Search Documents

By M. Sibanda

The diffusion of carbon in Co-5% Fe alloy was studied in a belt-type pressure system at temperatures of up to 1330°C and press loads or nominal pressures of 7 020 tons or 42±3 kbar. Under these conditions, this alloy is in the solid state. Discs of graphite and prealloyed Co-5%Fe were used to make up the diffusion couple. The diffusion coefficient increased with increasing press load due to the tendency of the low density graphite to dissolve in the metallic phase reducing the overall volume and increasing the density of the system. Furthermore, inhomogeneous plastic deformation may have promoted diffusion by creating defects in the alloy. Diffusion couples treated at atmospheric pressure exhibited graphite particles in the metal, while those treated at high pressures exhibited carbide in the form of Widmanstatten laths. Carbon analyses indicated increased carbon solubility with increasing pressure. This was confirmed from calculated high-pressure phase diagrams.

Jan 1, 2005

By Jannie Maree, Dieks Theron, Ryneth Nengovhela, Patrick Hlabela

In extracting base metals from ore bodies, sulphide as well as oxide, the main environmental concern is sulphur, whether in the form of sulphurous gases or sulphate in liquid form. Generally sulphur is in over supply in developed countries mainly because of strict legislation to capture it. In developing countries on the other hand there is usually a shortage of sulphur because of less strict environmental legislation. Africa falls in this second category and the African continent imports substantial amounts of sulphur despite the fact that large quantities of sulphur is emitted by smelters, thermal power stations, coal mines, fertilizer manufacturers and others. Other than making acid from gaseous emissions, existing methods to capture sulphur from gaseous and liquid effluents are uneconomical and it ends up in the environment either as ammonium sulphate (from gaseous effluents) or as gypsum (from liquid effluents). The CSIR?s Environmentek and Pyroserv has developed a process whereby gaseous sulphur emissions and sulphates in liquid effluents can be economically captured and converted into elemental sulphur and metal carbonates. The elemental sulphur is of high purity as it is precipitated from a gas stream and is readily marketable. The metal carbonates (barium or calcium) can be recycled back to the process or marketed. The only harmful byproduct of the process is carbon dioxide. Should natural gas or methane be available the carbon dioxide could be reduced by about one third. Should solar, wind or hydro energy be available to generate hydrogen the carbon dioxide emissions would be zero. Employing this technology could make Africa independent of sulphur imports and furthermore reduce the impact of acid rain and seepage of sulfate from gypsum and other waste dumps into the environment.

Jan 1, 2005

By A V. Nguyen

Spherical calcium dioleate particles (~10 ¦m in diameter) were used as AFM (atomic force microscope) probes to measure interaction forces of the collector colloid with calcite and fluorite surfaces. The attractive AFM force between the calcium dioleate sphere and the fluorite surface is strong and has longer range than DLVO (Derjaguin-Landau-Verwey-Overbeek) prediction. The repulsive AFM force between the calcium dioleate sphere and the fluorite surface does not agree with the DLVO prediction. Consideration of non-DLVO forces, including the attractive hydrophobic force and the repulsive hydration force, was necessary to explain the experimental results. The non-DLVO interactions considered were justified by the different interfacial water structures at fluorite- and calcite-water interfaces as revealed by the numerical computation experiments using molecular dynamics simulation.

Jan 1, 2005

By A Hewitt

Portland cement is the chief binding ingredient in mine backfill. In the presence of water, the chemical compounds within portland cement hydrate causing hardening and strength gain. During hydration, heat is generated. In certain cases, hydration heat may be produced significantly faster than it can be dissipated, which can create high temperatures in the underground environment. This paper presents the results of a series of investigations aimed at quantifying the heat generated by cemented backfill during hydration. Scaled stope models, instrumented with thermistors, were used in the investigation. Heat transfer to the hanging wall, orebody, footwall and cross-cut and production drifts was assessed during the backfill curing process and relationships between cement content, cure time, and heat generation were developed. The results of this work will assist mine operators in predicting the heat generated by cemented backfill and provide the necessary information to implement effective engineering control of heat in the underground environment.

Jan 1, 2005

Mine Terex articulated dump trucks are working on a large restoration project of an abandoned open cast coal site in Blacklaw, central Scotland. The project is part of the construction of a 42-turbine wind farm complex. During the scheduled 18-month duration of the project, three 28-t(31-st) Generation 7 TA30 dump trucks and the six 36.5-t (40-st) TA40articulated trucks are estimated to move about 1Mm3 (1.3 million cu yd)of material. The trucks are working12-hour shifts, 5.5days a week.

Jan 1, 2005

By Andy W. Stephens, William H. Langer

In Australia and America, encroachment by conflicting land uses, zoning restrictions, and the "not in my backyard" syndrome make it increasingly difficult to access high-quality aggregate resources located near the market areas. Attempts by government agencies in America to protect aggregate resources for future development have met with varying degrees of success. The State of Queensland, Australia, designates aggregate resource areas as Key Resource Areas, which protect the resource and the routes to transport the resource, provide a separation area from incompatible land uses, and indicate the likelihood that the area is free from conflicting social or environmental issues.

Jan 1, 2005

By Gregory Lorsbach, Wade Hutchison, Earnest Grigoryan

Comparing measurements from multiple seismographs, particularly when the instruments are deployed in a “side-by-side” situation, is often problematic. Measurements often differ by as much as a factor of two. These differences are attributed to issues related to calibration, geophone coupling, and differences in geology over very short distances. Unfortunately, these explanations are often purely qualitative, but are accepted as factual. Shake table testing often demonstrates that those seismographs that indicate large differences for a particular vibration event, may correlate within a few percent of each other and the known shake table input. Geophone coupling also does not fully explain the difference in measurements since geophones in side-by-side measurements are deployed identically. Differences in geology do not explain the difference in measurements since it would be unrealistic to expect significant differences in distances less than one meter in a normal monitoring situation. Utilizing a new technological approach to vibration measurement and analyzing numerous side-by-side measurements, it has become clear that a significant portion of the observed differences between seismograph measurements are instrumentation induced. This study examines and describes some of the most significant sources of the seismograph error budget.

Jan 1, 2005

By V Kumar, A S. Venkatesh, R K. Upadhya

The enormous iron ore deposits of eastern India are part of the volcano-sedimentary basins containing iron and to some extent manganese deposits that belong to the Iron Ore Group (IOG) of Archaean Singhbhum Craton, occurring as western and eastern limbs of a broad synclinorium. The eastern iron basin contains typically huge amounts of blue dust and powdery ores. There is a remarkable difference between the western flank ores and the eastern flank ores and the present study is part of the eastern flank ores from Noamundi. Demand for sintered fines as blast furnace feed coupled with the higher export price for lumpy ores that produce enormous amounts of fines during processing has created a situation whereby both primary and secondary fines, such as classifier fines, are being increasingly used as sintered feed for blast furnace. Systematic mineralogical and geochemical characterisation indicates that in many cases the ROM and classifier fines have to be processed to increase their Fe content and at the same time reduce their Al, Si and P contents. The fines which are already at micron sizes are amenable for beneficiation using the Mozley mineral separator and sink float test. It was observed that beneficiation was better and significantly greater by the sink float method than the Mozley mineral separator. Mineralogical and chemical studies of the fines reveal that around 80 per cent of alumina bearing minerals (gibbsite, clay and silicates) are present in the liberated form. Microscopic studies confirmed that the iron minerals are well liberated by controlled grinding to -300 mesh sizes with the beneficiation of iron ore fines and low-grade ores carried out using the Mozley mineral separator and sink float test. Beneficiation using the Mozley mineral separator increased the grade of concentrate with increasing flow rate of water as well as increase in amplitude of oscillation of the tray, but not very significantly with the increase in slope of the tray. In this method, though, iron concentration improved from 47 to 63 per cent with a recovery of around 67 per cent. It is not suitable for industry scale operation as only a small quantity of ores can be handled at a time. Beneficiation using the sink float test produced a better result with the Fe content increasing from 47 - 49 per cent to 66 - 68 per cent with a recovery of approximately 58 per cent. Initial feed Al2O3, SiO2 and Fe contents of 9.85 per cent, 15.3 per cent and 49.8 per cent respectively were beneficiated to 2.13 per cent Al2O3, 1.5 per cent SiO2 and 67.5 per cent Fe in the concentrate, with a recovery of 54.1 per cent. In contrast, using the Mozley table resulted in beneficiable contents 66.3 per cent Fe, 3.01 per cent alumina and 2.05 per cent silica. The combined alumina and silica content for the Mozley Table was >5 per cent, which exceeds the industry requirement of

Jan 1, 2005

By C. M. Diaz, S. W. Marcuson

In the late 19th century, the discovery of rich nickel-copper sulfide ore bodies in Sudbury and the need for tonnage quantities of the metal to be used in nickel steel armor provided the foundation for establishing the Canadian nickel industry. For almost 50 years, International Nickel was the key player. In 1930, Falconbridge Nickel entered the field. These two companies remain the key Canadian nickel producers. This paper discusses the factors that have influenced the evolution of nickel smelting processes. The initial Sudbury ore smelting and nickel copper separation technologies were imported from abroad. It was only in 1937 that International Nickel established a process research laboratory in Copper Cliff The explosive post WW II industrial development created a strong demand for a broader variety of nickel products. For both International Nickel and Falconbridge, R&D became an essential business tool to succeed in the new market scenery. In the last few decades, new technologies were developed and commercialized to respond to the raising cost of energy, society pressing environmental concerns, the advent of nickel laterites as an important source of new metal, the incorporation of new nickel producers to the market, and, therefore, the need to increase productivity. Canada thus became an important exporter of technology. In this paper, the authors review this history with the objective of highlighting the forces that have triggered the most important changes in Canadian nickel smelting.

Jan 1, 2005

By S C. Bhowmik, R Gupta

This paper presents the ventilation problem faced by Jaduguda uranium mine, operated up to a depth of 905 m. The first two stages of the mine workings are up to 555 m, which are nearly exhausted. The third stage of the mine is from 555 m to 905 m and presently most of the stopping and development activities of the mine are carried out in the third stage. The total available intake quantity in the third stage was only 21 m3/s. As a result, the mine was facing a radiation hazard. The different instruments and the methods used for monitoring of radiation levels are also presented in the paper. It was observed that the average individual effective dose (external + internal) of radiation workers in Jaduguda mine increased from 6.93 mSv/y in 1995 to 9.5 mSv/y in 2001 and during this period the average individual effective dose of mine workers of the world was less than 5 mSv/y. Keeping this problem in view, a detailed ventilation investigation has been carried out in this mine. Initially the requirements of intake air quantity have been assessed by carrying out field investigation in different stopes and it was found that the third stage workings require nearly 100 m3/s. A detailed ventilation survey has been carried out in the total ventilation network and a basic ventilation model of the mine has been prepared. Different alternative schemes for effectively ventilating the third stage workings of the mine were simulated and a set of recommendations were made for implementation. The recommendations were partially implemented in 2002. As a result the total intake quantity to third stage workings increased to nearly 70 m3/s and the average individual effective dose (internal + external) of mine workers came down from 9.5 mSv/y in 2001 to 6.65 mSv/y and 6.60 mSv/y in 2002 and 2003 respectively. The implementation of remaining recommendations is in progress. Finally, a mathematical model has been formulated from the first principle for predicting air quantity requirements in cut and fill stopes in uranium mines and this model is being validated for further use.

Jan 1, 2005

By D. Vogt

A brief summary of the propagation characteristics of rock provides the necessary understanding to design effective radar surveys. Measurements of the electrical properties of the major Bushveld platinum-bearing horizons and their host rocks show that radar is an excellent tool for both short -and longer-range mapping. Experimental work confirms the performance predictions. High frequency, 500 MHz ground-penetrating radar (GPR) is a first-rate tool for mapping features in the hangingwall of the orebody, locally known as a ?reef?, for the purposes of determining hangingwall stability. The triplet chromitites above the UG2 have been clearly mapped, as has the Leader Seam above the UG2. Borehole radar at lower frequencies has been used over longer ranges to map reef elevation. Potholes in the UG2 are clearly distinguished in range and elevation to within metre accuracy. The nature of the slump in the various footwall horizons is also apparent. In future, as GPR is routinely applied, it is likely to become used for other purposes. Borehole radar is being developed to operate at higher frequencies, which will allow it to be deployed from boreholes that are within 5 m of the target horizon. Keywords: GPR, borehole radar, Bushveld Complex, UG2, Merensky, pothole, triplet

Jan 1, 2005

By Brian Khalighi, Massimo Franceschi, Giovanni Giacomin, Gianni Porta

Headrace Tunnels and parts of the Access Adit Tunnels of Kárahnjúkar Hydropower project, KAR-14, in Iceland will be excavated using three full-face Robbins Tunnel Boring Machines (TBM). TBM sizes range from 7.23 to 7.63 meters in diameter and the total headrace tunnel length is approximately 40 km. The crushed rock is transported on conveyor belts to disposal areas near each Adit. The estimated average excavation rate is approximately 25 meters per day per machine. Electricity will begin to flow in April 2007, and the project is scheduled for completion in 2009. This paper is divided into four sections. In the PROJECT OVERVIEW section, a short overview of the scope of the project is presented. In the GEOLOGY section, the geological condition along the tunnel drives is briefly introduced. The TBM DESIGN section discusses the various design criteria and the resulting machine specifications. The paper concludes in the TBM OPERATION section with a case history describing the tunneling operation from start-up to the time of the writing of this paper.

Jan 1, 2005

By G. Beckstead, L. Gormely, R. Zimmer, K. Hanneman, B. Nethery

As part of the EIS and permitting activities for the Pogo Mine in Alaska, a risk assessment study for the water management plan was carried out. The basis for the study was a site water volume and contaminant balance model. Probabilistic modeling was carried out using the @Risk Monte Carlo simulation package to investigate the frequency, quantity, and quality of discharges under varying assumptions. The results were used in discussions with regulatory officials as part of the permitting process for the project. The simulation allows probabilistic modeling of key environmental parameters based on input frequency distributions involving both quality and quantity of flow. When combined with predictions of water treatment plant capacities and removal efficiency, this was very useful for defining the likelihood of important regulatory outcomes. Based on the model, certain project modifications were made. Using the simulation as a basis, ongoing dialog with regulators led to consensus that all potential risks have been considered and mitigated for the Pogo Mine according to their likelihood and severity, and that regulatory requirements would be achieved. The paper describes the model and some of the applications for which it was used.

Jan 1, 2005

By E. Varouchakis

Spartan Spatial Random Fields (SSRF?s) provide a new geostatistical framework (Hristopulos, 2003) with applications targeting environmental risk assessment and natural resources estimation. SSRF?s have the ability to incorporate constraints based on physical laws in the statistical description and have proved to be computationally fast in the analysis of synthetic data sets. This paper presents an application of a specific SSRF model and a new local-error spatial estimator (Hristopulos, 2005) in the mapping of environmental pollutants using a real data set. A detailed comparison of the local SSRF estimator with a classical kriging method is presented. It is shown that the SSRF approach provides a competitive alternative for spatial estimation.

Jan 1, 2005

By Milton Syamujulu

In 1994, Nkana smelter commissioned a Multimillion US$ Dollar Chilean Teniente converter (CT) in its operations in order to improve its smelting technological base. The main objective was to reduce the overall smelting energy costs and increase the sulfur capture for sulphuric acid production to support the company?s leaching operations at Nchanga Tailings Leach Plant. A decade of CT operations have since ensured following its installation and startup. This paper provides a Technical and Operational Audit of the performance of the CT in the first 10 years of its operations at Nkana smelter.

Jan 1, 2005

Analysis for pillar extraction potential (A-PEP) is an intelligent tool, which could be used as a preliminary output indicator when considering the secondary extraction of regional support pillars in the Witbank and Highveld coalfields of South Africa. The safe and economic extraction of underground coal pillars is of paramount significance and importance to the South African coalmining industry to ensure continuity of supply of this fossil fuel. Pillar extraction practices in South Africa have been responsible a significant proportion of safety and fatality statistics in relation to its relative output (less than 5 per cent of total South African coal production) and, as a result, research was undertaken in local pillar extraction operations and extended to similar operations in New South Wales, Australia to assess a way forward for pillar extraction in South Africa. It was found that, although little in the way of new technologies has emerged in this field in the recent past, significant contributions could be made in the field of risk analysis to obtain a generic design methodology for pillar extraction in South Africa. The resultant A-PEP tool to assess pillar extraction potential is based on certain physical, risk and economic factors, which combine to indicate operational success in terms of economic, health and safety attributes. At the time of A-PEP?s development there was alack of operating underground coal pillar extraction operations, which made it difficult to validate its applicability. Since then, however, A-PEP has been successfully tested and validated against two unique underground coal pillar operations, which is the discussion of this paper. One operation is situated in the Witbank coalfield and is extracting pillars, which are 20 years old and at a depth of 80 metres below surface, while the other operation is situated in the Highveld coalfield-which is extracting 6 month-old-pillars underneath a massive dolerite sill at a depth of 220 metres. A-PEP has shown that its predictive nature is consistent the workings at both operations, irrespective of their unique conditions, and as such it can be successfully used as a mine planning tool. The A-PEP mine planning tool thus represents a positive step toward an integrated approach to underground coal pillar extraction when considering legal and operational aspects, which could form the basis for legislative guidelines when considering the future of pillar extraction in South Africa.

Jan 1, 2005

By J F. Colinet, G, J A. Zimmer, R J. Timko

It has long been known that ventilation is a cost-effective method to lower respirable dust concentrations in all types of mining applications. The National Institute for Occupational Safety and Health has been working on a number of different research techniques that use ventilation as a critical component to lower respirable dust levels at surface and metal/non-metal operations in the United States. This article presents five such research efforts. The first research area discusses how improving the ventilation flow patterns in an iron ore mill facility lowered respirable dust concentrations by 31 per cent throughout the primary grinding area. The second research area examines how respirable dust levels were lowered at a dimensional stone shop by using air cleaning units suspended from the ceiling. A third area discusses how improvements in ventilation at underground limestone mines lowered respirable dust concentrations. The fourth area examines how improvements in dust filtration and pressurisation systems significantly impacted the air quality in enclosed cabs of surface mining equipment. The last area presents a newly developed clothes cleaning technique. This technique uses an air spray manifold to blow dust from a workerÆs clothing in an enclosed booth, which confines the dust for capture and removal by a baghouse dust collector. These research areas represent an array of different control technologies to lower respirable dust concentrations. Ventilation is an integral part of these control technologies.

Jan 1, 2005

By G Chen

Magnesite and dolomite are two salt-type minerals. The surface characteristics of these two minerals are almost the same. It is very difficult to remove dolomite from magnesite ores by flotation process. The present study was performed to develop a new collector and a better flotation scheme for magnesite from dolomite. The flotation tests show that there exists a significant difference in flotability between magnesite and dolomite when dodecyl phosphate synthesised with dodecanol, phosphorus oxychloride and other chemicals is used as collector. Sodium silicate was used as the modifier to improve flotation selectivity. It was found that sodium silicate selectively depressed magnesite at pH 4.5 - 7.5. The separation of magnesite from dolomite was achieved in a reverse flotation which resulted in a 76.1 per cent yield of magnesite with a grade of 47.3 per cent at 100 ppm dodecyl phosphate and 75 ppm sodium silicate. The flotation mechanism was investigated by characterising surface electrical properties and measuring the adsorption density of the reagents on magnesite and dolomite.

Jan 1, 2005

By R-H Yoon

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analysed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was also found that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K232) estimated from the film thinning experiments were used to predict the disjoining pressure isotherm using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (He) of the foam films stabilised by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, He increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is at its maximum level in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.

Jan 1, 2005

By Henri Letient, Tom Aley, David Evans

Antamina is a large open-pit copper and zinc mine located within the Central Andes of Northern Peru at an altitude of 4300 masl. The facilities are situated within the headwaters of several watersheds, within the Amazon basin. Nearby villages rely heavily on springs and streams for drinking and irrigation water. The principle source of baseflow during the dry season is from Cretaceous karstic limestone aquifers. Antamina will produce nearly 1.4 billion tonnes of waste rock over its mine life. Finding suitable sites for storing large volumes of waste rock is often a challenging task – especially in karstic, alpine terrain. Detailed hydrogeological investigations are essential for delineating the karstic hydrogeologic watersheds associated with the proposed waste facilities, which are often very different than topographic (hydrologic) watersheds. Contamination vulnerability mapping at Antamina consisted of geological and karst mapping, geophysical surveys, geochemical testing, dye-tracer studies, drilling and aquifer testing. Detailed mapping followed by dye-tracer studies proved to be the most cost-effective methods for characterizing the karst aquifer systems. The results were used to optimize waste rock management at the site to minimize potential impacts on groundwater resources.

Jan 1, 2005