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By Zhan Jing

Keywords: thermodynamic, Ni-Co alloy powders, composition, fibrous The mathematics model of Ni(II)-Co(II)-C2O42?-NH3?H2O-H2O of thermodynamic equilibrium system has been developed theoretically according to the law of conservation of mass and the law of simultaneous equilibrium, and the logarithm concentration-pH (log[Me2+]T-pH) diagrams of this system have been made. The effect of ligand and pH value was studied. Two issues in coprecipitation route to synthesize fibrous nickel-cobalt alloy precursor powder, com-position and morphology which are a first priority, are addressed based on thermodynamic analysis and experiments. The results show that suitable pH value range of coprecipitation of nickel ions and cobalt ions in theory can be obtained to maintain fibrous, excellent compositonal homogeneity and stoichiometry in coprecipitation products. Experimental demonstration is also carried out.

Jan 1, 2005

During 1995 a catastrophic accident took place at the No 2 Vaal Reefs shaft in South Africa, when a locomotive fell onto a cage, causing the death of 104 people. The subsequent Commission of Enquiry found that the safety detaching hook had opened when hit by parts of the falling locomotive, detaching the cage from the rope and allowing the cage to drop 400 m down the shaft. It was believed that had the hook not detached, the rope would have been sufficiently elastic not to have failed, implying that many fatalities may have been avoided. In addition, the risk of accidental opening of hooks due to impact with smaller falling objects in shafts became a concern. This paper deals with a comprehensive statistical investigation that was performed to quantify this risk, establish acceptable levels of such risks and to derive criteria for the resistance of detachment hooks against accidental opening caused by impacts. The investigation involved a survey, dynamic finite element analyses and Monte Carlo simulations.

Jan 1, 2005

By Numan Elmas

Barite deposits located in Dinek and surrounding region have important economic features with their large reserve capacity for Turkey. The objective of this study is to elucidate geological and depositional characteristics in terms of. site investigation and chemical analysis. In order to do this, geological area of about 300 km2 was examined and detailed geological map was constructed. It was observed that Barite mineralization in these deposits was occurred in carbonate and pelitic rocks of Lower Cambrian-Lower Ordovician. Deposits were exposed to advanced diagenesis regional metamorphism and tectonics that rotated and deformed the barites; therefore, barites shows secondary veins, brecciate and fracturing structure. Even though, a few light isotope values of barites may suggest hydrothermal and exhalative sedimentary characteristics or possible mixing with magmatic fluids, generally heavy isotope values indicate that the sulfate ions were supplied from coeval seawater and, many of sedimentary features and petrological, geochemical characters support dominantly sedimentary origin.

Jan 1, 2005

By K. B. Hodgins, P. Ouellette

"The North American mining industry faces challenging emissions regulations in the coming years with the introduction of new standards for off-road diesel engines. In order to remain competitive, industry stakeholders must invest in new technologies that are economically and environmentally sustainable.Westport Innovations Inc., Vancouver,British Columbia, has developed high-pressure direct injection (HPDI) technology that allows diesel engines to run primarily on natural gas with no intrusive engine modifications while reducing emissions of nitrous oxides (NOx), particulate matter (PM), and CO2 with no loss in performance. This is accomplished through late-cycle, high-pressure direct injection of natural gas into a diesel engine combustion chamber at the end of the compression stroke. A small amount of diesel fuel is injected first to initiate combustion, followed by the natural gas fuel main injection. The diesel cycle and its operating characteristics are fully retained including high combustion efficiency, lowspeed torque, high-power output, no engine knock, and fast response to load changes. Natural gas has not been an attractive fuel alternative in mining operations due to the reduced performance associated with spark ignition engines and the added weight and space required for compressed natural gas tanks. However, liquefied natural gas (LNG) can be stored with less impact on weight and space than compressed natural gas (CNG) by virtue of its increased energy density over CNG.Westport has applied HPDI technology to the Cummins QSK series engines for high horsepower applications such as power generation and mine haul trucking. HPDI can also be applied to other engine manufacturer platforms and market applications. Westport is interested in demonstrating the unique characteristics of HPDI in mine haul trucks to show diesel performance with low emissions levels using low-cost LNG fuel.Retrofitting a Tier 1 engine with HPDI would provide emissions reductions below the EPA 2006 Tier 2 standards while maintaining the performance and efficiency of the Tier 1 platform. The longer-term target is the Blue Sky voluntary standards of 3.8 g/kW-hr (2.8 g/bhphr) of NOx + non-methane hydrocarbons (NMHC), and 0.12 g/kW-hr (0.09 g/bhp-hr) of particulate matter (PM) and future standards. Typically, an HPDI engine is capable of reducing NOx emissions by 40% over diesel operation at the same efficiency. On a mining truck meeting Tier 2 standards, this NOx reduction would translate into NOx emissions approximately 14 t per year lower than under diesel operation. PM emissions are typically reduced by some 60% with HPDI fueling, which would translate into a yearly reduction of 650 kg. Similarly, engine-out greenhouse gas (GHG) emissions are reduced by 21%, resulting in a yearly reduction of approximately 950 t per vehicle.Above those of emissions reduction, efficient natural gas usage in mine haul operations would offer significant benefits in terms of fuel cost savings, which may be further combined with monetary emission credits. HPDI technology would enable operators to exercise environmental stewardship while gaining a competitive advantage in advance of new Tier 2 and Tier 3 emissions regulations. The advantages of natural gas use among mine haul truck operations can be replicated across a broad range of engines and applications."

Jan 1, 2005

By J. Brent Hiskey

INTRODUCTION Metal electrodeposition processes are of fundamental technological importance to a number of fields. Electrorefining, electrowinning, electroplating, and electrogalvanizing have all been the subject of intense study for over a century. More recently, electrochem- ical deposition has played a critical role in advances in microelectronics and lately has been an enabling technology for the production of certain nanostructured materials. Electrometallurgists have most frequently been concerned with the structure and morphology of massive deposits. For example, in metal recovery steps such as electrorefining and electrowinning, deposits demonstrating adherent coarse-grained characteristics are most desirable. In the case of electroplating, a bright fine-grained, tenacious and strongly adherent deposit is required. The fabrication of microelectronic devices and the production of nanoscale structures such as nanoparticles, nanowires, and nanorods requires a keen understanding of early stage deposition effects. The initial stages of metal deposition, usually referred to as electroclystallization, are fundamentally linked to nucleation and growth phenomena. Early stage deposits are typically very ordered. Whereas, bulk metal deposition structures are much more ran- dom. In both cases, the discharge of a metal ion at an electrified interface is represented by simple cathodic reduction as follows: [ ] Me(H2O)xn[ ] is a hydrated metal ion residing in the bulk solution and Me is the metal atom occupying a crystallographic lattice position. A similar reduction reaction can be

Jan 1, 2005

By Mikko Ruonala, Pertti Lamberg, Olli Hyvärinen

The smelting of copper sulphide concentrate is the dominant route in copper production (Figure 1). Heap leaching of oxidized copper ores with weak sulphuric acid together with copper solvent extraction and electrowinning has gained popularity during recent decades, and it accounts for close to 20 % of primary copper production. Heap leaching offers advantages such as lower costs and consequently the construction of a production plant at a mine site is made possible. Limited resources of oxidized copper ores, the long leaching time of chalcopyrite and inability to recover gold inhibit this growth. The HydroCopperTM process developed by Outokumpu Technology at the laboratories of Outokumpu Research, Pori, Finland, is a new chloride leaching technology /1,2/, which offers an alternative to smelting and heap leaching (Figure 1). In the HydroCopperTM process sulphidic concentrates with various mineralogy and grade can be treated at the mine site to produce high-quality copper. Instead of copper cathodes the HydroCopperTM end products are copper wire rod, copper bars or copper billets. One of the advantages of HydroCopperTM technology is that gold can also be recovered in the process simultaneously /3/. To confirm the functioning of the new process and to dimension equipment Outokumpu Technology built the HydroCopperTM demonstration plant in Pori, Finland /4/. It has a capacity of 1 metric ton of copper per day. After testing with Pyhäsalmi copper concentrate in 2003, the first commercial demonstration run with Erdenet copper concentrate took place in 2004.

Jan 1, 2005

By Y Peng, D Wannas

In the fine particle flotation technologies being developed today the fine hydrophilic (gangue) particles are usually well dispersed. These highly dispersed fine particles can be recovered into the flotation froth product by mechanical entrainment. Flocculation of hydrophilic particles caused by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxylapatite, galena and sphalerite, as well as on a relatively coarse quartz sample (-75+38 ¦m). Dodecylamine was used as a collector for the quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, potassium dichromate, corn starch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700 000 and 80 000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 ml flotation column. Both water and solid recoveries were recorded. The degree of flocculation and dispersion was determined by settling tests in 250 ml graduated cylinders. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of artificial mixtures of the -75+38 ¦m quartz and fine iron oxide or hydroxylapatite, polymer depressants that caused flocculation were found to perform better than the ones that did not cause flocculation.

Jan 1, 2005

By Yannick Beaudoin

The source of base metals in modern seafloor hydrothermal systems can be attributed to leaching of host rocks by hydrothermal fluids and/or potentially by direct degassing of magma. From an economic perspective, metal grade is the most important consideration for seafloor deposits. Tectonic setting appears to be a key factor influencing the development of high grade seafloor base metal sulfide deposits. Back-arcs have a clear advantage over other settings in producing large and rich polymetallic sulfide ores. Microinclusions of magma or so-called melt inclusions trapped in phenocrysts of lavas have contributed to our understanding of the ore-forming process. n this study, we present data from 103 melt inclusions mainly in plagioclase crystals hosted in basaltic to rhyolitic lavas from 9 modern seafloor tectonic settings: oceanic back-arcs (Manus Basin including an ODP Leg 193 drill hole, Bransfield Straits), continental back-arc (Okinawa Trough), mid-ocean ridges (Explorer, MAR), seamounts (Foundation, Axial, Pito), and a transform (Garrett). Most sites host active hydrothermal systems that are producing polymetallic sulfides.

Jan 1, 2005

By T. Rasmussen, T. G. Jørgensen, T. Fischer, R. K. McLimans, C. Knudsen, D. Frei

Ilmenite-bearing paleo-beach deposits were discovered in Jylland, Denmark using a combination of Ground Penetrating Radar (GPR), portable X-ray fluorescence (XMET), bulk XRF analyses, Computer Controlled Scanning Electron Microscopy (CCSEM), and wire line logging. The Miocene-age paleo-beach deposits are located below a thin Quaternary cover in a region of very moderate relief and essentially no outcrop demanding unique approaches in exploration. Initially, an isopach map of the Quaternary is prepared from existing water well data. A geological model for likely occurrence of Miocene paleo-beach deposits is generated and the coincidence of thin Quaternary cover and potential paleo-beach deposits define targets for detailed exploration. The defined targets are traversed with GPR to identify paleo-beach structures which are then used to define a drilling program. This methodology located a paleo-barrier island at the Vorslunde location with more than 10% ilmenite in the sand. During the drilling process, the TiO2 and heavy mineral contents of the sand were logged every meter with a portable XRF unit (XMET) and subsequently calibrated more accurately by comparison to bulk XRF and CCSEM analyses for selected samples. The bulk XRF data also provided more complete compositional information. Insitu determination of geology, heavy mineral abundance, and corroboration of the XRF logging was done using wire line logs, a combination of spectral gamma and induction conductivity logs. Detailed characteristics (abundance, grain size, shape) and chemical composition of minerals was determined by the GEUS CCSEM methodology (Frei et al, this vol.). The average weight percent TiO2 for all Ti-minerals is 62%, 60% excluding rutile. That elevated TiO2 content (>> ilmenite stoichiometric value, ca. 50 %) indicates that ilmenite experienced an iron-leaching environment. The source of the sand deposit was investigated by dating contained zircon. The results show that the likely sources of zircon are in southern Norway and southwestern Sweden with common zircon ages of ca 1100 Ma. and 1500 Ma.

Jan 1, 2005

The Pike River Coalfield is located on the West Coast of the South Island of New Zealand near the top of the Paparoa Range approximately 45 km north east of the coastal town of Greymouth. The Pike River Coal Company Ltd (PRCC) is owned jointly by New Zealand Oil & Gas Limited (NZOG) and private investors.   The project has followed a long and difficult road towards project implementation which is now a reality with mine construction scheduled to commence in November 2005. The first stage of the project, the consent and land access process has been the most difficult. Resource consents for the project were first applied for, granted and appealed in 1998. A second round of modified resources consents followed a similar path in 2001. Following consultation with a range of parties including local and central government as well as the Department of Conservation, in March 2004 the Minister of Conservation granted PRCC access through Department of Conservation land. In October 2004, the Environment Court issued a Memorandum of Consent granting resource consents with conditions that had been negotiated between PRCC and the appellants.   The second stage of the project, investigation and design, commenced in December 2004 and was completed in June 2005 with the PRCC board ratifying the project capital and operating budgets. While the investigation and design work was proceeding, PRCC were also engaged in securing private equity and bank debt funding for the project. Formal Board approval to proceed with project construction was granted in September 2005 following completion of fund raising.   The project consists of a number of significant construction activities, namely: +        10.5 km of mine access road through previous logged and virgin rain forest; +        2.2 km of tunnel through metamorphic rock; +        a coal preparation plant about 8.3 km from the mine portal; +        an underground coal preparation plant; and +        a major slurry pump station, high and low pressure underground water supply systems to support hydraulic mining units and underground coal transport respectively.   Project construction is expected to be completed in April 2007 with completion of the ventilation shaft. Mine production will commence in December 2006 with coal from pit bottom development which will be carried out by the mine owner.

Jan 1, 2005

Folklore suggests that oxidation is detrimental to sulfide mineral flotation, and in many instances is the reason given for values reporting in the tailing. However, while a considerable body of work examining galena oxidation is available in the literature there are very few studies that investigate the consequences of galena oxidation on its subsequent flotation in base metal sulfide ores. This work clearly demonstrates that pyrite forms a galvanic couple with galena, due to the large difference in their rest potentials, and results in accelerated oxidation of galena, particularly as the pyrite content of the ore is increased. The most obvious effect of the galvanic oxidation of galena by pyrite is the release into the system of galena oxidation products, providing an ample supply of lead ions available to activate gangue minerals, most notably of which in lead/zinc ores is sphalerite. The inadvertent activation of sphalerite by lead ions inevitably leads to the recovery of liberated sphalerite into the lead concentrate, and as a consequence a reduction in the lead concentrate grade. That is, a loss of selectivity for galena against sphalerite. If galena oxidation is excessive not only is there a considerable loss in lead concentrate grade, but also a marked decreased in lead recovery as the flotation rates of the gangue minerals increase, until they rival that of galena.

Jan 1, 2005

By Emre Biringen

"Results from a small-scale laboratory experimental program show the changes in the vertical stiffness and strength of a soft clayey soil adjacent to the shaft of an inserted pile (i.e. expansion of a cylindrical cavity). The experimental program provides a realistic axi-symmetric physical model of an element of a cylindrical pile and the surrounding soil. The study interprets the improvement and assesses its magnitude in vertical stress-strain-strength properties of a normally consolidated soft cohesive soil in response to preloading impact in the radial direction. The results verify that insertion of a cylindrical pile causes densification of surrounding soil in a radial direction due to change in stress state around the pile, and thus consolidating and stiffening of the soil.The test results indicate that most improvement in modulus and strength takes place within a distance of 4 times the radius of a pile, though significant improvement is realized to a distance of 8-10 times the radius, beyond where there is negligible effect. Settlement characteristics of the surrounding soil in a zone of 12 times the pile radius improve significantly after the formation of a cylindrical cavity. The miniature vane shear strength tests show a 1.5 times increase in a zone of 4 times the pile radius compared to the strength at 10 pile radii. The results also imply that the spacing of cylindrical piles should not be more than 4 to 10 times pile radius, so that the surrounding soil matrix may improve the vertical bearing capacity under any foundation or embankment loading.INTRODUCTIONThe engineering community is familiar with different techniques to improve the bearing capacity and settlement characteristics of weak cohesive and organic soils. Some of the in situ techniques to improve the properties of soft ground (e.g. soft clays) prior to placement of foundations are vertical preloading, deep cemenUlime mixing, stone columns, and grouting (Henn 1996; Moseley 1993). In addition to these methods, researchers have recently showed interest in achieving soft ground improvement by means of applying radial compression method for which different names exist including expanding pile (Kelleher et al. 2001 ), Preload™ Pier (Biringen and Edil 2003), and sand compaction pile (Lee et al. 2004). Handy (2001) has described how preloading can also be achieved by imposition of radial loading in soft ground with an expected improvement in stiffness. The idea behind the latter method is densification and consolidation of soft soil in the radial direction by controlled displacement for which the process can be viewed as a cavity expansion problem (Vesic 1972)."

Jan 1, 2005

By Monica Prezzi

"Auger cast-in-place (ACIP} piles and drilled displacement piles are being increasingly used as foundation elements for structures, particularly in projects requiring accelerated construction or involving the rehabilitation of foundations of existing, overstressed structures. Auger cast-in-place piles (also referred to as continuous-flight-auger piles) are widely used to construct the foundations of all types of structures. There are many different types of drilled displacement piles, with the installation methods varying according to the equipment used. Depending on the specific rotary piling technology used, responses ranging from those associated with non-displacement to those associated with full-displacement piles are obtained. Conventional pile design methods do not account for how the various construction techniques involved in auger piling change the soil state around the pile during installation and, hence, cannot accurately estimate the pile resistance in a consistent way. Research on this subject, identifying the different variables that must be accounted for in design and linking these variables to installation methods, is lacking. This paper describes the different piling methods available for auger cast-in-place and drilled displacement piles, the equipment used to install them and the quality control processes typically used. It also reviews some of the design methods currently used.IntroductionDeep foundations are extensively used in geotechnical engineering practice. The wide spectrum of piling methods results in a variety of pile types. Each type behaves differently, depending on the installation or construction methods. On one end of the spectrum are non-displacement piles, the classicql examples of which are bored piles or drilled · shafts. These piles are constructed by removing a cylinder of soil from the ground and replacing it with concrete and reinforcement. On the other end are full-displacement piles, such as closed-ended pipe piles or precast reinforced concrete piles, which are typically driven into the ground. Driven piles preload the materials below the toe of the pile and displace the soil surrounding the pile shaft laterally during the installation process. Therefore, displacement piles are, in general, more likely to have a stiffer response than non-displacement piles. This is true particularly in the case of sandy soils where displacement causes densification."

Jan 1, 2005

By C. -S. Xie, J. -H. Kong

The microstructure and mechanical properties of X80 hot-rolled thick steel strips with a thickness of 17.5mm produced in Wuhan Iron & Steel Company (WISCO) are introduced in the paper. The steel strips as fabricated through proper thermomechanical processing (TMP)/ on-line accelerated cooling (OLAC) processing have shown high strength and toughness, low brittle transition temperature, good weldability, and high Shear Area (SA) percentage in Drop Weight Tear Test (DWTT). The microstructure of the steel strips is characterized with mainly acicular ferrite, and fine dispersed Martensitc-Austenite (M-A) phases. It is determined that the mechanical properties are improved due to the presence of the fine M-A phases and precipitates, which could be formed by reducing the finish rolling and coiling temperatures.

Jan 1, 2005

By Ji-He Wei

Keywords: stainless steel, AOD refining, side and top combined blowing, mixing characteristics, water modeling The fluid mixing characteristics in the bath during the side and top combined blowing AOD (argon-oxygen decarburization) refining process of stainless steel have preliminarily been studied on a water model unit of a 120 t AOD converter. The geometric similarity ratio between the model and its prototype (including the side tuyeres and the top lances) was 1:4. On the basis of the theoretical calculations for the parameters of the gas streams in the side tuyeres and the top lances, the gas blowing rates used for the model have more reasonably been determined. The influence of the tuyere number and position arrangement, and the gas flow rates for side and top blowing on the characteristics has been examined. The results demonstrated that the liquid in the bath underwent vigorous circulatory motion during gas blowing, without obvious dead zone in the bath, resulting in a well mixing effectiveness. The gas flow rate of the main tuyere had a governing role on the characteristics, a suitable increase in the gas flow rate of the subtuyere could improve mixing efficiency, and the gas jet from top lance could make the mixing time prolong. Corresponding to the oxygen top blowing rate specified by the technology, a roughly equivalent and good mixing effectiveness could be reached by using six side tuyeres with an angle of 27° between each tuyere, and five side tuyeres with an angular separation of 22.5° or 27° between each tuyere. The relationships of the mixing time with the gas blowing rates of main-tuyeres and sub-tuyeres and top lance, the angle between each tuyere, and the tuyere number have been obtained.

Jan 1, 2005

By J. F. T. Agapito

Overcore measurements at the North Fork Valley (NFV) coal mines in western Colorado have shown that horizontal stresses are highly anisotropic. Measurements have been made in four mines at various depths. In many measurements, the maximum horizontal stress is three to four times higher than the minor horizontal stress. At the West Elk Mine, maximum and minimum horizontal stresses of 24 MPa and 6 MPa, respectively, have been measured at depths of 640 meters (m). Under highly anisotropic stress conditions, ground control problems associated with both high and low horizontal stresses can develop. While high horizontal stresses can produce cutter failures and floor heave, low horizontal stresses can allow block fallouts. This paper summarizes the horizontal stress measurements in NFV mines and, in particular, in the West Elk Mine where their role in roof fall and floor heave failures is discussed. This experience has led to an improved use of ground support and safer mining operations at depths of 640 to 700 m.

Jan 1, 2005

By David Royston

Conventional straight-radial SAG mill pulp lifters suffer from incomplete discharge of the rock portion of the charge. The resulting backflow of undischarged rock limits pulp lifter performance and is the major source of wear in pulp lifters. Backflow is increased in pulp discharge cone systems where multiple channels converge towards the central diversion cone. This paper covers recent experience with pulp lifter and discharge cone design supported by a single particle motion model that illustrates the discharge and backflow characteristics of pulp lifters, including the impact of discharge cone configuration.

Jan 1, 2005

By Bob King

Jan 1, 2005

By A. Nivala, S. Ulgiati, M. Canino

Mining and processing of bastnaesite ore, (Ln)CO3F, for lanthanides extraction is investigated in this paper. This series of elements proved to be applicable for a wide range of high-tech uses. In spite of the strategic importance of lanthanides, no LCA and energy analyses of their extraction have ever been published. We perform in this paper a Life Cycle Assessment of the Lanthanide production cycle, based on available database and literature data from Mountain Pass mine (USA) and other worldwide mining and processing sites, most of which in China. We investigated three main steps: mining, milling (including transport, grinding and drying), and flotation (for lanthanide chloride extraction). We do not investigate here the separation of pure oxides from lanthanide chloride, a compound which is also marketed as such. The conventional LCA was integrated by means of energy and emergy evaluations, aimed at investigating respectively the global energy cost and the environmental sustainability of the process. Indicators of material intensity, thermodynamic efficiency, and environmental impact (including LCA and ecological footprint impact categories) are calculated and discussed.

Jan 1, 2005

The Snap Lake Phase I project initiated a subsampling campaign on the material (kimberlite/metavolcanic/granite) mined and treated for diamonds. The campaign was aimed at determining the optimum subsampling program to subsample the feed to the bulk sample plant (BSP) for the duration of a sampling campaign. This paper describes the application of GyÆs formula for determining the subsample size and other good sampling practices to determine this subsampling campaign. Three main issues are discussed: the use of a hammer sampler to sample off a moving conveyor and the practical experiment to determine the optimum subsampling program; bias introduced by laboratory equipment including two sizes rotary splitters; and variability of the feed material to the BSP over time.

Jan 1, 2005