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The recovery of fine hydrophilic gangue in flotation is related to the recovery of water. Water is carried by bubbles as a film and wake into the froth. The amount carried (entrained) depends on bubble size, gas rate and the subject of this paper, frother type. To isolate the effect of frother type from that of bubble size and gas rate, gas holdup is used as the correlating variable. Measurements were made using a bubble column (no solids) operated continuously with the overflow recycled. Continuous operation meant some foam depth was required to ensure only entrained water is recovered. Using an automatically controlled 7cm foam depth the overflow rate of water is used as a measure of 'water carrying rate'. It is shown that the common frothers can be grouped into four families based on the water carrying rate-gas holdup relationship.

Jan 1, 2006

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006

By Pinakin C. Chaubal

Today?s steel industry is in a vibrant and resurgent mode. This transformation has been in the making for some time now. Over the last few decades, the industry was steadily transforming itself into becoming a high tech industry. New technology was adopted, efficiencies were enhanced, lean manufacturing concepts were brought in and a strong customer focus was developed. Today?s mills employ sophisticated instrumentation, computerized monitoring, on-line smart systems etc. driving processes that are producing at rates of many tons/minute. All this is not possible without judiciously using the latest available technologies in various fields and developing a more sophisticated work force. Prof. Sohn has been a pioneer in driving the concept of process engineering in process metallurgy. In this paper the focus is on some aspects of process engineering ? primarily process modeling - as applied to iron and steelmaking processes. Examples are shown to demonstrate how problems have been addressed. Some thoughts on future directions are presented.

Jan 1, 2006

By Jeremy Bosman, Johan de Korte

Traditionally the feed to coal preparation plants was de-slimed at 0,5 mm. The +0,5 mm size fraction was processed via dense-medium cyclones and the -0,5 mm size fraction was beneficiated with froth flotation, water-only cyclones or spirals. With the introduction of large diameter cyclones, the aperture sizes of de-sliming screens have progressively increased to about 3 mm in the belief that the larger cyclones are not able to effectively beneficiate coal which has a particle size below the ?breakaway? size. The efficiency of separation in the large dense-medium cyclones is improved by presenting a coarser feed to the units. At the same time, the capacity of the de-sliming screens is increased due to the larger screen apertures and in effect, the throughput capacity of the dense-medium section is increased. The 3 x 0,5 mm size fraction, which was previously processed in the dense-medium cyclones, is now added to the fine coal size fraction and processed by water-only methods such as Teetered Bed Separators (TBS) and spirals. Whether this practice is the most economical way to process the 3 x 0,5 mm size fraction requires further thought since the best processing route for the 3 x 0,5 mm size fraction will depend on a number of factors, amongst which are: o The washability of the coal and the amount of near-density material o Processing efficiency o Specification of the required product o The price paid by the customer for the product o The cost of processing the coal Breakaway size The ?breakaway? size is defined as the particle size below which the Epm of the smaller particles starts to decrease significantly. Bosman1 provides an approximate breakaway size versus cyclone diameter (Figure 1). It should be kept in mind though that the Epm of the small particles is a function not only of the cyclone diameter but also of feed pressure, medium density, medium viscosity, particle shape and density, top-size of particles in the feed, etc.

Jan 1, 2006

By H. Itou

A mechanism of scorodite formation at ambient pressure was investigated using transmission electron microscopy (TEM). Several types of iron arsenate were obtained from Fe/As solutions (Fe/As = 1.0 and 1.5) at pH values of 1.0, 1.25 and 1.5 at 95°C. Amorphous FeAsO4.xH2O was precipitated from solutions having a higher mole ratio of Fe/As at pH l.5, even after 9 hours. A few micron sized particles were observed by SEM, but these proved to be agglomerates of 10-50 nm amorphous FeAsarxH2O particles when observed by TEM. This means that supersaturation of the solution causes the acceleration of nucleation of iron arsenate hydrate. Crystalline scorodite was obtained from a solution in which the Fe/As mole ratio was unity, at pH l.0 and pH 1.5, after 3 hours. Almond-type crystalline scorodite particles were observed by TEM and most of them showed high crystallinity. The addition of scorodite seed material enhanced the crystallization. Amorphous FeAsO4.xH2O, however, was observed at the surface of the seeds during the early stages of precipitation. It is postulated that crystalline scorodite is not directly precipitated even on crystalline scorodite seeds, but requires a certain time to crystallize on the seed material.

Jan 1, 2006

By I. Bhattacherya

Over the last three decades, the mining industry has been moving towards underground mechanized mining methods and the number of load haul dump (LHD) vehicles utilized has increased. The growth of mechanization and automation has benefited both workers and mining companies. However, due to the design constraints with LHD vehicles and the limitations of the operating environment, restrictions to operator visibility has contributed to a number of accidents, including fatal injuries. Past researchers have used the light filament technique to collect obscuration zones around mobile equipment and have produced 2D visibility charts (shadow diagrams) of this information. The light filament method involves manually collecting visibility data, which results in errors and is time consuming, requiring around three hours to complete. This research utilizes a MENSI GS100 laser scanner along with 3D modelling software (3Dipsos) to collect and process operator visibility profiles for underground mobile equipment. Results from this test work indicate that a laser scanner can be successfully used to rapidly collect this data and utilize this information for improved mobile equipment design from a visibility perspective. Nomenclature FERIC Forest Engineering Research Institute of Canada ISO International Organization for Standardization JACK Software for digital human modelling and ergonomics LHD Load haul dump vehicle LOS Line of sight MASHA Mines and Aggregates Safety and Health Association (based in Ontario, Canada) PVD Polar visibility diagram SAMMIE3D human modelling computer aided ergonomics design system WSIB Workplace Safety and Insurance Board

Jan 1, 2006

By Zhitao Ma

The Cast-in-place Concrete thin-wall Pipe pile, referred to as PCC pile, is a new kind of pile for soft ground improvement. In this paper, firstly, the general introductions of the new pile technique, mainly including the technique principle, the structure of pile-driving machine, and the technological process were given, then based on the results of in-situ static lateral loading test, the pile lateral capacity, the relationship of load-deflection of pile at the ground surface, the lateral deflections versus depth and the soil reaction along the pile shaft were analyzed.

Jan 1, 2006

ITSL Technology group employs around 100 people at Mississauga in Canada. Its long and proud history as a driving force for the worldÆs nickel industry continues, progressively adapting to meet IncoÆs ongoing development needs. The nickel industry, unlike many others in the minerals processing world, has not evolved into one or two narrow technology paradigms. Rather, each process requires a degree of optimisation to meet the characteristics of the ore. Without a competent team to address this complexity, the uncertainties that arise can greatly increase the risk (and costs) associated with the nickel industry developments. The development work carried out at ITSL Technology ranges from milling and metallurgical processing of ores through to development of value added products for the battery and electronics industries. It covers routine evaluation of ores for exploration (mine planning and greenfield), and provides on the ground support to bring specialist technical perspectives to site-based projects. In recent years, ITSL Technology has had as its particular focus the process development and commissioning support for IncoÆs major projects. Over the next several years, Inco will commission its Goro laterite operation, design and construct the further processing facility for VoiseyÆs Bay, undertake major upgrades at Sudbury, Thompson and PT Inco, and bring forward some additional resources currently in the exploration stage. The appropriate mix of both internal and external resources to effectively manage this project portfolio will prove critical to success. The key to ITSL Technology meeting these development challenges has been in working closely with its internal customers to ensure alignment of the value proposition, to identify the critical issues to be managed, and to understand the deliverables required. This paper discusses examples to reinforce these principles in the definition and development for two different projects; processing of VoiseyÆs Bay ores and concentrates and resource optimisation at Thompson.

Jan 1, 2006

In their excellent paper, Milev and Spottiswoode have provided quantitative and definitive descriptions of an important phenomenon that hitherto has been largely the subject of conjecture. They convincingly show that ?site-response? can amplify the strong ground motions on the rock-wall of a stressed tunnel by a factor of 10 to 12 compared with the PPV in the solid rock mass (at the same distance from source). This knowledge gives us a firm foundation from which to begin to build an understanding of the mechanism of damage resulting from a rock burst. Regrettably this understanding is still far from adequate, in my opinion. The authors of this paper, however, have made some statements that are too reassuring and which tend to reinforce the sense of complacency that prevails among many members of the rock engineering community on the deep gold mines.

Jan 1, 2006

By Gene Baker

A new Safety Library Publication (SLP), SLP-27, which is titled “Security in Manufacturing, Transportation, Storage and Use of Commercial Explosives” was recently released by the Institute of Makers of Explosives (IME). SLP-27 makes recommendations for both general security and enhanced security at explosives sites when security risk levels, declared by the Department of Homeland Security (DHS) using its Advisory System, have temporarily increased.

Jan 1, 2006

By G. Ríos

Atlantic Copper Metallurgical Complex in Huelva (Spain) was commissioned in 1970 with a capacity of 40,000 tpy of copper from concentrate. In 1975 the old blast furnaces were replaced by the Outokumpu FSF technology. During the last 30 years, through several expansions and technical modifications, the production has increased up to 300,000 tpy of new copper. This paper describes the developments on the control of impurities that have been made to fit new situations, such as a new artificial gypsum plant, a new electrolyte treatment plant or different secondary materials handling management.

Jan 1, 2006

By C. Rocha R.

Petioles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world's foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Petioles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process, particularly the operation of the jarosite circuit and its effective removal of impurities such as arsenic, antimony, indium, selenium and tellurium, is reviewed.

Jan 1, 2006

By Guo Jun

In this study, BaTiO3 ultrafine particles surface-modified with stearic acid were synthesized by the hydrothermal method in a system of BaCl2-TiCl4-NaOH. The effects of NaOH/TiCl4 molar ratio, Ba/Ti ratio and time on structure and morphology of BaTiO3 ultrafine particles were investigated experimentally. The formation mechanism of different crystalline BaTiO3 particles was discussed, and it is considered that in a hydrothermal system, the main factors determining BaTiO3 crystalline are H+ replacement of Ba2+ causing H+ deficiency and anatase growth units involving in crystal growth, which clogs the axial channel for Ba2+ transference. By means of increasing the alkalinity of system and barium content, H+ deficiency and involvement of anatase growth units in crystal growth could be effectively controlled. The results show that when molar ratio of NaOH to TiCl4 is 9 and ratio of Ba to Ti 1.5, and time 8 hours, high purity tetragonal BaTiO3 ultrafine particles with a narrow grain-size distribution and nonpolar surface are obtained at 240oC. The particles have excellent flowability, which is ascribed that the surface polarity of barium titanium powder modified with stearic acid is changed and the interaction between the particles is weakened.

Jan 1, 2006

By C Hertle, B Goebel, R Fabre

The mining industry maintains a ælove-hateÆ relationship with water. Dewatering, aquifer, water disposal, irrigation, process water, tailings water, run-off water, seepage, leachate and sumps are all terms that are used on a daily basis in the mining industry, highlighting the numerous water usages on site and their associated quality. According to the Australian Bureau of Statistics (2001), each year the mining industry consumes over 530 000 ML of water. The increasing recognition of water as a limited and valuable commodity, and the associated environmental concerns with the management of water disposal to the environment has led the industry into improving on-site water management. Progressively, water balance models and water reuse strategies are being developed, incorporating more sophisticated water treatment processes. By way of example, membrane technologies, once restricted to industries such as the pharmaceutical industry or the drinking water industry, are now entering the mining world with the aim of producing clean water of suitable quality for ore processing or for advanced treatment prior to release to the environment. This paper will provide a review of the threats and opportunities linked to water use and recovery/reuse in the mining industry in Australia. It will open with an overview of current water usage and associated quality for various mineral industries and continue with identifying the threats and limitations associated with the quality of available water. It will then present how newly developed water treatment technologies and assessment tools can be incorporated into the system to enhance the recovery and reuse of water on site, reduce the risks associated with securing long-term water supply and further improve production, environment and safety (health risk control).

Jan 1, 2006

By H. Higuchi

The Sumitomo Metal Mining Company Ltd. (SMM) started to produce electrolytic nickel at the Niihama Nickel Refinery in 1939. In 1992, the conventional matte electrorefining process was converted to the matte chlorine leach electrowinning (MCLE) process, which is currently in practice. SMM has mainly used two kinds of nickel matte as the raw material for the MCLE process. Treatment of new raw materials, which have different impurity contents from the original nickel matte, has become mandatory because of changes in the market. Therefore, the MCLE process has been required to increase its flexibility to treat the different impurity contents in the new raw materials. An increase in the capacity for iron removal is included in such requirements. A new iron removal circuit in the MCLE process, based on a process development study, was recently installed. The iron removal circuit is in operation, and efforts are currently underway to optimize the performance of the circuit by changing the present operating parameters. In addition to the removal of the iron, the application is also expected to improve the nickel recovery. The outline of the new circuit and the current iron balance in the MCLE process are described in this paper, together with the effect of the circuit on iron treatment capacity.

Jan 1, 2006

Sampling of CIL/CIP circuits is typically done by compositing samples of feed and tails over eight or 12 hour periods. As the residence time in the leaching tankage may be approximately 20 hours, the tails from any period being derived from material entering the circuit 20 hours earlier do not correspond to the head from the same sampling period. Moreover, mixing in the series of tanks in a circuit also modifies correspondence between input and output. A special purpose simulator has therefore been developed to allow for the mixing and delay in the tankage and permit estimation of the head assays corresponding to any tailings sample. Thus more accurate assessment of the day-to-day recoveries of gold and silver follows. The model, programmed in Excel, assumes that the tanks are perfect mixers. By inputting the sequential head grades and considering that no leaching has occurred, the head grade which corresponded to the tailings for each period could be estimated. Allowance is made for variations in feed rate over the sampling period by computing the average flow rate of slurry and thus the residence time of each increment of the tailings. This simple model and its application have been found to be subject to some limitations, which are discussed in the paper, resulting in some unresolved variability in results. However, for a typical circuit even the simple model was able to greatly improve consistency of recovery data with variations being approximately halved by eliminating much of the anomalous variation arising from the lack of correspondence between head and tail when changes in head grade are occurring. Therefore, this permits genuine variations in metallurgy to be identified with greater confidence and thus operational shortcomings can be identified and addressed more quickly.

Jan 1, 2006

By A. D. Besser

The world production of lead has been growing continuously and reached over 7 million tonnes in 2005. At the same time, the structure of lead consumption has changed: the use of lead compounds to liquid fuel has been virtually terminated; the proportion of lead for manufacture of lead-acid batteries has been growing and reached 76.7% of the overall world production of this metal. This has taken place against the background of increasingly stringent environmental norms and environmental legislation. This is due to the lack of an alternative for lead in manufacture of local power sources. A solution to the problem of meeting the industrial demand for lead with simultaneous reduction in the primary lead production is in recycling. A large amount of batteries manufactured worldwide and their short life cycle, as well as the positive economics and a possibility to comply with the environmental requirements encourage the development of secondary lead production. Currently, over 60% of the world demand for lead is met due to recycling. The current situation with collection, transportation, storage and processing of spent lead-acid batteries has been analyzed in this paper. Examples are given to illustrate technological and equipment solutions and trends for improvement of secondary lead production discussed.

Jan 1, 2006

By A. Jain

During sheet forming, metal experiences not only multi-axial load, it also undergoes strain path changes. For example, metal in the flange region may be drawn, may bend and unbend through a bead, before bending around a die radius, etc. Compression data were obtained from AZ31 sheet after pre-straining in compression along an orthogonal direction. The compression directions correspond to the sheet product (rolling-RD, transverse-TD, and normal-ND) directions. Three cases are examined: slip dominated deformation (ND) followed by twin dominated (RD or TD) deformation, twin dominated (RD or TD) followed by de-twinning (ND), and twin dominated (e.g. RD) followed by cross-twinning or secondary twinning (e.g. TD). Slip induced pre-straining simply hardens the material, while twin dominated pre-straining alters the texture allowing the material to either de-twin or re-twin upon changing the strain path. Polycrystal plasticity modeling has been used to predict qualitative features of the flow curves during strain path changes.

Jan 1, 2006

By Pinakin C. Chaubal

Today?s steel industry is in a vibrant and resurgent mode. This transformation has been in the making for some time now. Over the last few decades, the industry was steadily transforming itself into becoming a high tech industry. New technology was adopted, efficiencies were enhanced, lean manufacturing concepts were brought in and a strong customer focus was developed. Today?s mills employ sophisticated instrumentation, computerized monitoring, on-line smart systems etc. driving processes that are producing at rates of many tons/minute. All this is not possible without judiciously using the latest available technologies in various fields and developing a more sophisticated work force. Prof. Sohn has been a pioneer in driving the concept of process engineering in process metallurgy. In this paper the focus is on some aspects of process engineering ? primarily process modeling - as applied to iron and steelmaking processes. Examples are shown to demonstrate how problems have been addressed. Some thoughts on future directions are presented.

Jan 1, 2006

By J. Nalaskowski

A study of the interfacial properties of the basal plane and the edge surfaces of talc is described in this paper. The isoelectric point measured at the two different crystallographic planes by the streaming potential method was found to be similar and exists at about pH 3.0. In the case of the edge surface the zeta potential increases at higher pH values which can be attributed to the hydration of magnesium ions at the edge surface. The atomic force microscopy (AFM) colloidal probe technique was used to measure interaction forces. For such experiments a 20 um talc particle was attached to the AFM cantilever and forces between the edge of the talc particle and two different crystallographic planes of talc were measured at various pH values. These measurements, while being qualitative due to the poorly characterized contact area, show differences between the properties of the base plane and edge of the talc and correspond to the results from streaming potential measurements. Finally, the differences in the hydration of the basal plane and the edge of talc are revealed from molecular dynamics (MD) simulations. The basal plane of the talc is much less hydrated than the edge, as can be seen from the water density distribution functions, which correlate quite well with the contact angle measurements at the basal plane surface and the edge surface of the talc sample.

Jan 1, 2006