Search Documents

By P Elliott, D Pershke

In a minerals processing context, sustainability is about using natural resources more efficiently to achieve maximum economic benefits with minimal environmental impacts. It embodies five overarching themes, which the paper will illustrate with practical examples from Australian minerals processing plants. These are:resource utilisation and materials efficiency,process waste reduction and enhancement of co-product values,reduction of water use and impacts,reduction of energy requirements and greenhouse gas emissions, andenhanced control of minor elements and toxic materials. Sustainability could be embedded profitably in minerals plant design in three dimensions: 1.technology,2.design, and3.operations. This presentation discusses a set of principles that could be applied to minerals processing technologies and provides an outline of sustainability assessment and opportunities evaluation tools. The application of the tools is illustrated through a case study by analysing a suite of nickel processing technology routes. The analysis reveals that current generation of nickel processing technologies do possess real potential to emerge as sustainability champions in integrated processing of nickel ores and concentrates, if they are designed, engineered, and operated for sustainability and adapted effectively to site specific constraints and opportunities. The paper will address data gaps and uncertainties regarding the impact of scaling up of pilot-plant performance, and provides strategies to overcome them.

Jan 1, 2006

By Ephraim Jeya Kumari

The demand for the titanium dioxide pigments and the shortage of higher-grade titaniferous ores with low radioactivity and zircon sands worldwide has encouraged the development of new techniques for the beneficiation of lesser grade titaniferous ores. The inferior quality ores are invariably richer in radio-active and lanthanide oxides, which severely interfere with the fluidized bed chlorination reaction (FBCR), in which ultra-high purity titanium tetrachloride is distilled off for pigment manufacture. However the present beneficiation techniques require high quality ilmenite ores and are not suitable for upgrading lower grade ilmenite ores which do posses trace metals in the form of lanthanides and actinides as Al-phosphates and zirconium silicates, respectively. The presence of mineral hosts, zircon sand and monazite in ilmenite and anatase also increase in chlorine gas consumption in the FBCR and contribute to a larger volume of hazardous waste production, which must be neutralised at a significant cost before being disposed off safely. In view of the problems described for lanthanide (Ce, Nd etc) and actinide (Th, U) trace impurities in titaniferous ores, an alternative route, which is flexible and more accommodating for processing difficult ores, is discussed. In the new process, which may be used for richer grades of ores too, the ore is roasted in air with sodium carbonate below 950°C to promote the formation of water-soluble sodium ferrite and insoluble sodium titanate phases. In this investigation, the high-temperature roasting process and the ensuing hydrometallurgical leaching steps have been analysed in the context of selective separation of lanthanide and actinide minerals from the main titaniferous mineral structures. Evidences for the selective separation are presented based on the chemical (XRD, XRF, AA) and microstructural analysis (SEM, EDX, EPMA) of roasted mass and the leached product. The efficiency of selective separation is also reported based on the chemicals analysis and the particle size of the materials derived after leaching. The paper highlights the various thermodynamic aspects of reaction equilibrium in the Fe-Ti-O-Na system, and the effect of Eh-pH diagram in the determination of pH required for the better control of the removal of iron and sodium. Two different types of Ti ores, namely ilmenite and anatase, their crystal structure and the phase transformation will also be explained on the basis of wet chemical analysis, XRF, XRD, EPMA and SEM-EDX studies. The method developed examines the technological feasibility of the selective separation process.

Jan 1, 2006

By Tang Chaobo

According to the principles of simultaneous chemical equilibrium and electronic charge neutrality, the system of Mg(II)-NH3-CO32--SO42--H2O at 25°C has been thermodynamically analyzed. And the rule of solubility of MgCO3(s) in the system is discovered, the high dissolution field of MgCO3(s) is discovered too. Furthermore, the solubility of MgCO3(s) is increased with the increase of the concentration of SO42-, but it is decreased first then increased with the increase of the concentration of all the CO32- and the total concentration of ammonia and ammonium, and decreased with the value of pH being higher. Those results will has important significance on prepare magnesium chemical products and other salts carbonate that are strict with the content of magnesium with carburization method.

Jan 1, 2006

By P. A. Olubambi

The leaching of zinc and copper from Nigerian bulk sulphide ore with sulphuric acid in the presence of hydrogen peroxide was studied. The aim of the study was to investigate the effectiveness of hydrogen peroxide as an oxidant for the sulphuric acid leaching of zinc and copper from a complex sulphide ore. Distribution of elementals within the various particle sizes was initially determined by ICP-OES and XRF to provide a basis for explaining the dissolution process. The effects of concentration of hydrogen peroxide, particle size, stirring speed, and leaching time at a constant temperature of 298K were studied. There were variations in elemental and mineralogical composition within the different sizes. The concentrations of zinc and copper reduced as particle size decreased while silica, sulphur, iron and lead contents increased. Dissolution results showed that the leaching rate of copper was lower than that of zinc. The highest recoveries of zinc and copper were obtained at a leaching time of 180 minutes, stirring speed of 160 rpm, particle size of 75 µm and a concentration of 1M H2SO4/1MH2O2. It was observed that the leaching rate of zinc and copper increased with increasing hydrogen peroxide concentration. Increased stirring speed had a negative leaching effect as it promotes hydrogen peroxide decomposition. Keywords: Nigerian sulphide ore, zinc, copper, hydrometallurgy, sulphuric acid, hydrogen peroxide.

Jan 1, 2006

By Rolf Schillinger

Blasting activities on the surface or underground necessarily involve the most sensitive aspect of environment remediation, human response or annoyance. Such effects are unavoidably characteristic of those activities. For this reason, blasting activities are governed by law and official regulations under surveillance of authorities, where companies and explosives engineers have to proceed within proper limits. Subject of the paper is a practical way of handling some necessary vibration standards being focused on blasting activities. The paper is based on the German Standard DIN 4150, Part 1 - 3, “Vibration in buildings”, Part 1: “Prediction of vibration parameters”, June 2001, Part 2: “Effects on persons in buildings”, June 1999 and Part 3: “Effects on structures”, February 1999.

Jan 1, 2006

By Leigh Freeman

This article provides an overview for a series of leadership development workshops offered through the SME Young Leaders Program. The first of these workshops, “Accelerated Development Plan,” will be held at the upcoming SME Annual Meeting in St. Louis, MO on Sunday, March 26. How does a foundation of technical competencies relate to the development of social competencies necessary for management and leadership roles in the resource sectors? Technical competencies provide the foundation for a successful career. Social competencies provide the framework on that foundation. Successful leaders will be those who develop competencies in all areas.

Jan 1, 2006

By Pinakin Chaubal

The campaign life of a modern blast furnace depends on hearth wear. Distributions of liquid iron flow and refractory temperatures have a significant influence on hearth wear. A 3-D comprehensive CFD model has been developed specifically for simulating the blast furnace hearth. It includes both the hot metal flow and conjugate heat transfer thorough the refractories. The model has been extensively validated using measurement data from actual blast furnaces. Good agreements between measured and calculated refractory temperature profiles haven been achieved. It has been used to analyze the velocity and temperature distributions and wear patterns at different furnaces and conditions. The results can be used to point out the directions for protecting the hearth.

Jan 1, 2006

By A. Exikis

Simulating a ventilation network of an underground mine can help in solving complex ventilation systems with many features, selecting proper fan specifications, location and settings. Early computer systems running simple network simulations were able to provide solutions to the most common and immediate problems regarding underground mine airflow. The more advanced systems available today can perform more sophisticated modeling and simulation of a mine?s ventilation network and present their results in a more understandable and easy to communicate form. This paper presents a ventilation network case study from an underground mine. All aspects of mine ventilation network modeling and simulation are discussed as well as the results from the simulation process. The algorithms and techniques used are thoroughly explained. Some useful guidelines for the application of ventilation network software are also provided in the text.

Jan 1, 2006

By W. Bullen

A hypothetical economic model has been developed for diamond projects in the Canadian Arctic using data from recent exploration and mining projects. The model reflects economic conditions applicable to the diamond mining industry in the Canadian Arctic at the present time. The economic model captures pre-production expenditures, production data, and post-production costs. Before- and after-tax cash flows are derived from the data along with the relevant economic criteria. From the corporate perspective, the model provides guidance concerning the minimum size and/or in situ value per tonne requirements of targets being sought in order to ensure economic success and predict exploration and development expenditures. From the government perspective, the model provides an indication of income and mining tax revenues that can be expected from a particular diamond project. The model shows, on average, diamond projects in the Canadian Arctic are expensive to explore for and develop, but are economically robust under the present conditions. They generate great economic return for mining companies and significant amounts of tax revenue for governments. The fact that diamonds can be transported directly from the minesite by air makes them particularly attractive targets for mining companies that operate in the Canadian Arctic.

Jan 1, 2006

By Paul J. Axtell

Two new railroad bridges in Kansas City, Missouri are founded on drilled shafts embedded into the soil and underlying shale. The uncertainty arising from the non-homogeneous, anisotropic nature of most shales, and the variability of shales across the U.S., makes it a difficult material to assign appropriate design properties. As was the case on this project, the uncertainty of foundation performance in shale can lead to overly conservative designs, particularly with drilled shaft foundations. An extensive Statnamic axial testing program was performed to verify that the load-settlement behavior of the drilled shafts would be acceptable for the intended railroad traffic. Axial Statnamic testing was applied in three increasing cycles of 927 kips, 1007 kips, and 3177 kips, respectively. The maximum movements recorded at the shaft head during each of the loadings were 0.052 inches, 0.062 inches, and 0.257 inches, respectively. The loads applied in each of the respective Statnamic tests were not sufficient to reach the capacity of the shaft; so direct comparison of measured and calculated capacities is not possible. However, evaluation of the estimated design capacity can be accomplished based on results from the Statnamic testing program by utilizing normalized load transfer relations presented by O?Neill and Reese (1999). Such comparisons necessarily require extrapolation of the data measured in the Statnamic tests following typical load-displacement response. Results indicate the Kulhawy and Phoon (1993) method for estimating side resistance in Pleasanton shale rock sockets, assuming a smooth socket, appears to agree well with observed behavior during Statnamic testing. Accordingly, the O?Neill and Reese (1999) method for estimating the toe resistance in intermediate geomaterials, assuming cohesive rock with Rock Quality Designation (RQD) between 70 and 100, appears to agree well with observed behavior during Statnamic testing. Finally, based on Statnamic testing at varying load magnitudes and normalized curves developed by O?Neill and Reese (1999), the contribution of side resistance to the capacity of a deep foundation can be determined assuming no load is transferred to the base of the foundation during lower magnitude testing. Furthermore, higher magnitude testing can provide a means to evaluate the accuracy of design end bearing calculations.

Jan 1, 2006

Outsourcing of mining operations and services is done for various reasons and there is no single model which fits all situations. Experienced contractors and mine owners have also developed, more often than not, jointly, numerous commercial arrangements and project delivery methods to suit their particular project. It is often the case that some mine owners who have not considered outsourcing to contractors do so because of a simple lack of understanding of the potential benefits. This paper will highlight the potential benefits and perceived disadvantages of outsourcing for mine owners and demonstrate how these issues have been addressed by the mining contracting community over recent times as well as demonstrate the evolution of current commercial arrangements in engaging mining contractors.

Jan 1, 2006

By Jose L. Garcia

The following document aims to cover all issues concerning the three main methods employed for the in-situ survey of concrete pile integrity. Within it are described both sonic coring and low-strain tests and the frequency and time domain analysis of their results, which are the most advanced techniques currently in use in Spain. The survey techniques described were developed and began worldwide deployment in the 1960s, but it was not until the 1980s that they saw large scale implementation in Spain, largely thanks to the miniaturisation of electronics and computer equipment that made them easier to use on-site. Sonic coring, echo and frequency-response testing or mechanical impedance tests are spreading further every day. However, there appears to be a need for standardisation of the testing methods, as well as their implementation, interpretation and the presentation of results. The goal of these Spanish recommendations is to serve as a guideline for test standards and to provide examples for a correct and commonly agreed interpretation of test results, as well as settling any differences in the evaluation of defects detected in foundation works.

Jan 1, 2006

By Jose Castro

The growing demand of scrap to supply the electric arc furnace has driven to search for new alternatives of raw material. The DRI produced using self-reducing pellets has become competitive due to the potential use of a wide range of carbonaceous materials such as coal, charcoal, biomass etc. In this context, the rotary kiln process using improved technologies such as post-combustion and self-reducing burden is a promising source of high quality raw materials. This paper presents a mathematical model of the rotary kiln process designed for self-reducing pellets and post-combustion. The model is based on the transport equation of two-phase flow, energy and mass transfer. The solid material is composed of a typical self-reducing pellet. The model considers the solid phase (C, volatiles, Fe2O3, Fe3O4, FeO, Fe, H2O, SiO2, Al2O3, MgO, P2O5, K2O, Na2O, FeS, CaO and gangue) and the gas phase (N2, O2, CO, CO2, H2, H2O, SO, SO2 and SiO). For each of the above components a conservation equation is solved and the mass and energy transport is accounted. The set of differential equations are coupled by the rate equations describing the kinetics of the several reactions, which take place within the rotary kiln. All the conservation equations are solved based on the finite volume method applied for a three-dimensional cylindrical coordinate system. Simulation results are presented for global parameters such as metallization degree, productivity, gas utilization ratio and calorific value. Inner conditions such as three-dimensional gas and solid temperature patter and compositions are discussed.

Jan 1, 2006

By Florian Kongoli

While calcium ferrite slags have been successfully used in continuous copper converting for the last 30 years, ferrous calcium silicate slag was proposed about 8 years ago as an additional alternative for copper smelting. Although both slags are normal extensions of each other their phase relations have not been completely clarified. In this paper the liquidus relations of both slags have been quantified at various areas that cover both of them. The existing experimental data have been first reviewed and discussed in relation to the solidification procedure. An original physical model is then used to predict various diagrams of the liquidus surface of both slags. It is shown that the ternary liquidus diagrams normally used for FeOx-SiO2-CaO system are not suitable for industrial slags. The new model diagrams of Fe/CaO versus SiO2 and Fe/SiO2 versus CaO as well as Fe/CaO versus Temperature and Fe/SiO2 versus temperature are proven to be much more convenient for ferrite and ferrous calcium silicate slags. Based on these diagrams the effect of SiO2 and CaO on the melting temperature is quantified. The effect of Cu2O is also quantified through the model. Some Fe/CaO versus Cu2O and Fe/SiO2versus CaO at various copper contents are predicted and the results show good agreement with the experimental data. It is also shown that in the presence of liquid copper, Cu2O is dissolved in the slag depending on the oxidation degree of the system and might lower the liquidus temperature. Some discussions are also presented taking into account plant observations and important conclusions are drawn for copper smelting and converting

Jan 1, 2006

By El-Sayed M. Sherif, J. D. Comins, Erasmus R. M.

Corrosion of copper in aerated acidic chloride pickling (0.5 M HCl) solutions and its inhibition by 3-amino-1,2,4-triazole-5-thiol (ATT) have been investigated using electrochemical techniques and weight-loss measurements, along with Raman spectroscopy. Electrochemical measurements for copper after varied immersion periods of 0, 24 and 48h showed that the presence of ATT and the increase of its concentration significantly decrease cathodic, anodic, corrosion (jCorr) currents and corrosion rates (KCorr), as well as the dissolution currents at 300 mV vs. Ag/AgCl, while increase polarization resistance (Rp), degree of surface coverage (?) and inhibition efficiency (IE%) to a great extent. Weight-loss measurements after different immersion periods of 6 ~ 48h revealed that the dissolution of copper decreased to a minimum and the corresponding IE% increased with ATT concentration increases. The detection of ATT molecules on the copper surface by Raman spectroscopy indicated that inhibition of copper corrosion is achieved by strong adsorption of ATT molecules onto the copper surface. Aerated acidic pickling solutions; 3-Amino-1,2,4-triazole-5-thiol; Copper corrosion; Corrosion inhibition; Raman spectroscopy

Jan 1, 2006

By Michael D. Justason

This paper describes the technology behind the development of an automated energy control system for a diesel pile hammer. Some background is given on experience using an energy monitoring system on the Route 1/I-95 interchange in Alexandria, Virginia. An adjustable hammer throttle and feedback from an energy monitoring system was then used to create a fully automated hammer energy control system. The performance of this system is described in reference to a piling project in Canada where the automated energy control system was used to obtain an unprecedented level of quality control and assurance ? data and graphs from the project are presented. The hammer energy control system (ECS) was used to successfully control and maintain a prescribed impact energy for the diesel hammer. This paper presents the first ever results from a truly automated diesel pile hammer and points to a new direction in quality control and assurance in pile driving.

Jan 1, 2006

By J. G. Wiese

Reagents are added to the flotation process of Merensky Reef ores to achieve specific functions that enable the separation of valuable minerals from gangue minerals on the basis of the difference in their surface properties. However, due to the complexity of the process, the various interactions that occur as well as the incomplete liberation of the ore and range of minerals present, it is difficult to quantify the behaviour of each of the reagents. More specifically, changes made to achieve a particular outcome may have secondary effects that can override the desired effect. If all the effects and interactions can be accounted for, it is possible to manipulate reagent suites and obtain better overall metallurgical performance. This paper discusses the effect of the addition of copper sulphate at different operating points of the recovery of the sulphide minerals. Batch flotation tests indicated that the recovery of chalcopyrite was not affected when operating conditions were varied, whereas pentlandite recovery was strongly affected by the point of reagent addition, and pyrrhotite recovery was enhanced by copper sulphate addition, irrespective of the point of addition, with the extent being dependent on the ore source. Floatable gangue was activated by copper sulphate in the presence of the dithiophosphate collector. Froth stability was also affected by copper sulphate addition.

Jan 1, 2006

By M Cooksey, C Goodes, G Wellwood

Light metals have great potential for application in the automotive and aerospace industries because of their excellent physical properties. The usage of aluminium, titanium and magnesium is limited by relatively high costs of production, associated energy costs and large ecological footprint. In the case of aluminium, significant improvement to the Hall-HTroult process is still achievable through advances in cell design, materials and process control. Alternative production processes, including carbothermic reduction and low temperature routes are also possible. Magnesium and titanium production are currently dominated by batch metallothermic processes and new process routes are required to develop these industries. Research at CSIRO, through the Light Metals Flagship, is currently focused on step change improvements in the production of light metals, aimed at lowering energy usage, increasing productivity and reducing the overall environmental impact. In this paper, the overall status of the existing technologies will be described, highlighting areas that are being developed around the world and at CSIRO.

Jan 1, 2006

By A. Yousefpour, M. Hojjati, G. Chouinard

In recent years, high performance thermoplastic composites such as PEEK and PEKK have been developed for aerospace applications. These materials offer, among the other properties, high toughness and damage tolerances. These are semi-crystalline materials and their processing can lead to different crystallinity that in turn have some impact on the final properties. The effect of cooling rate on degree of crystallinity of PEEK is studied to identify the processing window for manufacturing. Samples were heated at the constant heating rate of 20°C/min up to 375°C (above melting point) and held for 10 minute. The enthalpy of the crystallization was measured at different constant cooling rates of 0.5, 1, 2, 5, 10, 20, 30, and 40°C/min. After cooling, the samples were heated at constant heating rate of 2°C/min using modulated DSC. At temperature between 90°C to 375°C, two endotherm peaks were observed. Results suggest that endotherm peaks are related to a melting and recrystallization phenomenon of one crystal morphology. However, the second endotherm peak could be associated with another crystal structure or morphology.

Jan 1, 2006

By Natalya. N. Ankusheva

The problems of ore-bearing palaevolcanic structures in folded belts are actual because of their high productivity in nonferrous, ferrous and noble metals ores. Now relationships of location and conditions of formation for sulfide-massive and gold-bearing deposits are investigated very well in Urals. But carboniferous sulfide-barite mineralization, for example the barite veins in Arcaimsky palaevolcano are?nt studied enough now [3-5]. The purpose of this research is the studying of mineralogy and thermobarogeochemistry of barite from the hydrothermal veins. It will allow to determine the conditions of its formation and to compare it to the similar mineralization of others ore types.

Jan 1, 2006