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By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By S. Solar, G. Tiess, K. Nielsen, H. Wagner

The paper summarises the results of a recent study of minerals planning policies of the Member States of the EU. The study has shown that contrary to the public opinion the production of industrial minerals and construction minerals is significant the former accounting for about 20 percent of global production, the latter amounting to about 3 billion tonnes per annum. In contrast the importance of metal ores has diminished although metal production in some European countries can still be significant. The study revealed that very few Member States have clearly defined mineral policies. Common to most mineral policies is the emphasis on reducing minerals consumption and recycling whereas the important aspect protecting access to minerals resources is not adequately addressed by most policies. Access to mineral deposits is regulated in most Member States by land use legislation and administration. Information on mineral deposits in land use planning data bases tends to be scarce. This together with the absence of formal mineral policies places minerals at a disadvantage in land use decision making. The emergence in the recent past of environmental legislation and in particular environmental impact assessments has had a crucial effect on the duration of the authorization process for new mineral projects. Examples are given how minerals planning is handled in some of the Member States.

Jan 1, 2005

By AN. Kumar

Two fabrication stages in the manufacture of pipelines are identified as causing significant deterioration of the steel plates, namely cold bending and welding. The objectives of this work include quantitative assessment of the degradation of the quality of the steel plate by the loss of fracture toughness, and an estimation of the safe working pressure. The study was conducted on three API grade steels: X42, X46 and X60. After cold bending by the UO technique, various welding technique were employed for joining of the bend plates along the pipe length. A crack-tip opening displacement parameter (CTOD) was used at the onset of initiation and at the first load maxima as the criterion for assessing the toughness degradation under various fabrication stages and regime (such as WZ, HAZ and parent body). In addition, strength, hardness and impact energy values were determined to check the degree of degradation. Microstructural and microfractographic investigation of the fractured samples were also carried out in the scanning electron microscope (SEM). X60 grade steel plate suffers from CTOD toughness loss by around 38 and 55% after welding and cold bending, respectively, for the conditions studied. A combined effect of the two stages results in a loss in toughness by around 70% for the same steel. In X42 grade, the loss in impact energy ranges from 78 to 35 J due to electrical-resistance welding study (ERW). Crack resistance curves are also obtained for the steels to study the crack growth resistance behaviour and to supplement the information on crack initiation behaviour. The orientation of the pearlite banding, as observed on the fracture plane with respect to notch front and applied loading direction appears to have a strong influence on the microvoid-coalescence mechanism of fracture as well as the toughness values. An integrated analysis of the performance of pipelines, considering all these key factors, is discussed.

Jan 1, 2005

By Xiang-yang Zhou

Keywords: Low-Grade Dolomite, Low CaO Content, High Specific Surface Area, MgO. A low energy consumption preparation technology of magnesium oxide with low calcium oxide content and high specific surface area from low-grade dolomite has been investigated. The optimum technical conditions for the preparation of magnesium oxide are the followings: dolomite is partially calcined at 750-800° for 2 h; the optimum solid-liquid ratio range in calcined dolomite slurry is 20-30 g?l?1; carbonation temperature, carbon dioxide pressure and end point pH value of carbonation are less than 40°, 0.4-0.6 MPa and 7 respectively during carbonation process; decomposition temperature of Mg(HCO3)2 solution is near 100°; calcination temperature of the precursor (i.e. precipitated basic magnesium carbonate) is less than 850°. More than 90% of magnesium can be extracted by the technology. The MgO product (CaO < 0.38%) with a specific surface area of near 50 m2?g?1 also can be obtained by the technology.

Jan 1, 2005

By R. Krentz, P. D. Cordingley

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Major changes to the refining process were required when the Moa sulphide feed, with its unusually high cobalt content, was introduced in the early 1990&apos;s. In the period 1994 to 2005 the production capacity of the refinery has increased dramatically to match increases at Moa, and significant process improvements incorporated. The process flowsheet consists of the original ammonia leach process, optimized for cobalt chemistry and overall leaching capacity. Extraction of metal values is followed by the unique nickel-cobalt separation technology, in which most of the cobalt is separated from the ammoniacal nickel sulphate leach solution by precipitation as a nickel-cobalt hexammine salt. This salt is refined from a Co:Ni ratio of 1:1 to over 10,000:1 by selectively leaching nickel, redissolution and recrystallization in ammonium sulphate solution. Nickel and cobalt are recovered using the well-known Sherritt hydrogen reduction technology. This paper reviews the chemistry described above, examines some of the changes in operating conditions made over the years and highlights some of the recent physical changes made to the refinery.

Jan 1, 2005

By Janice Reed

The first seismograph was developed around 132 AD. Much has happened since then. The “modern” seismograph (> 1920) has seen a lot of changes. From falling pin seismographs to magnetic tape units to today’s Z-curve analysis models, the blasting seismograph remains a necessary and useful tool to the blasting community. But why so many changes? What forces drive the advancement of the seismograph? There are many answers and aspects to this question. Research, regulation, and technological advances are the primary forces behind innovation in our industry. But these three forces also drive each other. Research drove our industry from displacement seismographs to particle velocity seismographs. Technology took us from 80 pound seismographs to units weighing less than 5 pounds. Regulation (and litigation) - the driving forces behind the Z-curve analysis units. How have these innovations helped today’s blaster? Have there been any negatives? It is important for today’s blaster to understand how we got here and why.

Jan 1, 2005

By Leslie C. Taylor, Anthony L. Kee

Computational modeling of explosively loaded saturated sand on a suspended plate is an inherently complex problem. In this study a computational method is used to predict the dynamic pressure load/impulse from a buried charge. A fully coupled code modeling the explosive charge, sand and air with a Eulerian mesh and the plate structure with Lagrange elements, such as Gemini-Dyna, is an appropriate computational tool. In water-saturated sand, the loadings are soil and water-transmitted shock and bubble or blast effects depending on the depth and the charge size. The computations provide the capability to determine the total impulse load placed on a horizontal plate on or above the soil due to an explosion in the saturated sand for different burial depths in saturated sand and different plate stand off distances. The following test case will be presented: (a) 4.5 Kg (10 lbs) TNT, 10.16 cm (4 in) depth of burial to top of charge, and 20.32 cm (8 inch) stand off distance (Test 4).

Jan 1, 2005

By Bruno Bussière, Michel Aubertin, Anne-Marie Dagenais, Johanne Cyr

A five steps remediation program was commissioned in 1998 for the acid generating Lorraine mine site, located in the Témiscamingue region, Quebec, Canada. It included, as the main expenditure, a cover with capillary barrier effects (CCBE) used to limit oxygen migration. After construction of the cover, instruments were installed on site to monitor the CCBE performance. Modified oxygen consumption tests were also done to measure the oxygen flux through the cover. Results from water content and suction data, measured from 1999 to 2003, show that the capillary barriers effects are effective and that the water retention layer stays near saturation throughout the years. Oxygen fluxes estimated from monthly water content measures are generally below 10 g/m2/year. Results from modified oxygen consumption tests made on the site give almost similar oxygen fluxes. A two dimension numerical model of the Lorraine mine site was also constructed to verify that mathematical models could predict realistically the in situ conditions on such a large scale site. Numerical results obtained for three years show a good concordance between measured and calculated values. The results obtained form these different evaluation methods for the performance of a CCBE concur and confirm the efficiency of this cover in limiting acid mine generation.

Jan 1, 2005

By Augustine O. Orumwense

Ball mills are commonly used for regrinding operations in the mineral processing industry. But, in recent times, efforts are being made at the introduction of stirred mills particularly for those instances where very fine grinding is required. Media type (steel shot, glass beads, alumina balls and crushed quartz), media size, mill speed and the number of passes required to obtained the target product size are studied. The product size and energy consumption are used in the evaluation of the test results. The grinding media size, shape, density, filling ratio, mill circumferential speed and grinding time play a distinct role in product size fineness.

Jan 1, 2005

Strips of AA6111 automotive alloy were cast on a horizontal single belt strip casting simulator, Pure copper and carbon steels substrates plasma sprayed with different coatings for improving the strip surface quality, were used as chill moulds, Experimental studies revealed that a graphite coating provided the greatest benefit in achieving good surface quality. The interfacial heat fluxes during solidification of AA6111 strip were calculated by the IHCP method (Inverse Heat Conduction Problem). Temperature variations and cooling rates within the strips were then calculated through numerical simulations based on the time-dependent heat fluxes obtained by IHCP, The effects of casting parameters, including casting temperature and strip thickness, on interfacial heat fluxes, cooling rates and microstructures, were investigated, Although the maximum interfacial heat fluxes on the chill copper substrate were much higher than the results obtained from the steel substrates, the solidification times of the melts were mainly determined by strip thickness. Very fine equi-axed grains were obtained for both 1.2mm and 2.5mm thick strips thanks to the rapid extraction of heat, and effective grain refinement.

Jan 1, 2005

By W. Basuki, B. Setyotomo, L. Hakim, R. Hendrajaya

Due to high crack sensitivity of slab product of gas and oil line pipe application, its steel making process and alloy composition were evaluated and then improved to overcome its critical solidification process and reduced surface defects. The study was conducted at Slab Steel Plant Krakatau Steel. The purpose was to improve slab surface quality by reducing surface defects so that the slab surface doesn&apos;t need to be totally repaired. The method applied was by performing plant trial process, which the secondary process parameters such as alloying method and the casting parameters such as casting powder selection, metallurgical cooling, mould level control, and superheat were continuously monitored and then adjusted to the surface quality of the product. Based on the calculation of Ferrite potential of the steel, the chemical composition was designed to achieve optimum casting parameters in order to avoid high shrinkage during solidification. The results of the study are decreased surface defect quantity, and smooth casting process. The quantity of crack decreased by almost 90%. The slab surface repairing was significantly reduced from 85. % to less than 10%. These new casting parameters and developed alloy composition are then used and standardized for the mass production of the steel.

Jan 1, 2005

By Adrian J. Moore, Alan B. Richards

Airblast overpressure levels can commonly be increased by up to 20 decibels (dBL) by the effects of meteorology, due to inversions and wind shear. Existing atmospheric refraction models can provide a good evaluation of the effects of meteorology, but have been limited in the accuracy of their outputs by the accuracy of the meteorological data that is available for input. This paper uses case histories from open-pit coal mine blasting in the Hunter Valley area of Australia to provide examples of increases in airblast due to inversions, wind shear, and a combination of both. It gives details of our experience of the accuracy with which predictions and assessments can be made using meteorological data of various levels of accuracy, and on the design buffer that is required to prevent the exceedence of airblast limits. The accuracy of meteorological prediction and assessment will shortly be improved by the use of sounding equipment that gives continuous measurements of temperature and wind velocity at significant levels above the ground. The paper also gives details of an industry funded research project that aims to permit the effective use of this data at distances many kilometres (km) (miles) from the location of the sounding equipment, and to develop a short term predictive model that will permit the amount of meteorological reinforcement that will occur at firing time to be determined before a decision is made to tie up a shot.

Jan 1, 2005

By J R. Hernandez-Aguilar, C O. Go, C Acuna

The gas dispersion properties that are the subjects of this communication include three measured parameters, gas superficial velocity (gas rate), gas holdup and bubble size, plus derived parameter, bubble surface area flux. Over the past ten years sensors to measure these parameters have been introduced and those originating from McGill University are briefly described. The sensors have seen extensive use in plant campaigns and experiences on four cell types at three sites are discussed. The impact of frother in controlling bubble size by retarding coalescence is illustrated, introducing the need to understand chemistry/machine interactions in interpreting gas dispersion results. An increase in Sauter mean bubble size (D32) with superficial gas velocity (gas rate, Jg) was found, which followed the empirical relationship where Do ~ 0.5 - 0.6 mm and C and n are fitted parameters dependent on the system (machine and chemistry). Following this trend in Db - Jg, consistent bubble surface area flux (Sb) - Jg trends are also observed. The trend in Sauter mean versus number mean (D10) is used to help interpret the nature of the distribution; as the means approach numerically, the distribution is narrowing. Analysing gas holdup versus gas rate shows both a dependence on location in the cell as well as cell position in a bank, factors which must be accounted for when comparing data from different plants and circuits. The instrumentation and methodologies being developed are presenting new opportunities for incorporating cell hydrodynamics into metallurgical diagnostics. A case study at one plant serves as illustration.

Jan 1, 2005

By C J. Larder, S E. Turner

The concept of underground grinding is not new, but to a metallurgist and a mining engineer this could be considered unconventional. The idea of pumping a ground slurry several hundred metres from underground in a single lift could also be considered to present a daunting engineering challenge. Using a practical example of a mine in Australia where the owners have requested not to be identified, this paper challenges the conventional thoughts on these concepts and shows that with basic sound engineering practices the production of a ground slurry from underground could potentially provide significant operating cost savings. The supply of ore from the underground mine is currently drawn from depths approaching 800 m below the surface. The cost of hauling the ore to the existing underground crushing station located 500 m below surface has been steadily increasing. A number of alternatives to reduce the mining and processing unit operating costs were examined by Sinclair Knight Merz (SKM) and the mining company. The most radical of these is the use of hydraulic hoisting of ore at an increased production rate. Numerous questions were asked, such as: How does one get a SAG mill or an HPGR crusher underground? Where does one locate a grinding mill underground? Does the technology exist to pump the slurry to surface in a single lift? What will be the cost benefits? What are the risks involved? The study covered the two main technical issues underlying the potential benefits. Firstly, technical evaluations were undertaken on the pumping technology currently available for single and multiple lifts to surface. Secondly, the issues relating to the feasibility of delivering and locating a SAG mill underground were reviewed. Although the capital costs for this project are significant, the operating cost savings showed a potential payback period of less than two years, and furthermore provide the basis for an increased mine life, especially at lower metal prices.

Jan 1, 2005

By R Verreet

In April 2000 Mount Isa Mines installed hoist ropes of a new design on the double-drum winder at their P49 shaft. The ropes, CASAR Duroplast, were about three times as expensive as the previously used triangular strand ropes. The P49 shaft is situated at Mount Isa MinesÆ George Fisher Mine, located some 30 km north of Mt Isa. This shaft used the tried and proven 6 x 33 triangular strand style ropes. The rope life attained by these ropes at the time was acceptable due to many years of satisfactory performance. The following study indicates the improvement of service life using CASAR Duroplast rope in P 49 shaft, which depends on shaft and winder parameters of that particular shaft and cannot necessarily be generalised to other shafts.

Jan 1, 2005

By J L. Mauk

&nbsp;Broken Hills is an adularia-sericite epithermal Au-Ag deposit, hosted in flow-banded rhyolites and overlying rhyolitic pyroclastic rocks in the eastern Hauraki Goldfield. The 7.1 Ma deposit was the largest producer of gold in the eastern Hauraki Goldfield, and was one of very few economic deposits hosted in Pliocene rhyolites. This paper presents the results of a recent study in the upper levels of the deposit. Maps and cross-sections constrain structural and lithological relationships, and the lateral and vertical extent of a breccia pipe û the major feature of the upper levels. &nbsp; Previous studies in the upper levels of Broken Hills have shown that gold and silver values are concentrated around and within a large breccia pipe, mined by a series of æcaveÆ stopes and in veins. Contour diagrams of Au-Ag data from channel samples indicate that the breccia pipe was a major fluid channel-way for mineralising solutions. &nbsp; The breccia pipe deposits are part of the dynamic geothermal system that formed the Broken Hills ore bodies; they developed as a result of hydrothermal brecciation in areas of structural weakness within a rhyolite pyroclastic unit that overlies a massive rhyolite lava-flow unit. The main breccia pipe begins near the rhyolite/pyroclastic contact, having the shape of an inverted, inclined cone, and consists of silicified breccia, stringers of quartz, and irregular patches of clay-altered country rock. Smaller zones or pockets of hydrothermal eruption breccia are silicified and contain low grade gold in the matrix and in the adjacent silicified wall rocks. &nbsp; Quartz has been classified according to its physical characteristics as seen in situ and hand specimens indicate that vein definition decreases upwards, perhaps as a result of changing lithological conditions and/or increasing proximity to the paleosurface. Hydrothermal quartz is widespread as veins and as a replacement mineral, or lining fractures and cavities and overgrowing rock fragments. Breccias contain vein quartz, but some quartz veins cross-cut breccias, indicating that vein and breccia formation was relatively synchronous and overlapped in time. &nbsp; Disseminated gold-silver mineralisation is associated with vein quartz and silicic alteration of the wall rock within the breccia pipe. The auriferous zones are highly irregular and erratic, and sampling results show a wide range of gold-silver ratios, suggesting that highly volatile physiochemical conditions prevailed during mineralisation.

Jan 1, 2005

By G. T. Lapidus, R. M. Luna-Sánchez

In the present study, a series of cyanidation experiments were performed on a bulk sulfide concentrate which contained silver in four distinct phases, to determine its extraction rate, varying the oxygen concentration. The results showed that three of the four phases were refractory, aguilarite (Ag,iSeS) being the only leachable phase, and that the effect of the oxidant concentration is minimal. Mathematical simulations were performed, adjusting only the Damkohler number to adequately fit the experimental data. This model, and the mechanism implied, was compared with that found for acanthite (Ag2S) in a previous study, and the differences between the two discussed.

Jan 1, 2005

By R. L. Eadie, J. L. Luo

The effect of plastic deformation on near-neutral pH stress corrosion cracking (SCC) also known as environmentally assisted cracking was studied by cracking rate measurements. All the tests were conducted in a synthetic near-neutral pH solution. The traditional potential drop tests using compact toughness (C-T) specimens with 2-3 mm long pre-cracks showed varying plastic deformation by rolling would increase the material&apos;s susceptibility to SCC. This was confirmed by cyclic loading tests using double notched flat tensile specimens with 200-300 µm long pre-cracks which gave the same results that the specimen with large scale plastic deformation by tensile loading had a relatively faster crack growth rate than that with only small scale plastic deformation.

Jan 1, 2005

By Charles Merguerian

In medium- to high-grade metamorphic terrains such as found in New York City(NYC), rock mass texture and mineralogy are important factors in predicting TBM penetration destiny. Integration of data from over two decades of traditional field and tunnel mapping suggest that hard-rock TBM penetration in the NYC area depends upon textural, mineralogic, and structural control. The bedrock of NYC consists of many different lithologic units of varying age, composition, texture, and metamorphic grade including many varieties of intrusive rock. In addition, brittle faults of numerous orientations cut the polydeformed crystalline bedrock, producing zones of highly fractured and disturbed ground and high water inflows. Pre-bid compilation of published bedrock data, drill core analysis by geologists to establish lithologic and mineralogic trends, integrated surface geologic mapping along a proposed alignment, and targeted petrographic and geotechnical investigations to characterize the rock mass conditions together constitute an important prelude to successful subsurface bidding and tunneling. A carefully planned program of as-built geological mapping, structural analysis, fracture class mapping, and monitoring of machine performance data provide important information for adjusting to changed conditions. In complex terrains, a clear understanding of the structural geology of any proposed tunnel line is the simplest and most cost-effective method to mitigate losses encountered during TBM tunneling.

Jan 1, 2005

This paper describes a steam outburst in a metal mine which occurred in December 1992 in Japan, resulting in two fatalities. The outburst occurred just after blasting in a heading face 600 m below surface (SL-50 m), 1664 m from a mouth of the mine. The scale of the outburst was large and the fragments of the outburst spread up to 34 m from the face, the total volume of the outburst was estimated to be 206 m3. The outburst materials were mostly clay originated from the typical surrounding rock of sulfide ore and basalt. The shape of the larger outburst fragments were slabs with a thickness of 10 to 20 cm. The victims were found in a main ventilation air shaft, 175 m and 380 m from the face, respectively. The mine mainly produces copper, lead and zinc. The face was ventilated by a 560 mm diameter duct with a fan and the strata temperature of the rock was estimated to be in the range of 120 to 140¦C. There is a famous hot spring near the mine. A thorough investigation into the unprecedented accident was made including an on-site inspection and investigation of rock characteristics in laboratories.

Jan 1, 2005