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By J. -Y. Jia, G. -B. Qiu, C. -G. Bai, D. -F. Chen

Due to the great importance of the smelting process, it is essential to establish a calculation model on the viscosity of the slag system containing titania. In this paper, the calculation models of mass action concentrations and viscosity for the CaO-SiO2-TiO2slag system have been established according to the coexistence theory of the slag structure, as well as the referenced viscosities ofCaO-SiO2-TiO2at different temperatures and TiO2compositions. With the two models, corresponding calculated programs are made by means of programming language Matlab5.3, and the curves of viscosity of the TiO2concentration (?TiO2/%) at 1400°C, (R=0.9~1.0) are plotted. The results show that mass action concentrations of TiO2increases with increasing percentage ofTiO2, while the viscosity of CaO-SiO2-TiO2system is decreased. The results show that the models are in good agreement with the experimental and referenced data. They also shows that the models are reasonable for the CaO-SiO2-TiO2slag system. Keywords: coexistence theory; CaO-SiO2-TiO2slag system; viscosity ; calculation models.

Jan 1, 2004

By Rajendra Singh

Underground depillaring of contiguous coal seams/sections is a difficult problem, which becomes even more complex if the interburden/parting between them is thin. Conventionally, the depillaring with caving of contiguous seams/sections is done in descending order. However, if the parting is thin, the influence of the top sections/seams working over the standing pillars of bottom the sections/seams becomes extremely important for the safety and optimal exploitation of coal. Field investigations were carried out at Nowrozabad East mine where superimposed pillars of the Johilla top section were depillared above the developed pillars of the Johilla bottom section with a 3 m thick parting between the two sections. The competency of the 3 m thick parting (which consists of alternate layers of shale, sandstone and shaly sandstone) was improved by reinforcement (underpinning). The strata control investigations did not show any considerable instability problem of the 3 m thick reinforced parting and pillars of the bottom section due to top section depillaring. On the basis of this field investigation and a laboratory study on simulated models, simultaneous extraction of both the sections, along with reinforcement of the parting, was suggested for the geomining conditions of the Johilla top and bottom sections. Adopting the suggested simultaneous depillaring process, two sub panels of Johilla top and bottom sections have successfully been extracted without any strata control problem. This paper presents this case study along with the results of the strata monitoring conducted to evaluate performance of the underground structures during the field trial.

Jan 1, 2004

By M. Rigaud, N. Zhou, K. Sankaranarayanane, X. Zhou

The effect of amount and type of dispersants on the rheological behaviour of bauxite-based low-cement castables has been studied in detail. The rheological properties: flow resistance and torque viscosity, as measured by a rheometer, are found to be strongly influenced by the amount and type of dispersants. In the present investigation, a mix containing sodium hexametaphosphate, at an optimal level, is observed to be theologically superior at the given experimental conditions.

Jan 1, 2004

By Chris D. Shewmaker

So you want to install 2,600 augered cast-in-place piles, about 155,000 lineal feet, in 33 working days? It can be done. The Public Service Enterprise Group (PSEG) decided to build a combined cycle power plant in Lawrenceburg, Indiana. PSEG selected Fluor Constructors Indiana, L.P. to design and build the plant. Fluor Constructors, in turn, selected Richard Goettle, Inc. to install the piles. The initial plan was to install the 2,600 piles in 33 days, working six (6) ten hour days per week. After successfully installing and performing four pile load tests - up to 300 ton capacity - we set out to complete the work and meet the aggressive schedule. After three weeks of installing an average of 75 piles a day with three drill rigs, Fluor relaxed the schedule because we were so far ahead of their projected construction sequence. We elected to continue drilling on a ten-hour day, five days a week schedule. In all, we installed nearly 2,800 piles, totaling 175,000 lineal feet, in about 47 days.

Jan 1, 2004

By D. C. Panigrahi

Extensive field studies have been carried out to investigate the pillar fire problems in one coal mine in India. A Thermal IR gun and a Thermovision camera have been employed for thermal scanning to assess the state of heating in selected pillars. Special sampling set-ups have been designed to collect gas samples from the holes drilled into the selected pillars and the multigas detector is used to analyse the composition of samples in situ. In order to predict the spontaneous heating in coal pillars, different gas ratios have been calculated and it has been observed that some of the established gas ratios, viz. Graham?s ratio, Young?s ratio etc. have resulted in negative values in samples containing high amounts of methane. The modified gas ratios have been proposed which will be useful for predicting the pillar fires. These ratios may also be used for assessing the condition of fires in sealed-off areas.

Jan 1, 2004

By J. Fuller, L. Marsden

Windborne dust from alkaline salt flats and mining-related tailings ponds is especially prone to threaten applicable ambient air quality standards. Sodium carbonate crystals, typically present, weather to an exceedingly fine, non-cohesive dust, causing air quality problems for miles downwind. Recently developed specialized polymers react with alkaline dust to form sturdy, wind-resistant crusts with good longevity. An on-going demonstration project at a major trona facility has developed techniques for cost-effective application of these polymers over large areas of soft tailings or sediments in a wide variety of situations. Recently treated areas on the order of 80 acres show effective suppression of dust.

Jan 1, 2004

In a ætypicalÆ gold deposit each tonne of ore will contain tens of millions of very fine gold particles, whereas; at Bendigo the majority of gold in each tonne of ore is present in just five to 15 very coarse gold particles, a distribution more akin to diamond deposits. At Bendigo the minimum sample size required for good assay repeatability is estimated at 4.5 t for each assay. Drill core samples are several orders of magnitude too small to generate representative assays.The drilling data are characterised by a nugget effect approaching 90 per cent, a very skewed distribution and, on average, under-report in situ grade by 50 per cent to 75 per cent. Since 2002 Bendigo Mining NL has completed 47 000 m of diamond drilling, 1200 m of on reef development, collected and processed 100 bulk samples (150 t each), 800 mini bulk samples (50 kg each) and processed in excess of 25 000 t of ore through a pilot plant. The results of this work have provided the information required to develop and verify a robust grade estimation procedure. No standard geostatistical manipulation of the drilling assay data can generate an accurate grade estimate as the samples and associated assays are not representative of the ore being sampled. The recognition of this fact was critical as a radical transformation of the raw drill assay data was required to develop a workable methodology for grade estimation in such a high nugget environment. The aim of the transformation was to reduce the nugget effect and high variance and so approach a lognormal assay distribution. Ideally the average drill grade would approximate actual in situ grade and the assay distribution would reflect actual grade distribution within the reefs. Following the data transformation simple block modeling within the defined resources allows grade estimates to be made that can be used in the estimation of Indicated Resources and hence Probable Reserves. The grade estimates have been checked by extensive bulk sampling and processing of 25 000 t of ore (three per cent of total resource) through a pilot plant with planned full scale mining to provide the ultimate verification.

Jan 1, 2004

By J. L. Floyd

The Trapper Mine is a large surface coal operation located in northwestern Colorado US. The coal seams at the mine dip an average of 8 degrees so, historically, their dragline pits have been orien-tated parallel to the dip of the coal seam to balance stripping ratios. However, the mine plan in the future G and Z pits is designed to take advantage of pit orientations that are parallel to the strike of the coal. During the initial presplit and cast blasts in G pit, significant slope damage occurred. This damage included the opening of joints and tension cracking. There was also block movement directly above the L coal seam, which is the main plane of weakness in the slope. A detailed site evaluation was conducted to develop specific blast design modifications to protect the slopes during future blasting. The modified de-signs successfully controlled vibration levels during the blasting of the Z pit box cut. This paper includes a review of the blast vibration related factors that influence slope stability along with a detailed discussion of the field tests and design modifications developed.

Jan 1, 2004

By Randy Wheeler

In recent years the issue of seismograph calibration and accuracy has been a major focal point of the ISEE Blast Vibration and Seismograph Section. In fact, questions concerning the consistency and reliability of seismograph measurements essentially led to the development of this ISEE section. One of the early actions of the section involved the development of “Field Practice Guidelines” for the use of seismographs. These guidelines specifically state that “Placement and coupling of the vibration sensor are the two most important factors to ensure accurate ground vibration recordings.” This paper will address the results obtained from using different coupling methods to record vibration and airblast levels generated from production blasting in a limestone quarry. The data obtained clearly indicate that seismometer burial provides the best coupling for recording ground vibrations. Microphone height has also been an issue regarding the accuracy of recorded airblast levels. The data we obtained indicates that microphone height is not a significant factor.

Jan 1, 2004

This brief introduction tries to introduce delegates to this conference to the almost unbelievable attributes possessed by many microbes which might be relevant to geomicrobiology, and how most of these remain unexploited by us. It introduces some of the terminology which will be used and tries to suggest that there are rewarding times for those who set out to discover the natural biodiversity of bacteria in nature. Although we have exploited microbes, usually unwittingly, and suffered at their hands for millennia, it is only recently that we have begun to become aware of how they dominate our planet (most of the earthÆs biomass is bacterial) and are responsible consequently for most of what happens here. A few can cause us harm and occasionally kill us, but most bacteria are beneficial, impacting positively for example on how we grow our food and in cleaning up the pollution we create. They are simply indispensable to how we live. They have been responsible for many of the geochemical changes which have taken place on this planet and play major roles in the transformation of elements so essential to our existence (Newman and Banfield, 2002). No one should dismiss them as minor players in our game of life.

Jan 1, 2004

By Debbie Marshall

Process water is an important consideration in the development of a nickel laterite project. Depending on the location of the ore body, sufficient fresh water may not be available and it may be necessary to use seawater (or saline groundwater) for ore preparation. This introduces various species, which have major effects on materials of construction and leaching chemistry. This paper summarizes batch testwork completed at the Falconbridge Technology Center. The leaching behaviour of eleven different laterite ore samples were compared using seawater and fresh water. For brevity, six of the eleven samples are reported here-the other five samples showed similar results. Each ore type was leached under identical conditions in both freshwater and seawater and the leaching chemistry compared. The batch test results were confirmed in a continuous pilot plant, and leach kinetics for the two systems were compared. Keywords: high pressure acid leaching, laterites

Jan 1, 2004

By J. Zinck

The management of mine wastes generated by both active and inactive mining is an ever more challenging issue. The cost to manage and treat mine wastes, including tailings, waste rock, treatment sludge and slag, is estimated at over $50B in Canada and the United States alone. Cost-effective technologies are required to meet both short and long term challenges and increasing environmental standards. This paper will provide an overview of novel and conventional technologies to manage mine waste particularly in the areas of waste stabilization, treatment and disposal technologies.

Jan 1, 2004

By T. Watanabe, S. Hayashi, M. Hayashi, K. Nagata, H. Fukuyama

Chemical states of fluorine in CaO-SiO2-CaF2glasses in a composition range of CaO/SiO2=0.5?1.3 and 5?25 mol%CaF2have been investigated by 19F solid-state NMR with and without MAS. The isotropic chemical shifts of the glasses are close to those of cuspidine crystal (59.4 and64.3 ppm with respect to C6F6) and CaF2crystal (58.6 ppm). The fluoride ions are coordinated with four or less than four calcium ions in this composition range. The chemical shifts move to the lower frequency with an increase in the CaF2content, whereas those are not affected by theCaO/SiO2ratio. The ionic distance between calcium and fluoride ions increases with an increase in the CaF2content. The chemical state of fluorine is not disturbed by the degree of polymerization of the silicate network. Comparing the MAS and static NMR spectra, the second moment attributed to 19F-19F dipole-dipole interaction has been estimated. The values of the glasses range over 3.1?7.3107Hz2andthose are larger than the calculated value of cuspidine crystal. This indicates that fluoride ions form Ca-F clusters in the glasses and that the size of clusters increases with increasing the CaF2content. Keywords: chemical state of fluoride ion, CaO-SiO2-CaF2glass, solid state 19F NMR spectroscopy

Jan 1, 2004

By M. C. Mound, E. Gallestey, C. Colbert

Continuous operating performance and high profit is one of the major concerns in the mining industry. Information systems are expected to reinforce and enable conformance to these requirements. The companion efforts of business management and production information systems press for tighter integration to avoid over-laps, multiple instances of similar data, and expensive maintenance of databases. Implementation of advanced intelligent systems throughout a mine operation can reduce costs, optimize investment and create a shorter payback via conversion of the data accumulated by field and process devices into information, and subsequently, into decisions. However, in order to harness the potential power inherent in these intelligent devices, adequate and flexible modular knowledge-based solutions are required. Fortunately, there has been at least one such practical response to this challenge, namely the ABB IndustrialIT portfolio. With these tools in place, production efficiency is reached via integration of process, production, and quality information. Moreover, they permit immediate detection and remedial action to changes to process and boundary condition variables. Finally, using advanced optimization techniques supported by dedicated mathematical models, they allow for economic process optimization (process set points and coordination thereof, energy management, production planning, energy supply contract optimization, etc) of the plant as a whole.

Jan 1, 2004

By E. M. De Souza, J. F. Archibald

This paper examines aspects of Canadian mine backfilling operations that may be implemented to assist in reducing solid waste production, lowering energy costs, and restricting Greenhouse Gas emissions. Many Canadian underground mines use backfill to mitigate environmental effects associated with tailings disposal. Backfill production and disposal are energy intensive processes that require an average energy cost of 37.7 MJ/tonne of backfill to complete. Mine backfills, in engineering applications, also commonly make use of cement as a stabilizing agent. Cement requires an additional energy cost ranging between 4,637 and 6,600 MJ/tonne to produce. The large energy needs associated with mine backfilling and cement production operations create significant CO2 and Greenhouse Gas emissions. Approximately 1 tonne of CO2 and Greenhouse Gas is emitted for each tonne of Normal Portland Cement produced. For single mines producing 3,000 tonnes of backfill per day, considering both backfill and cement emission source terms, total emissions of CO2 ranging between 120.36 tonnes and 169.44 tonnes/day are anticipated. In Ontario, mining operations contribute 700,000 - 840,000 tonnes/year of CO2 and Greenhouse Gas emissions to satisfy backfill cement consumption needs alone. Potential reductions of cement in backfill would significantly reduce emission of these gases and lower their adverse environmental impacts. This paper identifies alternate, equally effective and lower cost binder agent strategies for cement in backfill that may lead to cement consumption reductions. Post-consumer glass represents one such potential alternative backfill binder. Over 950,000 tonnes of glass are disposed of annually in Canada, two-thirds of which exists in the form of easily recoverable glass packaging that is not currently recycled or reused. The partial replacement of cement by waste glass may address goals for reducing non-recyclable glass waste disposal; enhancing mine back filling operations; reducing total backfill energy costs; and ultimately reducing Greenhouse Gas emissions levels currently generated by the Canadian mining industry.

Jan 1, 2004

By V. T. McLemore

The mining industry is at a crossroad. To sustain our technically based society, demands for commodities are increasing, and exploration for these commodities is a must. The debate is between sustainable development and the status quo and begins with exploration, where it is determined if a mineralized area contains enough potential ore to be mined economically. Mineral deposits are relatively rare and depend upon certain natural geologic conditions to form and may not always occur in locations that are most suitable to society. Exploration can be compatible with environmental protection and social responsibility, but difficult challenges face the industry to develop a property that is environmentally, economically, and socially responsible.

Jan 1, 2004

By M. Hosseinzadeh

By changing the quality of consumed refractory bricks in burner zone of sarcheshmeh copper complex anod kiln removing of carbon precipitation phenomenon was studied. For blister deoxygenation LPG is blowing in anod kiln and cause destoring microsturcture and bonding of refractory bricks. Studies are shown that in a part of the bricks which have a temperature of 800 - 1000 °C , iron content phases in magesia - chromite bricks are like catalist and cause increasing the rate of carbon precipitation reactions . In a way that in comparsion of two bricks with best and medium quality with different analysis, this problem is more critical in best quality bricks containing high iron oxide. Therefore special magesia spinel bricks suggested and installed in burning zone.

Jan 1, 2004

By J. A. Cox, R. P. H. Willis, J. R. Dixon, A. D. Pooley

The paper describes the issues that should be considered when introducing mechanization to a mining operation. In South Africa, traditional methods of mining are well entrenched after more than a century of mining. To successfully change from these methods requires an integrated holistic approach that considers all aspects of a mining operation including setting of objectives, selection of personnel, recruitment, training and remuneration policies, organizational design, mine design, equipment selection, maintenance philosophy, standards and procedures, and monitoring and control. The paper makes reference to experience gained during a variety of on-mine case studies in drawing generic conclusions and making recommendations.

Jan 1, 2004

By Andreas Orth

Outokumpu Lurgi Metallurgie has developed a process for the calcination and reduction of laterite nickel ore tines where the reduction of iron and nickel to the wustite/metallic states respectively, is performed in a fluidized bed reactor using reduction gas generated very cost effectively from natural gas in an autothermal catalytic reactor. As an option coal can be used as reductant as well as additional fuel. The process of reduction and calcination is very energy optimized. It uses the off gas from the fluidized bed reduction reactor, which still contains energy, to dry and calcine the nickel ore fines in a primary stage circulating fluidized bed (CFB) reactor. The product shows high metallisation of nickel and iron oxides reduced to the wustite stage. This results in considerable energy savings in smelting the prereduced product to ferro-nickel. Alternatively the product can be leached to produce nickel. Laboratory tests showed very high recovery of nickel and cobalt. Keywords: Fluidized Bed, Prereduction, Calcination, Ferro-Nickel

Jan 1, 2004

By K. Morita, N. Sano

Thermodynamic properties of chromium oxides in molten slags are very important for optimization of stainless steel refining processes as well as reduction processes of chromium ores. The solubility of chromite into molten slags has been found to vary considerably with oxygen partial pressure and slag composition in former studies by the authors. In the present study, activity data and redox equilibria of chromium oxides measured under moderately reducing conditions, PO2= 6.95x10–11atm, at 1873 K are summarized. For the CaO-SiO2-CrOXsystem, the activity coefficient of chromium oxide increased with increasing basicity, and the optimized slag composition for stainless steel refining is assessed as that saturated with CaCr2O4and Cr2O3usingthe phase relations determined. On the other hand, the presence of MgO and Al2O3brings about different behaviour of chromium oxide activity and redox equilibiria and the 44 mass per centCaO-39 mass per cent SiO2-11 mass per cent Al2O3-6 mass per cent MgO slag is recommended toreduce the chromium oxidation loss in the practical stainless steel refining process at 1873 K. Keywords: chromium, activity, stainless steel, AOD, VOD, oxidation loss, redox, CaO-SiO2-Al2O3-MgO slag

Jan 1, 2004