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By A. D. Pelton, Y. -B. Kang, S. A. Decterov

Computerized thermodynamic databases for solid and liquid metal, slag and solid oxide phases in the Al2O3-CaO-CoO-CrO-Cr2O3-FeO-Fe2O3-MgO-MnO-NiO-SiO2-S system have been developed by critical evaluation/optimization of all available phase equilibrium and thermodynamic data. The databases contain parameters of models specifically developed for molten slags, liquid steel and solid oxide solutions such as spinels, pyroxenes, olivine, monoxide (wustite, periclase, lime), corundum, etc. By means of the optimization process, model parameters are found which reproduce all thermodynamic and phase equilibrium data within experimental error limits. Furthermore, the models permit extrapolation into regions of temperature and composition where data are not available. The databases are automatically accessed by user-friendly software that calculates complex equilibria involving simultaneously slag, metal, refractories and gases, for systems with many components, over wide ranges of temperature, oxygen potential and pressure. A short review of the available databases is presented. The critical evaluation/optimization procedure is outlined using the Al2O3-CaO-FeO-Fe2O3-SiO2and Al2O3-CaO-MnO-SiO2systemsas examples. Several applications of the databases to deoxidation of iron and to inclusion control in steel are discussed. Keywords: thermodynamics, phase equilibrium, phase diagrams, databases, ferrous metallurgy, steelmaking, inclusion control, slags, oxide systems.

Jan 1, 2004

By M. A. W. Bryson

Platinum group metals are extracted almost exclusively in South Africa from three very different zones in the Bushveld Igneous Complex, called the Plat, Merensky, and the UG-2 reefs. The Plat reef is currently being exploited only by Anglo American Platinum, whereas the Merensky reef is exploited by them, Impala Platinum, Northam, and Lonplats. The UG-2 reef, on the other hand, is also processed by these producers, but Kroondal and Barplats have operations that exclusively treat ore from this reef. At present the extraction of pgms from ores in South Africa follows the traditional route of upgrading to a concentrate in a minerals processing circuit, further upgrading to a matte in a smelter, and final upgrading and separation of the individual metals in a refinery. Thus all operations that extract pgms require a minerals processing circuit, the design and performance of which is a topic of much interest, as it is a poorly understood and not a very efficient process in relative terms, compared to the other processes. Recoveries across the minerals processing circuit of between 75 and 90% are the norm.

Jan 1, 2004

By Guillaume Blanc

The development of marine mining in the offshore areas adjacent to most of the insular and continental European States is limited by the complex and evolving nature of its legal regime on the basis of the relevant applicable international, European and domestic rules. As the development of marine mining requires investments in capital-intensive technologies, the bankable feasibility of marine mining projects is very much dependent on the legal security of mining rights, assets and operations in offshore areas. This is quite difficult to assess due to the constant accumulation of applicable and potentially conflicting international and domestic laws in these areas, in particular the coastal zone, the territorial sea, and the Exclusive Economic Zone (EEZ). The often conflicting interaction of international treaties, laws and regulations in offshore areas raises specific and major issues in terms of permitting processes, access rights, ownership rights over the mineral resources explored and mined, flag vs. coastal State jurisdiction over mining vessels and marine mining equipment, international environmental liabilities, and unitisation and multi-forum disputes. In addition, the determination of jurisdiction and the legal regime under which marine mining could take place is becoming even more complex with the development of EU Law and the recent revision of the International Law of the Sea, particularly the new extension regime of the EEZ and jurisdiction over the continental shelf.

Jan 1, 2004

Airblast overpressure legislative limits can be extremely difficult to meet throughout Australia, which has by far the most stringent limits of any nation in the world. As the difficulty in meeting the limits is strongly dependent on the scale of mining, it is not surprising that the Australian coal mining industry is experiencing particular difficulties in meeting these limits. Eight full scale overburden blasts have been modelled with respect to overpressure impact for a strip coal mine, involving both dragline (cast) blasting and pre-strip (non-cast) blasting. Overpressure levels in the range 100 to 125 dBL have been measured at distances varying from 2.4 to 5.7 km, and modelling has successfully estimated both the amplitude and shape of overpressure waveforms to within an average of 1.2 dBL. Typical errors of prediction are around 0.6 dBL. This accuracy of prediction has been achieved by considering the impact of only the face holes, and the accuracy of prediction of both shape and amplitude suggests that it is these holes which dominate the environmental overpressure impact at distances in the range two to six kilometres, for cast and pre-strip blasting operations. Modelling has been based upon the Elemental Overpressure Wavelet proposed by Richards and Moore (2002), incorporating actual hole coordinates, actual delay timing, and assumed delay scatter statistics. The incorporation of delay scatter statistics has been particularly significant, and allows the determination of the range over which the peak overpressure levels are expected to vary. To date, modelling has considered only the use of conventional pyrotechnic delays, though simple adjustment to the scatter definition would allow estimation of overpressure levels, and their variability, with electronic delays.

Jan 1, 2004

By Lisa Burke

In underground coal mines, concrete block stoppings are widely used to control mine ventilation. Although stoppings are not intended as roof support, they are subjected to roof to floor convergence, and may fail as a result of this loading. Premature failure of stoppings can significantly affect mine ventilation, limiting the amount of fresh air reaching the working faces and increasing the risk for methane explosions. Softening materials are often used in stoppings to reduce the damaging effects of roof to floor convergence. However, to date, research has not focused on the behavior of stopping construction materials subjected to roof or floor loading, leaving the design process to trial and error. A combination of numerical simulations and large scale physical tests were employed to develop a scientific understanding of stopping performance. The first series of physical models were constructed using standard CMU (concrete masonry unit) blocks and tested in a load frame. The behavior of these walls was simulated with a distinct element model. A key finding was that very small variations in block size and irregularities in block shape significantly affect wall performance. These variations, which are inherent to the type of blocks typically used underground, create stress concentrations that initiate the failure of stopping walls. A second series of models employed concrete stoppings that incorporated woos planks, a shredded wood material, and foam planks like those commonly used underground. Numerical models were again able to match the physical test data. Analysis of the softening layers used in stopping construction indicated that the strength and stiffness of the material relative to that of the wall is crucial in determining the amount of roof to floor convergence the wall can withstand prior to failure. The product of this study is a numerical model that can be used to evaluate the performance of stopping materials and different wall geometries in a controlled environment. Testing was done in a laboratory setting with walls constructed on flat, parallel surfaces and subjected to uniform loading at a constant rate. Parametric studies with the model indicate that in this ideal environment it is possible to control the amount of vertical displacement the stopping can withstand by adjusting the number of softening layers built into the wall and the thickness of the layers. Additionally, under these conditions, the position of softening layers within the wall appears to have little effect on the amount of displacement walls can withstand prior to failure.

Jan 1, 2004

By Jim Bruce

This paper presents details of a slope stabilization scheme built in late 2003 at a 16m-high railway embankment in southern Ontario, Canada. The owner, faced with continuing maintenance and safety issues arising from numerous nuisance slides, and residential neighbors in close proximity to the slope, sought new proposals to replace a previous recommendation to cut down all trees and undertake a deep soil nailing scheme. A non-reticulated micropile array with surface cap beam was proposed and built on the south side of the embankment with no tree removal required. A detailed FLAC analysis was completed, using multiple iterations to arrive at the eventual, optimized micropile depth and spacing. Analysis predicted an 18% increase in the factor of safety. Short term inclinometer monitoring and performance evaluations in the months since construction so far corroborate the prediction.

Jan 1, 2004

By S. Luyckx

This paper reports hardness and abrasive wear resistance test results from a wide range of WC-Co alloys, varying in cobalt content as well as WC grain size. The results show that the abrasive wear resistance increases with increasing hardness and that the rate of increase is higher for larger WC grain sizes. The increase in abrasive wear resistance was found to be parabolic up to a critical hardness value and exponential above that value. The transition from parabolic to exponential behaviour was found to occur at the same contiguity value for all grain sizes, which suggests that at that contiguity value the WC skeleton becomes continuous in all WC-Co alloys.

Jan 1, 2004

By J. Härkki, R. Hiltunen

The Akanvaara intrusion (surface area 50-55 km2) in Savukoski, Northern Finland, hosts 23 distinct monocumulate layers of small euhedral chromite crystals enclosed in a silicate matrix. These chromitite layers have been divided into four groups; UC (upper chromitite), ULC (uppermost lower chromitite) LC (lower chromitite) and LLC (lowermost lower chromitite). The driving force for investigating the Akanvaara chromites and their reduction behaviour originated from their very low MgO content and relatively low Al2O3 content, giving them a unique quality which based on thermodynamics should facilitate the reduction. Another interesting feature is the high amount of V2O3 present especially in the upper chromitite. The chromites included in this study are from the UC and ULC layers (24.9 and 22.7 per cent Cr2O3 respectively). To obtain a better understanding of the reduction behaviour of Akanvaara samples in comparison to MgO-bearing chromitites, Kemi chromite from the ferrochrome works in Tornio, Finland, was included in the study as a reference sample. The reduction experiments were isothermal in a temperature range of 1000-1400°C in CO atmosphere. Experiments were also conducted with coke addition in pellets and briquettes in CO/Ar/H2 atmospheres. The results of the reduction experiments complemented with microanalytical research indicate that the Akanvaara chromites do reduce to a higher degree than the Kemi chromite. Although the aim was to characterize the mechanisms of reduction focusing on gas-solid reactions, the nature and amount of the gangue minerals was such that a considerable amount of slag phase was formed, which affected the reduction mechanisms extensively. The structural features together with low MgO and high FeO content in both Akanvaara chromites are important factors resulting in better reducibility than in the Kemi chromite.

Jan 1, 2004

By J R. Robinson

Prior to mine development, exploration drilling within the Luise Caldera on Niolam Island encountered gold mineralisation to the northwest of the main Minifie and Lienetz orebodies. This mineralisation was referred to as the Kapit orebody, and ten diamond drill holes were subsequently completed over the area to investigate its economic potential. Several significant mineralised intercepts were returned. These were interpreted using the orebody model developed for Lihir at that time which invoked a strong horizontal control to mineralisation. Additional consideration was given to the elevated geothermal temperatures encountered, the proximity of the mineralisation to the ocean, and its perceived depth below sea level, resulting in the Kapit area being given a low priority for follow up investigation. As a result, no further work was completed over Kapit until recently. The Kapit orebody was the target of an intense diamond drilling programme during 2002/2003. Data from this latest round of drilling has significantly improved understanding of the mineralisation and associated geology. The significant orebody now delineated at Kapit substantially differs from past interpretations, and the latest data has upgraded its economic potential. A resource estimate and other critical studies completed in 2003 enabled an updated reserve statement to be issued in February 2004 including the Kapit mineralisation for the first time. Total Probable Reserves at Kapit stand at 25.2 million tonnes (Mt) at 5.28 grams of gold per tonne (g Au/t), for a total of 4.3 million ounces (Moz) of contained gold.

Jan 1, 2004

By TA Louw, Dr CM Lownds

In an era where profits are constantly being eroded, mines are looking towards technology developments to assist them in solving mining problems and reducing mining costs. An emerging technology that could assist mines in becoming more cost effective is electronic detonators. Electronic detonators have been under development for several years. Over the past three years, the spotlight has fallen on commercial use of electronic detonators and the extent to which the promise of precise and programmable timing can assist mines with their environmental and productivity problems. This paper uses case studies to demonstrate both surface and underground applications where electronic detonators and blasting systems were used to solve typical mining problems such as vibration and fragmentation. Safety aspects such as hanging wall conditions and high wall stability also benefited from the use of electronic detonators. The paper also demonstrates how the use of accurate electronic detonators and blasting systems has resulted in improved/more even fragmentation with further downstream efficiencies. These efficiencies may include increased cast percentages, reduced oversized rocks, quicker cleaning times and increased production rates.

Jan 1, 2004

By R Berthelsen

The Peak Gold Mines Pty Ltd (PGM) operations are located approximately 9 km south of Cobar, NSW. PGM currently mines and treats ore from three separate orebodies within 5 km of the original plant. Production from the original Peak orebody ceased in April 2002, with ore currently sourced from underground at New Occidental and Perseverance, while New Cobar supplies ore from an open cut mine. In March 2003, Wheaton Minerals Asia Pacific purchased the operation from Rio Tinto who operated the mine for around ten years. The Perseverance deposit is situated between 600 and 1000 m south of the Peak orebody. Access is via shaft from Peak to 630 m below surface and then by decline to the northern end of the deposit locally known as Zone A. Development of the resource commenced mid 2002 to set up for a long hole open stoping operation at 25 m level spacing. The first production stope was successfully brought on line December 2003. The Perseverance deposit is hosted by sediments and volcanics along the eastern margin of the Devonian Cobar basin and is one of many deposits with the Cobar Gold Field. The Cobar Gold Field has produced approximately 2.5 million ounces of gold since 1880. The Perseverance area had long been considered prospective due to the presence of old workings at the southern extensions of Peak line of lode. Significant mineralisation was first discovered at Perseverance in 1994 when PGM drilled a hole targeted 950 m below the historic workings. The target was based on an apparent plunge to the stratigraphic controls to the Peak Orebody. Subsequent exploration within and around the ægreaterÆ Perseverance area has been significantly aided through the use of downhole electro-magnetic surveys due to the close spatial association between gold and sulfide mineralisation.

Jan 1, 2004

By V. L. Ketellapper

This paper discusses the technical issues and stakeholder collaborative processes which resulted in achieving a balance between the reclamation of abandoned mine sites, providing affordable housing, and preservation of open space at the French Gulch Site. Through this process, it was discovered that mine site reclamation would need to be conducted in conjunction with two priorities for community sustainable development: providing affordable housing for locals who work in the resort town of Breckenridge, and open space preservation. It was found that conducting these activities concurrently would result in providing resources necessary to complete mine site reclamation. The first phase of the affordable housing development is almost completed. This development resulted in redevelopment of mining impacted lands and was recognized by the U.S. Environmental Protection Agency (EPA) with a National Smart Growth Award in 2002.Negotiations are also underway to preserve the remaining 1,800 acres of land held by the mining company as open space. This transaction will in turn provide resources to address water quality issues associated with mine discharges.

Jan 1, 2004

By A. J. Abraham, K. E. Seitz, J. D. Humphrey

Caterpillar has led the way for sound reduction in off highway trucks (OHT) used for mining. In 2000 Caterpillar introduced the 793CXQ sound reduction OHT (Figure 4) to meet local noise level demands in the Hunter Valley near Sydney, Australia. The sound level of the mining equipment in the Hunter Valley is being reduced to pre-serve the quality of life for the residents of the area. To meet the levels established required a major redesign of the 793C, as a result the sound power level was reduced by 9 dB (A), which is a less than 1/8the original sound level.

Jan 1, 2004

By Y. P. Chugh

About 60-70% of the underground mined coal in Illinois is extracted using a room-and-pillar mining method that permits extraction of about 50% of the coal. The remaining coal is left behind in the form of support pillars to control surface and subsurface movements. Illinois coal seams are typically associated with water sensitive weak floor strata whose thickness varies 0.31 - 1.3 m. The current mining geometry mostly uses pillars of constant size within a mining area. This traditional practice suffers from the disadvantage that pillars within the center region are subject to much higher loads than the pillars located on the outer edges of the panel. This results in a higher incidence of rib spalling, and roof falls, creating a potentially hazardous work environment. In addition, this concentration of loading at the center of the panel provides initiation points for floor failure to occur. The primary goal of this study was to reduce ground control problems and production costs in Illinois mines by considering alternate mining geometries. The development and subsequent field demonstration of an alternate geometry is presented in this paper.

Jan 1, 2004

By William R. Yernberg

The 26th Peruvian Mining Convention (Convención de Ingeneieros de Minas del Perú) was held Sept. 15 through 19, 2003, in Arequipa. The convention was sponsored by the Peruvian Institute of Mining Engineers (Instituto de Ingeneiros de Minas del Peru). The Institute has been organizing these events since 1954. They are now held every other year. The conventions spotlight Peru’s mineral resources and have contributed to the tremendous growth of the Peruvian mining industry. This year’s meeting consisted of technical sessions, forums, field trips and social activities. It was held at the Tecsup Institute of Technology of Arequipa. More than 3,000 mining professionals attended. As always, the meeting was well organized, and participants expressed gratitude to the organizing committee for another successful meeting.

Jan 1, 2004

By Adrian J. Moore, Alan B. Richards

Responsible blasting requires that rock throw be controlled to ensure that no danger will result to people and property. This paper describes the development and testing of empirical field calibrated formulae that can be used to evaluate rock throw, provide an early warning of when reduced burden will endanger people and property, and prevent flyrock incidents. Inputs to the formulae are charge mass, burden or stemming height, and a site constant that lies within a general range that can be tightened by site calibration. The output is the distance that rock will be thrown, and this ‘design your own flyrock’ quantification can be used to establish both safe clearance distances, and the critical range of burdens and stemming heights where the situation changes rapidly from safe to hazardous. Examples are given of the use of the model to control flyrock in open-pit mining and quarry operations, in situations which are controlled by both burden and stemming height.

Jan 1, 2004

Since the 1970s we have seen a marked corporate response in terms of the environment. In part this has come from regulation but it has largely come from stakeholders and the community. We now see a similar trend towards sustainability. The Brundtland (1987) definition of sustainable development provides a direction for advocates: the advance of human prosperity in a way that does not compromise the potential prosperity and quality of life for future generations. In my view its three essential components are: economic, environmental and community. The Global Mining Initiative and the contributions to the Rio World Summit and the Johannesburg World Summit on Sustainable Development indicate that sustainability is being taken very seriously by the mining industry. But does the minerals industry really embrace sustainability as they claim? There is a view that in reality sustainability is a non-event and that the triple-bottom line approach is only a convenient catch-cry for companies who are actually focussed very strongly on the economics part of the equation. Chemical engineers are showing a strong trend to more sustainable practices and the chemical industry has shown real commitment to research into developing sustainable processing systems. This requires a framework for thinking and design and the chemical industry is demonstrating true innovation as it moves towards æno wasteÆ technologies. Whilst there are limits to the rates of change that can occur the minerals industry should also be moving in a much more determined manner towards the notion of processing of products designed for whole-of-life cycle û with minimum/no waste. But is the minerals industry just paying lip service to the importance of research to sustainability?Several common themes influence the science and innovation agenda in Australia, which will affect the development and adoption of innovations by AustraliaÆs minerals sector. First is the well-proven link between peer-reviewed scientific excellence and commercial application. Second is the rise of multi-disciplinary Mode 2 research, which has developed in response to the complexity of problems faced by contemporary researchers, which are best analysed by combining expertise from two or more disciplines. Successful innovation outcomes, in any field, including minerals processing, is promoted by Mode 2 research which benefits from greater levels of networking and collaboration. Kofi Annan in his Message to the World Social Forum puts it very succinctly æThe way forward lies in finding constructive solutions togetherÆ.

Jan 1, 2004

By S. Kahraman, K. Develi, E. Yasar

Four hydraulic top hammers, one pneumatic top hammer, and three down-the-hole drills were observed in several rock types at quarries and highway construction sites to measure the performance data. At the same time, drill cuttings from each drill hole were collected for the determination of the coarseness index (CI), which is the sum of cumulative weight percentages of a particular size-graded sample of debris, and for the determination of median particle size (MPS), which is defined as the particle for which the quantity of particles equals 50% of the total of the cumulative distribution. After the sieve analysis was carried out on the drill cuttings in the laboratory, CI values were calculated and MPS values were obtained from the plots of cumulative undersize vs particle size. The performance data of the drills, CI values, and MPS values were analyzed using the least square regression method. It was seen that strong linear relationships usually exist between penetration rates and CI values, and penetration rates and MPS values for both top hammer drills and down-the-hole drills. Penetration rates increase linearly when increasing the CI and MPS values.

Jan 1, 2004

By D-J Min

Strategies and achievements in the Asian steel industry to construct industrial ecological chain are reviewed largely in the case of Japan, Korea and China. Emphasis is placed on the development of resource circulatory system for the minimisation of various wastes and emissions of green house gases (GHG), toxic gases and polluting particulates. The minimisation includes:Rationalisation of iron and steelmaking processes; Implementation of available relevant measures/technologies; Life cycle assessment in designing steel from semis to assembled products; Reduction, reuse and recycling of materials and energies; and Utilisation of core competence technologies to process domestic and industrial wastes. In view of global nature of the above wastes- and emission-issues, inter-industrial linkage and international cooperation across the borders in the Asian countries have become more important. Inter-industrial linkage definitely serves to cut back the wastes and emissions. Examples of such linkage and factors influencing the sustainability of the linkage are described with expectation for further development of the linkage. Importance of international cooperation cannot be overstressed under the circumstances where steel production in China exceeded 220 Mt and world production exceeded 945 Mt in 2003 and is still increasing. Practical measures are discussed to enhance the linkage and cooperation for effectively promoting the reduction, reuse and recycling, including implications for the nonferrous industry.

Jan 1, 2004

By M. Jahazi, M. Brochu

This paper describes the advantages/disadvantages of electron beam freeforming using two different types of filler metal: (1) brazing paste and (2) solid wire. Sound buildups were obtained from both filler metal. The freeforms produced with the brazing paste showed a certain level of porosity, which was reduced by successive melting. In comparison, the solid wire buildup was practically free of pore. When compared with the solid wire filler, the brazing paste produced narrower buildups but a larger scattering of the width.

Jan 1, 2004