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By D. Bartley, R. McClure, W. Reisz

Ever since the 8ms criterion was developed in the early 60’s there has been an ongoing debate among many blasters as to its actual value in controlling ground vibration. The perpetuation of the myth surrounding the 8ms window can be partly attributed to its simplicity and convenience as a means for regulatory compliance. Unfortunately, the mindset that many blasters have adopted has hindered the development and use of more effective techniques and in many cases can actually be counter productive to vibration control.

Jan 1, 2006

By Florian Kongoli

While calcium ferrite slags have been successfully used in continuous copper converting for the last 30 years, ferrous calcium silicate slag was proposed about 8 years ago as an additional alternative for copper smelting. Although both slags are normal extensions of each other their phase relations have not been completely clarified. In this paper the liquidus relations of both slags have been quantified at various areas that cover both of them. The existing experimental data have been first reviewed and discussed in relation to the solidification procedure. An original physical model is then used to predict various diagrams of the liquidus surface of both slags. It is shown that the ternary liquidus diagrams normally used for FeOx-SiO2-CaO system are not suitable for industrial slags. The new model diagrams of Fe/CaO versus SiO2 and Fe/SiO2 versus CaO as well as Fe/CaO versus Temperature and Fe/SiO2 versus temperature are proven to be much more convenient for ferrite and ferrous calcium silicate slags. Based on these diagrams the effect of SiO2 and CaO on the melting temperature is quantified. The effect of Cu2O is also quantified through the model. Some Fe/CaO versus Cu2O and Fe/SiO2versus CaO at various copper contents are predicted and the results show good agreement with the experimental data. It is also shown that in the presence of liquid copper, Cu2O is dissolved in the slag depending on the oxidation degree of the system and might lower the liquidus temperature. Some discussions are also presented taking into account plant observations and important conclusions are drawn for copper smelting and converting

Jan 1, 2006

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By Jeong-Soo Sohn

Physical treatment and chemical treatment of spent lithium-ion battery were studied in our research team. Especially we developed two types of acidic leaching for crushed powders containing LiCoO2 of spent lithium ion battery. One of them is sulfuric acid leaching with H2O2 as a reducing agent. The leaching rates of cobalt, lithium and the other metals were above 99 % at the condition of 2 M H2SO4, 10 vol. % H2O2, 75 °C, 300 rpm agitation speed, 250 g/5L solid liquid ratio and 75 minutes reaction time. And the other leaching process is the oxalic acid leaching. In this process more than 99% of Li and less than 1% of Co were dissolved at the condition of 3M oxalic acid, 80°C reaction temperature, 300rpm agitation speed, 50g/L initial solid/liquid ratio and 90min extraction time. Each process has its advantage and disadvantage. In sulfuric acid leaching, leaching reagent is very cheap and cobalt could be recovered into cobalt hydroxide. On the other hand, oxalic acid is more expensive than sulfuric acid but lithium could be dissolved selectively. Also cobalt could be recovered into cobalt oxalate and it could be changed into cobalt oxide after heat treatment. In order to select the effective recycling process, recovery rate and purity of cobalt hydroxide and cobalt oxalate were compared and it was investigated which process was more environment-friendly and economical.

Jan 1, 2006

By M. Christou

The LIFE-Environment Demonstration Project ?Treating Waste for Restoring Land Sustainability?(www.bangor.ac.uk/ies/TWIRLS/TWIRLS_home.htm), a project initiated by the University of Wales, Bangor, UK in which NAGREF is a partner, aims to demonstrate the effective use of industrial and municipal wastes for the remediation of post-industrial and degraded sites in urban and rural sites. Within the framework of this project, a schist quarry, which is located in a mountainous area near Athens and which has been exploited in the past for cement production, was chosen for bioremediation experiments in collaboration with the quarry owners, TITAN Cement Co. Three different areas within the quarry were selected representing 3 different topographies. These were a compacted, flat area with seasonal water logging (untreated control), a gently sloping, land formed area; and artificially created mounds of overburden rock material formed on the flat area. Compost produced from mixing municipal waste, green waste and digested sewage sludge at the recycling plant of the Association of Communities and Municipalities in the Attica Region (ACMAR), near Athens was used for nutrient amendment. Six replicates of three treatments were applied with varying compost application rates in order to examine the effect of the addition of organic matter in the establishment of suitable vegetation on the infertile schist material. Pine trees (Pinus halepensis Mill.), 4 per replicate, were pocket planted in a volume of 3 liters of schist or schist-compost mixture (1:2 and 2:1). Tree height, main stem diameter and branching were measured following planting and these measurements will be repeated annually to test hypotheses that compaction and water logging reduce Pine establishment by natural regeneration and that nutrient addition improves establishment of pine on schist waste. The availability of nutrients and variation in other soil physico-chemical parameters will also be studied in each treatment and related to plant growth. As a demonstration project, open days are planned on the site for the public and official bodies involved in municipal waste handling and other relevant areas. The aim of these will be to illustrate the effective re-use of waste for the sustainable restoration of post-industrial and degraded land.

Jan 1, 2006

A number of impending and actual pit wall failures have been observed and documented, which have been interpreted to initiate on newly generated structural features. This infers failure through intact rock. Failure mechanisms have been postulated resulting from circumferential stress, extensional strain and brittle flexure. These will be discussed in the context of the failures and the associated monitoring. The implications of failure initiating on ?unknown? features has a significant impact for deep open pit mines where designs are based on the expected structural regime. Being able to anticipate such failures is important for design. Equally important is management of such changes as they arise. In this context, monitoring using high resolution microseismic techniques will be discussed as a means of providing early warning of such failures.

Jan 1, 2006

By Gustavo Armijo

Slippery and unstable working platforms spoiled not only by natural weather conditions but also by the effects of the construction process (drilling mud, grout slurry) are among the main sources of hazards. Due to this fact a set of recommendations for execution and maintenance of working platforms are presented in this paper, which is based on a study on this subject that is being carried out by AETESS, the Spanish Federation of Geotechnical Contractors. The main objective of this paper is to establish the basis for the right execution and maintenance of working platforms for geotechnical jobs with the idea of increasing safety and productivity. All the aspects involved in working platform safety are analyzed: ground and equipment characteristics, geometric conditions and working platform maintenance. From this analysis a set of general requirements is proposed together with the necessary specific controls before and after the equipment arrival to the job site. In order to facilitate this analysis some flow charts and tables and specific appendixes for each geotechnical technique are included.

Jan 1, 2006

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By Ravinder N. Reddy

Electrochemical capacitors are charge storage devices. They bridge the gap between dielectric capacitors and batteries in terms of energy and power density. Electrochemical capacitors are classified into two types, electrochemical double layer capacitors (EDLCs) and capacitors based on pseudocapacitance. In EDLC, charge is stored at the interface between electrode and electrolyte. Carbon is considered to be prime electrode material for EDLCs due to its many favorable characteristics. In this study carbon materials are derived from thermal decomposition of catechol- formaldehyde polymers and are studied as electrode material for electrochemical double layer capacitors. Carbon electrode surface is characterized using NOVA 1200 gas sorption analyzer. It is also characterized using XRD and SEM. Carbon electrodewaselectrochemically characterized using cyclic voltammetry (CV). A highest capacitance of 110 F/g was observed in 30 wt% H2SO4.

Jan 1, 2006

By F. T. Cawood, M. A. Jooste

This paper describes the survey monitoring processes at Venetia, which are discussed under visual inspections, ad hoc investigations, system monitoring and slope stability radar monitoring. This is followed by a description of the main survey monitoring methods. The next section briefly states typical problems, i.e. the atmospheric corrections required to adjust total station distances, maintenance of the system and management of the monitoring process. The paper ends with some important lessons that could be applied to similar monitoring programmes. These lessons are firstly, communication is most important, process a vital part of the system, a champion must take responsibility for the programme and system planning ensures that the monitoring results are needs driven.

Jan 1, 2006

By J. Golamnejad

This paper attempts to model long-term production scheduling problems by chance constrained binary integer programming in a stochastic environment. This stochastic model is set up to account for ore block grade uncertainty. The probability distribution function of grade in each block is used as a stochastic input to the optimization model. This distribution function in each block should be determined using a Geostatistical Simulation approach. The deterministic equivalents of these chance constraints are then achieved, which are in the form of nonlinear in binary variables. A confidence level at which it is desired that the uncertain constraints holds, is specified in each scheduling period. Rather than the previous risk-based model, this formulation will yield schedules with a high chance of achieving planned production targets while maximizes the expectation of net present value and minimizing the variance function simultaneously. Using this method, the grade uncertainty is integrated explicitly into the optimization process.

Jan 1, 2006

By L. Rosato

In the past decade, as a result of increasing iron loads, Canadian Electrolytic Zinc (CEZinc) has become a pioneer in understanding the critical factors that affect the roasting of concentrates with high pyrite contents as well as those factors governing the effects of high iron loads on the leaching circuit. De-bottlenecking efforts in the roaster and acid plant section of CEZinc have given rise to a better appreciation of the impact of iron on roaster productivity. High standards for impure solution quality, zinc recoveries and residue disposal have all led to an increased comprehension of the limits of the leaching circuit and the optimization potentials with respect to iron and ferrites. In this paper, the impact of iron on the roasting and leaching circuits of CEZinc will be reviewed and special emphasis will be given to some of the more recent process optimization and improvement activities.

Jan 1, 2006

By A. Singh

Deformation structures after tensile and compression tests on Mg926Zn64Y alloy extruded at 250°C and 400°C are studied, in as-extruded and heat treated conditions. The icosahedral phase particles stimulate recrystallization during extrusion, resulting in fine grain size. Tensile and compression tests at room temperature show comparable yield strength, with a yield asymmetry ratio up to 0.98. c-type dislocations are observed in the grains near the submicron size icosahedral phase particles. The source of these dislocations is believed to be dissociation of <c+a> type non-basal dislocations. No dislocation pile-ups on icosahedral phase particles are found. {10 1 2} type twinning occurs in compression.

Jan 1, 2006

By Panfeng Gou

In order to solve the problems of supporting the roof of the gateroads affected by a fault, the movement characteristics of roof strata must be fully understood. In this paper, a plane stress physical simulation model was constructed to study roof strata displacement and deformation of gateroads driven in the hanging wall of the fault after the coals in the footwall were extracted. The results indicated that, due to the effect of fault, vertical cracks, orienting parallel to the dip of the fault, occurred in the horizontal direction of the model within the areas affected by the fault. The roof strata are discontinuous. On the other hand, non-uniform subsidence of roof strata occurred due to the bedding plane separation in the vertical direction. Roof strata, especially the lower roof strata, dip toward the fault. Failure of the surrounding strata is not symmetrical with the roof and floor close to the fault being deformed severely. In the selection of type of supports for the gateroads, the U-shaped steel supports are superior to roof bolting.

Jan 1, 2006

By J. Loredo

The Asturian Central Coal Basin, in northern Spain, has been from 18th century an important coal producing area in Spain. Previously to mining activity, aquifer systems were of multibed porous type but the secondary porosity induced by mining operations and constituted by mine voids and fracturing modified the aquifer systems to karstic-porous type. The pumping stop associated with mine closure processes results in the flooding of the mining works. This causes important modifications in the hydrogeology and the hydrology as well as in water flow and in water quality. As a consequence of mine flooding, water overflows through shafts and old galleries or through not controlled ways of water leak to surface. Water tends to recover the original piezometric level, but materials significantly modified by the mining activity behave differently in terms of hydrogeology, and thus, the recuperation of the water level can affect infrastructures and housing in the area of the mine. When pumping stops, the quality of water can also be seriously affected when water comes in contact in oxidant conditions with sulphides and sulphates present in the surface of the materials that are flooded, especially in the subsequent period immediately after pumping stop.

Jan 1, 2006

By Donald R. McMahon

This paper presents a unique case history that documents the use of a braced secant pile wall to underpin a heavily loaded footing inside of a manufacturing plant. Construction of a pit for a new manufacturing process directly next to the footing necessitated the underpinning. The footing supports an overhead crane that needed to remain operational throughout construction of the pit and therefore, settlement of the footing could not be tolerated. The base of the footing was about 7.7 feet above the base of the 17-foot deep excavation. The footing bears on a silty clay deposit that grades from a stiff consistency beneath the footing to a soft/medium consistency near the base of the pit excavation. This paper describes the design and construction of the secant pile wall and bracing to control wall deformations, ground movements and settlement of the footing. The footing was monitored for settlement throughout construction of the pit and no measurable movement was observed.

Jan 1, 2006

By M. Gous

Keywords: Pyrometallurgy, Namakwa Sands, ilmenite, DC arc furnace, titania slag, pig iron Namakwa Sands is a heavy minerals mining and beneficiation business in the Anglo Base Metals Division, and operates along the West Coast of South Africa. The business encompasses mining, mineral concentration, separation, and smelting operations. The smelting process comprises the carbonaceous reduction of ilmenite to produce titania slag with a TiO2 content of 86%, and iron with a carbon content of 2.5%. The Namakwa Sands smelter, situated near the Saldanha Bay harbour, commenced smelting operations in 1994, when a 25 MW DC arc furnace was commissioned. The smelting operations were expanded in 1999, with the commissioning of a second 35 MW DC arc furnace. Despite the fact that ilmenite smelting poses a technical challenge in terms of the high temperatures required, the physical characteristics of the slag, the constraints placed on the feedstock, and the tight product specifications, Namakwa Sands has continually increased slag production since 1995. High furnace feed-on utilisation and furnace stability, complemented by continuous improvement drives, will be the vehicle to drive performance in the short term, with longer-term performance enhancements due to strategic process development.

Jan 1, 2006

By David Norval

Water solidification of mattes, metals, alloys and certain slags with high metal entrainment has customarily not been practiced due to the belief that such processes are too dangerous and unproven in the Pyrometallurgical Industry. Slag granulation on the other hand is extensively applied, although in some cases crudely, with disastrous effects, as a result of not recognising the high heat capacities prevalent in slags. This paper will examine the most common air solidification processes and compare such processes with water solidification, mainly slag and matte granulation processes and design criteria for safe and reliable operation. Finally, purpose designed granulation and solidification processes will be discussed taking into account specific applications and the individual signatures of alloys and slags, emphasising that no slag, matte or alloy responds in similar fashion to a granulation practice.

Jan 1, 2006

By Maria Cristina Ruiz

The removal of iron from the leaching circuits is a common problem in the hydrometallurgical processing of non ferrous metals. Among the currently available processes, hematite precipitation is the most recommendable from an environmental point of view. This paper is concerned with the batch precipitation of hematite from ferrous sulfate solutions. One of the main objectives of the study was to determine the effect of the experimental conditions on the extent of iron precipitation as well as the purity and the particle size distribution of the precipitates. The main variables studied were temperature (180 to 220 ºC), concentration of sulfuric acid (1 to 10 gpl), initial iron concentration (1 to 15 gpl) and partial pressure of oxygen (3 to 7 atm). The results showed that increasing the oxygen partial pressure from 3 to 7 atm produced a very small increase on the rate of hematite precipitation indicating that a large partial pressure of oxygen is not needed for an effective ferrous to ferric oxidation. An increase in the temperature produced finer precipitates with lower sulfur contents. On the other hand, an increase in sulfuric acid concentration and initial iron concentration produced precipitates with larger particle sizes and higher sulfur contents.

Jan 1, 2006

By P. Soupios

Seismic geophysical methods have long been used by geologists and geophysicists to delineate subsurface features. These techniques work because different types and strengths of soil and rock transmit energy at different velocities. The Crosshole-Downhole tests (CH-DH) and seismic refraction survey (RS) are among the most used methods in engineering applications to obtain the elastic properties of subsurface layers. As a result, seismic methods have evolved into a cost-effective tool for rapidly determining depth to bedrock in engineering and construction projects. The seismic methods are best suited to sediment thickness analysis, bedrock quality determination and detection of the presence of weaknesses in the bedrock before the erection of any civil engineering structures such as bridges, tunnels, dams and portals. Seismic methods are also useful in estimating the rippability of bedrock ahead of construction. These methods are particularly useful for large-scale projects that require a significant number of drill holes, resulting in a substantial investment of time and costs for drilling. The CH-DH and RS methods are typically comparable in total cost to drilling, but provide significantly more information in 2-D and 3-D and therefore reduce the likelihood of conceptually oversimplifying the subsurface conditions. The above mentioned methodologies were considered to be the most appropriate geophysical methods for investigating the shallow structure and the dynamic soil properties of the area where the Ilarionas Dam is scheduled to be constructed. The main target of this work was to prove the potential of geophysical methods in providing accurate information to the civil engineer and to obtain information on the dynamic soil and rock properties for earthquake design analyses for the dam construction. Specifically, nine refraction seismic profiles and three cross-hole-downhole seismic tests were implemented to determine the subsurface conditions of the study area. The tests determined the shear and compression wave velocity profiles versus depth and other crucial parameters such as Young and Rigidity modules. Furthermore, they allowed the detailed 2-D mapping (along several profiles of the study area) of the subsurface variation of the soil and rock dynamic moduli.

Jan 1, 2006