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By Wen-Ming Chien

Keywords: AN-KN Phase Transition, Lattice Parameters of AN-KN, X-ray Diffraction The lattice parameters of the low and high temperature phase of KNO3-rich (in NH4NO3) solid solutions have been determined by the X-ray diffraction method. The low temperature single KNO3 phase (KN II) are from 92%-100% KNO3 in NH4NO3 composition range and from room temperature to 393 K showing in X-ray diffraction patterns. The high temperature KNO3 phase (KN I) showed very broad composition range between 20% to 100% KNO3. The lattice parameters of KNO3-rich (KN II and KN I) solid solutions have been calculated at different temperature range. The volumes of orthorhombic KN II phase decrease from 0.3208(3) to 0.3195(3) nm³ at the room temperature as the compositions increase from 95% to 100% KNO3. The lattice constants of the hexagonal KN I phase show that there is no significant change in a-direction when the temperature increases. Details X-ray results and lattice expansion equations during heating will be presented.

Jan 1, 2005

By T. MacKinnon, M. C. Bétournay, D. Eastick, F. C. Delabbio, C. Graves

"The successful implementation of a new technology in an underground production mine requires many challenges to be overcome. These challenges include mine hardening of new technology, mitigation of safety risks and hazards, mine operation support, and technology transfer to mine staff. In the end, the majority of these challenges relate to the human aspects of implementation. The approach selected to overcome these challenges must be customized and appropriate for each unique situation.This paper outlines the approach used to address these challenges as part of successful implementation and resulting demonstration of the hydrogen fuel cell locomotive at the Placer Dome (CLA) Limited Campbell Mine. This technology demonstration at Campbell Mine is critical for determining technical, regulatory, and implementation aspects to be incorporated into future fuel cell prototypes such as the LHD project."

Jan 1, 2005

By David D. DiPonio, John DiPonio, Roger Van Omen

The greatest opportunity to attain the most favorable prices for underground construction projects occurs during the competitive bidding period. The Owner, Engineer, and Contractor need to have a thorough understanding of the project’s design concept, how it is going to be built, and what it is going to cost. This paper presents the opinions of three engineering professionals who are well established in their sectors of heavy civil underground public works construction. This paper will outline and summarize the considerations that the three principal contracting parties of Owner, Engineer, and Contractor need to make to obtain good price quotes at the time of bids.

Jan 1, 2005

By P. A. Plunkert, D. E. Morse, L. McCartan, J. F. Papp

The mineral sector is a fundamental part of the U.S. economy. It contributes to the real gross domestic product (GDP) at several levels — basic (mining), intermediate processing, manufacturing of finished goods and construction. The real GDP during 2004 increased by 4.4 percent. The nominal GDP was about $11.7 trillion. Housing starts were up by slightly more than 4 percent for the year. And the nation’s unemployment rate decreased to5.5 percent in 2004 from 6 percent in 2003. Interest rates continued to be low (prime rate was 5.25 percent at the end of 2004) but have risen gradually, following rising inflation.

Jan 1, 2005

By Robert S. Thomas, Bernard M. Tarralle, Nasser Massoudi

"The Commonwealth of Virginia is restoring and expanding its Capitol of great historic significance. Designed by Thomas Jefferson in 1785, it is the second oldest Capitol building in the United States. The building expansion required excavations immediately adjacent to its South Portico. The building, which rests on shallow brick footings, is very sensitive to any disturbance caused by construction and excavation. A comprehensive and secure plan of operations was devised by the design team to ensure that this national monument remains unharmed by the new construction. Various construction techniques were implemented to satisfy the strict movement goal of 0.25 inch and distortion of U2000. They consisted of jet grout columns to stabilize the upper soils, compensation grouting for future foundation leveling, a tied-back reinforced concrete diaphragm wall for excavation retention and foundations, and realtime instrumentation for monitoring. This paper describes the design approach for the retention system, providing information on the various construction phases and techn iques, and reports on the movements recorded by the real-time monitoring system during the course of the project. At the time of this manuscript preparation, and the deep excavation complete to final grade, the results indicate that the extremely restrictive building movement criteria have been met. The success can be credited to detailed design, close cooperation among the project team, prudent construction methods, and real-time monitoring. INTRODUCTIONThe Commonwealth of Virginia is undertaking a comprehensive renovation and expansion of the Virginia Capitol building located in Richmond, Virginia. The Capitol building was designed by Thomas Jefferson in 1785, with construction of the original building starting the same year. The Capitol building was designated a National Historic Landmark in 1960 and was listed on the National Register of Historic Places in 1966.A part of the comprehensive renovation and expansion of the Capitol is a 25,000-square foot, two-level subterranean extension on the south side of the Capitol building, which will serve as a new Visitor Center and public entrance for the Capitol. Deep excavations were required for the construction of the new Visitor Center. The excavation required a permanent retention system to accommodate an approximately 40- foot deep excavation."

Jan 1, 2005

By J. A. Ober

China, Mexico, Spain and Turkey are the leading producers of celestite (strontium sulfate), the most common strontium mineral. Of an estimated 510 kt (562,000 st) of celestite produced worldwide during 2004, 98 percent was produced in those countries. Deposits of strontianite (strontium carbonate), another strontium mineral, have been identified in China and Malawi. Relatively small quantities are reported from the deposit in China. Although celestite deposits occur in the United States, no domestic celestite has been mined since 1959.

Jan 1, 2005

Operating CIP/CIL gold recovery plants in the arid regions of Western Australia face unique challenges due to water and ore quality issues. The presence of cations of Mg, Fe and Cu metals in water supplies and leached sulphide ores can have considerable effect on plant consumption of lime and cyanide, due to pH buffering and complexation effects. Reagent costs are critical to many of these operations. In this paper, computational modelling is used to analyse a number of process options to mitigate such issues. This requires careful consideration of the chemistry of the process system, and the ability to predict accurately the response of speciation and precipitation reactions to changing process conditions. The Mg-Fe-Cu-CN-H20 system is specifically modelled in this application. The Gibbs Free Energy Minimisation thermodynamic framework has been selected to model equilibrium phenomena. Furthermore, this approach has been extended to the process flowsheet level, incorporating multiple unit operations and recycle streams in a steady-state mass balance model. The Gibbs equilibrium composition module of HSC Chemistry software has been successfully integrated into the commercial flowsheeting package SysCAD. Consideration of the Gibbs Energy Minimisation capabilities of other flowsheeting packages has also been given. This approach has been successful in simulating the aqueous process chemistry typical of such plants. It has resulted in a predictive capability where equilibrium states respond appropriately to process changes. Potential cost savings may be identified by examining alternative process conditions to minimise overall reagent consumption.This methodology may be extended to other hydrometallurgical plants where issues of solution ideality, temperature and other equilibrium processes are sufficiently understood.

Jan 1, 2005

By Mary Ann Bennett, Val Nichols, Colleen Proctor

"In 1997 when Royal Oak Mines Inc. went into receivership, the mineral processing technicians (mill operators) who had been working at Giant Mine in Yellowknife, Northwest Territories for most of their career walked out with no credentials to serve as testimony of their knowledge and skills.As a result of new diamond mining activity and the establishment of socio-economic agreements, mining industry representatives approached the Department of Education, Culture and Employment (ECE), Government of the Northwest Territories, in 1999. They requested support and direction to promote training and recognition for mineral processing technicians at BHP’s (BHP Diamonds Inc.) Ekati mine. ECE recommended the development of occupational standards and certification.This paper describes the development process and end products that resulted from this collaborative project between industry, government and education. In addition, industry representatives involved in the project share their views on the development process and the benefits of standards and certification.The conclusion invites industry members to support national occupational standards and certification with their associated benefits: standardized training in the workplace and institutions, proof of competence for hiring, recognition of prior learning, and a nationally and internationally recognized credential.INTRODUCTIONSwiftly changing labour market demands are nothing new in the North. The fur trade and mineral discoveries have brought employment to workers in a feast and famine cycle for decades. In the late 1990s, the Giant, Con, Lupin, Polaris and Nanasivik mines were nearing the end of productive runs. Many experienced workers found that without credentials, they had no proof of their abilities to offer prospective employers."

Jan 1, 2005

By L R. Marshall, M J. Rubenach, T G. Blenkinsop, J S. Cleverley

The source and transport regions of fluidised (transported) breccias outcrop in the Cloncurry Fe-oxide-Cu-Au district, providing insights into the origins of other fluidised magmatic-hydrothermal breccias such as kimberlites. Discordant dikes and pipes with rounded clasts of metasedimentary calc-silicate rocks and minor felsic and mafic intrusions extend several kilometres upwards and outwards from the contact aureole of the 1530 Ma Williams Batholith into overlying schists and amphibolites. The brecciation initiated at depths >10 km and may have resulted in surface breaching. We used analytical equations for particle transport to estimate clast velocities (eÆ 20 ms-1), approaching volcanic ejecta rates (up to 80 ms-1). The wide range of CO2 fluid inclusion densities (up to 150 MPa), the localisation of the base of the breccias in contact aureoles, and the scale and discordancy of the bodies suggests the breccia transport process was triggered by an abrupt release of overpressured fluid. At these depths, such extreme behaviour may have been achieved by release of dissolved fluids from crystallising magma, in combination with a strongly fractured and fluid-laden source, sitting under a strong, low permeability barrier, and such parameters may be analogous to the asthenosphere/lithosphere boundary in the case of kimberlite initiation. The relationship of these breccias to the Ernest Henry iron-oxide-Cu-Au deposit suggests they may have been either fertile or æfailedÆ orebody feeders.

Jan 1, 2005

By Q Liu

Open stoping is one of the widely adopted methods in underground bulk mining. In this method, fanned or parallel holes are often drilled from a top sill down to a sublevel in the ore zone and blasted ring by ring into a stope for excavation. A mass stope blast may involve blasting rock from multi-level drift rounds and displacing the muck to specific locations in order to allow safe and easy access for ore removal. This paper presents a strategic mass stope blast that took place at a large lead and zinc underground mine in eastern Canada. The blast consisted of more than 800 holes drilled in six blocks from three different sublevels. The challenge lay in the control of ground vibration and muck movement using precise timing to complete the blasting within 6.5 seconds. During this time span, sufficient voids were created in each level to allow the muck to move from the upper to the lower levels in sequential order across the six mining blocks without bridging. This paper describes stope blast simulations using a discrete element computer code for modeling blast-induced rock displacement as well as the application of electronic detonators. These detonators provided the means to accomplish the desired firing sequence including a drop raise blast at the start of the mass blast. The modelling concept is also described in the paper.

Jan 1, 2005

Coal mining legislation makes frequent reference to æSafety Management SystemsÆ but there is a chronic shortage of useful guidance material as to how these might be applied to hazardous exposures. Several studies have indicated that for each death that is reported as a result of an industrial æaccidentÆ, there are five deaths that caused by occupational exposures. Because the deaths from occupational exposures do not occur on site and often well after employment has ceased, they are generally unreported. Improved access to mortality data from coroners, the Australian Institute of Health and Welfare and superannuation service providers (early claims from death and total permanent disability), has given rise to some analysis of death and disability data that provides evidence that there are emerging opportunities to develop and improve safety management systems for hazardous occupational exposures. Issues explored include how safety management systems might be developed in relation to dusts and chemicals and other hazardous exposures to ensure the risk of disorders with long latency periods are reliably assessed and the exposures effectively managed. The current standards and guidelines which refer to safety management systems in general or to management of exposure related hazards are examined. Many standards are based on dose-response studies that provide for an acceptable percentage of workers to suffer adverse health outcomes. An alternative management system might be to apply dose-response relations to health surveillance to identify æat riskÆ individuals and effectively manage health and related safety risk at an early stage.

Jan 1, 2005

Conditional simulation can be used to determine the probabilities of block iron-grades being above selected cut-offs. However, there are much faster alternatives that can produce acceptable results. In this paper blasthole data from a selected area of Joffre Member hosted ore of the Brockman Iron Formation at the Mt Whaleback orebody is used as the basis of a case study to assess alternatives to simulation. Iron grade, in per cent, is interpolated from a blasthole dataset into a block model using ordinary kriging. Samples are then removed from this blasthole dataset to produce data subsets. A complete distribution of iron grades for points or blocks is obtained utilising the data subsets and the following techniques: conditional simulation, median indicator kriging, the probability from conditional expectation and confidence intervals attached to the estimation of blocks in the framework of the discrete Gaussian model. The complete blasthole dataset is considered to represent the true iron grades at sample point support while the ordinary kriging estimate derived from these samples is considered to represent the true block grades. The distributions obtained from point estimates, block estimates and simulations are compared to each other and to the true estimates of iron grades using graphs and statistics. The conditional expectation technique reproduced the results obtained from conditional simulation extremely well and it is a viable alternative to simulation at point support. At block support the confidence intervals technique reproduced the results of the conditional simulation more closely than the median indicator kriging and in the data subsets tested the confidence intervals technique actually reproduced the true grade distribution more closely than the conditional simulation.

Jan 1, 2005

Mining ventures are essentially risky businesses. Explorers and project developers (plus their investors and financiers) attempt to minimise the risks involved or at least manage them. Core considerations are the obvious technical and commercial risks, but the socio-political system and regulatory environment in which the project will operate can be more important. Successful mineral investments in a country depend upon obtaining realistic and reliable technical results in a country that provides certainty, to gain and maintain investor confidence in a project. Brief commentary is provided on the usefulness of professional accreditation and ethics plus other specific reporting codes (eg JORC/VALMIN Codes) in reducing risks by reinforcing high technical competence and reputable individual professional behaviour (particularly in the context of currently perceived high corruption levels in so many countries). These various risk components are reviewed, especially in a global context, to showcase New ZealandÆs current position. Successful projects are those which provide investors with credible and reliable optimal results in less volatile environments because investors/lenders hate uncertainty and surprises even more.

Jan 1, 2005

By J L. Mauk

The Sovereign, Jubilee, Scotia and Jasper Creek prospects occur in an area of ~3.0 km by 2.5 km (~7.5 km2) in the Hauraki goldfield. The prospects are hosted by andesitic to dacitic flows, autoclastic breccias and localised pyroclastic and air fall deposits. Jubilee and Sovereign prospects lie along the northern and southern parts of the Waitekauri Fault, respectively, whereas Scotia is located ~1 km to the E, and Jasper Creek a further ~1.2 km to the ENE. Wall rocks are typically intensely altered, although the degree of alteration becomes more variable east of Scotia and at Jasper Creek. Alteration minerals include quartz, adularia, albite, chlorite, pyrite, illite, interstratified illite-smectite, smectite and calcite. Several of these minerals have distributions that show distinct zonation with adularia most abundant at Sovereign and Jasper Creek, but restricted to shallow levels at Scotia. Illite occurs throughout Sovereign and Jubilee plus the western margin of Scotia where it grades into interstratified illite-smectite; smectite predominates at Jasper Creek. Veins are uncommon and typically narrow, but show distinct zonations. Quartz veins are more abundant at Sovereign and Jubilee, whereas calcite veins are more abundant at Scotia and Jasper Creek. Laumontite veins occur at Scotia, and rare clinoptilolite, mordenite and stilbite veinlets with calcite occur at Jasper Creek. Fluid inclusion in quartz and calcite homogenised between 141¦ to 272¦C and trapped a dilute solution with an apparent salinity of less than 2.6 weight percent NaCl equivalent. Homogenisation temperatures are hottest at Sovereign (average 241¦C) and Jubilee (average 239¦C), cooler at Scotia (average 204¦C) and coolest at Jasper Creek (average 162¦C). Calculated paleowater table elevations suggest the water table was 680 m to 750 m above sea level at Sovereign and Jubilee, 450 m at Scotia and 225 m at Jasper Creek. The current data suggest three scenarios that can explain why Sovereign and Jubilee are deep and hot, whereas Jasper Creek is cool, shallow and marginal; 1.   some or all of the prospects may represent separate overlapping hydrothermal system, 2.   a high-relief hydrothermal system on the side of volcano with an inclined water table and outflow towards Jasper Creek, and 3.   a low-relief hydrothermal system that has been either tilted or block faulted with greatest uplift and erosion to the west.

Jan 1, 2005

By Mohammad Noaparast, Babak Fotoohi

"Due to certain advantages in (semi-)Autogenous-Ball mill circuits in most of the high-throughput ore grinding units of mineral processing plants, much attention is paid to optimize the mill performance. Despite the maturity of the grinding mill mechanical design, there had been made less attention to the efficiency of the grinding media in the past. In this research, the possibility of establishing a relationship between liner/lifter wear rate and variations in the composition of the iron ore (from Chadormalu mine) is investigated.Measurements and determination of liner/lifter wear rates and patterns concluded in recognition of critical liner segments exposed to much abrasion during the ore grinding. After metallurgical analysis of liner materials and correlation of wear rate with the ore composition, the homogeneity in the metallurgical microstructure of the alloyed steel (such as the uniform distribution and amounts of the constituent phases) was determined as the most influential factor in the response of the liner/lifter to the variations in the ore composition. Magnetite with greater abrasion index than hematite, in finer particles, is responsible for additional abrasion of liners; hematite with greater work index exists in the mill with larger particle sizes, thus it could produce wear on liner parts with less tolerance to impact as is the situation for martensitic steels.INTRODUCTIONThe mineralization in Chadormalu plutonic iron ore deposit is consisted of mostly magnetite, hematite, martite, apatite, quartz and carbonates. The average composition of the ore is presented in Table 1. In the processing circuit, the gyratory crushed ore reduced to 30 cm would finally be the feed to three similar 32’ semi-autogenous mills in parallel processing lines. The pulp in the mill would have the characteristics mentioned in Table 2. The quality of the mill output has its direct effect on the downstream processes either physically or chemically (e.g. in cycloning or flotation respectively). In order to take advantage of optimum performance for these circuits, a close control of the ore grinding conditions is necessary; because any shortages in throughput, liner/lifter damage or changes in ore composition could bring the unexpected casualties. In this work, it has been attempted to find (possibly) a reasonable relationship between variations in ore characteristics together with liner quality and the amount of wear rate in different liner/lifter segments of a semi-autigenous mill. Liner/lifter segments are supplied by three different domestic steel making companies. The alloy structure of the liners/lifters is made up of pearlitic chromoly steel."

Jan 1, 2005

By J P. Moodie

Recent trends in flotation technology are briefly reviewed. These show that considerable development has been made as the operators, suppliers and technologists have responded to the challenges of the industry. Most of these advances have been based on empirical and phenomenological methods. There is a considerable opportunity to make further advances through a more fundamental, scientific approach. Some of this work is discussed and, although progress is being made on this front, industrial uptake has been somewhat slow. A number of specific issues facing the industry are discussed.

Jan 1, 2005

By T Ye Koltunova an, L A. Otrozhdyonnova

This paper presents the results of studies on the development of an efficient non-cyanide technology for processing massive, finely disseminated, copper-zinc ores of the Urals deposits. Copper is mainly represented by chalcopyrite and zinc û by sphalerite. The main ore mineral is pyrite, with its content in ores varying from 50 to 80 per cent. At the present time, separation of copper concentrate at the Urals concentrating plants is achieved in a lime medium by non-cyanide technology using sodium sulfide and zinc sulfite as depressors of zinc and iron sulfides and butyl xanthate as the collector. Copper content in copper concentrates amounts to 15 - 17 per cent; considerable losses of zinc are associated with copper concentrate and final tailings. Various collectors were tested during the studies: xanthates and aerofloats with different lengths of hydrocarbon radicals, thionocarbamates, Aerofine 3418A of Cytec Industries, reagent S-703G of Mineral Reagents Int, and modifiers û sulfur dioxide, sodium sulfide and zinc sulfite, with a pH of the medium varying from 5 to 12. Optimum results of copper concentrate separation were achieved in a weakly acidic medium using S-703G as the collector and sulfur dioxide and zinc sulfite as modifiers. The copper content in the copper concentrate was increased by 4.8 per cent. Total copper recovery into the copper concentrate and zinc recovery into the zinc concentrate exceeded five per cent.

Jan 1, 2005

By M. Popescu

In the southern part ?f the Occidental Carpathians an iron ore body embedded in crystalline schist was exploited. The presence of minerals such as magnetite, pyrite, pyro-chorine, allanite, monazite and xenotime, which also include within their structure substituted thorium isomorphic, was pointed out. The iron ore was processed by crushing, grinding and magnetic separation in order to obtain magnetite concentrates. The environment was affected by pollution generated by the mining activities. In 1995 due to the economic reasons, it was decided to cease mining exploitation and remediate the area. The paper presents the ecological impact caused by mining activities on a number of environmental targets and the population. The pollution sources, namely sterile dumps and mine waters are characterized (from the physical, chemical and radiometric point of view); the pollution pathways and theirs effects on potential targets, namely soil, vegetation, hydrographic network and population are identified as well. The degree of pollution due to all sources was assessed and maps of pollution sources distribution were generated. The supplementary effective doses for the population were assessed using rigorous scenarios and considering all exposure pathways. The rehabilitation plan includes solutions for dumps geometrization, covering and revegetation as well as mine waters management.

Jan 1, 2005

By L M. Lobato, J C. S Seoane, F J. Baars

The Carajßs Province presents several volcano-sedimentary sequences that comprise the Itacai·nas Supergroup. The rocks represent bimodal volcanism, and clastic and chemical sedimentation in relatively unstable basins subject to recurrent structural events with subsidence and volcanism. The Grpo Parß Group represents one of these sequences with mafic volcanic rocks that enclose discontinuous jaspilite lenses, with development of large high-grade orebodies (Fe >65 per cent). This unit is named the Carajßs Formation and presents peculiar characteristics compared to other iron districts in the world, thereby departing from the classic Lake Superior or Algoma iron formation types. Owing to the dense vegetation, lack of outcrops and harsh landscape, the structural analysis of the district can only be accomplished by combination of regional field work, detailed structural work on the open pits, and remotely sensed image interpretation, in this case Landsat ETM7, JERS-1 images and the SRTM digital terrane model. The regional trend of the several sequences of the area is approximately N-S and the structure is dominated by a flattened flexural fold system with axes moderately dipping WNW, intersected by several strike-slip faults subparallel to their axial plane. The Serra dos Carajßs represents an s-shaped synform-antiform pair, herein named the Carajßs Fold. This regional structure is partially disrupted by the Carajßs Shear Zone that divides it in the northern (Serra Norte) and the southern (Serra Sul) Ranges and also probably prepared the terrane with the development of pathways for mineralising hydrothermal fluids forming large high-grade massive iron bodies. Syntectonic granitic bodies played an important role in the structural evolution of the area as well. They caused localised ductile flattening deformation and thermal contact metamorphism in surrounding terranes. The Estrela pluton, for instance, was responsible for the discontinuity of the regional trend between the Serras do Rabo and Leste. The Carajßs Province is regionally the upper crustal product of a very shallowly eroded dome-and-keel geometry of Neo-Archaean volcano- sedimentary units intruded by syntectonic calc-alkaline intrusives and overlying pre-existing infracrustal rocks. The lithostructural data suggest continental-margin back-arc basin development and closure in an oblique collision belt, with N-S shallow crustal shortening, parallel to the inferred pre-existing strike of the stratigraphy.

Jan 1, 2005

By H. Tan

The effect of carbonaceous matter on gold extraction was investigated in cyanide systems with pure gold as well as pre-robbing sulfide gold ores. Auger studies demonstrated that the carbonaceous matter preferentially smeared on iron sulfide rather than aluminosilicate surfaces during wet or dry grinding. During mechanically mixed leaching, coating of sulfides and silicates and stripping of carbonaceous matter occurred simultaneously. TEM and XPS studies indicated preferential coating in the form of elemental (graphitic) carbon at the edges and the defect sites of particles. Interestingly, carbonaceous matter extracted from the gold ore was predominantly graphite and not preg-robbing in a solution with a high KCN concentration. However, the carbonaceous coating had a significantly detrimental effect on gold dissolution when gold was pre-ground with the gold ore. Artificial coating on gold surfaces with the natural carbonaceous matter from the ore was also found to substantially retard gold dissolution. With the addition of the natural carbonaceous matter from the gold ore, gold extraction from two non preg-robbing sulfide gold ores was inhibited owing to carbonaceous coating. The presence of carbonaceous matter significantly reduced the current density for gold oxidation and increased the current density for pyrite oxidation. This could explain the fact that carbonaceous coating hindered gold dissolution while enhanced sulfide preg-robbing.

Jan 1, 2005