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By Ronald F. Ayers

The study upon which this paper is based was completed by Battelle's Columbus Laboratories for the U.S. Army Corps of Engineers in 1974. It is but part of an overall effort by the Corps to evaluate the costs and benefits to the nation of waterway improvements. This study is primarily concerned with future coal markets for production from those counties near the Wabash River in the heart of the Eastern Interior Province. An objective here is to consider a most pessimistic energy (and hence, coal) demand for planning purposes.

Jan 1, 1976

By R. D. Hutchinson

I consider it an honour to be the opening speaker in this afternoon's session on "Canadian Exploration". I also think it most appropriate that this joint meeting of the MMIJ and AIME should consider this subject, because Canada is a major exporter of mineral products and Japan and the United States are our two largest customers. Clearly, therefore, both countries have a valid interest in developments on the Canadian minerals scene. I represent the Mineral Development Sector of the Canadian Department of Energy, Mines and Resources. I will therefore speak from the point of view of the Federal Government. At this point I would like to acknowledge the help and constructive criticism I have received from several of my colleagues in Mineral Development Sector in the preparation of this paper. In any discussion of exploration in Canada, it is essential to emphasize at the outset that Canada has a federal system of government, with powers shared between Ottawa and the provinces. Under our constitution, the federal government has jurisdiction over the north, and over offshore areas, while the provinces own the natural resources within their boundaries. They control the systems of land acquisition for exploration and the terns under which mining titles are issued, and are therefore able to determine the rate and conditions of exploration and development of these resources. It follows that the Federal Government can influence the exploration and development of the provincial resources only indirectly by consultation with provincial authorities. However, once the resources are developed and begin to flow to market, the Federal Government can exert a much stronger influence because of its constitutional right to control both inter-provincial and international trade, as well as through its general fiscal and tax powers.

Jan 1, 1976

By David J. Dunn

Mill liner design is an important factor in grinding. Testing and selection of the optimum liner profile for a given set of mill operating conditions can improve mill capacity, liner life, and liner wear rate At a time when mill avilability is at a premium, production costs are going up, and lead time for mill liner castings is a year or more, the mill liner that grinds best, lasts longest, and costs least is a necessity for economic mill operation. In testing four mill liner profiles for 13' x 12' overflow ball mills, Climax found that an improved design increased mill tonnage by 3 tons per hour while reducing finish grind by 1.7% + 100 mesh, reduced liner wear rate, and almost doubled liner life.

Jan 1, 1976

By William A. Rehrig

During recent years, there have been frequent investigations on the geochemistry of biotite. This work has emphasized, and no doubt was prompted by, factors related to mineral exploration, particularly for those deposits of the porphyry copper type. A large number of papers have been devoted to the obtainment of trace-element data from plutonic biotite. These data have been used to extract primary geochemical information pertaining to the parent magna and the hydro-thermal system which together give rise to porphyry copper deposits. In two early works, Putman and Burnham (1963) and Parry and Nackowski (1963) analyzed base metal contents of ferromagnesium minerals, primarily biotite, from various barrenfmineralized plutons of the Basin and Range Province. One similar conclusion from the two studies was that the Cu, Zn, and Pb contents of magmatic biotite served as indicators of ore development within the granitic rocks genetically related to ore. This theme was then pursued vigorously by a number of authors until the present time. Results, however, have been contradictory, as reviewed by Coope (1974). For example, studies by A1 Hashimi and Brownlow (1970), Lovering et a1 (1970), Putman (1972), and Graybeal (1973) continued to support positive primary relationships between the trace-metal content (usually copper) of biotite and associated sulfide mineralization. By studying biotite in close spatial association will sulfide occurrences, Putman (1972) and Graybeal (1973) developed models for base metal partitioning in magmatic systems based on their discovery of inversely distributed copper between silicate (biotite) and sulfide phases. Conversely, research by Bradshaw (1967) and Blaxland (1971) plus the recent findings of Parry and Jacobs (1975) and Kesler et a1 (1975) found little if any evidence to support a correlation of biotite base-metal or

Jan 1, 1976

By Carl F. Wingquist

Electrical resistance heating to effect thermal fragmentation of semiconductive rock was examined by the Bureau of Mines. Tests were carried out on copper-bearing ores of the Nonesuch Shale Formation in the laboratory and in the the field at White Pine, Mich. Fieldwork included primary and secondary breakage tests. Heating tests on in situ rock failed to produce thermal dam-age to an extent considered useful; however, boulders up to 30 ft3 were effectively broken by the method. Power input to the test rock was taken from a 50-kV, 5-amp dc power supply.

Jan 1, 1976

By T. B. Braun

Cathode contamination is the principal factor affecting the quality of electrorefined copper. It is commonly accepted that annealability is unfavorably affected by the following elements, in decreasing order of adverse effect: tellurium, selenium, bismuth, antimony, and arsenic. Silver in cathodes has importance as it represents a nonrecoverable loss of silver to the refinery. Mechanisms for the contamination of cathodes by these elements are examined and the effect of operating variables on contamination, including anode composition, electrolyte composition, electrolyte temperature, addition agent practice, and electrolyte discard rate, are discussed.

Jan 1, 1976

By G. W. Murrie

A geologic study of the Mary Lee Group of coalbeds in the Black Warrior coal basin was undertaken to examine coal stratigraphy and determine regional trends and extent of the coalbeds. The area investigated encompasses 835 square miles in Jefferson, Walker, and Tuscaloosa Counties, Ala. More than 700 core logs were used to construct a structure map, coal, interval, and overburden isopachs, and cross sections. There is evidence that structure affected sedimentation. Coalbed isopachs indicate the Mary Lee Group was deposited in fluvial-deltaic and low-lying coastal plain environments. The Mary Lee coalbed is the only coalbed which is continuous throughout the area, commonly with two benches which have a combined thickness of 2 to 12 feet. The Mary Lee coalbed changes rank in the basin from high-through medium-to low-volatile coal. The methane gas potential of the Mary Lee Group coals is estimated to be greater than 1 trillion cubic feet. There is an excellent correlation between the orientation of surface cleats with those measured underground in the Mary Lee coalbed. The face cleats roughly parallel the axes of the area's folds and trend northeast-southwest.

Jan 1, 1976

By W. P. Diamond

Coalbeds exhibit a directional permeability, with the maximum permeability oriented parallel to the face cleat. Thus, the most efficient pattern of vertical degasification holes for a coalbed is dependent upon cleat orientation. Surface joints, infrared photolinears, and Ronchi grating photolinears were investigated as potential estimators of subsurface cleat orientation. Cleat orientations were measured in 18 mines, in the Pittsburgh coalbed in southwestern Pennsylvania and northern West Virginia to be used as a standard against which prediction techniques would be evaluated. Two cleat systems with a strong geographic segregation were measured in the study area: N 670 W -N 280 E (950 separation) for the north, and N 76° W -N 17° E (930 separation) for the south. Directional data obtained from the three techniques investigated yielded satisfactory regional predictions of cleat orientation. Analysis of surface joints was the only technique considered sufficiently reliable on a local basis. Prediction of cleat orientation is based on the pairing of the principal directional sets into all reasonable combinations of fundamental systems. The system or systems composed of the most dominant sets nearest to 90° separation are likely to be a reliable prediction of cleat orientation. The most dominant set of the system selected is likely to be the face cleat.

Jan 1, 1976

By Wayne R. Hopkins

Southern Arizona has one of the world's principal concentrations of copper ore bodies. Twenty miles south of Tucson, close to the Mexican border at Sahuarita in Pima County, is the Twin Buttes mine. In mid-1973, the Anaconda Company and American Metals Climax Incorporated (AMAX) established a 50-50 partnership to operate and expand the Twin Buttes property. Anamax Mining Company was established as the operating company for this joint venture. The production from the Twin Buttes mine is shared between the two partners who market independently. A major expansion of the Twin Buttes operation has included an accelerated stripping programrne for the pit, an expansion of the sulphide concentrator, the construction of an oxide leach plant and a 57 MW diesel generating power station. Part of this major expansion, the large tonnage oxide processing plant was brought on stream in 1975 and is now close to design capacity. The "mine to market gap" has been closed by producing high-purity copper cathodes at the mine site from oxide ore reserves. By using a hydrometallurgical process route, copper production is possible with negligible effects on the environment.

Jan 1, 1976

By R. P. King

Flotation plant simulation, a relatively recent methodology in mineral processing, is defined and corresponding uses are discussed. Typical simulation structures are compared. Current problem areas exist although these are not insurmountable. Following a brief state of the art discussion, the N. I. M. simulation program is reviewed. In general, digital plant simulation is expected to be of substantial benefit in the near future.

Jan 1, 1976

By Belcher C. B

A simple gravimetric procedure was developed for the rapid determination of carbon dioxide in coal mine roadway dust samples and the result is used for the subsequent calculation of incombustible matter contentaccording to the requirements of the Queensland Coal Mining Act. The carbon dioxide is determined through loss of mass by a semi-enclosed apparatus, following room-temper.ature hydrochloric acid attack on the sample.With a sample containing 36 per cent carbon dioxide, the achieved standard deviation (ls) of 0·3 per cent CO. is adequate for coal mine roadway dust analysis.This simple procedure enables relatively unskilled labour in mine laboratories, to analyze coal mine roadway dust samples in accordance with the Act. Some 50 analyses can be achieved per day compared with 8 by the Australian Standard Method for coal.

Jan 1, 1976

By S. R. Rao, J. Leja, K. S. Moon

A prolonged grinding of sulphide ores in steel mills appears harmful to flotation recovery and selectivity whenever xanthates are used as collectors. Particles finer than about 10µm show a pronounced decrease in floatability. A supposition was made that the cause of the reduction in floatability of ground sulphides is the presence of metallic iron abraded during grinding and deposited on the ground particles. Electro- chemical measurements were made of mixed potentials developed by different sulphide-mineral electrodes (galena, chalcopyrite, pyrite, marmatite, pyrrhotite) in xanthate solutions, without a direct con- tact or in contact with a metallic iron electrode. These measurements showed that without a galvanic contact between the sulphide and the iron, the values of mixed potentials were in the vicinity of the xanthate/dixanthogen redox potential. When contact with iron was established, the mixed potentials shifted towards the more negative reducing or cathodic values. The shift was greater the higher was the ratio of the surface areas: iron electrode to sulphide electrode. Further, the shift in mixed potentials was greater the more reducing were the conditions on the sulphide electrode. Chemical analysis of reaction products produced on the surfaces of sulphides and in the bulk solution showed that less thiosulphate was formed in all of the sulphide-xanthate systems and that more elemental sulphur was detectable on the pyrite and marmatite surfaces. Adsorption of xanthate parallels the amount of thiosulphate formed with which xanthate is exchanged by metathesis. If the supply of oxygen is limited, the demand for oxygen by the abraded metallic iron competes with that by the valuable sulphide, resulting ultimately in poorer hydrophobicity. If excessive amounts of pyrite or pyrrhotite are present as well, the conditions are so reducing that there is little adsorption of xanthate ions on the valuable sulphides to make them hydrophobic and floatable. The presence of increased quantities of sulphur on pyrite or marmatite is responsible for a non-selective flotation. Flotation tests on synthetic mixtures with and without metallic iron powder in the feed confirmed the above conclusions from electrochemical and chemical measurements.

Jan 1, 1976

The aim of this paper is to examine the problems confronting the planner, designer, constructor and management when rehabilitating the works associated with road building- and including quarry and borrow areas. The importance of further investigation into the many factors involved, including species, methods of planting and aftercare is stressed as is the need for trained personnel and the consequential availability of specialised training courses. Emphasis is placed upon the relevance of a rational and unemotional approach to rehabilitation with respect to the landscape and to the high degree of co-ordination and co-operation between all disciplines involved.

Jan 1, 1976

By D. W. Fuerstenau, S. Raghavan

This paper presents a brief summary of some of the thermo- dynamic aspects of flotation processes. Thermodynamic considerations that control interfacial and wetting behavior in mineral/water/air systems are discussed. Particular attention is given to the thermodynamics of collector adsorption.

Jan 1, 1976

By C. G. Palagi, S. S. Stillar

The C. E. Weed concentrator treats 51,000 tons per day of 0.5% to 0.7% copper ore received from the Berkeley Pit, the Continental East Pit and the Butte underground mines. Improved operating techniques and conversion from semi-autogenous secondary grinding to ball milling have increased tonnage from an original design of 42,000 tpd. Separate treatment of sands and slimes, with recovery of soluble copper from the slimes, has increased total copper recovery. Concentrator tailings are pumped 600 vertical feet and 20,000 horizontal feet for disposal.

Jan 1, 1976

By Han Kook-Nam, Lawson F

The recoveries of the three cobalt minerals in the Mount Cobalt deposit, cobaltite CoAsS, erythrite CO3(AS04)8H20, and new cobalt mineral with a composition approximating 2CoO.CaO.Fe203.2As205.11H2O were investigated using physical and surface-chemical processes.Over 80 per cent cobalt recovery was achieved by tabling a cobaltite-mineralized sample, while about 76 per cent cobalt recovery was obtained by dry feed magnetic separation of a sample containing erythrite and the new cobalt mineral. The resultant primary magnetic concentrate with a cobalt grade of 5.5 per cent, was able to be upgraded to 14.4 per cent cobalt by regrinding .and a further magnetic separation.Electrophoretic mobility - pH responses for each of the three cobalt minerals were found to be similar. Each mineral remained negative over the pH range 3 to 11 and was most negative at mildly alkaline pH values.Cobaltite was floated effectively with amyl and ethyl xanthate collectors under acidic conditions at collector concentrations of 10-2M to 10-5M. Erythrite showed a similar flotation response using 10-sM amyl xanthate. The practical application of these laboratory separations to an industrial process is suggested.

Jan 1, 1976

By Albert J. Shohet

The increasing scarcity of bentonite coupled with the potential of improved pellet strength have created a need for understanding the effects of thorough bentonite dispersion in taconite concentrate. It has been known for more than a decade that under certain conditions substantial savings of bentonite are realizable by using thorough mixing of bentonite as compared to poor mixing. Extensive work done by J. O. Zetterstrom l at the Univer¬sity of Minnesota indicated the effect of thorough bentonite mixing in a controlled laboratory testing. Commercial hardware was not available at the time Zetterstrom1 paper was published and not much work was done until R. L. Stone, J. M. Karpinsky2, did work with Muller mixing. Nabush 3 worked with the pugmill principle, and Hoogovens 4 and Robe River 5 used the fluidized bed principle. It was very hard to convince iron ore industries to improve the mixing of Bentonite and taconite for the following reasons: A. The initial capital investment for improved mixing equipment; B. The relatively low bentonite cost a few years back, which was not enough to justify new equip¬ment investment;

Jan 1, 1976

By J. C. Irvine

Meramec Mining Company is a joint venture by Bethlehem Steel Corp. and St. Joe Minerals Corp. which mines and pelletizes iron ore at the Pea Ridge Mine. The Pea Ridge property is located near Sullivan, Missouri, about 70 miles southwest of St. Louis. The orebody was delineated in the mid-1950's by St. Joe during a lead exploration program. The first test holes drilled on the Pea Ridge magnetic anomaly revealed the presence of a large magnetite deposit; further drilling in 1956 and 1957 confirmed that the orebody was mineable, Meramec Mining Co. was incorporated in 1957 and shaft sinking began late in the year. Production commenced in April 1964. The orebody is overlain by about 1300 feet of flat-bedded sediments. It is tabular, about 2600 feet long and up to 600 feet thick. It dips about 80° and is of unknown depth. The ore is mainly high grade magnetite with small zones of specular hematite. The wall rock is a Precambrian rhyolite porphyry. The mine was initially started with five major levels on 150 foot intervals. Crosscuts were driven across the orebody on 190 foot centers. Banks of scopes were mined between the crosscuts by a modified shrinkage stoping method. This was done by undercutting a 40 foot wide by 150 foot long block and blasting horizontal "lifts" drilled on 5 foot intervals. A 65 foot still was left between levels which contained the slushing drift, fingers, crown pillar, and adequate thickness for support. By 1971 a ?lattice? of pillars had been left and mining had progressed to the point that an orderly pillar recovery program was necessary.

Jan 1, 1976

By R. E. Mason

Shotcrete has been used for approximately 20 years to facilitate tunnel excavation through poor ground. Early examples of such usage in North America include the recuperation of the Granduc Mines access tunnel in Northern British Columbia, and similar work performed in the Carley V. Porter and Big Walker Tunnels in the United States. Mining companies such as Craigmont Mines in B.C. and Hecla Mines have used shotcrete in their workings for the past ten years. Shotcrete is now a widely utilized fool in the mining and tunnel construction industries in North America, but the accumulated experience is too limited for many to fully appreciate the capability of shotcrete to control ground movements and to understand the limitations of this tool. It is common, for instance, to use shotcrete to "bridge the gap" between rock bolt-supported and steel-rib supported ground and to avoid the use of shotcrete in water-bearing ground. Shotcrete can, and has been, used economically and practically under most severe ground conditions.

Jan 1, 1976

By Gordon H. Dechman

This report presents the concept, design, and testing of a sonic velocity monitoring system for the early detection of slope failure in open pit mines. The heart of the system is a device for producing reproducible sonic signals in rock. Because changes in the velocity of sound through rock near the top of the pit wall are a measure of extent and rate of fracturing of the rock, velocity histories obtained from periodic, automatic sonic velocity surveys provide positive information about developing slope instability.

Jan 1, 1976