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By K. A. Allison, D. R. Van Orden, R. J. Lee

Continuing analysis of environmental samples for asbestos content has resulted in the misidentification of non-asbestos amphibole particles as asbestos fibers. These errors have received wide publicity (such as in the asbestos-in-crayon story) and have caused unnecessary reformulation of products. The primary cause of these errors has been a poor understanding of mineralogy and analytical techniques among the many asbestos laboratories that arose following the passage of the AHERA regulations. Presented here is a procedure based on published data that can be used to correctly classify an elongated particle as asbestos or as non-asbestos.

Jan 1, 2005

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

The Pike River Coal Company is set to develop the Pike River Coal Mine in the Paparoa Ranges of New ZealandÆs South Island. The mine will be developed to extract a coking coal deposit of the Brunner Seam, some 46 km north-east of Greymouth, using a combination of continuous miners and hydraulic extraction.   The mining area is located within Department of Conservation (DOC) land and is adjacent to the escarpment of the Paparoa Range and the Paparoa National Park. As such, the major restriction to planned extraction is protection of:   +        the western escarpment, +        vertical and sub-vertical rock faces, +        permanent water courses, +        significant vegetation, and +        steep slopes.   The mine will use its elevation advantage to hydraulically flume coal from the working faces to the pit bottom area where it will be slurried to approximately 35 per cent density of solids and pumps down a slurry line to the coal prep plant some 10.5 km down the Pike River Valley. The coal will be sold on the export market as a high quality coking coal for international steel making.

Jan 1, 2005

By Allison

During the 1980’s, laboratories opened throughout the United States to serve the analysis needs of a rapidly growing asbestos abatement industry. The samples analyzed were either collected during the abatement of known asbestos-containing materials or were suspect asbestos-containing construction materials. Many asbestos analysts received minimal training and used analytical protocols that were industry specific. False positives (reporting a sample as containing asbestos when none is present) went unnoticed or had minor repercussions. The mindset of the industry was to err on the conservative side – it would be better to identify a non-asbestos fiber as asbestos than visa versa. With growing public awareness of the health hazards of asbestos, other materials began to be tested for asbestos content. Rock and ores began to be tested for naturally occurring asbestos by these laboratories using the same protocols or an in-house protocol. Analysts were given no additional training and accreditation, in most cases, it was not required. With no consistency in sample collection, testing protocol or expertise in analysis, significant discrepancies in final results can be expected. If we further complicate this scenario with misidentification of naturally occurring look-a-likes for asbestos, expensive false positives are likely. To avoid the repercussions of misidentification of naturally occurring chrysotile asbestos from look-a-like fibers in rock and ores, correct sampling and analysis protocols with more stringent scientific diagnostic criteria are needed.

Jan 1, 2005

Commercial SOFC systems will likely utilize hydrocarbons or hydrogen produced from hydrocarbon fuels and therefore will likely be exposed to sulfur impurities. Conducting-Atomic Force Microscopy (C-AFM) is a scanning probe microscopy technique which maps both sample topography and conductivity with tens of nanometers resolution. In Ni-YSZ, C-AFM measures the resistance of the metallic network at scanned locations, with the ability to differentiate between interconnected and isolated metallic particles. We have applied C-AFM to Ni-YSZ SOFC anode materials, with the goal of monitoring changes in the conductivity of the Ni anode network resulting from SOFC degradation processes, such as H2S poisoning.

Jan 1, 2005

By F J. Rios

In the eastern high-strain domain of the Quadrilßtero Ferrffero, Brazil, hard and soft high-grade hematite ore may occur as schistose bodies in shear zones mainly related to the Cambotas-Fundpo thrust system. These orebodies are almost entirely constituted of oriented specularite platelets that develop both as a product of crystal-plastic deformation of hematite and solution-precipitation processes. Both mechanisms interact in the partitioning of the strain, while solution-precipitation is responsible for the precipitation of hematite and localised leaching of silica resulting in the formation of syntectonic ores. The analyses of fluid inclusions from specularite crystals of the Conceitpo and Timbopeba deposits, located in the northern and southernmost areas of the eastern high-strain domain of the Quadrilßtero Ferrffero, were studied using infrared microthermometry and Synchrotron x-ray fluorescence. The results indicate the participation of highly saline aqueous H2O-NaCl fluids containing other additional cations (Ca, Fe, K and probably Ti) in solution and homogenisation Temperature (Th) averaging between 130¦ - 190¦C. However, the partial fusion of metastable saturation phases indicates crystallisation temperatures of approximately 400¦C. The mineralisation process produces high-grade orebodies as well as Fe-rich specularitic itabirites that are explored in that area. The shear zones are related to thrust faults mapped and interpreted as related to the PanAfrican/Brasiliano Orogeny that affected the Quadrilßtero Ferrffero, thrusting the Paleoproterozoic platform sequence of the Minas Supergroup over Mesoproterozoic quartzites of the Espinhato Supergroup. They intersect and even overprint an early metamorphic and tectonic fabric of Paleoproterozoic age (Transamazonian Orogeny). The geological and fabric relationships lead to the conclusion that the fluids involved in the mineralisation were most probably of external origin, of still unknown source (possibly igneous), during the closure of the Spo Francisco Craton.

Jan 1, 2005

By C Standing, R Lacourt Rodrigues, C Q

The value of iron ore depends on the grade of the contaminants. Scheduled iron, and the associated contaminants, provides mine planners with a measure of stockpile feed and blending requirements. Blending at the stockpiles is one approach to optimising iron grade, while minimising the variability of contaminant grades. These schedules are typically based on resource models incorporating geology and iron and contaminant grades. Resource models reflect best estimates of trends for each of the elements rather than the potential variability, which is critical for accurate short-term blending. Conditional simulation provides a tool to describe the likely variability of each element. Only recently has conditional simulation technology allowed the inherent correlation between elements to be incorporated into the process. This paper presents the stepwise co-simulation process used to simulate and describe multi-element variability for effective mine planning. A case study using the multi-element conditional simulation and the subsequent uncertainty in the schedule and stockpile planning is presented. This process supports proactive mine planning to minimise unexpected fluctuations in the final product.

Jan 1, 2005

By Wayne E. Kilker, Michael J. McBride, William P. Levy, Thomas J. Lamb

Between 1989 and 2004 the Massachusetts Water Resources Authority (MWRA)constructed several major wastewater and water tunnels associated with three major projects in the Boston area of eastern Massachusetts. There were many similarities and differences in the bedrock conditions encountered and among the contractual approaches for these independent projects. Through a clarification of the approach similarities and analysis of the contract differences, this paper addresses and presents what are considered to be valuable lessons learned. In doing so, the paper follows the evolution of such disparate issues as contract conditions, baseline reports and dispute review boards. The authors believe that the lessons learned even represent what, in certain cases, could be referred to as “universal truths” that are intended to have application to the next generation of tunneling contracts.

Jan 1, 2005

By Calvin Konya, Steven S. Spagna, Ed Smith

During Summer 2001, the U.S Army Corps of Engineers awarded a contract to the construction firm of Bush and Burchett of Allen, Kentucky, for the purpose of developing a 13 acre redevelopment site by removing approximately 2.5 million cubic yards of rock (fig. 1). The Redevelopment Site will be the future home for a large portion of the City of Grundy, Virginia. Additional work items include the construction and relocation of 3,000 feet of the Norfolk Southern railroad bed, the placement of 95,000 cubic yards of fill and the placement of 16,000 cubic yards of stone slope protection along the Levisa Fork River. Bush and Burchett received a notice to proceed with construction in July 2001. Currently, the contract is near completion. Current activities include: hauling of material from the Redevelopment Site to the disposal area; placing fill material on the Redevelopment Site, and placing Stone Slope Protection (SSP) along the Levisa Fork river. Approximately one year into the construction highly weathered rock, degraded to near soil- like condition, was encountered in the upstream portion of the excavation. Over one-third of the original cut slope was adjusted and the blasting specifications had to be amended to accommodate for the material that was encountered in this area.

Jan 1, 2005

By E. Dernedde

Industrial plants located in the province of Quebec, Canada, are subjected to large variations of the ambient air temperature, Building ventilation systems of these plants must have some flexibility in order to meet industrial hygiene standards (TLV for chemical substances, heat stress and cold stress) at any time of the year, The building ventilation of a bath treatment plant of an aluminium smelter in Quebec was examined under summer and winter conditions, Part of the plant has periodic emissions of hydrogen fluoride gas and heat from hot anode butts, CFD modeling was used to optimise the building ventilation of the bath treatment plant, The present study proposes a modified building ventilation system, which improves the internal environment, complies with industrial hygiene standards and also reduces heating costs by 20 % during winter.

Jan 1, 2005

By Marthie Kotze, Jacolien Wyethe, Bert Van Hege, Richard Bell

Base metal refinery effluent streams may contain low metal concentrations that cannot be recovered by precipitation. Although the concentration is low, the total mass of unrecovered metal can have significant value because of the volumes of effluent generated. This metal may be recovered with high efficiency using selective ion exchange resins. Three process schemes are considered, viz., fixed bed column ion exchange, continuous countercurrent resin-in pulp, and continuous carousel resin-in-pulp. Each of these has different requirements in terms of equipment, resin inventory, capital and operating costs, and different limitations on feed conditions. Bateman and Mintek recently developed a model which allows an upfront economical evaluation of ion exchange options. The model evaluates the capital and operating costs for each process scheme for various base metals. This provides a general guideline for selecting the appropriate process arrangement for a given process stream.

Jan 1, 2005

By D. J. Pyra, J. Kudelko, Korzekwam W.

Polkowice region (Lower Silesia, Poland) is an area, where the copper mining activity started about 40 years ago and new technologies were applied. There are 3 underground mines, 3 processing plants, tailings pond (the biggest one in Europe), pipelines for flotation waste transport, railways. Although new technologies were applied during the copper ore exploitation, the environment in this area were polluted mostly by dust containing copper, lead, zinc and arsenic. Estimated values of heavy metals in polluted soils were compared to the natural contents of this metals. The geochemical background for Polkowice area was defined. The pollution zones occur around mining facilities. Copper ore exploitation and processing is planned for the next 20-40 years depending on market situation. After mines and other facilities closing the most important problem will be sustainable development of this area. To evaluate the scope of revitalization activities the analysis of recent soil environment condition will be necessary as well as forecasts for pollution migration. Geostatistic methods used also in mining will be very helpful for this task.

Jan 1, 2005

By I Jabouri

There are many physical factors that can affect the self-heating rate of coal. The presence of seam gas has often been referred to as inhibiting coal self-heating due to the limited access of oxidation sites created by the presence of the gas adsorbed on the coal pores. Similarly, the presence of bed moisture in the coal also acts as an inhibitor of oxidation by blocking access of air into the pores. Gas drainage of a coal seam prior to mining removes both gas and moisture from the seam. Bulk coal self-heating tests in a two-metre column on both gassy, as-mined and gas-drained, dried high volatile bituminous coal show that removal of gas and moisture from the coal accelerates the rate of self-heating to thermal runaway from 8.5 days to 4.25 days, from a start temperature of 30¦C, with an airflow of 0.25 L/min. The corresponding gas evolution pattern for each of these situations is different. Therefore, it is necessary to take this change in coal condition into consideration when developing a spontaneous combustion management plan.

Jan 1, 2005

By D. Bigby

The current British Standard on rock reinforcement components used in coal mining (BS7861:1996) employs the axial double embedment tensile PET) test to determine the main system load transfer performance criteria, in terms of bond strength and stiffbess. This test involves measurement of load/displacement characteristics of a tendon fully grouted into internally threaded thick-walled steel tubes. Part 1 of the Standard covers rock bolting systems and Part 2 covers birdcaged cable bolting systems. Both parts are highly prescriptive, defining a specific design of bar (AT) and cable bolt (birdcaged). In 2000, it was agreed by the UK Rockbolt Research Liaison Committee that Part 1 of the Standard should be revised to allow further industry innovation of bolts and resins. Amongst other aspects, it was recognised that the double embedment test was limited by its inability to examine load transfer between the bolt and the host rock and the UK Health and Safety Executive commissioned an RMT research project to develop a new test to replace the DET test. The new test, the Laboratory Short Encapsulation Pull (LSEP) test has now been incorporated into a draft revision of BS7861 Part1 which has been issued for industry wide consultation. In 2003, it was agreed to begin revision of Part 2 of the Standard to encompass the many types of long tendon reinforcement which were, by then, being used in the UK coal mining industry. These included flexible bolts, deformed strands and tensionable systems encapsulated with resin, cementitious grout and combinations of the two. A second RMT research project was funded by the HSE to examine adapting the Laboratory Short Encapsulation Pull Test for the revised long tendon Standard. This project is nearing completion and a revised Part 2 of the Standard is being drafted. This paper presents some of the results of the two research projects, describes the laboratory tests and acceptance criteria developed and discusses the implications of the research on improving the understanding of reinforcement performance and its characterisation. In particular it shows how the new test can reveal very different load transfer characteristics to the double embedment test, as it takes the load transfer at the holefrock wall into account.

Jan 1, 2005

By A. Karadogan, G. Tuncer, A. Kahriman

Determination of optimal blast parameters have been the priority act for blasters on the field due to financial and technical properties of the operation. Therefore many researchs were done to establish a general formula for many years. These intends could reach some empirical and numerical design frames consisting the rock, geology and explosives properties. Blasting parameters have to be adjusted according to the desired fragmentation rate especially on the mines where particle size distrubition after blasting has a great importance. Therefore the blast designs have to be evaluated considering the particle size distribution after the blasts. The Kuz-Ram model which was modified by Cunningham is one of the tools for estimating the particle size. Although it doesn’t give an accurate result, it can be very succesful on modifying the blasting design parameters by establishing a back correlation between the blasting parameters and the exact particle size distribution results which can be easily achieved by digital image processing system. Within the scope of this study, the particle size distribution after blasting was assessed by Split-Desktop digital image processing system and bench blasting parameters were studied considering the desired particle size distribution at Espey colemanite mine using Kuz-Ram and digital image processing system combination to determine the specific blasting parameters for this site.

Jan 1, 2005

By S. Krukowski

Iodine is a bluish-black, crystalline solid with sub-metallic luster, and has a specific gravity of 4.93. It volatilizes (sublimates) at ordinary temperatures into a blue-violet gas that has an irritating odor. Iodine is the least active of the halogens, all of which readily displace it. Only slightly soluble in water, iodine also dissolves in carbon disulfide, carbon tetrachloride and chloroform, giving a deep violet solution. The primary sources for iodine production are sub-surface brines associated with petroleum and natural gas deposits, and as a byproduct from nitrate deposits in Chilean desert caliche. The largest source of iodine is seawater which contains 0.05 ppm, or about 31 Mt (34 million st). Seaweed of the family Laminaria can extract and accumulate up to 0.45 percent iodine on a dry basis. Seaweed was an important source of iodine prior to 1959. However, it remains a significant source of iodine in the diets of many populations throughout the world.

Jan 1, 2005

By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

Computer modelling is being used to simulate rock fracture, caving and stress redistribution about longwall panels with increasing confidence. The models are being assessed against field monitoring and have significantly increased the understanding of caving mechanics within the overburden. This paper discusses the modelling approach and provides some examples of its application to overburden damage and induced hydraulic conductivity. Computer models used in this study simulate the fracture process in the geological units throughout the overburden. Analysis of the mining induced fracture patterns and in situ joint patterns allows an estimation of the hydraulic conductivity within the overburden. The cubic flow relationship has been used in the examples presented.

Jan 1, 2005

By D. Bois, P. Poirier, B. Bussière

Environmental desulphurization is an attractive alternative for the management of acid generating tailings. Bulk sulphide flotation is the most commonly used method to produce desulphurized tailings, as shown from many previous works. This process can reduce the volume of problematic tailings to manage by making a sulphide fraction concentrate. The desulphurized tailings can then be used as construction material for an engineered cover to prevent acid mine drainage. In this paper, the results from different laboratory and pilot scale flotation tests are presented. These results confirm that low sulphide non-acid generating tailings can be produced by froth flotation. It is also demonstrated that sulphide concentrates obtained from desulphurization mixed with the appropriate binders can be used as feed material for paste backfill. From previous work on the evaluation of operating and capital costs of the desulphurization process for different ore types, the use of desulphurization as a tailings management approach was studied for several scenarios. The desulphurization process was then compared with other technologies (underwater disposal, engineered soil cover) currently used to prevent acidic drainage (AD) for a new mining operation. Results show that partial or total desulphurization are technically and economically viable options to manage tailings during mine operation. Mine waste managers should consider desulphurization as an efficient technology.

Jan 1, 2005

Advanced high temperature electrochemical systems such as fuel cells, electrolyzers and ionic transport membranes are currently being developed for a wide variety of energy conversion, storage and gas cleanup applications. These systems offer high electrical efficiency, multi fuel capability, modular construction, no/negligible emissions (SOx, NOx, VOC, particulate matters) with capability to sequester green house gas emissions (GHG). Electrochemical processes and electrode reactions will be discussed. Cell and stack component materials and fabrication processes will be presented. Bulk, surface and interface degradation processes responsible for cell and stack performance degradation will be examined.

Jan 1, 2005