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By W. G. Pariseau

Regression analysis of calculated on measured displacements were used to assess the influence of fill and fold plunge on shaft pillar mining at the Homestake Mine. These effects were neglected in the original three-dimensional finite element analysis undertaken in 1991. An average fold plunge of 15? and a 24K fill (Young’ modulus of 24,000 psi or 165 Mpa) were used in the reanalysis. Measured displacements were obtained from an array of 36 m (120 ft) multiple-position borehole extensometers installed in June 1994 and read to March 2003. Results indicate the effects of both on calculated displacements and thus on regression parameters are noticeable. However, these neglected effects would not have changed the original inference of Ross Shaft stability during pillar mining.

Jan 1, 2004

By M. T. Worley

Joint Development Associates International, Inc. (JDA) began humanitarian relief and community development in Central Asia in1992, following the collapse of the former Soviet Union. Appropriate technology has played an important role in their efforts to assist those segments of society that are most vulnerable to poverty and disease. Three case histories are described to illustrate the successful implementation of simple, but effective technology in community development.

Jan 1, 2004

By M. Kockler, S. J. Jung

Underground operations at the Rain Mine averaged 360 tonne/day (400 ton/day) utilizing underhand drift-and-fill and longhole stoping with delayed fill between 1993 and 2002. Mining from four ore zones produced over 803 800 ore tonnes (886 000 tons) at a grade of 9.32 gm/tonne (0.270 oz/ton). Even though openings in the ore could be as large as at 9 m (30 ft) wide, 30 m (100 ft) high, and over 60 m (200 ft) long, the weak rock surrounding the ore zones restricted development size to 3 m (10 ft) wide by 3.7 m (12 ft) high.

Jan 1, 2004

By R. A. Mantz, V. N. Balbyshev, A. N. Khramov, N. N. Voevodin

Corrosion protection properties of the hybrid organo-silicate coatings on aluminum substrate can be significantly improved by means of encapsulation of organic corrosion inhibitors within the coating material. In order to achieve sustained release of corrosion inhibitor and long-term corrosion protection, a secondary chemical equilibrium of either ion-exchange interaction with the coating matrix or cyclodextrin-assisted molecular encapsulation of the inhibitor has been employed. Several organic corrosion inhibitors, such as mercaptobenzothiazole, mercaptobenzimidazole, mercaptobenzimi¬dazolesulfonate, and thiosalicylic acid have been examined by a group of electrochemical methods including potentiodynamic scan, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. It has been found that the formulations that contain ß-cyclodextrin demonstrate superior corrosion protection capabilities as the complexation equilibrium results in a continuing delivery of inhibitor to corrosion sites. The approach is considered a promising way for active corrosion protection of high-strength aluminum alloys when integrity of barrier coating is compromised.

Jan 1, 2004

By Julian Johnson

The effect of changing redox potential (Eh) on the high temperature sulfuric acid leaching of Western Australian dry-land nickel laterite ores has been investigated. In particular, the effect of added reductant (sulfur, sodium sulfite) or oxidant (potassium chromate) on Eh, leaching kinetics, metal extractions, acid utilisation and leach residues has been determined. Three separate ores - nonhonitic ores from Murrin Mumn and Bulong, and limonitic ore from Cawse - were used in the study. Sulfur addition varied from 0 to 7.8 kg/t ore. The total acid loading was kept constant at 430 kg/t (Murrin Murrin ore) and 330 kglt (Cawse ore), whilst acid loading for Bulong ore was varied according to the presence of either reductant or oxidant. The extraction of both nickel and cobalt from limonite ore remained unaffected when small amounts of sulfkr were added, but addition of even small amounts of reductant to nontronitic ore decreased both nickel and cobalt extraction. Increased manganese and iron dissolution were observed as the levels of reductant increased, accompanied by a decrease in chromium dissolution. As the iron dissolution increased, free acidity decreased, with a subsequent decrease in nickel extraction. In contrast, addition of oxidant lead to reduced iron and manganese dissolution and slower extraction of nickel and cobalt. Keywords: Limonite, Nonhonite, Eh, Nickel Extraction

Jan 1, 2004

By C. H. Bucknam

Principles of Green Chemistry provide useful guidance for sustainable mineral process development. Laboratory bench scale testing was carried out using pregnant cyanide leach solutions, and a number of commercially available mercury precipitation reagents were compared using jar testing to determine the most efficient and selective reagents for mercury precipitation. The most efficient reagent identified was sodium polymeric thiocarbonate (NaPTC).Coagulation experiments with fine diatomaceous earth resulted in a stable precipitate, with good settling properties. On line monitoring of the mercury in solution is recommended for process implementation to conserve reagent removing approximately 90-95% of the mercury with minimal silver and negligible gold losses.

Jan 1, 2004

A mining companyÆs approach to managing the risk of theft of explosives and initiating devices should be underpinned by an organisation-wide policy developed with internal and external consultation. It should be based on the principles of sound proactive risk management, planning, monitoring and remedial action. This paper aims to provide mining (and construction)organisations with the rationale and many of the tools they need to control explosive security risks. As with all legislative compliance, they are best managed by incorporating the statutory and legal requirements into company policies, management systems and plans, operating procedures and culture. This is the approach that has been adopted in this paper. Trends we should expect: more prescriptive legislation and stricter government regulations; enhanced enforcement and more prosecution; more sophisticated detection systems, eg airports; additional compliance costs; additional vigilance on record keeping; improved risk awareness and risk communication; wider use of explosives policies, management systems and plans; and additional security staff with investigative skills.It should be noted that mining companies will be required to play their part in reducing the likelihood of explosives, intended for mining purposes, being wrongfully used to threaten, hold to ransom or to injure individuals or members of the public or to produce property damage. This will be done by putting in place safeguards to reduce the risk of theft of explosives while they are under their control. On that basis, this is a business risk assessment rather than a hazard risk assessment. A conclusion of this paper is that mining companies can and should play their part in reducing the supply of explosive materials that can then be used for illegal activities. In fact, mining companies have always had this duty, but now the stakes are higher û æcomplacency no longerÆ.

Jan 1, 2004

By C. Klinkenberg, G. Zhu, K. Hulka, S. V. Subramanian

A quantitative model based on strain accumulation in multi-pass rolling is developed to overcome a large critical strain for dynamic recrystallisation in a Nb microalloyed steel with high Mn content (HTP steel). The larger the critical strain for dynamic recrystallisation, the finer is the dynamically recrystallised grain size. The initial mill trial showed that it is feasible to achieve ultra-fine grain size by dynamic recrystallisation but the prevention of static recrystallisation in between passes is identified as an essential condition to suppress mixed grain size. The data-base on static softening kinetics at short interpass time was experimentally determined on WUMSI and incorporated in the model. The model is used to optimise the strip rolling schedule to prevent static recrystallisation in the interpass time. The rolling simulation of strip rolling schedule has validated the model prediction that it is possible to obtain a uniform ultra-fine ferrite grain size of about 1-2 micrometer diameter in final ferrite microstructure for industrial rolling parameters. A user friendly software package has been developed to apply the model for off-line control of mill processing parameters, i.e., time-temperature-deformation schedule of finish rolling in order to accumulate large strain to overcome a large critical strain for dynamic recrystallisation. The model is a powerful predictive tool for grain size control in multi-pass rolling.

Jan 1, 2004

By Bobby Dupree

I remember a big problem with a seismograph in the winter two years ago. In response to a citizen’s complaint I placed a transducer near the corner of a two-story home. It was a pretty nice day for the winter months, the people were pleasant, and I had no problems digging a hole to place the transducer.

Jan 1, 2004

By F. -Z. Ji, A. G. Irons, M. Barati, K. Coley

In order to optimize carbon injection into oxidizing slags, in terms of carbon and iron yield, we must have a detailed understanding of the kinetics of the reactions involved. The current study measures the rate of carbon oxidation during injection at steelmaking temperature by means of injections of coal into EAF slags. The compositions of analysed outgoing gas were used to calculate gas flow rate and hence the gasification rate of carbon. A fundamental equation to predict residual carbon in slags was developed. The predictions using this model at moderate injection rates are in good agreement with experimental data. The reaction rate of EAF slag with carbon is under mixed control by the slag gas and the gas carbon reactions. The relative importance of each step depends mainly on the v-ratio of slags. A relative reactivity parameter ? has been defined and it is found to be important to carbon-slag reaction kinetics and slag foaming. Key words: carbon-slag reaction, kinetics, slag foaming.

Jan 1, 2004

By B M. Patterson, A J. McKinley, M E. Grassi

Large-scale column experiments were undertaken to determine the effect of a step decrease in groundwater pH on metal remediation by bioprecipitation. Metal contaminated groundwater at pH 5.5 was amended with ~1 g/L of ethanol in one column using a polymer mat ethanol delivery system to promote bioprecipitation, while another column was left unamended and used as a control. Sulfate reduction and zinc removal were observed after eight weeks. Zinc removal was observed in the zone of sulfate reduction, indicating precipitation as ZnS, while, copper was removed in the denitrification zone. Once steady state bioprecipitation of zinc had been established, the pH of the metal contaminated influent groundwater was decreased stepwise from 5.5 to 4.25. As a result of the change in pH, a significant increase in copper concentration was observed in both columns. In the ethanol column, the zones of denitrification and copper removal migrated up the column, while both sulfate reduction and zinc removal ceased. Bioprecipitation of metal contaminated groundwater via sulfate reduction was shown to be an effective remediation strategy for zinc removal. However, this in situ biological remediation process was sensitive to changes in groundwater pH.

Jan 1, 2004

By C Gormley, G Lane, J Kwak, A Hopkins

Complex processing plants present a myriad of safety issues to the design engineer. The extent to which the design engineer manages to lay the foundations for a safe plant ultimately sets the stage for life long safety performance. Industry traditionally measures engineering safety performance by indicators such as Lost Time Injuries, Restricted Work Case Injuries, Overall Incident Frequency Rates, etc. While these measures are useful indicators of performance for the construction, commissioning and operations phase of a project, they do not necessarily drive the most appropriate behaviours for Safe Plant Design. Achieving an inherently safe design requires a diligent focus on low frequency, high consequence events. First and foremost the engineering team needs to have a design culture and methodology which leads to a plant which is as close as possible to being inherently safe. Such a culture might come from an organisation that has æmindfulnessÆ about safety, and which is nurturing a culture where warning signs are recognised and addressed. This paper explores the development of mindfulness and warning signs in design.

Jan 1, 2004

By A. V. Roschin, N. V. Malkov, V. N. Karnoukhov, V. E. Roschin

Reduction interactions in solid phases are widespread and occur in most complex metallurgical processes. Among these processes, reactions between oxides and carbon have a special importance. The authors conducted experiments for comparison of reduction by different reducing agents of impregnated chromite ores, in which grains of the reducible chromite spinel are isolated from direct contact with the reducing agent by layers of non-ore material. The results of the experiments have revealed that the beginning of reduction is preceded by thermal and impurity order-disorder transformation of the oxide lattice whilst the transformation of the oxide lattice into the metal lattice takes place as a result of removal of oxygen anions from the zone of metal germ nucleation. Since anions are charge carriers, increase of their mobility can be monitored by changes in electrical conductivity of oxides. Respective measurements of electrical resistance of ores of different metals and a number of pure refractory oxides under heating have indicated that the beginning of reduction coincides with the time of drastic (tens of thousands times) increase of conductivity of the oxides. Besides, the temperature of the beginning of carbon-thermal reduction is in line with the Tammann temperature, i.e. the temperature of transition from the predominantly surface diffusion to volume diffusion. Segregation of metals from the oxide lattice occurs as a result of merging of anion vacancies with defect electrons on defects of the oxide lattice. The transformation of the oxide lattice into the metal lattice requires a certain concentration of anion vacancies and inflow of electrons from the reducing agent to the site of metal segregation. Such inflow has no difficulties due to the mixed anion-electron nature of high-temperature conductivity of oxides. Thus, the reduction is not determined by oxygen diffusion, it is determined by oxygen vacancies diffusion whose speed exceeds the speed of oxygen diffusion by orders of magnitude. This determines that the kinetics of reduction considerably exceeds the kinetics of oxidation at similar temperatures since oxidation proceeds by means of mass transfer of oxygen through the layer of the generated oxide.

Jan 1, 2004

By Lawrence W. Gubbe

Air blast associated with detonation of explosives in mining, construction or military applications is often responsible for complaints by people who live or work in the vicinity of the activity. Most often, the complaints are based on the perception that vibration caused by the airblast damaged one or more residential buildings that may be located within several hundred feet or several miles from the blast site. The potential for airblast to cause damage is related to the amplitude and frequency of the airblast overpressure wave at the receptor. Amplitude and frequency of the overpressure wave are, in turn, dependent upon the type and amount of explosive detonated; the degree of confinement; the distance the wave travels; the topography between the blast site and the receptor; and, atmospheric conditions. It is well known that, as the result of atmospheric focusing, the amplitude of airblast overpressure that exists relatively far from the blast site may be substantially higher than the amplitude associated with the attenuated wave in an isotropic atmosphere. Two methods are available to predict baseline overpressures 1) the Sandia Laboratories, Atomic Energy Commission method as extended by the Naval Ordinance Laboratory (NOL method) and the Ballistic Research Laboratory method (BRL method). These methods are developed by different techniques, are based on different idealized atmospheres and predict widely different results. The amplification factor applied to account for the effect of focusing must be consistent with the method used to predict the baseline overpressure. Theoretically, the amplitude of the overpressure at distances several miles from the blast site could be more than 25 to 100 times the amplitude of the attenuated wave predicted by the BRL method. However, based on comparisons with measured overpressure data is probably less than approximately 3 times the amplitude of the attenuated wave as predicted by the NOL method. This paper is based on research conducted as part of investigations of airblast damage complaints associated with an accidental explosion near Eveleth, Minnesota and with the disposal of military explosives by detonation at the Sierra Army Depot near Herlong, California. The techniques available for estimating the airblast overpressure that might be generated at various distances from the blast site and criteria for evaluating the potential for damage are examined.

Jan 1, 2004

By M. Reuter, C. Schuffeneger, T. Seppälä, L. Holappa

Reaction kinetics of solid-state reduction of chromite pellets (laboratory made and industrial) and lumpy ore was investigated by the thermogravimetric analysis (TGA) technique. Carbon monoxide was used as the reducing agent, with the presence of graphite in proximity to chromite. The experiments were carried out at both rising temperature and constant temperature in the range of 1450 - 1550°C. Scanning electron microscopy was employed to observe and analyse the structure and composition changes of the chromite samples. For the lab-made chromite pellets, the effects of particle size and bentonite addition on the reduction behaviour were studied. The pellet with smaller particle size gave a higher reduction rate. Bentonite addition had slightly negative effect on the reduction rate. When reducing industrial pellets, temperature and CO flow rate had positive influence on the reduction rate. Reduction of lumpy ore took place slower than reduction of a pellet. In all samples, chromite reduction proceeded longer in the outer part of the sample than in the centre part. The porosity of the chromite samples was determined before and after the experiments. The porosity of lumpy chromite increased significantly during the reduction. However, the porosity of lab-made chromite pellet decreases due to sintering effect. The reaction mechanism is discussed on the basis of experimental results and earlier investigations.

Jan 1, 2004

A physical modelling study has been carried out to simulate the slag-metal dispersion induced by a high-strength bottom gas injection. Water and kerosene were utilized to simulate metal and slag respectively. A water model of CLU (Creusot-Loire Uddeholm)vessel was used with three different nozzle orientations, namely, off-centre, triangular off-centre and centre. The gas flow rates changed from 0.00599 m3/s to 0.01081 m3/s. Height of heavy and light phases was kept fixed at 0.23 m and 0.02 m respectively. The dispersed phase hold-up was determined at various axial and radial distances, gas flow rates, and tuyere configurations. The observations revealed that at a fixed gas injection rate, as the vertical distance increased in the centerline, straight off-centre orientation resulted in greater dispersed phase hold-up values than those of the centre configuration and the triangular off-centre orientation. The dispersed phase hold-up was found to increase with gas injection rate and decreased with axial distance. The variation of the dispersed phase hold-up with the dimensionless axial distance and the gas injection rate was correlated by using the modified Froude number. The experimental values of the dispersed phase hold-up were found to be in reasonable agreement with the correlated values obtained from the modelling equations. The findings of the present study may be utilized in the ferroalloy refining vessels in terms of designing tuyere locations for optimum processing conditions.

Jan 1, 2004

By Shekhar Bhansali, Shyam Aravamudhan

"This paper reports on the design and simulation results of a silicon bulk-micromachined diaphragm-type piezoresistive pressure sensor capable of operating linearly over a wide dynamic range (0-1000 meters of water). The piezoresistor elements of the sensor are arranged in a wheat stone bridge configuration to achieve a higher output response. Simulation results (output voltage and sensitivity analysis) obtained using coupled MemPZR-MemMech module of the CoventorWare2003 Finite Element tool are presented. The effect of diaphragm size, diaphragm thickness and thickness of the piezos on output sensitivity were analyzed and optimized to get a linear response over the wide dynamic range.IntroductionThe physical and biological processes in the ocean are critically influenced by ocean parameters (pressure, salinity and temperature). Thus there is a need to develop inexpensive and reliable sensors to continuously measure large volumes of sea-space over long time spans. A key component in any such system will be a pressure/depth sensor. This sensor is routinely employed in marine applications such as wave and tide gauges, tsunami detection, platform leveling etc. More significantly, pressure measurement is needed for depth determination. Depth sensors are vital for remote operated vehicles (ROVs), profiling instruments and towed arrays.Several techniques have been routinely used in the past to measure pressure in the marine environment [1-3]. In general, the pressure sensor design is based on a flexible membrane as the spring element for the sensing pressure [4]. The deflection of the membrane, induced by the applied pressure, is converted into an electrical output through a component that is sensitive to diaphragm deflection (capacitive coupling) or associated stresses (piezoresistors, strain gauges). The temperature compensated pressure measurement can be readily converted to depth using"

Jan 1, 2004

By Nigel Fung, J. D. Humphrey, R. H. Oats, J. H. Ingle

Production dozing of cast material is a cost effective method of improving dragline or mobile equipment overburden removal. Yet dozer productivity is reduced during the part of the process that requires the dozers to cut material away from the highwall. One solution is to use a hydraulic excavator to remove this material and throw it into a windrow for the dozers. By freeing up the dozers for more productive work the overall system productivity increases 25% and cost per yard is reduced by up to 10%. Dozer fleet sizing can be determined to match a specific production schedule or can be sized to balance with an excavator’s production.

Jan 1, 2004

By Sandy Tavelli, Thomas L. Barkley

This discussion will present a case study in developing solutions to a metropolitan quarry’s public relations, legal, environmental, and productivity problems. It details an extensive and detailed project to address the blasting practice in a medium sized quarry that is surrounded by residential and industrial zones. The principle work was done over a four-month duration during the normal production season. It included detailed drilling and blasting audits for baseline information. In addition, geologic characterization, seismic modeling, correction of deviations from best practices, and implementation and monitoring of precise electronic timing to provide dramatic solutions for the quarry. The quarry is in the near suburbs of a large metropolitan city. It is framed on two sides by residential municipalities and on two sides by industrial zones. At the start of the project, the quarry was in court as a result of the lawsuit by one of the neighboring towns that was suing to close the quarry. The lawsuit had progressed to the advanced stage where in the Judge had appointed an arbitrator to make the decision of continued operation. This arbitrator was to observe our progress and recommend to the Judge the disposition of the case.

Jan 1, 2004

By Aly M. Mohammad

The Howland Hook Terminal Facility located in Staten Island, New York is one of the most active container terminals in the Northeast United States. Due to the high capacity of the facility, the Port Authority of New York and New Jersey (PANYNJ) recently acquired the adjacent 37-acre Port Ivory Facility. Expansion of this Site facilitates the additional transfer of goods for rail transport, where formerly the facility was solely highway transport. Upon completion, the facility will have the ability to transfer containers directly to a freight rail line onsite by crossing from Howland Hook Site to the Port Ivory Site via a proposed bridge over Bridge Creek. The geology of the Port Ivory Site consists of shallow glacial deposits left by the leading edge of the last advance of the Wisconsin Glacier. Glacial and marine action over the millennia and the modifications of past construction combined to form a challenging site geologically. Prior to the PANYNJ acquiring the site, the Port Ivory Facility was occupied by Proctor and Gamble for nearly 100 years. Over the course of time, the site has had a variety of structures constructed and demolished at the site. The earliest structures were often supported on shallow foundations and the foundation types used progressed over the years transitioning from low capacity timber piles to various new pile types as they became available; such as Raymond tapered piles, steel piles with concrete cores, precast piles and cast in place foundations. Currently, we are designing 4-foot diameter high capacity drilled shafts to support a new bridge over Bridge Creek to connect the two sites. Drilled shafts proved to be a very economical solution from both a design and construction point of view to carry the axial load of the bridge of approximately 400 tons per shaft. The paper will present a historical evolution of the progress of deep foundation types used at the Port Ivory Site; from low capacity timber piles to high capacity large diameter drilled shafts. The paper will also present changes and modifications of geotechnical design criteria over time that affects the type of deep foundations used. For instance, utilizing new seismic design criteria requires selecting a deep foundation system that withstands seismic loading conditions and overcomes the effects of liquefaction.

Jan 1, 2004