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By M. Visser

Keywords: Pyrometallurgy, furnace, ferrochrome, Samancor, ferrochrome process Samancor Chrome has been, and continues to be, a major player in ferrochromium production. The company has a proud history and possesses benchmark technology and operations. Currently five business units are operating: two sets of mines and three smelter plants. Samancor Chrome produces around one million tons of charge chrome annually. Chrome ore, intermediate-carbon ferrochrome, and low-carbon ferrochrome, form part of the portfolio. Electrode paste is also manufactured through a joint venture with Highveld Steel and Vanadium. Samancor Chrome has a balanced approach towards operational strategy, and has entered into a number of joint venture partnerships. Through its access to quality raw materials, knowledge, and experience of various production technologies, and its strategic abilities, Samancor Chrome is well positioned to reap the benefits from opportunities in the current and future industry context.

Jan 1, 2006

By J. L. Huisman

Bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are becoming more and more accepted. In this paper the THIOMET process for general effluent treatment is described. With this process, it is possible to produce sulfide on-site and on-demand and to use the sulfide to precipitate metals, even selectively when required. The process is ideally suited as a treatment to remove metals after, for example, an acid regeneration process. Another process is proposed that deals with stainless steel pickling bleeds. Such effluents typically contain nitrate, iron, nickel, chromium(VI) and other species. This one process handles these compounds, as well as other metals.

Jan 1, 2006

By Osamu Yamamoto

In antibacterial evaluation of carbon-ceramic composites, we prepared two type composites with emphasis on carbon-ZnO system; one was porous carbon materials containing ZnO nano-particles and another was porous ZnO coated with carbon thin film. Porous carbon samples containing ZnO at highly dispersed state were prepared by carbonizing the resin exchanged by Zn2+ ion. Porous ZnO coated with carbon thin film was obtained by the pyrolysis of poly (vinyl alcohol). Antibacterial activity of these composites obtained was evaluated by measuring the changes in electrical conductivity with bacteria growth. The antibacterial activity on the composites increased with the increase of t he amount of ZnO in composite and decreased with the increase of carbonization temperature. The antibacterial activity for Staphylococcus aureuswas found to be stronger than that for Escherichia coli. No activity of the carbon samples without ZnO was observed. The occurrence of antibacterial activity was supposed to be due to the generation of hydrogen peroxide from ZnO in composite. In the present work, antibacterial activity of carbon-ZnO composites was studied in the details.

Jan 1, 2006

By R C. Schodde

The future of any mining company depends on maintaining and growing its access to high-quality mineral resources. Often the true size of a given resource is not fully recognised until after mining has commenced. Also, the strong desire to increase production puts pressure to expand the resource base of the mine to get maximum value out of the capital employed. This, plus diminishing M&A opportunities and declining world-class greenfield discovery rates, makes brownfields exploration a high priority activity in any operating company. For the success and long-term survival of the company it is critical that this is done well. The primary aim of brownfields exploration is to find or acquire new deposits within economic transport distance of an existing mine that will add materially to shareholder value through: mine or capacity expansion, displacement of lower-margin ore from the mine plan, preserving and extending the mine life, and ensuring potential value is understood in order to maximise potential future mine development or exit. A number of strategic principles are important in any program designed to achieve these aims: understanding the life of mine (LOM) production profile and the related key drivers for exploration, understanding the dynamic nature of the brownfields search space, understanding and measuring depletion of the brownfields search space, understanding the potential of the near-mine region, investing in exploration technology to expand the search space, and investing in a basic geological understanding of the ore-environment. Examination of the LOM profile will highlight critical issues facing development plans for the mine including future grade and throughput issues, key technology requirements or innovations and scenarios for increased production. Exploration targets in the brownfields program should address these key issues. Often it is as æsimpleÆ as keeping mine development sufficiently far ahead of extraction to allow time for the various phases of exploration and resource assessment drilling. Because of the low additional capital costs required, expansion of the brownfields search space is strongly leveraged to: metal prices, development of new markets, incremental operating cost reductions, strategic changes in downstream requirements in integrated businesses, depletion of higher unit-value ores, and new technologies (both extraction and exploration). Therefore the brownfields search space is likely to incrementally expand through time and must be regularly reviewed. This is also important as any given search space will be progressively exhausted, resulting in smaller and higher cost discoveries. It is therefore important to monitor and critically review sustained trends of increasing brownfields discovery cost. The first wave of discoveries in any camp are usually empirically driven and do not need a strong geological understanding. However, an improved geological understanding is critical to making the next generation of hidden discoveries. To illustrate these points, a case study was carried out on the exploration and development history of the Kambalda nickel camp. Over a period of 40 years, more than 40 deposits were found containing over 1.7 million tonnes of nickel metal. Efficient mines need to maintain reserves for operating flexibility. Consequently, the company needs to clearly understand the global resource in order to maximise its full potential. In addition, understanding the full brownfields potential earlier in the development of a deposit rather than later, creates optionality through the flexibility that this understanding brings to future development choices. To ensure best practice in attaining this aim, the roles and responsibilities of the exploration team and the mine operation should be clearly understood. It is important for the explorers and the operators to have shared views about what needs to be done. Typically, mine operators would be accountable for identifying future resource requirements to support the life-of-mine production schedule whilst explorers would be accountable to ensure best-practice assessment of brownfields exploration opportunities. This would include an assessment of the global undiscovered endowment in the regional near-mine area. The balance between brownfield exploration drilling and resources to reserve conversion will need to be decided to ensure efficient operations are maintained. Both need to agree the optimum level of brownfields funding taking into account: urgency to replace or grow reserves, and quality of opportunities (relative to those elsewhere). The ultimate cost of ignoring the full brownfields potential of an operating asset can be significant, ranging from inefficient and poorly planned operations, lost opportunity cost and resultant value through under-utilised resources and, in the worst case, early exit from the asset at the bottom of the commodity cycle û leaving behind huge amounts of shareholder value.

Jan 1, 2006

By Seyed Mohammad Taghavi

In this report, the efficacy of different factors such as temperature of reaction, time of reaction and depth of bed are investigated in a process of recovery of zinc oxide from zinc ore concentration residues in a fluidized bed furnace. Under optimum conditions, there was more than 93.5% zinc oxide in products.

Jan 1, 2006

By M. Kawakami

In order to make titanium ingot directly from molten slag, the metal pool was tried to form and used as the cathode. The electro-slag remelting (ESR) unit was used for the purpose. The unit is composed of water-cooled copper mold and the DC power source of 2000 A and 100V. The graphite electrode was used for anode and the base plate was used for cathode. The commercial and re-melted slag of CaO-CaF2 was melted in the mold with the addition of TiO2. The following reactions are expected to occur. Ti4+ + 4e = Ti at cathode 2O2- + 2C = 2CO + 4e at anode During the process, large amount of molten slag splashed out from the mold, showing the CO evolution at anode. The metal deposit was obtained but in the form of block and piled up on the base plate. The metal pool was not obtained perfectly because of shortage of heat supply. The cathodic current efficiency was 60 % at maximum. The metal deposit contained much impurity. In order to reduce the impurity and increase the current efficiency, the effect of electrode distance was examined. The electro-slag re-melting of titanium was tried in order to examine the condition to make metal pool.

Jan 1, 2006

By F. H. Samuel, A. M. Samuel, H. R. Ammar

Casting imperfections, such as porosity, in cast aluminum components greatly influence their fatigue properties. The effect of porosity on the fatigue life of 319-F and A356-T6 aluminum alloys was studied, where the porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The results show that porosity has the most detrimental effect on the fatigue life: 92 % of all tested samples fractured due to porosity acting as the main crack initiation site. In the absence of casting imperfections, other microstructural aspects such as slip bands can be responsible ( 4 % ). The porosity was investigated in terms of the pore size at the sample fracture surface and its location i.e. near the edge or close to the interior. It was found that porosity located far from the sample surface (edge) has less influence on the fatigue crack initiation, and the fatigue life decreases as the size of the pore located at the sample surface increases. Aluminium

Jan 1, 2006

By S. Amira

The corrosion behavior of high pressure die-cast and thixocast AXJ530 magnesium alloys has been investigated in 0.05M NaC1 solution at pH 6.0 using potentiodynamic polarization tests, electrochemical noise (EN) technique, electro-chemical impedance spectroscopy (EIS) and scanning reference electrode technique (SRET). The behavior of die-cast and thixocast specimens were compared using each of these techniques and the results discussed. Further tests have been carried out with die-cast AZ91D alloy to better compare and interpret the results. Experiments indicate that the thixocast specimens of AXJ530 alloy have a better corrosion resistance than those of die cast alloy in neutral solution.

Jan 1, 2006

By Tejs Vegge

The lack of suitable means of storing hydrogen for use in the transport sector is generally viewed as a primary showstopper for a hydrogen economy. Recent developments within solid state hydrogen storage in complex hydrides and metal ammines have sparked new hope of a long term solution, but as of now, no materials fulfill all the DoE targets for onboard storage [1]. A detailed physical understanding of the ab-/desorption processes and the role of the essential catalytic additives is an essential prerequisite for the development of new optimized hydrogen storage systems. Here, we illustrate the potential of utilizing the synergy of combining state-of-the-art in theoretical methods and experimental techniques in the analysis and design of materials for hydrogen storage. Recent advances in computer hard- and software has made it possible to treat many of the essential problems in such materials, i.e. structural stability, hydrogen dissociation and diffusion, with high accuracy methods like density functional theory. We rely on such results to guide our synthesis of new materials, and to interpret our experimental results from, e.g. time dependant in situ x-ray diffraction, synchrotron/neutron experiments, and advanced materials testing. Through a continuous feed-back optimization loop between theory and experiments, the obtained nano-scale insight is used to expedite the design and development of novel materials for hydrogen storage.

Jan 1, 2006

By Kang-In Rhee

Nonferrous metal recycling not only provides energy saving and environmental benefits but also is a significant factor in the supply of various types of metals used in our society. Recycling plays an important role in establishing the sustainability of materials. The total amount of recycled nonferrous metals by weight accounts for less than 5% but their value is larger than 50% compared to ferrous metal recycling which consists of about half of the total metal recycling in weight. This paper describes trends and typical achievements in nonferrous metal recycling and overviews the present and future of nonferrous metal recycling technology and business in Korea.

Jan 1, 2006

By G. S. Rao

Levitated drops of Fe-18%Cr-2%C were reacted with oxygen-argon mixtures to study the reactions that occur in the AOD process, where the gases are injected into the melt and form bubbles. In the laboratory an argon-oxygen pulse, followed by pure argon, was flowed past the levitated drop to simulate the transient conditions in the gas phase as the bubbles rise in the melt. Oxide layers formed on the drops immediately when they came into contact with gas pulses containing 75% or more oxygen. Once the oxygen flow had ceased, the oxides reacted with the carbon in the drops to form CO gas and eventually disappeared. The de-carburization reaction occurred without oxide formation when the gas contained 50% oxygen or less. Melts that were sampled after EAF tapping, ready to be charged into the AOD, showed a higher tendency to oxide formation and consequent carbon boil than pure ternary Fe-18%Cr-2%C alloys made in the laboratory. The actual steel samples contained significant impurities, such as 0.25% Si and 0.56% Mn. A similar effect of oxide-forming impurities had been observed previously with binary Fe-C alloys. Movies were taken of the oxide formation and decomposition, and the results will be presented, along with data on the experimental conditions, including temperature and oxide compositions. The results are important because they give an insight into the reaction mechanisms in the AOD, which must be understood in order to improve and model the process.

Jan 1, 2006

By Józef Czernecki

Chalcocite-bornite concentrates of KGHM contain, similarly to chalcopyrite concentrates, 20-30 wt.% Cu but several times less iron (2-7 wt.%) and sulphur (9-12 wt.%). Another useful characteristic of KGHM concentrates is the presence of organic carbon (5.5-8.5 wt.%) in them, which serves as fuel in the flash smelting process. The main contaminants of the concentrates are lead (1.3-2.5 wt.%) and arsenic (0.05-0.4 wt.%) which require appropriate technological treatment in order to remove them from the copper pro-duct. Chalcocite-bornite concentrates are processed in KGHM by two different processes: ? a flash smelting process (Glogow 2 Smelter) ? a shaft smelting process (Glogow 1 Smelter, Legnica Smelter) The shaft smelting process used in the Glogow 1 Smelter and in the Legnica Smelter has higher production costs than the flash smelting process of HM Glogow 2. Additionally, the shaft smelting process employs several concurrently running installations (six dryers, seven briquetting lines, six shaft furnaces, nine converters), the operation of which, including maintenance, requires significant financial expenditure. Therefore, the Company is currently considering the substitution of the shaft furnace process in the Glogow 1 Smelter and in the Legnica Smelter by the one stage flash smelting process located in the Glogow Smelter, with output equaling the copper production capacity of both smelters, i.e. 320 000 ? 350 000 t/a. There are two technological options being considered which differ from each other in their man-ner of flash slag cleaning. In the first, the slag cleaning would be the same as in the existing Glogow 2 Smelter, i.e. the slag would be cleaned by pyrometallurgical reduction of the oxide copper and other metal compounds in the electric furnace in order to produce waste slag containing below 0.6 wt.% Cu. However, the other option of the flash slag cleaning would be carried out in two stages. After preliminary slag reduction in the electric furnace to 3-5 wt.% Cu, there would be flotation of the partially reduced slag.

Jan 1, 2006

The following paper outlines the types of employment immediately available to graduates following their university degree, a discussion on mine manager requirements, mentions career advancement and time frames to achieve this as well as providing some key information regarding student vacation work. The author hopes to educate present graduates, as well as inform students of characteristics to develop the most opportunities in life.

Jan 1, 2006

By Chai Liyuan

This paper focused on the preparation of porous ceramic pellets for microorganism carriers. A new method for the process was developed using simple gel-casting and bubble-in-water-in-oil type of multiphase double emulsion. The globules, consisting of a foamed sepiolite slurry suspension, were dispersed and consolidated in spherical shape in liquid paraffin as gelation progressed. The green pellets were sintered at 1100°C. The influence of surfactants, extension ratio and impeller revolution rate on the process and characteristics of the pellets was investigated. The pellet size was in the range of 1~4mm and determined directly by impeller revolution rate. The fine cell diameter of porous ceramic was in the range of 100~500m and the micropore diameter was less than 5m. The inner macropores were interconnected and extend to the external surface. It is impossible to analyze a result by SEM micrographs and digital camera.

Jan 1, 2006

By I. Loomis, D. Rachmad, I. Duckworth

During the past two years the Underground Mine Ventilation Group at PT Freeport Indonesia has undertaken to upgrade their Hygiene Laboratory. This process has included upgrading equipment for dust sampling and gas monitoring, as well as procurement of an OCEC analyzer for Diesel Particulate Matter analysis. While the laboratory equipment represents one factor, these changes have also required re-evaluation of the sampling protocols and the burden of ventilation monitoring personnel. This paper provides a review of these experiences.

Jan 1, 2006

By Sam Ash

The Murray Mine was one of the first mechanized cut-and-fill underground gold operations in northern Nevada. At the end of 2002, mine production began to decline. So the mine entered a phase of remnant mining and began preparations to close down. The remaining mining took place along the ore waste boundary in previously condemned areas and in challenging ground conditions. To remain economically viable, new techniques were implemented in operations, geology, engineering and rock mechanics. These improvements pushed the edge of known and accepted mining practices and have allowed the Murray Mine to remain in operation.

Jan 1, 2006

By K. P. Nishad

The origin of many casting defects can be traced at the mold filling stage. Entrapped air/gas pockets and oxide film formation are notable examples. In the present work, the mold-filling process is simulated using a mathematical model, built on a multi-physics based commercial package PHYSICA. The simulation code has the capability to solve multi-phase problems. The numerical model addresses a complicated dynamics of filling operation including free surface flow and subsequent flow behavior and is based on conservation of mass and momentum. The Free surface is modeled using the scalar equation method (SEM). The model is validated with benchmark experimental results from the literature. The role of turbulence and the pouring rate on variables affecting sites prone to oxide film formation are investigated using a simple but novel technique. Key findings of the work are presented.

Jan 1, 2006

By Tianjiao Luo

Some literatures discussed on how to recycle the various reagent, but the discussion on how to reuse the waste liquid directly is very little. How to reuse the waste liquid directly was researched in this paper. Firstly, the waste liquid should be filtrated to remove the impurity; then some quantity of H2O2 solution was dripped into the waste liquid to pretreat it; finally, CuSO4solution was added into the treated waste liquid and the pH was adjusted to about 12, then some HCHO solution was added into the waste liquid, in which the treated carbon fiber can be plated. The morphology and composition of coatings were investigated by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS), the deposition rate was mensurated by the way of dissolution. The results indicated that, the plating effect was basically identical with new plating solution, and the solution is stable, and the plating rate is still about 0.8µm/h, and the copper coating is even and combines closely with carbon fiber. According to this way, the waste liquid can be reuse 5~7 times.

Jan 1, 2006

By Eun-young Kim

Electrogenerated chlorine leaching of waste printed circuit boards was investigated in hydrochloric acid solutions. The pulverized printed circuit board contained about 37.6% of metal component, in which copper was about 83.6%. The leaching rate of copper was greatly affected by current density and agitation speed. The leaching of copper up to 98% was achieved at 20 mA/cm2, 50?, 180 minutes, and 600 rpm in 1M HCl solution. Increasing agitation and lowering current density enhanced utilization efficiency of electrogenerated chlorine. Leaching of copper was suppressed at initial stage, while the minor metal elements, such as aluminum, lead, and tin, were dominantly leached out.

Jan 1, 2006

By S Speed, N Corlis, A Goldstone, G N. Browne, M Fitzpatrick

In 2005, Solid Energy New Zealand Limited obtained non-notified consent for the disposal of 1Mt of coal ash at the Rotowaro minesite, forming part of a coal supply agreement with the Huntly Power Station. A non-notified resource consent was sought which necessitated that environmental effects be shown to be æless than minorÆ, and resulted from robust science and a pragmatic approach to design. As part of the assessment of environmental effects, there was a need to understand the effects of boron concentrations on aquatic organisms (ie algae, plankton, plants and invertebrates) in the receiving environment. Boron is a naturally occurring element that is found in the form of borates in the oceans, sedimentary rocks, coal, shale, and in some soils but Waikato coals and ashes have particularly high boron content. Boron is an essential micronutrient for higher plants with interspecies differences in the levels required for optimum growth. As aspects of the ANZECC (2000) derived boron limits are based on toxicity of aquatic algae and plants to boron it was important to assess these components in the environment. The effects on the receiving environment of the Awaroa Stream were assessed using predicted water chemistry and comparing actual boron concentrations in a comprehensive and multifaceted reference-condition approach of catchment ecological indicators. In addition a toxicological-based assessment of boron and a re-calculation of the ANZECC trigger levels were undertaken and applied to the ecological indicators. The reference-condition approach revealed that habitat and overall water quality attributes at and between sites was more influential in determining the aquatic biotic communities than boron concentrations alone. There was no evidence of any gradient of changes in ecological indicators with changing boron concentrations, nor evidence of any residual effect of high historic boron concentrations on the aquatic biota.

Jan 1, 2006