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By Purnima A. Shivdasan

The fluorspar deposits at Okorusu, Namibia are closely related to an alkaline igneous ring complex of late Cretaceous age (125±7 Ma). The fluorite ores consist of relatively fine-grained purple replacement fluorite and subsequent coarser grained purple and green vug-filling fluorite crystals. Homogenization temperature measurements for 38 primary fluid inclusions shows that main stage purple to green fluorite crystals were deposited over a temperature range from 166°C to 144°C, and minor late yellow fluorite was deposited at lower temperatures from 132°C to 128'C. Homogenization and freezing temperatures measured for 18 primary fluid inclusions shows that the fluorite-depositing fluids were less saline than MVT ore fluids and overlap the lower temperature range of fluids that deposited epithermal ore deposits. Mining in two open pits (A and B) at Okorusu has gradually provided exposures which reveal that the fluorite orebodies have been emplaced primarily by the preferential replacement of carbonatites. Evidence for the replacement of carbonatite includes: 1) replacement remnants of carbonatite within the fluorite ores, 2) goethite pseudomorphs after the carbonatite minerals, pyroxene, pyrrhotite, and magnetite that are disseminated in the fluorite ores, 3) partial replacement by fluorite of a titaniferous magnetite rimmed carbonatite dike in the A pit, and 4) partial replacement by fluorite of a large sill-like carbonatite body in the B pit. Electron microprobe analyses of minerals in unreplaced portions of the carbonatites show that their mineralogy consists of titaniferous magnetite, diopside pyroxene, apatite, biotite, and calcite. Magnetite contains 6.97% to 10.46% Ti02, averages 8.44% Ti02, and has an average V203 content of 0.35%. At high magnifications under the SEM, the magnetite shows abundant fine ulvöspinel exsolution lamellae arranged in a cloth texture. Apatite contains moderately high fluorine contents that range 3.21 to 5.0% and average 4.2%, and apatite crystals range in total rare earth oxides from 1.7% to 2.61%. Pyroxenes in the carbonatites are iron-rich diopside, and they contrast to pyroxenes in the fenites that are aegirine-augite. All of the microprobe analyses for mica crystals in the carbonatites give biotite compositions. The fluorite ores also have replaced marble locally in the A pit, especially along the A band in the B pit, and dominantly in the orebody proposed for the new C pit. Carbonatite and marble were preferentially replaced by fluorite because the calcite was readily soluble in the presence of the fluorite-depositing fluids and the dissolution of calcite provided calcium for the formation of fluorite.

Jan 1, 2005

By H. Ito, T. Takasu

Effects of a mechnochemical treatment to oxide Ni ores have been investigated to enhance the extractive ratio of Ni from them in acid leaching process. High intensity grinding by a planetary boll mill showed strong effect to enhance the extractive ratio of Ni, for example , 10% of extractive ratio of Ni in sulfuric acid leaching(0.05mo1/1,at room temperature) increased to more than 90% with 60min. of planetary boll milling. Effects of additives(sulfur and some oxidants) on the mechnochemical treatment have also studied. Sulfur showed almost no effect to enhance the total Ni extractive ratio but increases the selectivity of Ni extraction. More than a half of Ni could be extracted by water when Ni ore was grinded at addition of Na2S207 in the milling treatment. Some effects of mechnocemical treatments to Ni ore are summarized in this paper.

Jan 1, 2005

By Douglas W. Fuerstenau

This paper concern the specific adsorption of sulfate anions on nonmetallic minerals and its role in flotation. The specific surface affinity of sulfate ions in various systems has been observed in the results of electrokinetic measurements that show conditions under which sodium sulfate can reverse the sign of the zeta potential. The electrical double layer model provides a means for interpreting the results and for estimating the free energy of adsorption of sulfate ions. Because of their surface activity, sulfate ions not only can function as a depressant in the flotation of oxide minerals with physisorbed anionic collectors but also can function as an activator for flotation with physisorbed cationic collectors. Their role in depressing or enhancing the flotation of the sparingly-soluble mineral barite is also explained in terms of the double layer model.

Jan 1, 2005

By J Rapkoch, M Cerna

As long as the tendency of Chilean copper ores continues to feature high levels of impurities, the smelters will tend to produce high-impurity mattes. The most notable impurities include As, Sb, Pb and Zn. Producing high-quality copper with such materials is a major challenge to metallurgical engineers and operators. More investigations into process optimisations and/or alternatives are needed, using both theoretical knowledge and operational skill. Converting of matte in Chile depends on the matte grade using established technologies. Mattes up to 66 per cent Cu, such as those from Outokumpu Flash furnaces, are converted in two stages, while typical Teniente Converter mattes, ranging from 70 - 74 per cent Cu are converted in one blow, directly to copper. In this paper thermodynamic data are used to evaluate possible variations in the use of traditional technologies applied to smelt copper concentrates with high impurity levels. The results of this analysis help to predict the impurity distributions between matte-slag-gas during the slag blow, and between copper-slag-gas during the copper blow. For converting high-impurity white metal, the effectiveness of volatilisation in the slag blow is analysed. In the copper blow, the type and the amount of flux (SiO2, CaO and others) are altered with the aim of optimising impurity distribution to the slag and gas.

Jan 1, 2005

By A Sellgren, M R. Carstens, R Visintainer

There is a wide variety of industrial pastes or non-settling slurries pumped in mining, dredging and reclamation projects as products, refuse and tails. The types and/or names of some of the common ones are alumina red mud, phosphate clays, tar sands mature fine tails, tar sands (CT) consolidated clays and fly ash. The pipeline performance or friction of these varies dramatically with the type, its concentration and the particulars of the actual slurry making it difficult to select pumping equipment and to design associated pipelines. The GIW Hydraulic Laboratory in Grovetown Georgia has tested a number of these slurries over the last 30 years for various mining customers. Where available in the public domain and/or where permission has been obtained, the results of those tests are presented in this paper in a form usable for pipeline and pump system designers and users.

Jan 1, 2005

By G. McIsaac

"This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone’s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place.Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. “Whatif” scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan."

Jan 1, 2005

By K. E. Wood, K. J. DiRocco, L. A. Becker

The Russia Wharf segment of the Silver Line Phase II Project for the MBTA incorporated ground freezing and underpinning during New Austrian Tunneling Method(NATM) tunneling through timber pile foundations, urban fill, and abandoned wharf structures beneath two historic 7-story buildings with steel frames and masonry facades. During construction, the project team implemented an extensive program to monitor, evaluate, and mitigate the ground and building movements caused by the various construction activities. Mitigation included freeze cycling and building raising/lowering to compensate for ground movements and safely maintain the serviceability and occupancy of the buildings. In this paper, we present the history of the freeze, tunnel construction, and thaw-related movements that occurred and the building response that we observed.

Jan 1, 2005

By Thierry Bernard

For many years now electronic initiation has brought the time parameter to the centre of blast designs forever. Although this parameter existed before the era of electronic detonators, Blasting engineers or blasters could not directly handle it; technology imposed it. Only discrete values were available. Today, the fact that we can choose any detonation time for an explosive charge questions the viability of most of the rules applied for blast design. Thus, the very famous charge per delay method, that enables a level of vibration to be forecast at a given distance (“Chapot’s law”), is no longer necessarily valid when using electronic initiation. Therefore, it must be approached in a totally different manner. The KUZ-RAM formula, that allows fragmentation to be forecast, is also subject to the same distortion. The aim of this article is to show how the calculation laws used for blast design are influenced by the time parameter (sequence) and how we can efficiently make the most of this, in particular for vibrations. Copyright ©

Jan 1, 2005

By T. M. Ahmed

Sherritt International Corporation experienced corrosion failures with the 316L stainless steel tubing in a high-pressure still condenser employed for ammonia recovery. A detailed failure analysis was conducted on the condenser tubing to determine the mode and the root cause of the failure. The analysis included both optical and scanning electron microscopy (SEM) of the inner and outer surfaces of the tube as well as characterization of the corrosion products using energy-dispersive X-ray spectroscopy (EDX). Results revealed that the corrosion attack was confined to the first ?100 mm of the tubing at the inlet where the tube was connected to the top tubesheet. The tube suffered both external stress-corrosion cracking (SCC) and crevice corrosion from the shell side (water side), and wall thinning of the inner surface (the tube side) due to erosion corrosion. It was evident that failure of one of the tubes occurred due to SCC that penetrated the whole wall thickness and resulted in a leak failure. Some prevention measures are proposed to avoid this type of corrosion attack in the future.

Jan 1, 2005

By M. J. Steffens

ESPLIM is a novel separation technique that combines the advantages of solvent extraction and electrostatic dispersion but its application in the extraction of nickel by the direct solvent extraction route and the effect of high electrostatic field on the stability of organics have not been explored. These were investigated in this study and it was found that the technique allows 97% extraction of the nickel in a single stage compared with 3 stages by the conventional solvent extraction. Also, three months of exposure to 5.0 kV under simulated operational conditions had no adverse effect on the stability of organics.

Jan 1, 2005

By P J. Harris, C T. OÆConnor

Collectors are used to impart hydrophobicity on particles thus increasing their chances of reporting to the froth phase. Also, the extent to which naturally hydrophobic gangue particles, such as talcaceous minerals, report to the froth can be reduced by the use of depressants. Thus the use of collectors and depressants will directly influence the extent to which hydrophobic particles report to the froth. However these hydrophobic particles will also have a direct effect on the characteristics of the froth phase, more strongly hydrophobic particles causing a reduction in the stability of the froth with the expected concomitant effects on grade and recovery. This study included microflotation (ie frothless flotation) and batch flotation of various ores using a number of different collectors and depressants and a newly developed froth imaging device (SmartfrothTM). Flotation performance was characterised by mass and water recovery, and recoveries and grades of the valuables. This paper shows how the various reagents influenced the behaviour of the pulp and froth phases. The critical importance of managing the type and dosage of reagents used in flotation with a view to optimising their influence on the froth phase is discussed.

Jan 1, 2005

By A. Wilkinson

An investigation into the performance of support systems that are currently used in South African coal mines was conducted. Five most critical components of a support system have been identified. These components are resin, bolt, hole, machinery/equipment and the rock type. All five of these components are equally important as failure in any of these components will result in an inadequate support system. The performance of resin used in South Africa was investigated through in situ short encapsulated pull tests. The results indicated that in the majority of pull tests, failure took place at the rock-resin interface, indicating that the rock failed before the resin shear strength had been reached. It is therefore concluded that the strength of resin currently used in South Africa is adequate. It is found that although the maximum bond strengths achieved form both resin suppliers were similar, there was a considerable difference in the stiffhess of the resins. Roof bolt diameters and rib heights of bolts from three major manufacturers were evaluated (approximately 80 roof bolts from each manufacturer). The results showed there is a significant variation in bolt diameters and rib heights in the same batch in roof bolts supplied by certain manufacturers. The results also showed that on average there are insignificant differences between the parameters that determine the bolt profile (rib angle, spacing between the ribs and rib thickness). The influence of these parameters on bolt performance was very small and could not be established in situ. Roof bolts from four major suppliers were also evaluated through in situ short encapsulated pull tests. The results showed that the reinforcing system using roof bolts from all four manufacturers performed almost identically in sandstone, but somewhat differently in other rock types. The effect of bit types was evaluated. Both the stresses and the maximum loads obtained from the two-prong bits were greater than those obtained from a spade bit. Borehole annulus was found to be another important parameter that determined the support performance, and was investigated. The results from these tests showed that an annulus between 2.8 mm 4.5 mm resulted in the highest bond strengths. The results also showed that as the annulus drops below 2 mm, it appears to have a negative effect on the bond strength. The effect of wet and dry drilling on support performance was investigated. The results showed that wet drilling can-provide relatively greater system stiffnesses and slightly greater bond strengths. Short encapsulated pull test results showed very distinct differences between bolt system performance in different rock types and that sandstone produces significantly better results than shale and coal. From the results it is concluded that rock type is probably the primary factor influencing support system performance. A detailed investigation into the specifications of roofbolters that are currently being used indicated that the quality of installation of a support system is directly related to the performance of the equipment that is used to install the bolts. The important parameters, torque, thrust and speed of bolting equipment were investigated. The results showed that there are significant variations in these parameters in South African roofbolters.

Jan 1, 2005

By P. C. Patnaik

Performance of industrial gas turbine engines in terms of power output, reduced cooling and efficiency have been continuously increasing in parallel with aero gas turbines due to the advances made in the development of new materials, protective thermal barrier coatings (TBCs) and the advanced diagnostics to monitor service induced problems such as hot corrosion, thermal and thermo-mechanical fatigue and other operational issues, Environmental attack (hot corrosion or high temperature oxidation) is a common degradation mode in the hot section of the gas turbine, Hot corrosion occurs when Na or K bearing compounds in the environment or in the fuel combine with other contaminants such as S and Pb or V to form corrosive sulphates or vanadates thus attacking the protective oxide on the turbine airfoil, These problems pose far more threat to new turbine engine materials such as directional solidified, single crystals and ceramic matrix composites (CMCs). The CMCs due to their increased temperature capability, when used in the combustion chamber, are likely to reduce the peak temperatures attained during combustion and therefore provide the benefits of reduced emissions of oxides of C and N, These issues will be reviewed critically and their impact will be assessed on gas turbine lives. With respect to alternate fuels, past experience has shown that utilization of residual oils and coal derived fuels in gas turbines have resulted in complex deposition and corrosion processes, In recent years biomass derived alternate fuels have been used either through a gasification cycle or through direct firing of the biomass derived liquid fuel with a view to reduce Green House Gases (GHGs) and improve the climatic conditions. In both cases, the resulting high temperature corrosion processes (in the presence of alkaloids in the fuel) are also very complex, leading to premature removal of hot section components, Technology solutions mitigating these fundamental problems will be reviewed and solutions presented.

Jan 1, 2005

By I. M. Morsi, S. Z. El-Tawil, O. A. Fouad, K. A. El-Barawy, M. B. Morsi, M. M. Nasr

Upgrading of a low-grade titanium slag (~55% TiO2) with high silica, calcia, magnesia and iron contents has been studied using sulphation roasting technique using SO2/air gas mixture followed by hydrochloric acid leaching. XRD analysis of the sulphated slag reveals the presence of kennedyite (Fe2O3. MgO. 3TiO2), rutile (TiO2), calcium sulphate (CaSO4) and calcium silicate (3CaO.SiO2) phases. The residue after leaching contains mainly kennedyite, rutile phases and free silica with traces of calcium silicate phase. Synthetic rutile that has about 83% TiO2 can be produced at the optimum conditions. Thermodynamic calculations give rational explanations of the obtained results.

Jan 1, 2005

By Elif Çevik

This study deals with the mineralogical-geochemical characteristics and the industrial usage of the olivine from the dunites that crop out on the west of the Topuk village (Orhaneli). Mineralogical compositions of non-altered dunite samples are averagely as: Olivine (>90%), serpentine (1-4 %), opaque minerals especially chromite, magnetite, pyrite (1-3 %), and secondary minerals as magnesite, chlorite (1-2 %). X-Ray Diffractograms of the dunite samples indicate that olivines are in forsterite (93 on an average) composition, and chlinochrysotile and lizardite accompany to the forsterite. Chemical analyses of the dunites show that MgO, SiO2, Fe-,03 and LOI contents vary from 40,99 to 50,2 %, 34,67 to 40,6 %, 6,8 tol3,7 %, 0,11 to 11,27 %, respectively. SE-TAT Mining Company states that the study area has 400.000.000 tonnes proved, 800.000.000 tonnes probable and totally 1.200.000.000 tonnes olivine reserve. Consequently, all studies indicate that Orhaneli Olivin has convenient mineralogical and chemical properties and the grain size (0.04-40 mm) for industrial usages such as abrasive, olivine sand products, steel slag conditioner, balast and covering material in industry: Orhaneli olivines are demanded especially from the firms related to refractory industry, iron-steel factories, naval forces and shipyards. SE-TAT Mining Company also exports these olivines to different countries such as Macedonian and Spain.

Jan 1, 2005

By Alan Bye

Sandsloot open pit is situated on the northern limb of the Bushveld Complex, 250 km north east of Johannesburg, South Africa. Sandsloot is currently the largest open pit platinum mine in the world and is one of six potential open pits in the area. The geotechnical strength properties of the Platreef have posed significant mining and processing challenges to the PPRust operation since inception in 1992. In order to optimise the whole business as opposed to isolated cost centres a mine to mill initiative was embarked upon in 1997. Initial work focussed on ore characterisation and an entire suite of data was collected for each rock type. This included mineralogy, geochemistry, geotechnical, blastability indices as well as metallurgical strength data. The second phase involved the clear definition of customer requirements, namely the optimum performance criteria for the plant and mining departments. This involved extensive field trials and data capture to measure the interaction and influence of the mine to mill value chain. Once the design targets were defined a 3D geotechnical model was constructed to ensure that the targets were consistently achieved. The model is very similar to an ore reserve model however it is populated with geotechnical, metallurgical and blast index data. Through software queries the appropriate blast powder factor for each mining block can be obtained thereby ensuring the correct fragmentation is blasted for the plant and mining operation. The initiative has delivered significant results showing improvements across the mine to mill value chain. These include increased loading rates, reduced electricity and crushing consumables as well as higher plant throughput. Additionally, the initiative has benefited both Brownfield and Greenfield projects on the PPRust operation.

Jan 1, 2005

By R W. Wilson, A R. Branch

For hot mines, the use of mechanical refrigeration machines has become an essential feature of ventilation and cooling systems. Over the last 30 years, considerable effort has been made in developing refrigeration strategies and equipment to provide cooling that is cost-effective, reliable and energy efficient. In addition to these general design requirements it is necessary to take into account project specific factors such as long term mine cooling needs, operating strategy and installation time. This paper examines a number of actual mine cooling installations which illustrate how these features have influenced the design and installations. For many mines, it is known how the cooling requirements will increase as the mine develops, based on the life of mine plan. The design of the cooling installation must cater for both short- and long-term needs. The initial installation (to meet short-term requirements) must form an integral part of the ultimate cooling installation and as additional equipment and refrigeration machines are installed, it is necessary to ensure that the system remains cost-effective, reliable and energy efficient at all stages. For many mines, refrigeration machines are installed on surface and either operated near-continuously, or for the summer months only. Different maintenance strategies and policies with regard to standby equipment are highlighted for three mine installations. In spite of developments in cooling strategy, the cost of providing refrigeration remains expensive and many mines delay the introduction of refrigeration, as long as possible. When it is finally accepted that refrigeration is absolutely necessary, it is frequently necessary to æfast trackÆ the installation. To minimise site erection time and meet installation deadlines, factory pre-assembly and standardised modular equipment are widely used.

Jan 1, 2005

By A. J. Benham, H. Kessler

In the UK a high proportion of land-won sand and gravel is extracted from sub-alluvial gravels and river terrace gravels located within river valleys. However, extraction from deposits of this type is increasingly proving to be less acceptable. Quarries within river valleys often have a high visual impact and the cumulative impact of these operations in close proximity to each other can be high (figure 1). River valley operations are almost always restored to open water. Whilst these may be attractive for nature conservation and provide leisure activities, they can also have a serious impact on the natural hydrology of the flood plain. Wet restoration of quarries located close to airports or airfields can also lead to concerns regarding increased risk of bird strike on aircraft. The Civil Aviation Authority recently suggested that an exclusion zone of 13 km be applied around all airports and airfields to reduce the potential for bird strikes on aircraft. This action is likely to have a serious impact on the availability of potential sand and gravel extraction sites in river valleys.

Jan 1, 2005

By C. Hu

A MOS capacitor hydrogen sensor array is reported for hydrogen gas distribution mapping. Si(100) was used as substrate for film deposition. After silicon oxide growing on the silicon surface with dry thermal oxidation, palladium film was sputtered on silicon oxide as hydrogen-sensitive gate material in MOS structure. The 3x3 sensor array was patterned on silicon substrate and packaged in one chip. Sensors' response was test with impedance analyzer. The sensors in array were calibrated in the hydrogen concentration range from 10ppm to 10000ppm. The 2D hydrogen concentration distribution was obtained with the calibrated sensor array.

Jan 1, 2005

By J Manuel, R Muddle

The demand for iron ore has increased significantly in recent years, with new iron ore sources being mined to meet this demand. As the composition of sinter blends changes with the availability and cost of iron ore, so too does interest in the impact of new ore types on granulation and ultimately productivity. This paper describes a study into granulating characteristics of seven iron ore types, including various hematite and goethite ores. The effect of ore type on feed moisture requirements, green bed permeability, green bed strength and granule size distribution was examined for single ore blends containing coke, flux and returns. The ore size distribution was varied in these blends and its effect on granulating characteristics examined. It was found that the optimum moisture requirement of the ore was more dependent on ore type than ore size distribution, but ore size distribution (and specifically intermediate particle loading) had a greater effect on green bed permeability. The saturation moisture value for an ore was found useful in predicting both optimum granulation moisture and green bed permeability.

Jan 1, 2005