Search Documents

By Dyno Nobel

Impact of Enhanced Security on Operations Budgeting - What is the “value” I receive for enhanced security? Is there a “return” for the money I spend? Regulatory driven Economic driven

Jan 1, 2006

By Jong-Oh Jo1

Thermodynamics of Ti, N and O in liquid iron was studied in order to establish a data base for the prediction of TiN and TiOx formation in liquid stainless steels containing various alloying elements including Cr, Ni and Si as a function of temperature. The interaction parameters of these elements on Ti and N were determined using the metal-nitride-gas equilibration technique. The TiN stability diagram for a commercial stainless steel grade was constructed from the measured thermodynamic parameters, and its validity was confirmed experimentally. The interaction parameters between Ti and O, and the equilibrium constants for Ti deoxidation reactions for the formation of Ti2O3 and Ti3O5 were also determined by the equilibration of the melts with those oxides identified by the XRD and the EPMA analyses.

Jan 1, 2006

By H. Al-Kazzaz

The effects of laser power and joint gap on the welding quality of 2-mm butt joints of ZE41A-T5 sand castings were investigated using a continuous wave 4 kW Nd:YAG laser system and 1.6-mm EZ33A-T5 filler wire at a welding speed of 6 m/min and surface defocusing. The smooth weld profiles with the minor welding defects were obtained at a laser power of 4 kW and joint gap of 0.3-0.4 mm. The hardness values in the fusion zone are similar to those of the base metal but there is a drop in the heat-affected zone after a natural aging of 18 months.

Jan 1, 2006

By C J. Moran

The Gladstone region, as one of the most industrially intense regions in Australia, uses significant quantities of fresh water. Awoonga Dam, situated on the Boyne River, is the only major source of water in the region. The current typical annual usage is 53 GL (Porteous, 2006) and approximately 80 per cent of the water is used by heavy industry (Gladstone Area Water Board, 2004). Until relatively recently, there has been ready and easy access to raw water for industrial use. The recent drought, which resulted in severe water restrictions in 2002 and 2003, emphasised the importance of water for a dominant industrial region like Gladstone. Although now in the process of changing, the typical contractual arrangements in the past have provided little financial incentive for efficient water use. From research undertaken on potential water reuse opportunities, several key questions have emerged related to water management in an industrial region such as Gladstone. This paper highlights these key questions, presents findings from recent regional strategies and assesses the potential for water reuse. Even though there is no clear-cut financial incentive for reusing water, there could be stronger regional and risk mitigation drivers for doing so. Initiatives to incorporate adaptive capacity through collaborative industrial synergies would allow for robustness and resilience in water security, leading to long-term sustainable water management across the Gladstone region.

Jan 1, 2006

This paper focuses on the dissolution of various Manganese based compact additions into liquid Magnesium. The experimental procedure employed cylindrical compacts with various Manganese compositions. The various temperatures of the additions and the Magnesium bath were measured simultaneously during the immersion of the additions into Magnesium bath. The exothermicity level of these additions during their dissolution into liquid Magnesium was determined. The relation of the exothermicity level with the dissolution kinetics was also examined. In addition, SEM and EDX work was conducted for additions, which were withdrawn from the Magnesium bath. Finally, the recovery of these additions was estimated by taking samples from the Magnesium bath and conducting ICP analyses.

Jan 1, 2006

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By J. A. Rusnak, M. M. Gadde, S. S. Peng

In situ stresses are one of the key inputs to a successful underground excavation design. Because of the complex mechanisms involved in arriving at the current state of stress at a point in the Earth’s crust, often the only reliable way of estimating in situ stresses is by actual measurement. In the United States coal mines, overcoring relief method is by far the most popular technique used for estimating the virgin stress field. Typically, for stress measurement with overcoring, a vertical borehole is drilled into the roof or floor of an underground coal mine opening to a certain distance and change in borehole diameter is monitored at multiple points along the length of the hole when this borehole is overcored. For the measured stresses to represent the pre-mining stress field, the measurement points should be located beyond the influence zone of the mine opening. Actual data from several US coal mines have been collected to check if the measured stresses by overcoring represent true in situ stresses. The data indicate that most of the stress measurements were within the excavation influence zone. A three-dimensional numerical modeling methodology was applied to one of the collected cases to correct the measured stresses for the excavation influence. The modeling approach demonstrated the usefulness of integrating numerical modeling into a stress measurement program to estimate ‘true’ in situ stresses.

Jan 1, 2006

By William F. Anderson

A series of pile load tests (maintained load tests, constant rate of penetration tests at different rates, and statnamic tests) was carried out on an instrumented model pile installed in clay beds prepared by consolidation of a slurry in a calibration chamber. The total load, shaft resistance and end bearing during the pile load tests were investigated. Following this, alternative methods of deriving the static load-settlement curve from a Statnamic test in clay taking into account damping effects have been proposed. These methods have then been used to interpret a statnamic test on a full size instrumented pile installed in a stiff glacial till.

Jan 1, 2006

By P. Su

Friction stir spot welding of a range of Mg-alloys is investigated (AZ91, AZ31, AM50 and AM60). The peak temperatures during friction stir spot welding of all Mg-alloys are close to their solidus temperatures. Also, the apparent material viscosity of Mg-alloy sheet is lower than that when Al-alloy sheet material is spot welded. This is important since it means that the widths of the stir zones forming during spot welding of Mg-alloy sheet are smaller than those when Al-alloy sheet is welded (when identical welding parameter settings are applied). These lower apparent viscosity values must be taken into account during numerical modeling of the Mg-alloy spot welding process. The efficiency of energy utilization is very low when Mg-alloy sheet is spot welded and is of the same order as that when fabricating Al-alloy sheet. The energy generation contributions of the rotating pin and the tool shoulder are investigated. When the spot welding operation is carried out without the application of a dwell period, the contribution made by the rotating pin vis-à-vis energy generation is around 66%. The contribution made by the tool shoulder increases to about 65% when a dwell period of four seconds is incorporated during the spot welding operation. This increase results from a longer contact time between the tool shoulder and material within the stir zone, The failure load during overlap shear testing increases when the bonded area and the energy input increase during spot welding. Sample failure initiates from unbonded regions and from discontinuities at the edge of the stir zone. The formation tendency of discontinuities is increased when Mg-Alloy sheet is spot welded because of the limited deformation characteristics of the base material at lower temperatures.

Jan 1, 2006

By L. C. Stilwell

The paper will attempt to identify the threats, however obscure, that could confront the South African platinum industry. South Africa has the largest reserves of platinum group metals in the world, and is the largest producer of those metals. This situation is no different from that which existed in the gold sector fifty years ago. Since then South Africa?s share of world gold production has dwindled, and the gold mining industry has lost its dominance. Unlike gold, platinum has widespread use as an industrial commodity. Its investment value is a minor portion of its total value. It is therefore subject to different market forces. The sheer magnitude of the industry in South Africa obscures the fact that it is a wasting industry, and that South Africa exports almost all its production as a refined metal in the form of autocatalyst. Since Hotelling published his seminal work The economics of non-renewable resource in 1931,the science of mineral economics has developed exponentially. The paper will present a background of mineral economic theory and compare to this the development of the South African platinum industry. Of particular concern to a mineral exporting country is the question of mineral rent?its definition and employment. This will be the mail theme of the paper.

Jan 1, 2006

By C. Braun, C. Kennedy, P. Katsabanis

A series of small scale tests, simulating multi-hole blasts have been performed to establish the effect of delays on blast fragmentation. The blasts were performed in high quality granodiorite blocks, which were cut from stone prepared by dimensional stone quarry operations. The pattern used was equilateral triangular, with a distance of 10.2cm between boreholes, which had a diameter of 11mm, were loaded with detonating cord and the coupling medium was water. The delays used were achieved using different lengths of detonating cord for the cases of delays between 0 and 100 microseconds between holes and a sequential blasting machine firing seismic detonators for larger delays up to 4ms. All fragments were collected and screened. The experiments showed that the coarsest fragmentation was achieved with simultaneous initiation of all charges. Fragmentation became finer with delay time between holes up to 1ms between holes. The results show that in moderate to competent rock, similar to the granodiorite of the experiments, fragmentation optimization requires delays of few milliseconds per meter of burden. In view of the findings, which agree with previous published work, the current trend of selecting fast firing times for fragmentation optimization is questioned.

Jan 1, 2006

By M. Furuta

Tamano Smelter of Hibi Kyodo Smelting Co., Ltd. has been operating without a slag cleaning furnace (SCF) since its start-up in 1972. It has used its own developed coke combustion technology, the Tamano-Type Flash Smelting Furnace (T-FSF). The coke combustion technology that is the core of the process, along with the installation of a computer guided system and the improvement of the concentrate burner combustion in the T-FSF have all contributed to having acceptable copper loss levels in the slag without using a SCF. However, recently, because a high concentrate charge rate has been used in order to achieve a high matte grade in the T-FSF, a short settling time has been experienced and copper losses in the slag have become difficult to maintain at a lower level. Furthermore it is estimated that copper losses will further increase after the completion of the next expansion because with the aim of having a higher matte grade operation at 67% less coke will be charged and the reduction effect of the settler will be smaller. Therefore, in order to maintain the copper losses in the slag within proper levels the installation of SCF was decided. This paper, describes the operation before the introduction of SCF along with some theoretical considerations of slag chemistry.

Jan 1, 2006

By A. Kraly, M. Complojer, P. Paschen, K. Gamweger, H. Antrekowitsch

Increasing quality of aluminium alloys and continuous optimization of the production process leads to an improvement of the gas purging systems. The application of porous plugs for the treatment of liquid aluminum is nowadays not widely used in the aluminium industry especially in Europe. The Department of Nonferrous Metallurgy and the Christian Doppler Laboratory of Secondary Metallurgy of Nonferrous Metals intensified the research and development of refining and alloying processes by gas treatment during the last years. CFD-modeling supports these experiments, which should lead to lower hydrogen content, lower suspended particles and a better distribution of alloying elements in the melt. Different parameters such as temperature, bubble size, gas amount and which kind of gas is used influence the quality of the products.

Jan 1, 2006

By V. K. Kalyani

The present paper discusses a three layer feed forward artificial neural network (ANN) model, trained using the error back propagation algorithm, has been established to simulate the column flotation circuit used for beneficiation of Sillimanite. Parameters such as superficial air velocity, wash water rate, froth height, % solid, feed velocity, sodium silicate and oleic cid are considered as process operating variables and % yield of Sillimanite is the output of the experiment. The results from the ANN modeling, involving the non linear relationship between inputs and outputs, indicate good agreement with experimental observations. The network model validates the experimentally observed trends. The optimal model parameters in terms of network weights have been estimated and can be used for computing parameters of the process over wide-ranging experimental conditions.

Jan 1, 2006

By Holger Cordes

X-ray diffraction has long been used for qualitative and quantitative mineral analysis but Rietveld data analysis is still an under utilized method for mineral exploration and processing applications. In this full-profile approach the structural parameters of each mineral phase, together with experimental parameters, are refined by least-squares methods to minimize the difference between observed and calculated diffraction patterns. The result is a standard-less, quantitative analysis of the mineral abundance in the sample that is more accurate and considerably faster compared to traditional methods. The TOPAS software package combines a user-friendly interface with a unique approach to resolve overlapping peaks. Automated analysis options are also available and significantly reduce analysis time for routine samples. Several examples on a wide range of naturally occurring rock types are shown that illustrate the capabilities and limitations of the method. The examples include several options for the quantification of amorphous constituents like volcanic glasses.

Jan 1, 2006

By David B. George

Kennecott Utah Copper adopted Outokumpu Flash Smelting and Kennecott-Outokumpu Flash Converting in 1995, a process based on granulating high grade copper matte. While nickel mattes and very small quantities of copper matte had been commercially granulated for years, no large scale copper matte granulation system had been built. This paper summarizes the history and benefits of copper matte granulation, the Kennecott design basis, the successful operation for over 10 years and potential problems inherent in some matte granulation approaches.

Jan 1, 2006

By Javier Rodriguez

Adaptive re-use of existing structures in urban environments has become very common due to lack of available space in our cities and requirements for increased structural capacity. Often, it involves retrofitting existing foundations to support increased loading. In such cases, Engineers face the need to review existing deep or shallow foundations for their true load carrying capacities in order to determine the required magnitude of retrofit work, if any. To accomplish this, the engineer must track down and cull through the existing construction documentation to determine what was actually constructed, complete an investigation to confirm these conclusions, possibly sample the foundation elements for strength properties, and on occasions complete non destructive or full scale load testing of indicator elements. This paper describes the typical procedure followed by the authors for design of retrofit schemes for existing buildings in the Washington DC metropolitan area. Three case histories are presented that illustrate various issues encountered during design.

Jan 1, 2006

By Peter Moser, G. Reihholf

Holcim, one of the world's leading suppliers of cement, aggregates and concrete, has set up a few years ago a working group “Quarry” in order to optimize the performance of its central European quarry operations in terms of work safety, environmental standards and economic performance. One of the activities of this working group "Quarry" addresses the subject of blast fragmentation in the quarries. A benchmark study of the blast work in all quarries has shown substantial differences for the various operations in terms of drill& blast costs. Especially big differences were found with respect to the drilling patterns as a function of the borehole diameters and with respect to the utilization of the borehole volume for charging the explosives.

Jan 1, 2006

By R. Hardy

LaModel is a boundary-element program capable of calculating the displacements and stresses in thin bedded deposits such as coal, salt, or potash. Throughout its history, it has continually been upgraded in order to expand analysis detail and stay current with the latest advances in computer technology. The most recent enhancements include: an increased grid size capability, a significant increase in the speed of the automatic grid generation using an AutoCAD visual interface, implementation of subsidence-based horizontal strain calculations for multiple-seam situations, and pillar safety factor calculations. To demonstrate these new features, a multiple-seam case study of a longwall panel undermining an active set of main entries is presented.

Jan 1, 2006

By G. Diaz

Técnicas Reunidas (TR) has been involved for over 30 years in the development of process technologies for the recovery of zinc from different primary and secondary feed materials, such as the ZINCEXTM process. Because of the complexity of the feed mineral resources, solvent extraction (SX) is an invaluable technique to concentrate and purify zinc solutions. When applied to a pregnant leach solution, solvent extraction can produce an extremely high quality zinc electrolyte, suitable for obtaining SHG zinc ingots, after electrowinning and melting and casting processes. However, the high affinity of most organic extractants for Fe(III) poses a serious problem, which may adversely affect the zinc extraction process. Different methods may be applied to deal with the negative effect caused by Fe(III). An acid regeneration step and electro-reduction stripping have been considered as the most viable techniques to remove the iron from the organic phase. This paper describes some findings of Técnicas Reunidas in the area of zinc solvent extraction, especially on removing Fe(III) from the organic phase.

Jan 1, 2006