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By John O. Marsden

The past fifteen years have seen a number of important developments in copper hydrometallurgy, including the commercial application of biological heap leaching of secondary (chalcocite-dominant) copper ores, the commercial demonstration of chalcopyrite concentrate leaching technology using pressure leaching and biological processes, and the application of novel configurations of solution extraction circuits. Significant emphasis is now being placed on the development of effective stockpile leaching practices for primary ores (chalcopyrite and bornite-dominant mineralization). Some of these developments have been highly successful, and will pave the way for further development and commercialization. Others have been less successful. These developments are reviewed in the context of the metal price cycle and trends for the future are identified.

Jan 1, 2006

By M. E. Reed

Clyde Materials Handling (CMH) and WorleyParsons have developed a concept for a flash furnace feed system using the specialist pneumatic conveying equipment expertise of CMH and the flash furnace process experience of WorleyParsons. CMH has developed a proprietary volumetric feeder (called a Rotofeed) which is extremely accurate and overcomes many of the problems inherent with loss-in-weight screw feeders and drag chain conveyors, previously regarded as state-of-the-art. Initial indications are that the Clyde-WorleyParsons Feed System could deliver the following benefits to Flash Furnace operation: ? Accurate pulse-less delivery of feed material to the head of the burner leading to improved combustion performance and process stability; ? Highly accurate split to the individual quadrants of a conventional burner tube, or provision of a smooth hollow curtain to a burner without guide vanes; ? Decreased pressure pulsation in the furnace due to improved combustion control and performance; ? Decreased temperature fluctuations in the furnace due to improved combustion characteristics and hence reductions in refractory thermal stress and wear; Plant measurements have indicated a correlation between the discharge of concentrate from the drag chain conveyor and high speed pressure fluctuations in the flash furnace settler. Pilot scale test have been conducted to illustrate that the system delivers pulse-less feed to the burner with even feed distribution axially.

Jan 1, 2006

By P J. Fourie, J R. Walklate

Gravity separation techniques have been in use in the mineral sands industry for decades; from the Reichert cone to Wilfley tables, Wright sluices and the Kelsey Jig, all attempting that elusive perfect gravity separation. Just as the gravity separation industry evolved, Richards Bay Minerals also evolved in their use and approach to gravity separation. This paper discusses the history of gravity separation at Richards Bay Minerals and briefly comments on future developments. History Primary Concentration Richards Bay Mineral?s (RBM) first mining concentrator and mineral separation plant commenced operation in 1977 to process ilmenite, rutile and zircon bearing dunal deposits along the northern Natal coast. The orebody contained a greater proportion of non-valuable magnetic heavy mineral in the SG range of 3 to 4 compared to West Australian and Florida USA deposits, making mineral separation more difficult(1). The deposit was mined using two dredges feeding a floating 2000 tph concentrator. Concentrator feed was screened and fed to two four-stage circuits consisting of primary, scavenger, cleaner and recleaner Reichert cones [see Figure 1]. The primary units were fed at a rate of 80 tph and a density of 60% solids by weight.

Jan 1, 2006

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By Roberto Parada

In a long term program for the optimization of the Outokumpu Flash Smelting Furnace at Chagres Smelter many different subprograms are being developed. One of them is the design and application of a sampling method that can allow the direct diagnostic of the quality of the copper concentrates combustion. We present in this paper the evolution of the sampling devices used in a ten months of continuous sampling campaigns and an example for the sulfur elimination and magnetite formation in the flame from 60 cm to 100 cm under the burner. These type of information combined with the appropriate mathematical modeling of the combustion must propose some considerations to correct the classic criteria in the preparation of the charge for the smelting of copper concentrates based only on the mass and energy balance from the chemical and mineralogy composition of the concentrates.

Jan 1, 2006

By Marek Dworzanowski

Dense medium separation (DMS) is critical to the operation of coal and diamond beneficiation plants. It is also utilised in iron ore, manganese, chromite and andalusite beneficiation as well as pre-concentration for platinum-bearing UG2 ore. Gravity concentration plays an important role in the processing of diamonds, coal, gold, platinum, titanium minerals, zircon, chromite, iron ore and manganese. The DMS and Gravity Concentration operations and technology in South Africa conference will focus on the operation of DMS and Gravity Concentration circuits in the South African Mining Industry. The current status of the technologies and equipment employed will be presented as well as future developments. The conference was set up to showcase South African DMS and Gravity Concentration operations and provide a forum where operators, technology and equipment suppliers can engage in knowledge sharing. The papers cover a wide spectrum of topics, including descriptions of operations, optimisation projects, new capital projects, equipment applications, process monitoring and process selection. Most commodities and unit processes associated with DMS and Gravity Concentration are covered. The conference venue was selected to be the CSIR Convention Centre in Pretoria. The CSIR has contributed to DMS research in South Africa and it is located not far from many coal, diamond, gold, platinum and chrome mines that extensively utilise DMS and Gravity Concentration in their beneficiation plants. I believe that the papers and presentations submitted for this conference will provide a valuable future reference for DMS and Gravity Concentration, thus making the work of all the contributors to this conference highly rewarding and worthwhile.

Jan 1, 2006

By Ketan H. Trivedi

This paper describes the method of analyses used for the design of temporary and permanent Secant Pile Walls, describes various aspects of construction including, guide walls, sequence of pile installation, plan alignment and verticality tolerance, methods of drilling (auger, wash boring, cased and open holes), lateral bracing for secant piles, cutting of keys in secant pile walls for the connection of permanent floor slabs, sealing of water leaks and waterproofing. The paper concludes with a brief case history of a secant pile wall project recently constructed in New York City.

Jan 1, 2006

By Mike Fabius

The Lakehead Region Conservation Authority is responsible for slopes along the Kaministiquia River, one of the largest tributaries to Lake Superior in Canada. After arresting toe erosion for a mile of riverbank, the remainder of the slope required stabilization to stop further crest regression and to protect the houses, street and services at the top. Stabilization of the 100 ft. high slope was tendered as design-build with a target safety factor of 1.3 and a design life of 75 years. The successful bid was a system of 1.4 inch diameter soil nails up to 40 feet long, installed perpendicular to the slope on a 3 to 5 foot grid. The conventional shotcrete facing was replaced with a ?green? biotechnical facing and special transverse plate heads on the nails. The key to keeping costs low proved to be installation with light equipment working on the slope, and driving the nails without drilling or grouting. Rather than tension, the design was based on bending in the nails, similar to a laterally loaded flexible pile. The paper describes the design and installation of this innovative system. The design is discussed in terms of soil properties, nail resistance as it varies with depth, failure modes, corrosion protection, root design and nail head design. Construction challenges are discussed. The system is compared to an adjacent anchored soldier pile wall built along the same slope 20 years ago. Post construction monitoring results confirm predicted performance.

Jan 1, 2006

Current design guidelines for the surface catalysed oxidation of Fe(II) on Fe(OH)3 (Ochre) in passive mine water treatment systems are based largely on empirical data as the details of rates and mechanisms have not fully been revealed. Also the effects of elevated carbonate concentrations, typical of many UK minewaters, on the surface catalysed oxidation rate are unclear. In order to move away from empirical design and towards sound engineering that is based on geochemical and hydrological understanding it is necessary to quantify these reaction rates. In this study the effects of Fe(OH)3 and carbonate on the rate of Fe(II) oxidation by dissolved oxygen have been investigated with an aim to delineate the reaction mechanism. Experiments were conducted under well-controlled conditions. Preliminary results indicate that the surface catalysed reaction is an order of magnitude faster at pH ~6.4 with 200 mg/l Fe(OH)3 than the homogeneous rate and is dominated by an elevated rate of removal and oxidation of Fe(II) from the solution phase. It is also apparent that the oxidation rate of actual adsorbed Fe(II) is substantially retarded with respect to the homogeneous rate. Carbonates were not shown to affect the surface rate within the bounds of this preliminary study.

Jan 1, 2006

By Glen Mc Gavigan

The roof of the Sishen cave is being mined in order to exploit 6.8Mt of high grade ore. The cavity is filled with quartzite backfill in order to support the roof in the event of collapse. The cave dips at approximately 37o, is 260m along dip and 70m along strike and has a total volume of 261,391m3. GPS and optical monitoring techniques were attempted to detect subsidence but proved to be impractical. The GroundProbe Slope Stability Radar (SSR) uses differential interferometry to measure sub millimetre movement in a rock face. The SSR was applied in a non production situation and detected subsidences of 38mm/day before visual signs of instability were detected. The rate of deformation detected was slowing as a result of the roof coming to rest on underlying backfill. Monitoring during production drilling detected a sudden subsidence of 18.6mm/hour which resulted in the evacuation of personnel from the area. Further inspection of data showed that the rate of deformation was slowing and production was allowed to continue without further incident. The SSR has helped dispel the fears of workers and has proven that subsidence can be accurately measured and delineated with the SSR.

Jan 1, 2006

By J. E. McGill

The junior and small-scale mining sectors in South Africa play an important role in the livelihoods of numerous communities. Mining presents an opportunity, in the post-1994 democratic era, for many individuals to obtain access to much required empowerment and socio-economic development. These sectors are, however, not without numerous characteristics that pose problems for operators, legislators, and other role-players. Mining is inherently risky, with operators experiencing frequent difficulties and challenges throughout the life of mine. Opportunity exists, and needs to be enhanced, for junior and small-scale prospects and operations to include technical risk assessment techniques in documentation presented in search for funding, and in optimizing monthly planning and longer-term functioning. The focus here is to explore how the risk management cycle may currently be applied to a mineral resource suitable for exploitation by the junior and small-scale mining sectors. No management process can create additional value in the ground, but various available mechanisms can go a long way to quantifying the inherent risk that exists, highlighting the need to manage the risks and hopefully allowing the entrepreneur access to the intrinsic opportunities of the emerging mining sector in South Africa.

Jan 1, 2006

By Grant Loveday, Vincent Dieudonné, Andrew Jonkers

Bateman Minerals & Metals supplies the APIC Technologies which include the under-bed air-pulsed APIC jig and related technologies such as the JigScan controller and advanced mathematical models of the jig process. Bateman have developed a methodology for predicting process performance for jigs from simplified testing and modelling, based on batch equipment matched to industrial designs. Batch tests conducted on laboratory scale air-pulsed jigs can process small batches of material, such as those obtained from drill core samples. The novelty comes from using an advanced jig process model, ASTRAD, to link the results of batch and continuous jigs. The batch jig presented as a novelty in this paper has been designed to be hydraulically equivalent to the full-scale APIC Jig, allowing the generation of equivalent pulse shapes and using JigScan controller. Lump and fine ferrous ore material have been separated in this unit and any feed >1mm can be tested and extracted. The global test procedure and further modelling focus on the stratification of material, with emphasis on key aspects such as pulse shape, feed characteristics and residence time. The splitting of rejects from concentrates is itself more difficult to reproduce in batch jigging, however the ASTRAD model includes a separation imperfection module, and the APIC Technologies have extraction systems adapted to each type of material. Air pulsed batch jigs are available in several locations and are relocatable. They have been used to treat samples from Australia, South Africa and India as part of studies into ore processing using jigs. Each test layer is available for various physical testing procedures (density and chemical analyses). Test-work is performed on a case by case basis, and analysed using an advanced model ?now available over the internet. Some fundamentals of air-pulsed jigging are recapped along with some of the features of APIC jigs. The process of designing a ?hydraulically equivalent? batch jig test is then described. Some results from jigging tests are presented plus the results of the ASTRAD advanced jig model, which was first developed at the JKMRC with ferrous ores and coal and is now being supported and further developed and utilised by Bateman.

Jan 1, 2006

By Georg Breitsprecher

The technique of Stabilising Columns (product names are for example "Stabilisierungssaulen" (STS) or "Coplan Stabilisierungs-verfahren" (CSV)) is gradually becoming well accepted for ground improvement. The installation, dimensioning and quality control are standardized by DGGT (German Association for Geotechnique), working committee 2.8, of which until now only part one exists for dry columns. This paper describes the installation and testing of stabilising columns for a ground improvement project. To achieve comparable results in testing both ready mixed concrete and dry binder had been used for production.

Jan 1, 2006

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N'-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By M. J. Latva-Kokko

This paper describes the behaviour of iron and the methods used for iron control in the nickel matte leaching process. OMG Harjavalta Nickel Oy processes approximately 10 000 t/y of iron, which enters the process with the nickel matte raw material. Iron dissolves and precipitates in several different stages of the leaching process. Compounds like ferric hydroxide, parabutlerite, goethite, hematite and jarosite are found. Iron removal is done within the leaching process, and this means that the dissolution of nickel sets the limiting conditions for iron precipitation. A leach residue consisting mainly of the iron precipitates is neutralized and stacked in the waste pond. When iron is precipitated from concentrated nickel sulphate solution, some nickel is lost by co-precipitation. Recent studies have shown that Ni-Fe ratios less than 1%, attributed to co-precipitation, can be obtained with jarosite precipitates, compared to 2-3% ratios typically found with hematite precipitates. Iron can be precipitated as jarosite under the optimal nickel leaching conditions by adding ammonium sulphate to the feed slurry of the autoclave.

Jan 1, 2006

By S. Sundararajan, J. Brousseau, P. Bocher, M. Galopin, N. Barka

This research is committed to the prediction of the hardness profile produced by induction heating, using a computer-modeling software. The paper presents the simulation of the induction hardening process to analyse the sensitivity of the induction parameters on the hardness profile of a low alloy steel specimen. The developed numerical model includes the coupling effect between electromagnetic and thermal fields, and takes into account the non linear behaviour of the material properties. The study applies an enlightened experimentation method to build the feasible domain of the process and to achieve predictive empirical modeling. The ultimate goal is to replace the trial and error method that is usually used for the development of new parts, by costless experiments with the numerical model. Further development of this approach will lead to the computation of the residual stresses and finally to the assessment of the mechanical properties of the part. The end result will be the ability to shorten the development time and to improve the quality of the hardened part.

Jan 1, 2006

By M. Cross

Heap leaching presents a complex physico-chemical process to model and a significant challenge to develop a comprehensive model enabling reliable predictions of heap behavior over the long term. A computational modeling framework is described for the analysis of multi-phase flows in reactive porous media suitable for tracking metals recovery, for example, in heap leaching and environmental recovery processes. This modeling framework employs appropriately formulated, parameterized, and solution procedures to capture: 1) liquid and gas flow through heterogeneous porous media subject to variably saturated flow conditions, 2) the complex and dynamically changing nature of the porous media structure, 3) the transport of reactants and products of reaction, 4) the simultaneous mass and heat transfer, and 5) the role of bacteria as a catalyst for reactions. A second class of challenges to accurately model heap processes is to identify and then capture all the process data to characterize the reactivity of particular ores, the mine planning for the construction of the heap, leach schedules, meteorological data, etc. The objective of this paper is to outline these challenges and to describe a modeling framework that can cope with arbitrarily complex geometries and provide tools for rapid and accurate process assessment.

Jan 1, 2006

By John O. Marsden

The past fifteen years have seen a number of important developments in copper hydrometallurgy, including the commercial application of biological heap leaching of secondary (chalcocite-dominant) copper ores, the commercial demonstration of chalcopyrite concentrate leaching technology using pressure leaching and biological processes, and the application of novel configurations of solution extraction circuits. Significant emphasis is now being placed on the development of effective stockpile leaching practices for primary ores (chalcopyrite and bornite-dominant mineralization). Some of these developments have been highly successful, and will pave the way for further development and commercialization. Others have been less successful. These developments are reviewed in the context of the metal price cycle and trends for the future are identified.

Jan 1, 2006

By Rachel De Lucas

Current methods of hydrogen storage are an impediment to the transition of our energy infrastructure from a hydrocarbon to a hydrogen base. The transportation, handling, and storage costs of hydrogen gas account for a majority of its selling price. Magnesium hydride slurry is a safe, environmentally friendly alternative for hydrogen storage. If this form of storage is to be adopted on a large scale, a cost-effective method for recycling the enormous amounts of magnesium hydroxide byproduct must be identified. The solid oxide membrane (SOM) process can be used to recycle the magnesium hydroxide byproduct into magnesium metal, which can be reformed into magnesium hydride and reused for fuel storage. Conventional magnesium extraction/recycling technologies require a great deal of energy and create byproducts that are harmful to the environment and human health. The SOM process poses none of these detrimental effects and requires less energy and feed preparation. The economic viability of a facility that utilizes the solid oxide membrane process for the direct reduction of magnesium must be examined in more detail if industry is to consider it. Cost analysis data related to the commercial viability of a scale-up will be compared to two standard industrial processes: current magnesium production techniques including electrolytic and metallo-thermic processes. We have shown in our cost comparison that the SOM process is cheaper than these traditional techniques and that it is also comparable to aluminum's Hall-Héroult process in cost but with none of the environmentally harmful byproducts.

Jan 1, 2006

By Yang Tian-zu

The separation of precious metals from base metals containing in gold-antimony alloys by selective chlorination leaching under controlling potential was studied in this work. The effects of the consumption of hydrogen peroxide, the concentration of hydrochloric acid, the concentration of sulfuric acid, leaching temperature, leaching time and the liquid-solid ratio in hydrochloric acid system on the leaching efficiencies of the base metals have been investigated. The optimal leaching conditions of the gold-antimony alloys are as follows: hydrochloric acid concentration 4.0mol?L-1, sulfuric acid concentration 1.2mol?L-1, liquid-solid ratio L:S=7.5:1, the leaching temperature 80 0C, leaching time 2h, and the oxidation potential of the leaching system 400±20mV( vs SCE).The leaching efficiencies of copper, nickel and antimony are more than 99% and the gold leaching efficiency is about 0.042% under the above leaching conditions. The base metals containing in the gold-antimony alloy are separated from the precious metals thoroughly.

Jan 1, 2006