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By R-H Yoon

Increasing the upper particle size limit of flotation would allow operators to increase mill throughput, save operating costs, simplify flow sheets, and increase rate of return. However, coarse particle flotation is difficult for various reasons, of which bubble-particle detachment has been identified as the major limiting factor. In the present work, the process of bubble-particle detachment has been studied by directly measuring the forces required to detach air bubbles from hydrophobic solids. The measurements were conducted using a hanging balance apparatus. The measured forces were converted to detachment energies that can be compared with the work of adhesion, which in turn is a function of hydrophobicity, surface tension and contact area. The results were converted to detachment energies using the Young-Laplace equation for capillarity. In the present work, the solid surfaces were hydrophobised by coating them with octadecyltrichlorosilane and cetyltrimethylammonium bromide. The results show that bubble-particle detachment occurs in two steps. In the first step, air bubbles are deformed, while the three-phase contact (TPC) line is pinned, until contact angle reaches advancing angle. In the second step, the TPC line moves along the surface until solid/air interface is replaced by solid-liquid interface. In general, the energies of detachment measured in the second step are in good agreement with calculated work of adhesion. Thus, the energy required during the first step effectively represents an energy barrier for bubble-particle detachment. It has been found that the energy barrier varies with surface roughness and surface tension. The results of the present investigation suggest, therefore, that coarse particle flotation can be improved by control of particle hydrophobicity, surface roughness, and surface tension.

Jan 1, 2005

By D. W. Olson

Estimated world production of natural and synthetic industrial diamond was about 630 million carats in 2004. Natural industrial diamond deposits have been found in more than 35 countries, and synthetic industrial diamond is produced in at least 10 countries. About 80 percent of the global output was produced in Ireland, Japan, Russia, South Africa and the United States. Russia and the United States are the world’s leading producers of synthetic industrial diamond. In 2004, the two U.S. synthetic producers, one in Pennsylvania and the other in Ohio, had an estimated output of 250million carats. Also in 2004, nine U.S. firms manufactured polycrystalline diamond (PCD) from synthetic diamond grit and powder.

Jan 1, 2005

CSIRO Minerals, in association with the AJ Parker CRC for Hydrometallurgy, has an active program of hydrometallurgical research in which physical and computational modelling are used to better understand and improve a range of different unit operations. The modelling is based on flow simulation (Computational Fluid Dynamics or CFD), but incorporates other physical and chemical phenomena of importance, such as droplet break-up and coalescence, species transport and reaction. This paper reviews some of the major projects that have been undertaken at CSIRO Minerals and will illustrate the critical importance of hydrodynamics to the performance of unit operations and the improvements that can be made to performance using such modelling techniques. Unit operations that are discussed include solvent-extraction, gravity thickeners, flotation cells, bio-heap leaching and stirred tanks.

Jan 1, 2005

By Steve Kral

The coal mining industry in the western United States is seeing the same boom as the rest of the country and the world. Most coal mines in the West are operating flat out as the nation’s appetite for energy continues to grow. And many of the coal mines have either increased their production capacities or are in the process of doing so. However, transportation issues along with environmental restrictions are keeping many mines from expanding even further. Some coal companies held off on further expansion plans until Congress and President Bush could agree on a national energy policy, one that recognizes coal as the nation’s leading source of electricity. In August, Congress passed and the president signed into law such a measure (see Washington Survey, page 7). The legislation includes research funding for clean coal technologies. So western and eastern coal could become even more important in the national energy picture. This is particularly true as supplies of natural gas diminish and the price of oil continues to increase.

Jan 1, 2005

By Chen Song

Keywords: Mixed extractant, Copper, Cobalt, Nickel, Synergistic effect During separation process of copper and cobalt from nickel sulphate solution, the effects of constitutions and compositions of mixed extractant D2EHPA and PC88-A or Cyanex 272, has been studied. In one step extraction cycle, the following results are obtained:[Ni]/[Co]>4000 and [Ni]/[Cu]>40000 in nickel sulphate solution, [Co]/[Ni]>1000 and [Co]/[Cu]>30000 in cobalt chlorinate solution, [Cu]/[Ni]>10000 and [Cu]/[Co]>200 in copper sulphate solution. It was elucidated that the above-mentioned synergistic mixtures can effectively separate cobalt and copper from nickel sulphate acid solution and achieve a greater synergistic effect.

Jan 1, 2005

By D. Hamilton

The electrode of a PEM fuel cell consists of two distinct sections - the catalyst layer and the porous transport layer (PTL). There are several kinds of PTL material, although all use carbon fibres as the solid fraction. The fibres can be matted to form a paper, woven into a cloth, or chopped to form a felt. Despite the different morphologies of the media, they are all anisotropic in structure, that is the majority of continuous fibres lie perpendicular to the direction of bulk transport. Currently, no models account for anisotropy and all transport coefficients are calculated as volume weighted averages or from empirical correlations (not developed for fibrous porous media). The present work presents a new methodology for determining anisotropic transport coefficients in fibrous porous media. A numerical experimentation process is employed wherein random samples of the PTL are generated and used to solve a diffusion transport equation. Effective transport coefficients are determined by integration of flux across the domain boundaries once a steady state solution has been reached. Multiple random samples at each porosity are generated in order to predict statistical variance. The results are correlated for ease of implementation in full PEM models.

Jan 1, 2005

The ~2500 km long Kermadec-Tonga arc northeast ofNew Zealand is the longest continuous intraoceanic arc in the world. At least 94 volcanic centres along the arc are submarine, most (87 per cent) within the Kermadec arc (de Ronde et al, 2003a). Volcanic rocks range from basalt to rhyodacite with trace element and isotopic data indicating significant magma source heterogeneity both along and across the arc.   The entire ~1300 km of the Kermadec arc has now been surveyed for hydrothermal emissions (de Ronde et al, 2004). First-stage surveys utilised surface vessels. In February 1996, the first sulfide samples from the southern Kermadec arc were dredged from the Brothers and Rumble II West caldera volcanoes (R/V Tangaroa cruise TAN96/03; Wright et al, 1998; de Ronde et al, 2003b). In September 1998, low-temperature, diffuse venting was discovered at Monowai, Rumble III and Clark volcanoes, and high-temperature, black smoker venting was found within Brothers caldera (R/V Sonne cruise SO-135; Stoffers et al, 1999). The NZAPLUME cruise of March 1999 surveyed 13 volcanic centres (each mainly comprised of single, large volcanoes) of the southern Kermadec arc and documented hydrothermal emissions above seven of them (de Ronde et al, 2001; Baker et al, 2003; Massoth et al, 2003). In July 2001, additional mineralised and hydrothermally altered samples were dredged from Brothers volcano (R/V Tangaroa cruise TAN01/07). The NZAPLUME II cruise of May 2002 confirmed venting was still occurring at all the known hydrothermal sites, and that ten active vent sites occurred along the mid-part of the arc, between Brothers and Raoul Island (de Ronde et al, 2002). In September-October 2004, NZAPLUME III surveyed the northern-most part of the Kermadec arc where another nine volcanic centres are hydrothermally active.   Second-stage exploration of the Kermadec arc hydrothermal systems utilised deep submergence vehicles. In October-November 2004, the Japanese submersible Shinkai 6500 made four dives on Brothers. Samples recovered include vent fluids, chimneys, altered rocks and various animals and microbes. In April-May 2005, a more extensive expedition using the American submersible Pisces V made 23 dives on nine different volcanic centres, eight of them for the first time.   Extensive plume surveys show Brothers volcano is host to the most hydrothermally active sites of all those known along the Kermadec arc. In total, nine dives have been made on Brothers, six on the NW caldera site and three on the cone site. The NW caldera vent site is a long-term hydrothermal system that is today dominated by evolved seawater but has had episodic injections of magmatic fluid. The cone site is a nascent magmatic-hydrothermal system where crack zones localise upwelling acidic waters (de Ronde et al, 2005). A SE caldera site represents the main upflow of a relatively well-established magmatic-hydrothermal system on the seafloor where sulfide-rich chimneys are extant. Each of these different vent sites represent diverse parts of an evolving hydrothermal system, any one of which may be typical of submarine volcanic arcs.

Jan 1, 2005

By J Cahill, D Holden, R Stuart, G Cryan, W Power, W Stratford, S Garwin

The combination of Stage 1 Geoinformatics legacy data intervention processes with the Stage 2 ultra-detailed airborne geophysical prospecting demonstrates a new approach to converting data to information to knowledge, and converting that knowledge into exploration results.   The Coromandel region of the North Island of New Zealand has long been know to host gold deposits of economic viability (Hauraki Gold Fields). To the SE of this area lies the Taupo Volcanic Region (TVR) where the geology and structural setting mirror the Hauraki Gold Fields, however mineral exploration in the past has been hindered by the blanketing volcanic ash deposits. Glass Earth Limited recognised that this whole potential epithermal gold province could be effectively explored utilising rapid, risk orientated processing to review legacy geoscience data: The Geoinformatics Data Intervention Process; which in turn directed ultra detailed airborne geophysical surveys over the TVR. Results have outlined 21 new drillable potential epithermal gold targets; and a plethora of other targets with high prospectivity.

Jan 1, 2005

By C Agreda

The Cushion Blasting Technique applied to solve the high risk case history represented by a 10,704 TM rock locate at 120 M from the hydroelectrical plants of 350 KV each, is described, analyzed and discussed. The generation and distribution of 700 KV produced by two hydroelectrical plants must not be interrupted by any reason, because the 26 district of the province of cajatambo, of the Lima department; would not have electrical power. The search of the best alternative and methodology, the drilling and blasting pattern calculations, charge design and loading, connections and initiations of the 50 blasts are described, analyzed and discussed. Finally, the excellent results from a technical, economical, enviromental and safety point of view of the 50 primary blasts are discussed and emphasized.

Jan 1, 2005

By G McLeay, T Moran

Long Shaft has traditionally been seen as one of the most challenging mines in the Kambalda area with operations having been suspended by the previous owners in 1999. When mining recommenced in October 2002, the current owners (Lightning Nickel) decided that a different approach was required for mining operations in such an aggressive geotechnical environment. This paper describes how Lightning Nickel has successfully and safely operated the Long Shaft complex on a traditional mining approach, which encompasses the key learnings of the previous owners.

Jan 1, 2005

By James R. Hein

Methane and hydrogen sulfide vent from a cold seep above a shallowly buried methane hydrate in a mud volcano located 24 km offshore of Los Angeles, California in 800 m water. Bivalves, authigenic calcite, and methane hydrate were recovered in a 2.1 m piston core. Aragonite shells of two bivalve species are unusually depleted in 13C (to -19? d13C), the most 13C-depleted shells of marine macrofauna yet discovered. Carbon isotopes for both living and dead specimens indicate that they used in part carbon derived from anaerobically oxidized methane (AOM) to construct their shells. Although the?d13C values are highly variable among specimens, most fall within the range -12 to -19?. This variability may be diagnostic for identifying cold-seep/hydrate systems in the geologic record. Authigenic calcite is abundant in the cores down to about 1.5 m subbottom, the methane hydrate horizon. The calcite is strongly depleted in 13C d13C = -46 to -58?) indicating that AOM was the main carbon source. Three sources of methane are likely: a geologic hydrocarbon reservoir, and biogenic and thermogenic degradation of organic matter in basin sediments. Oxygen isotopes indicate that most calcite formed out of isotopic equilibrium with ambient bottom-water, under the influence of gas hydrate dissociation and strong methane flux. High concentrations of Ag, Hg, Cd, Tl, and other elements in mud volcano sediment reflect leaching of basement rocks by fluids circulating along an underlying fault. Fossil (geologic) methane was likely transported with these fluids.

Jan 1, 2005

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By I. Colquhoun

Current practice tends towards "integrity as an afterthought". That is, integrity is treated as an isolated aspect of operations and maintenance. In fact, this works quite well. But it would work so much better and with less uncertainty if integrity management measures were introduced at the design phase and addressed the entire life-cycle of the pipeline asset. The talk will address the measures and metrics that can be implemented on a new pipeline during design to optimize integrity and deliver a comprehensive operating manual and integrity management program for the pipeline system. This deliverable should describe the risks to be assessed and monitored, and the actions to be taken to control these risk adequately. Properly executed, integrity by design will provide a good working estimate of the life-cycle integrity management costs and maximize system reliability.

Jan 1, 2005

By C. A. Pickles

Microwaves are being applied industrially in a number of fields and possess a number of potential advantages that could be applied in extractive metallurgy. Microwave heating has a number of unique characteristics, which distinguish it from the conventional heating methods. In microwave heating, the absorption of energy occurs at the molecular or atomic level and therefore the heat is generated within the material itself. In conventional heating, the exterior temperature is usually higher than the interior, but with microwave heating, the temperature gradient is inverted and thus the interior temperature can be much higher than that of the surface. The energy densities in microwave systems can be relatively high and this in combination with the low thermal conductivities of oxide ores, can lead to very high internal heating rates. In this research, the application of microwave energy for the reduction of a nickeliferous silicate laterite ore has been investigated. The real and imaginary permittivities are the two fundamental properties which determine the microwave absorption characteristics of a material and these were measured for the ore, both with and without carbon additions using the cavity perturbation technique. The microwave heating and reduction experiments were performed in a 0 to 2 kW CTC microwave system. The effects of power input, processing time, sample mass and charcoal additions on the microwave absorption were investigated. Then reduction experiments were performed and the nickel grade of the magnetic concentrate and the nickel recovery in the concentrate were determined.

Jan 1, 2005

Computer software has been developed to link real-time information generated by underground mine ventilation airflow monitoring sensors into a network simulation program to undertake network simulations and allow interpretation of key system data and operational changes. Results were used in the development of a computerised monitoring and simulation system to provide immediate or real-time data on air behaviour within each branch of an underground mine ventilation network through linking of sensors to the ventilation network simulation software. The outcome of the project is an online system that can report changes in the mine ventilation system, allow causes of changes to be isolated and rectified, improve balancing of available air throughout the mine, allow improved approaches to regulator setting and dispense with much of the labour used for underground ventilation measurement. The work activities in both coal and metalliferous Australian mines have involved examination and modelling of regulators, software modification and considerable mine site testing and optimising activities. There is some discussion on approaches to control of flow through ventilation systems with increased information. New systems will be part of a total mine information management system. They will have to be cost effective and justified by gains in productivity. New systems will need to provide simulation of contaminant production such as diesels, vehicle heat, strata heat, radiation, blast fumes and other gases. More robust real-time ventilation simulation systems will be required. Personnel and vehicle identification and production tracking will be collected to provide integrated ventilation system monitoring and control. This paper examines a study to gain greater understanding of computerised real-time airflow monitoring and control within the mine production system to provide immediate simulated information in each branch of an underground ventilation network and to allow interpretation of key system data and operational changes. A case study implementing a real-time airflow monitoring and control is discussed. Approaches to control of flow through ventilation systems with increased information are discussed. The concept of a system that can be linked to or be part of a total mine information management system is developed. Such a system can form the base for mine automation that allows mines to incrementally and cost effectively implement monitoring and control to further seek gains in productivity.

Jan 1, 2005

By A. Varma

Successful technology commercialization occurs when a company is focused on creating shareholder value by providing a reliable product at a price point attractive to the market, while at the same time maintaining strict control of its internal cash burn rates. Developing a technology platform and a market platform are equally important in the commercialization of new technologies such as fuel cells. This paper will discuss some of the key barriers that may prevent successful market entry for emerging and disruptive technologies, such as: R&D priorities, supply chain / manufacturing issues, materials, cost reduction strategies, customer needs, developing a market pull strategy, institutional barriers such as existing regulatory/approvals processes and/or current design/purchasing practices, product reliability and resilience, and finding the right path to market. SDTC is an arms length foundation that aims to financially support the successful market entry of emerging and disruptive technologies that can provide significant environmental benefits to Canada. The fuel cell industry, which represents one such technology, is at a critical point in its evolution where market receptivity and the technology platform are converging to potentially create significant customer advantages for fuel cell products being developed today. Since its inception in 2001, SDTC has received over 850 business cases from which it has identified successful strategies to overcome the noted barriers to commercialization. While maintaining commercial confidentiality, the SDTC database will be mined to: Identify specific success stories that have overcome various barriers and discuss their strategy; Identify specific fuel cell related industry experiences that hinder successful market uptake. The general attributes and trends of successful technology developments identified in this paper will hopefully provide guidance to technology developers and prepare them to successfully tackle the next set of hurdles on the path to commercializing their technology, once they have proven their technology works in the laboratory.

Jan 1, 2005

By Sunil S. Basarkar, Dilip M. Dewaikar, Rajesh H. Gajjar

"A load transfer program AXPILE was developed for simulation of the loadmovement characteristics of socketed piles of the Mumbai reg ion. This program used empirical relationships for ultimate shaft resistance at pile-rock interface recommended by Zhang and Einstein (1998). According to their recommendation, ultimate shaft resistance at pile-rock interface is related to the square-root of uniaxial compressive strength of intact socket material by a parameter C, which ranges from 0.4 for smooth sockets to 0.8 for rough sockets. Results of three instrumented pile load tests were compared with the AXPILE generated results. The comparison of analytical and field estimates of the unit shaft resistance confirm the recommendations of Zhang and Einstein (1998) on the unit side shear parameter c,, which was found to be in the range of 0.35 to 0.67.INTRODUCTIONInstrumented pile load tests were carried out on the test piles at the Bandra-Worli sea link project in Mumbai city of western India. High capacity socketed piles were required to take up loads from the superstructure. Hence, in addition to the available toe resistance, an accurate measurement of the shaft resistance in socket portion was desired. The instrumented load tests incorporated Osterbergcell (0-cell) assisted by strain gauge instrumentation to estimate the shaft resistance mobilization in the socket portion.AXPILE load transfer program was developed for load-movement simulation of socketed piles (Basarkar, 2004). The load transfer algorithm based on Coyle and Reese (1966) was incorporated in this program, which used empirical correlations and functions to account for load transfer in piles through shaft and toe resistance.This paper compares the computed unit shaft resistance from the AXPILE program with the measured values recorded from the instrumented pile load test."

Jan 1, 2005

By P Carrasco, E Me, M Campos, J Tapia

Correct sampling practices are of vital importance to the mining industry; key decisions for the business are made on the basis of samples in all the value chain. Geology plays a relevant role in pre- and post-investment stages. Actually the understanding of natural variability is essential for geological modelling, geometallurgical modelling, mine planning, grade and process control. Improper sampling practices obstruct this objective introducing irrelevant variability components, which can cause monumental economic losses. A good approach to accomplish this understanding is the application of heterogeneity and IngamellsÆs tests, which are useful tools to quantify the variability of a certain well-delimited geological unit at different comminution scales. The application of heterogeneity test can help minimise Pierre GyÆs fundamental sampling error and to study the impact of other sampling errors. IngamellÆs test allows us to define the correct mass of sample for chemical analysis. This paper presents the results of several heterogeneity and IngamellsÆs tests done in Chilean porphyry copper deposits that belong to CODELCO Chile (Chuquicamata, Mina Sur, Radomiro Tomic, El Salvador, Andina and Teniente), in different geological units (endogenous oxides, exotic oxides, supergene sulfides and hypogene sulfides) and for several elements (Cut, Cus, Mo and As). These tests, considering the natural variability, have helped us develop accurate sampling protocols to minimise the fundamental error to acceptable levels. A major contribution of these tests (more than 30) is the generation of secure sampling protocols using the highest sampling constant obtained in the tests, for new porphyry copper deposits that donÆt have information given by heterogeneity and IngamellsÆs tests.

Jan 1, 2005

The products required by customers today have become far more complex and consequently more demanding to handle. And thereÆs the dilemma. Nowadays, people tend to stick to a trade for just a few years instead of for a lifetime, and this means that the customerÆs employees cannot be expected to get more than general knowledge of how to handle modern mining and construction equipment. To meet this challenge, major steps are being taken by suppliers to make their æmusclesÆ more user-friendly. Also the supplier is assuming a larger share of responsibility for the product including operators training, supply maintenance services and, in many cases, performance guarantees. In other words, the supplier is today supplying a function or an activity rather than just muscles. Some of the new generation drill rigs have been on the market for a few years and reliable experience has been collected and is addressed in this paper. Some of the information is well supported by figures while others are just statements from users of the rigs.

Jan 1, 2005

By M. J. Gagnon

The agglomeration of particulate materials is used in many mineral processes to enhance the settling of the fine particles, Depending upon many physical and chemical parameters, the aggregates demonstrate specific density-size distributions, In this study, a fractal model of the agglomeration process is introduced, Based on reliable experimental data and on physical calculation, the model presented helps to envisage the initial formation of the micro-flocs, and to interpret the subsequent interactions between the aggregates in terms of either coagulation or flocculation, Data from different sources, materials and different agglomeration processes are analysed and compared in the light of the proposed model.

Jan 1, 2005