selecting the deposition technology and post mining management of open pit excavations was showed. The importance of filling the post-mining spaces for restoration the useful function of brown fields and for neutralization of negative effects of mining activity, was underlined.

Jan 1, 2006

By O. Y. Ntrama

Lebowa Platinum Mines has been in operation since the late 1960s and is a relatively small producer compared to Anglo Platinum?s other operations. The mine has never had substantial capital investment to expand its production scale even though its resource base is estimated in excess of 100 years at current mining rates. It is forecast that the mine will become unprofitable after 2008 due to the workings of the ageing infrastructure, the Merensky Reef operations being further from the shafts, decrease in productivity and increase in operating costs. In order to reverse the forecast decline in operational inefficiencies and profitability the replacement of the Merensky Reef operations at Vertical and UM2 shafts with the development of a 120 Ktpm Brakfontein Merensky Reef Mines is in progress. This paper covers the operational readiness framework developed from the control budget estimate and outlines an integrated business process adopted to ensure that the requirements of the investment proposal are met. The operational readiness framework, which addresses the transition process, will ensure that at operational start-up, all appropriate operating systems, procedures, information and legal requirements are in place, whereas the business integration process will aim to develop and sustain an organization with the appropriate infrastructure and workforce equipped with the necessary skills to meet Brakfontein?s requirement, and where possible embark on an optimized accelerated production initiative to ensure that the objectives of the investment proposal are sustained. Keywords: operational readiness, business integration, optimized accelerated production initiative, organizational development.

Jan 1, 2006

By Gi-Chun Han

This study focused on stabilization of heavy metals and removal of chlorine in MSWI bottom ash by artificial carbonation with washing. Artificial carbonation was carried out by applying CO2(g) injection in washing for fractions above and below 4mesh for reuse as construction materials like aggregate, As a result, carbonation with washing could satisfy Korean environmental regulation and remove chlorine in bottom ash more effectively by resolving residual friedel?s salt(3CaOAl2O3CaCl210H2O).

Jan 1, 2006

By Daojin Cao

Aiming at many controversial reports on Raman spectral pattern of octamolybdate ion in aqueous solution appearing in the literature, a new method for the establishment of corresponding relation between Raman spectral pattern and chemical components of aqueous molybdate solution was put forward using spectroscopy measure and component analyses of saturated solution of ammonium octamolybdate hydrate known structure. It was found that the main characteristic of Raman spectral pattern of the saturated solution was described as the same ?double-peaks, hereinto a weak peak at the boundary? as some literature, but chemical components of the saturated solution were affirmed to be octamolybdate ion (Mo8O264-) and double protonated heptamolybdate ion (H2Mo7O244-), which were in equilibrium in aqueous solution each other. The authors propose that the pattern of the saturated solution can be regarded as the standard pattern of primiparous octamolybdate ion during acidified molybdate solution. It is satisfying that the standard pattern is applied to the identification of primiparous octamolybdate ion during acidified molybdate solution.

Jan 1, 2006

By M. Stoica

Bioremediation is a complex process which involves mass transfer, chemical and biochemical phenomena. In particular, the adsorption kinetics of a substance by biomass may by model by taking into account: - Enzymatic kinetics type; - Combined kinetics - enzymatic kinetics at the same time with the Monod type biomass growth; - Chemical kinetics for substance adsorption according to Freundlich and Langmuir ad-sorption isotherms; - New empirical kinetics models based on experimental data. In this paper modelling of kinetics of bivalent lead ions on live vegetal biomass (aquatic plant Pistia stratiotes) as well as of hydrocarbons on dead vegetal biomass (pyrolysed nuts) is studied (Stoica, 2004). Modelling was carried out using experimental data and relative equations with an error of 5%.

Jan 1, 2006

By E. F. Schnitzer, C. Lidstone, D. Cramer, P. J. Wampler

The River Island mining site is located at approximately river mile (RM) 15 on the Clackamas River, a large gravel-bed river in northwest Oregon. During major flooding in February 1996, rapid channel change occurred. The natural process of meander cutoff, slowed for several years by dike construction, was accelerated by erosion into gravel extraction ponds on the inside of a meander bend during the flood. In a matter of hours, the river cut off a meander and began flowing through a series of gravel pits located on the inside of the meander bend. The cutoff resulted in a reduction in reach length of approximately 1,100 m. Erosion by bed lowering, knick point retreat and lateral erosion of upstream river banks occurred quickly. Within two days of the peak flow, 3.5 hectares of land and 105,500 m3 of gravel were eroded from the river bank just above the cutoff location. Much of this gravel moved a short distance downstream into the excavation. Reach slope increased from 0.0022 to approximately 0.0035 in the cutoff reach. Between 1996 and 2003, the knick point from the meander cutoff has migrated 2,290 m upstream, resulting in increased bed load transport, incision, and local lowering of the water table. In 1993, prior to the meander cutoff, transects were surveyed in the River Island reach upstream of the cutoff location. Resurvey of these transects and aerial photo analysis indicates that 96% of the knick point migration occurred during the first winter following meander cutoff. Connection of the flowing river to the off-channel ponds has had minimal effect on water temperatures in the mainstem Clackamas River. It is likely that this minimal change in temperature will decrease as ponds are isolated from active river flow by gravel bar deposition. Fish net-ting in spring 2002, suggests that salmonid use of the pond in the spring is minimal. The most abundant native species netted were large-scale sucker and northern pikeminnow. The most abundant non-native species netted was brown bullhead. Early regulation by state and federal agencies did not adequately evaluate potential impacts to the river and the floodplain; nor did it evaluate future impacts related to geomorphic processes and sediment transport. New permit evaluation methods, currently implemented by both Oregon and Washington, incorporate 1) river dynamism through historic river migration analysis; 2) stability of human structures in light of river dynamics; and 3) sediment transport and its impact on channel stability and dynamics. The gravel pit capture at River Island highlights the potential risks of mining in an active secondary channel of a large gravel-bed river. Mining deeper than the depth of the adjacent channel, within the active migration zone, may increase off-site impacts. In locations where multiple gravel excavations are present within the meander zone, a comprehensive reclamation and restoration plan should be developed which provides long-term channel stability within the natural variability of the entire river reach.

Jan 1, 2006

By Katsunori Yamaguchi

The zinc, lead and alumina contents in copper smelting slag are increasing with the increase in waste recycling. The recovery of base metals such as lead and zinc from copper converter slag is important from both an economical and environmental perspective. As a fundamental study of the metal recovery by reduction process, activity coefficients of ZnO and PbO in the CaO-SiO2-FeOx-5mass%AlO1.5 slag under iron saturation at 1573K are derived from the data of slag-metal equilibrium experiments. On the basis of the obtained data, the activity coefficients of ZnO and PbO in the CaO-SiO2-FeOx-5mass%AlO1.5 slag were compared with those of the CaO-SiO2-FeOx ternary system. Addition of alumina increases activities coefficient of ZnO and PbO in SiO2 rich side of the slag, and decreases them in CaO rich side.

Jan 1, 2006

By G. Azimi

Calcium sulphate precipitation, mainly as gypsum, during neutralization of acidic hydrometallurgical process solutions can lead to excessive scaling problems. In this work, a self-consistent fundamental chemical model is presented based on the OLI software platform. The model employs the new Mixed Solvent Electrolyte (MSE) activity coefficient model of OLI. A thermodynamic database has been developed and calibrated on experimental data from metal sulphate solutions. The model predicts very well the solubility of calcium sulphate within a wide temperature range and can be used to assess the scaling potential of a particular process stream composition. The effect of temperature, acidity, and divalent metal concentration on the solubility of calcium sulphate in multi-component process streams is also simulated and discussed.

Jan 1, 2006

By L Whitbourn, K Yang, P C, E Ramanaidou

The potential of hyperspectral mineral mapping within a mine environment is demonstrated. Central to this capability has been the development of portable or vehicle-mounted, hyperspectral mine face-mapping systems. Data from these systems were used to detect subtle mineralogical variations and map their distribution across rock faces in a fashion that previously was not possible. In one study, the data usability was enhanced by ædrapingÆ the mineralogical determinations over a three-dimensional æmodelÆ of the rock-face. The eventual melding of the spectral mine face-mapping and three-dimensional spatial technologies will result in a new generation of mineralogical and structural information becoming available to mine geologists, engineers and metallurgists. Specific uses for spectrally-derived, mineral mapping data sets could include:ore grade mapping systems based on either direct detection of ore minerals themselves (eg iron and nickel oxides), or mineralogies that may be used as surrogates for ore-grade information (via various alteration minerals) after a suitable orientation survey; detecting mineralogies that have a deleterious effect on milling, metallurgical processing or have occupational health implications (talc, swelling clays, carbonates, asbestos, etc); selective mining and blending by collecting, processing and displaying such mineralogical images in near real-time to monitor ore grade and quality, and allow the separation of ore from waste during loading operations at the mine face; a mineral detection and mapping capability to assist in structural and geotechnical mine planning applications; and an enhanced geological detection and mapping capability for ore mineral species or alteration mineralogies that may be used to vector further mineralisation, update the existing mine ore model, or provide input to assist in the control of autonomous mining equipment. Within the Woodlawn open pit, Fe- and Mg-chlorites and phengitic- micas associated with sulfide mineralisation were detected and mapped. Subsequent studies using a second generation face-mapping system demonstrated the direct detection of ore-grade materials for iron-ore and nickel laterite mining activities. Satisfactory and meaningful results were extracted from data that were collected under a variety of challenging conditions. However, these non-ideal climatic and operational conditions would be expected under most operational situations in a mine environment. Development of a system using artificial illumination, permitting night-time (and eventually underground) operation and elimination of atmospheric absorption effects is underway.

Jan 1, 2006

By V. M. Paretsky

Most recent developments made in the Gintsvetmet Institute in the field of technologies and equipment for single-stage autogenous smelting of copper sulfide raw materials to produce white metal and blister copper on the basis of oxygen-flame smelting process and separation of highly basic calcium-containing slags have been discussed. This technology includes the oxygen-flame smelting process (KFP Process) to produce highly basic self-disintegrating ferrite-calcium slags with their subsequent flotation to recover copper and a basically new sparging smelting process (FBP Process) to produce combined slags subjected to decopperizing inside the same furnace. Results of special investigations of the slag structure obtained in the KFP and FBP processes and substantiating selection of their chemical and phase composition have been presented. It has been demonstrated that the above processes meet the stringent world-level requirements to advanced technologies with respect to energy conservation and environmental safety with different scales of production and within a wide range of specific conditions of particular operations.

Jan 1, 2006

By Kang-In Rhee

Nonferrous metal recycling not only provides energy saving and environmental benefits but also is a significant factor in the supply of various types of metals used in our society. Recycling plays an important role in establishing the sustainability of materials. The total amount of recycled nonferrous metals by weight accounts for less than 5% but their value is larger than 50% compared to ferrous metal recycling which consists of about half of the total metal recycling in weight. This paper describes trends and typical achievements in nonferrous metal recycling and overviews the present and future of nonferrous metal recycling technology and business in Korea.

Jan 1, 2006