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The corrosion behaviour of a low carbon steel was investigated in natural seawater and various synthetic seawaters. It was found that the steel corroded nearly four times faster in a 3.5% NaCl solution than in natural seawater for an exposure time of 21 days. The corrosion rate after immersion in synthetic seawaters (ASTM D1141 and Marine Biological Laboratory seawater) is similar to the corrosion rate after immersion in natural seawater. Calcium carbonate (aragonite) deposits were found on the surface of the steel after immersion in natural seawater and the synthetic seawaters. Some magnesium-containing deposits were also found after immersion in the natural seawater. These deposits act as a barrier against oxygen diffusion and thereby lower the corrosion rate. The morphology of the calcium carbonate deposits that formed during immersion in the natural seawater is different from those formed during immersion in the synthetic seawaters. This may explain the slightly lower corrosion rates obtained in the natural seawater. X-ray diffraction also showed that the oxy-hydroxides formed in the 3.5% NaCl solution differed from those formed in the other solutions. Keywords: Corrosion, seawater, low carbon steel, 3.5% NaCl, aragonite

Jan 1, 2006

By Bjørn Nilsen, Brian J. Ballou

The Tellnes open pit mine in Southwestern Norway has been operating since 1960. The maximum height of pit walls is currently about 150 meters with the current mine plan extending this distance to 400 meters with slope stability being a major controlling factor. As a result of unfavorable combinations of directions of major joints and faults, local stability problems have occurred several places in the pits walls. Stability problems have affected the reliability of main transport roads on several occasions. Most of such incidents have occurred during heavy rainstorms and during periods of repeated freezing/thawing. This paper reviews some of the stability problems and the measures taken to deal with such stability problems.

Jan 1, 2006

By W. D. Guo

With an experimental apparatus developed recently, model tests on piles were conducted in sand subjected to triangular soil movement profiles. Four instrumented piles tests are reported, which show the pile behavior predominantly determined by soil sliding depth. Axial load can create additional bending moment and pile deflection, which also make mode of pile-soil interaction change with sliding depth. Limiting resistance was found 1.5~3 times higher than currently used for laterally loaded piles in sand.

Jan 1, 2006

The present work is mainly focused on developing intermetallic inert anodes for aluminum electrolysis. The anode alloy based on Al-Ti-Cu system was prepared by casting, followed by the application of a protective coating. Behaviour of corrosion and the passivation under anodic condition was characterized using the electrochemical and microscopic techniques. The results obtained clearly demonstrate that the oxide coating can provide good corrosion resistance via surface passivation of alloy anodes, rendering them inert in cryolite melt.

Jan 1, 2006

By Roberto Parra

The wear and corrosion phenomena in the furnace lining of the ferrous and non ferrous pyrometallurgical processes are complex problems where chemical, interfacial and mechanical phenomena are presents. The characteristics of the processes determine the conditions to which these materials are submitted, where the thermal conditions reached during the operation is one of the most important parameter. Assuming that all the degradation phenomena are thermal activated, the rate of the different steps of the wear mechanism will depend on the thermal field in the lining. In view to apply the independent physicochemical knowledge of degradation mechanisms to the analysis and design of furnace lining the methodology of the Nodal Wear Model (NWM) was done. It combines the mathematical modelling of the heat transfer in the lining with the physicochemical control equation for the wear-corrosion phenomena. The NWM has been applied to different examples: theoretical analysis, laboratory scale test and industrial applications. We present in this paper the theoretical background of the model and two examples of applications: the sole of an electric furnace and the earth of a blast furnace.

Jan 1, 2006

By F. A. Guo

Ultrafine-grained surface layers were obtained by surface mechanical attrition treatment (SMAT) in copper and titanium samples. The thermal properties of the deformed layers were characterized using a scanning thermal microscopy (SThM) that allows thermal conductivity to be mapped down to the submicrometer scale. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a powerful tool for the thermal property and microstructural analysis of ultrafine-grained microstructures.

Jan 1, 2006

By Li Rongxing

A general regular solution model put forward in this paper defines a general interaction parameter that includes both composition and temperature dependence. On the basis of this model, analytic express of solution excess properties was obtained by least square fit using the composition and temperature relations in binary alloy phase diagram. After some solution excess properties analytic expresses of correlated binary alloy system obtained, the analytic express of ternary alloy system could be obtained by superposition of general geometrical model. The ternary alloy system Pb-Sn-Zn has been predicted in terms of this method and the result was very in agreement with actual measured value.

Jan 1, 2006

This paper is for mine managers. It is about maintenance of mining equipment. This is an extremely broad subject so this paper is given with the caveat that it necessarily contains generalisations, not true in all cases, but broadly correct. The job of mine managers is to be good at making money from the excavation and preliminary treatment of mineral. To do this well, they need to understand the cost and value drivers in the business. This includes understanding the drivers associated with maintenance. Maintenance is often identified as a problem at mine sites. It is frequently listed as the cause of production shortfalls when reporting. The state of maintenance within mining as an industry is generally among the lower end of the range, when compared to manufacturing, petrochemicals, etc. Why is this? Experience and review of many audits and evaluations of maintenance has shown that some patterns are consistent with good performance and some consistent with poor performance. These often centre around the time horizon of the management team and are associated with knowing the sensitivity of the business to certain maintenance drivers and the mechanisms of maintenance and their results. To summarise, some common misunderstandings can be listed as statements that are obvious and extrapolations from those, which are not necessarily correct. For example: High availability of equipment is necessary for production. Incorrect extrapolation:focus on availability will produce high production. Design is often the greatest factor in determining the reliability of a mining machine. Incorrect extrapolation: the newest and biggest machines generally have the lowest cost operations. Operation has an enormous impact on machine productivity and reliability. Incorrect extrapolation: the fastest operators are generally the best from a productive point of view. Some maintenance improves the performance and reliability of machines. Incorrect extrapolation: more maintenance will give you more reliability. Some maintenance depends on disassembly and reassembly of components. Incorrect extrapolation: assembly is basically the reverse process of disassembly. Maintenance improvement in the mining industry in the last 15 years has focused largely on planning and systems improvement. Incorrect extrapolation: most of the problems in maintenance can be traced to a lack of planning. Actions based on flawed extrapolations will steer a business suboptimally. It is therefore important that the mine manager understands these issues so that the improvement effort can be directed to the greatest benefit.

Jan 1, 2006

By H. C. Verakis

This paper summarizes blasting accident data for over a quarter of a century (1978-2004) for all types of surface and underground mining operations in the United States. Although many billions of pounds of explosives and blasting agent have been used by the mining industry, the accident safety record has improved significantly in the past 25 years. Over the past decade, approximately 5 billion pounds of explosives and blasting agents were used annually in the United States. Coal mining has been and continues to be the dominant user of blasting agents.

Jan 1, 2006

By L Mariani, G. Mendoza-Suarez

In this investigation, TiH2 powders were coated with copper and nickel by electroless plating to delay hydrogen evolution. Copper-coated samples were found to have a mixed acicular (2D growth) and cauliflower (3D growth) morphology whereas the nickel-coated samples had a cauliflower morphology. Examinations of the coated powder cross-sections revealed that the coating thickness ranges from 0.2 µm to 4 µm. Uncoated areas on the powder surface and coating flakes unattached to TiH2 particles suggest poor adhesion between the coating and the substrate. The phase transformation undergone by the TiH2 during dehydrogenation was studied in samples taken at intermediary points in the heating cycles and examined by XRD. The findings reveal that as the powder is heated from room temperature to 800°C, it changes from TiH1.971 to Tiu and to aTi. Differential Thermal Analysis (DTA) was performed to study the effects of the coatings on the temperature of hydrogen release. It was found that increasing the number of plating iterations, and therefore the thickness of the coating, creates a significant shift in the temperature of gas release.

Jan 1, 2006

By Shinroku Matsuzaki

Data the measurement sensor installed with spatial distribution on the blast furnace were successively accumulated online from the process computer to the database system over a long period. This is a new system that accurately considers the relation with the installation position of each sensor, and picture computerization of the measurement data was developed. The overall operation state of a blast furnace, which skilled operators can see in their mind?s eye, was objectively visualized as pictorial information.

Jan 1, 2006

Iron removal using biologically produced organic acids was investigated as a treatment option for the production of refractory grade bauxite. A leaching solution containing 98mM oxalic and 67mM citric acid was prepared from a sucrose medium using for fermentation the fungus Aspergillus niger. The leaching capacity of the metabolic product was tested on a bauxite sample containing 16-19% iron (as Fe2O3). Aerobic and anaerobic leaching tests were carried out at pH 3, 50°C and in the absence of light. Results indicated that more than 80% of total Fe can be removed from the ore, when the sample is finely ground and applying a two stage treatment. The presence of oxygen was seen to affect adversely the kinetics of the process, suggesting that leaching follows a reductive mechanism. Experiments that were carried out with different particle size fractions indicated that for obtaining efficient removal of iron particles should be finer than 0.63mm. Reduction of the operating temperature from 50 to 30°C caused a decrease in the rate of iron removal by more than 10 times.

Jan 1, 2006

By H. Kurokawa

Sumitomo Metal Mining decided to expand copper production capacity of Toyo Smelter and Refinery to cope with the recent copper demand growth in Asia, and to survive by reducing cost. The expansion plan is promoted to increase electrorefined copper production capacity from 270,000 metric tons in 2001 to 450,000 metric tons in 2007. The major changes in smelting section are introduction of the rotary steam dryer, renewal of the feeding system for flash furnace, improvement of the concentrate burner, modification of the flash furnace cooling materials, renewal of the slag cleaning furnace, modification of the flash furnace waste heat boiler, installment of a new converter furnace, enlargement of two anode furnaces. In addition, the gas cleaning system was upgraded and the second acid plant was installed. In the refinery section, the existing tank houses have been operated at high current density of 300A/m2 using the conventional starting sheet cathode technology and moreover a new tank house utilizing the permanent cathode technology was constructed. Although the copper production capacity has been increased, SO2 emission has been kept the lowest in the world through consideration of influence on the environment by expansion project.

Jan 1, 2006

By Ryosuke O. Suzuki

A combined process of electrolysis of CaO in the molten CaCl2 and of calciothermic reduction, so-called OS process, was applied to prepare metallic vanadium directly from V2O3. The fine metallic powder containing 1860 mass ppm oxygen was obtained using 0.5mol%CaO-CaCl2 melt for 10.8 ks at 1173 K. The oxygen level did not decrease further even when twice electricity was applied. Because the metallic vanadium could be electrochemically deoxidized to the level of 10 ppm oxygen from 1.48 %, the large amount of by-product, CaO, due to reduction and the large surface area of the fine particles are the reasons of high oxygen content in the reduced powder.

Jan 1, 2006

By David Kennedy, Noel Hsu, Miguel Araos

The use of bulk explosive for mining applications started in the 50’s. Since then millions of tons of that material have been transported by road. However during that time, there have been several road incidents involving them. This type of incident has forced the explosives manufacturers as well as regulatory organizations to look for a better classification of explosives in order to regulate the industry as well as to mitigate community concerns over the classification of mixtures of substances that are regarded as precursors to explosives.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

The object of this paper is to show in some detail the mining challenges that have been presented and overcome during the successful development of the main exhaust ventilation drive that will service the Ballarat East mine during its 20+ year lifespan. Topics to be discussed in this paper include the ground support regimes employed, the ground conditions encountered during construction, how the heading was recovered after falls of ground and the effectiveness of geotechnical probe drilling at Ballarat.

Jan 1, 2006

By Tom Goforth, Rongmao Zhou

The interest of seismologists in mining explosions has increased substantially with the construction of the International Monitoring System (IMS). The IMS supports the Comprehensive Nuclear Test-Ban Treaty by providing global data coverage from seismic, hydro acoustic, infrasonic, and radionuclide sensors that will detect a host of natural and man-made events at regional (<2000 km) distances. Ideally, the recorded data can be used to identify those events that have explosive characteristics and therefore might be clandestine nuclear tests. The regional observations assure the detection of mining explosions, and these must be properly identified to avoid false alarms of the monitoring system. Cooperation with the mining industry, including documentation of the firing programs, provides critical information necessary to characterize the seismograms.

Jan 1, 2006

By Vince Luongo

"INTRODUCTIONThe West Side Combined Sewer Overflow (CSO) Tunnel Project is located in Portland, Oregon and is part of the Willamette River CSO Control Project. The purpose of the West Side CSO Project is to reduce the frequency and volume of combined sewage overflows from the drainage areas on the west side of the Willamette River using the West Side CSO tunnel as a combined storage and conveyance facility. The sewage is then directed to the Pump Station on Swan Island, which is located on the east side of the Willamette River. From here the combined sewage is pumped through force mains that discharge into the existing Peninsular and Portsmouth tunnels.The West Side CSO tunnel has an inside diameter of 14-feet (4.27m) and is approximately 18,150-feet (5,532m) long. The tunnel slopes at a constant down gradient of 0.0018 from south to north over the entire length of its alignment.The tunnel passes beneath six existing bridges; Hawthorne Bridge, Morrison Bridge, Burnside Bridge, Steel Bridge, Broadway Bridge and Fremont Bridge. The general tunnel alignment follows beneath the Naito Parkway starting at Clay Street Shaft and connecting three other shafts on the west side of the Willamette River, Ankeny Shaft, Upshur Shaft and Nicolai Shaft. It then passes below the Willamette River and on to Swan Island to connect with the Confluent Shaft, which will combine flows from the West Side CSO and East Side CSO (not part of this contract) and then continues to the Pump Station Shaft.The Nicolai Shaft is the primary mining shaft from which two TBM’s were launched to construct the West Side CSO tunnel. The first TBM started mining south and terminated at the Clay Street Shaft. The second TBM started mining north below the Willamette River and terminated at the Swan Island Pump Station Shaft."

Jan 1, 2006

By Philip Dubbeling

Conventional dynamic sheetpiling techniques are ill-suited to urban development because of the emission of excessive noise and ground vibrations. Drilled shafts and slurry walls alleviate some of these environmental concerns but add additional problems due to large bulky machines, reliance on dusty concrete plants and urban trucking grief. To solve these problems, pre-fabricated sheetpiles are hydraulically jacked-in by reaction principle using a compact and lightweight press-in machine, a so called the "Silent Piler". Through scientific analysis, definition and systemization of press-in machines and methods, new construction concepts such as the one-step approach, implant structures, functional design and life cycle design have been developed to comply with new basic construction principles.

Jan 1, 2006