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By F. Bonnet, J. Lehmann, H. Gaye

A review of thermodynamic information and models of slags, including associated software when available, is presented. The pertinence and accuracy of these models is discussed by comparison of their predictions for various slag thermodynamic properties with the available experimental data. Practical industrial applications will be illustrated by a literature review of the dephosphorization process of ferromanganese alloys and by the description of Ti behavior during silico-manganese alloys production. This latter example will show how the thermodynamic models have been used to propose a flotation treatment at low temperature to enhance TiC removal.

Jan 1, 2004

By R. Pelletier, Herny. E., C. Allaire

Corrosion of refractory linings by molten metals is controlled by interactions between penetration and chemical reaction. Corrosion of aluminosilicates by molten aluminium is no exception. The early stage of corrosion can be described as a particular case of reactive wetting over a porous medium. Although the reactivity between aluminium and silica is great, which should improve wetting and penetration, the presence of air and the formation of a protective oxide layer disfavours initial penetration. This paper presents the results of an exploratory study on the effect of some parameters on the initial stage of aluminium penetration. Penetration kinetics and metal intrusion tests have been performed on alumina and silica powders with pure aluminium and Al¬5%Mg. Capillary models are used as tools of interpretation. Penetration kinetics tests had a poor reproducibility and the kinetics itself can not be explained very well by the capillary-tube-bundle model. On the other hand, a capillary model initially developed for ice intrusion into freezing soils produced predictions in reasonably good agreement with intrusion pressure measurements. The effect of particle size and alloy composition can be predicted using this model. However, the effects of temperature and powder chemistry need additional interpretations to be rationalised. An unusual resistance to penetration of silica powder by molten aluminium have been observed in a series of experiments. This led the authors to the strange conclusion that oxygen should be seen as an excellent non-wetting agent and that there might be ways to use it in industrial applications.

Jan 1, 2004

By G. Forté, R. Girard

The Alcan Bayer Process Experimental Centre (BEC) is an essential development tool for the Bauxite & Alumina researchers at the Alcan Arvida Research and Development Centre in Jonquiere, Quebec. Between the laboratory tests and the industrial prototypes or the industrial applications, the BEC is a key element for technology transfers. The Bayer process is the extraction of aluminium oxide (or alumina) from the bauxite ore. The Bayer Experimental Centre's history and flowsheet are presented. The major pieces of equipment are described. Safety and design considerations are presented. Finally, examples of applications, double digestion and pressure decantation, are briefly described.

Jan 1, 2004

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By R. Guimarães, L. Silva, J. Milboume

The São Bento concentrator was built by Gencor in 1985 to treat refractory gold-bearing flotation concentrate. The plant was the first commercial application of pressure oxidation for refractory gold ore following about a year after the first use of pressure oxidation on a whole ore at Homestake's McLaughlin operation in California. Ore from the Sao Bento mine is remarkably consistent in gold grade and arsenic and sulphide concentration as is typical in banded iron formations (BIF) (l). Gold content is approximately 9 g/t with approximately 30 - 40% free milling. The balance is associated with arsenopyrite and pyrrhotite. An expansion of both process facility and mine was undertaken between 1996 and 1998, raising the treatment capacity from 32,000 t/mo to 45,000 t/mo.

Jan 1, 2004

By T Leach, I Pringle

The Bowdens Silver Deposit is a low sulfidation epithermal silver-base metal deposit that has formed on the northern margin of a hydrothermal system within air-fall breccias, ignimbrites and crystal tuffs of rhyolitic composition. The deposit lies near the north-eastern margin of the Lachlan Fold Belt and the rhyolitic host rocks are of Early Permian age. The silver mineralisation occurs as flat-lying zones of disseminations and silicic fracture-filling within the Rylstone Volcanics and is closely associated with sulfides of iron, arsenic, lead and zinc. High-grade silver mineralisation is also found in steeply-dipping fracture zones which host banded sulfide veins. Studies of the alteration products indicate that high temperature fluids, flowing from south of the current project area, resulted in quartz (¦adularia) û illite/sericite alteration. Cool, low pH steam-heated waters on the northern and eastern margins of the prospect area resulted in siderite û smectite-illite clay û Fe-carbonate û marcasite û kaolinite alteration. Mixing of the two fluid types resulted in the deposition of iron and base metal sulfides, a decrease in both sulfur activity and pH of the mineralising fluid, and subsequent silver mineralisation.

Jan 1, 2004

Anhydrite-based dam constructions, which have been implemented successfully in other geological formations, were investigated with regard to their suitability in salt mines. The laboratory investigations show that anhydrite-based building materials with suitable additives bind safely in spite of the high temperatures in salt mines which normally pre-vent hydration. The dependence of the compressive strength, swelling behavior, porosity and permeability upon the choice and ratio of binding material components and additives was determined. Based on the results of these investigations, a pilot-scale experiment was carried out at the GSF Research Mine Asse (Germany) using a mixture suitable for the prevailing conditions

Jan 1, 2004

By W. Song, C. Richards, B. Q. Li

"This paper presents a two-phase flow numerical model for spouting gas-particle flow reactors used in chemical vapor deposition processes for manufacturing heart valves and other biomedical implants. The model is developed based on the Eulerian-Eulerian formulation of gas-particle flows, with the k-e engineering model modified with the presence of particles for the description of turbulent gas flows. In parallel with the numerical model development, physical models are set up, where the particle image velocimetry is used for visualizing the particle flows and spout shapes and heights and optical probes are used to measure the particle velocities. The numerical model predictions are compared reasonably well with the experimental measurements.IntroductionVarious biomedical implant components, such as bone joints, dental components and heart valves, are coated with bio-compatible thin films by chemical vapor deposition in particle-laden chemical reactors [l-5]. In these reactors fine particles are used as packing and supporting media. During the coating operation, these packed particles are fluidized by an upward gas jet from the nozzle, reach a certain height and fall back on the top of an annulus region. These recirculating particles are mainly for levitating the implant components (usually one or two in a reactor at one time) so that every portion of them is equally exposed to the gaseous atmosphere. An equal exposure is critical for forming a uniform, mechanically strong and corrosion-resistant coating on implants. Plant experience shows that the quality of the coating is directly related to a stream of operating parameters such as temperature, particle size and loading, and gas flow rates [6]. Optimization of these operating parameters for improved reactor performance depends crucially upon our fundamental understanding of the physics governing the gas-particle flow, heat, and mass transfer phenomena taking place in these reactors."

Jan 1, 2004

By Francis Kendorski

One of the most dangerous events in underground coal mining is unexpectedly encountering water inrushes from undetected abandoned mines in the same seam. The surest and most confident method is probe drilling either from the mine or from the surface. However, drilling is expensive and may even miss the suspected mine voids entirely by drilling through pillars. Many operators rely upon one or more of several remote sensing techniques for detecting mine voids. However, mine "voids" often are not air- or water-filled open cavities, but are collapsed, rubble-filled chimneyed columns in the strata. Geophysical techniques, such as seismic reflection and refraction, electrical resistivity, magnetics, ground-penetrating radar, and others, often assume a continuous or fractured rock mass that has varying properties which provide the signatures that allow discrimination of one strata from another, or of strata from voids. However, a rubble-filled cavity has rock block-to-rock block contact throughout its volume and can still respond as a continuous rock mass with the rock blocks allowing signal transmission or mass detection, rather than a void space. Hydraulically, a rubble-filled cavity is essentially as transmissive to water as an open mine void. Thus, the problem of detecting a mine void with confidence is significantly compounded.

Jan 1, 2004

By R. Schmidt

The computational fluid dynamics (CFD) technique was used to analyze and optimize the design of the dynamic air classifier integral to Raymond® Bowl Mills. Flow patterns and particle behaviors were modeled in the RB Bowl Mill equipped with various classifier designs. These CFD simulations resulted in the development of a hybrid turbine classifier that has now been field-tested, yielding significant improvements to both mill throughput and product size distribution. This paper demonstrates the viability of CFD as a tool for air classifier design and as a technique that can be extrapolated for use with other pulverizer and classifier arrangements.

Jan 1, 2004

By Walter Curlook

An improved process of hydrometallurgical treatment of laterite ores of the limonitic type for the recovery of nickel and cobalt using sulphuric acid has been developed and patented [I]. The major improvement is brought about by recycling a significant portion of the "mother liquor" emanating from the pressure leaching reaction back to the feed preparation stage thereby substituting for all or at least a major proportion of the fresh water that must be added. The amount of process effluent waters is correspondingly reduced. Concomitantly with the major savings in fresh water requirements, a degree of reduction in new sulphuric acid requirements is effected, along with a savings in limestone and lime required for subsequent neutralizations. Keywords: Acid pressure leaching; Nickel laterites

Jan 1, 2004

By Yoshimasa Funakawa, Kazuhiro Seto, Akio Kobayashi

A new hot rolled high strength steel consisting of ferrite matrix and nanometer¬sized precipitates was developed. The ultra fine precipitates were identified as TiMoC2, and the strengthening by the precipitates was evaluated more than 300MPa in case of TS/800MPa grade steel. Due to the strengthening effect of the ultra fine precipitates, alloy elements for solid solution hardening can be reduced. It is notable that the steel shows very high yield strength (730MPa in case of TS/800MPa) and very high local elongation leading to excellent stretch flange formability at the same time. The mechanical properties of the steel are attractive for chassis parts and structural parts of auto body. The steel has been produced commercially, and applied to the parts successfully.

Jan 1, 2004

By A. Innus, R. Pelletier, C. Allaire

Refractory used for molten aluminium confinement is typically assessed separately for thermo-physical properties and molten aluminium resistance. This present work provides a case study comparison of four commercial refractory products that were subjected to a test procedure that combines mechanical impact, thermal shock with molten aluminium contact. The main conclusion of this work is that physical and mechanical property values by themselves do not, and cannot, predict the response of refractory to potential interactions between molten aluminium contact and thermal shock and mechanical impact. Adequate physical simulation is imperative to quantify the effect of such interactions.

Jan 1, 2004

By R. Frank Chiappetta

A new blasting technique has been developed by International Technologies, LLC. to eliminate subgrade drilling, lower ground vibrations, improve fragmentation and reduce explosive consumption. The new technique utilizes a uniquely designed borehole plug, with a bottom hole air deck and a predetermined stemming mass on top of the plug. This combination is referred to as the Power Deck?. Single holes and full scale tests were conducted by Blasting Analysis International, Inc. (BAI) to determine how the system works, the mechanisms behind its success and the best design parameters to use for the given rock conditions. Results have shown reduced or eliminated subgrade drilling, ground vibration reductions of up to 33%, reduced explosive consumption by 16 to 25%, and improved fragmentation by up to 25%. This paper summarizes the methodology, field test setups, analyzes procedures and results for one series of single hole and full-scale tests which were performed in a Pennsylvania, USA quarry.

Jan 1, 2004

By V. G. c Papangelakis, M. Huang

A conductivity cell, developed previously, was employed in an effort to investigate the inter-relation between electrical conductivity and acidity of sulphuric acid - metal sulphate solutions at high temperatures. The measured solutions include the H2SO4-H2O, MgSO4-H2O, H2SO4-MgSO4-H2O, H2SO4-MgSO4-Al2(SO4)3-H2O solutions. All solutions reported in this paper were measured from 15 to 250 °C at equilibrium vapour pressure. The maximum measured concentrations of H2SO4, MgSO4 and Al2(SO4)3 were 0.45 m, 0.30 m and 0.10 m, respectively. It was found that, from 15 to 250°C, there is a linear relationship between H2SO4 concentration and electrical conductivities for acid concentration up to 0.45 m. At 250 °C and constant H2SO4 concentration, the solution conductivity drops with the increase of MgSO4 concentration. Lt is suggested that this drop is caused by a decrease in the concentration of H. Finally, an empirical model was developed based on the available measurements. This model has been tested against real laterite leach solutions where sulphuric acid and metal sulphates are dominant electrolytes. The average difference between the estimate acid concentration from this model and the one from titration was less than 5%.

Jan 1, 2004

By E. V. Konopleva, H. J. McQueen, V. M. Khlestov

In addition to increasing grain boundary area during hot working of austenite, the dislocation substructures create potential sites for nucleation of ferrite both at original grain boundaries and at transition boundaries between deformation bands. This development gives rise to a marked increase in the rates of nucleation, of growth and of transformation to ferrite. The combined net effect is product grain refinement that requires less stringent cooling between finish rolling and coiling; hence determination of the above rates would advance process optimization. The important control parameters are the preheat temperature (degree of homogenization), finishing temperature, strain (accumulation near finishing) and the extent of recrystallization after finishing. These effects vary greatly with steel composition; nevertheless, some general rules have been formulated. Moreover, there is also potential for deformation of the refined ferrite. There are other thermo-mechanical processes such as warm forming of metastable alloy austenite to provide a dense substructure that is carried into the martensite on quenching. In other processes, the austenite may be deformed during cooling through the transformation to develop a dense substructure in the ferrite that is stabilized by fine carbides.

Jan 1, 2004

By S. P. Taite, A. R. Charest, P. D. Lewis

The El Sauzal deposit is a classic, high sulfidation, epithermal gold system located in southwestern Chihuahua State, Mexico. The prospect was discovered by a Francisco Gold Corp. geologist in1995. El Sauzal was encountered as a result of an extensive grass-root exploration program in the rugged, dissected volcanic terrains of the Sierra Madre Occidental, around the historical Batopilas Silver Camp. At El Sauzal, high grade gold is hosted within a series of more permeable, low-dipping, lithic and fine-grained dacitic rocks of early Tertiary age. The mineralization appears to be both structurally and lithologically controlled. The alteration characteristics are typical of a high sulfidation system including kaolinite, illite, alunite, dickite and pyrophyllite. The deposit’s gold distribution, as recorded from drill-hole data and surface samples, varies from 0.2 to 650.0 g/t. The estimated geological resource, as calculated from an independent study completed in 1998, was 3.0 million oz @ 2.03 g/t including a minable reserve of1.8 million oz @ 3.3 g/t.

Jan 1, 2004

By K Niyomjinda, B Etschmann

Chatree Gold Mine is currently the only modern day gold mine operating in Thailand, and is situated approximately equidistant from Chiang Mai in the north and Bangkok in the south. Environmental guidelines set by the Thai authorities require Chatree Gold Mine to achieve a Total Cyanide level of 20 ppm or less in the process plant discharge slurry stream prior to release into the tailings storage facility. This paper describes both the initial difficulties faced in achieving compliance on this limit utilising the conventional INCO SO2/Air cyanide destruction system and the subsequent process improvements initiated to both the leaching process and the standard INCO process to achieve the current compliance levels of approximately 99/100 shifts. Improvements were focussed on the dual aspects of reducing the formation of WAD cyanide and ferrocyanide species in the leaching circuit coupled with process changes to improve removal of the ferrocyanide species from solution during the cyanide reduction stage.

Jan 1, 2004

By B. T. Lu, J. L. Luo, T. Yu, C. W. Chen

In this paper, the synergism in erosion-corrosion process occurring in oil sand wastewater transportation caused by the interaction of mechanical and electrochemical factors was experimentally investigated. The erosion-corrosion tests were conducted with A1045 steel in synthetic slurries comprising tap water and silica sand. The material loss due to corrosion-enhanced erosion was assessed with the chemo-mechanical model developed by the authors recently. The results indicate that the material loss produced by corrosion-enhanced erosion at the open circuit potential can be formulated as a linear function of logarithm of corrosion current density. The wastage caused by the erosion-enhanced corrosion was analyzed based on the concept of non-equilibrium thermodynamics. The material loss induced by the erosion-enhanced corrosion is approximately a linear function of overall erosion rate measured in synthetic slurries, indicating that erosion-enhanced corrosion could be reduced by adopting surface strengthening techniques to improve the resistance to the plastic deformation in surface layer.

Jan 1, 2004

By B. Simser, V. Falmagne

"Noranda’s Brunswick mine is a 10 000 t/d producer of lead-zinc-copper-silver ore that has been in operation since 1964. Mining of this multiple lens deposit is primarily by blasthole stoping techniques between 400 m and 1200 m below surface. The combination of a high overall extraction ratio, an overall steeply dipping tabular shape, and high horizontal stresses (twice the vertical) have elevated the induced stress regime to levels comparable to much deeper operations. Improved mine design, and a better understanding of how the rock mass responds to mining in high-stress environments is essential to improve overall recoveries and maintain safety. Seismic monitoring has proven to be an essential tool at Brunswick, for both short-term safety of workers, and long-term strategic planning.Practical case studies illustrate how seismic data, particularly source parameter information, can be used to measure the rockmass response to mining and improve mining layouts in difficult regions. As the global trend continues toward mining in deeper, higher stress environments (e.g., South African Witswatersrand Basin, Sudbury Basin) and as local extraction and thus ground stresses continue to increase in existing deposits, seismic monitoring will play a critical role in mining safely and economically."

Jan 1, 2004