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By Matthew C. Janes, Mark C. Spence

"A former coal gasification site next to Rock Bay in Victoria, BC, Canada required a barrier to permit dewatering and excavation of the bay and surrounding property. The adjacent property owners had stringent requirements at the boundaries of their properties. Isherwood Geostructural Engineers designed a temporary steel sheet pile (SSP) water retention structure and excavation shoring system along the perimeter of the site. The project involved challenging geotechnical conditions in soft clay soils and a multi-faceted construction staging plan involving the diversion of two large storm water outfalls that drained into the bay. Despite a well-conceived design and construction plan, unexpected site conditions and delays led to significant changes in design and construction approach. Employment of the Observational Method and on-the-fly geotechnical investigation were instrumental in maintaining project momentum and schedule. The paper presents the geotechnical and geostructural design details and construction events as they transpired, highlighting the key issues, discussions and lessons learned.INTRODUCTIONFor over 100 years, the Rock Bay Site, in Victoria, British Columbia, Canada, had a legacy of contamination left behind from previous industrial activities. The site was the former location of a coal gasification plant that was in operation from 1862 to 1952. The site was also an infilling location for a nearby tannery and sawmill. The remediation of the Rock Bay Site involved the excavation and replacement of approximately 300,000 tonnes of contaminated soils on Transport Canada’s property. The project commenced in 2004 and has occurred over several phases on multiple properties. In the third and final phase of the project, a temporary steel sheet pile (SSP) excavation shoring system and ocean barrier wall – required to seal off the bay – was employed to enable disposal and replacement of approximately 90,000 tonnes of contaminated soils from the shoreline and base of the bay."

Jan 1, 2016

By Chu E. Ho, Alfredas Daugiala, Nicola Ebanks

"The construction of an ancillary structure for the new Second Avenue Subway Line in Manhattan, New York City involved a deep excavation in highly variable rock conditions adjacent to a fragile masonry building. The maximum difference between the lowest and highest rock elevations was about 30 feet, which posed a problem for the installation of secant piles that formed the supporting retaining wall for the excavation. At certain areas, the rock levels were higher than the top of the invert slab of the ancillary structure. To avoid disturbance to the adjacent fragile building, the secant piles were fully cased for drilling through the overburden soils and the rock sockets were formed using non-vibratory technique. This paper discusses the design and installation details of the secant pile wall and the contingency measures that were considered to mitigate the highly variable rock conditions. Monitoring of the adjacent fragile building showed that impact of pile installation were controlled within tolerable limits and safety of the building was not compromised.INTRODUCTIONThe 96th Street Station forms part of the newly constructed Second Avenue Subway Line on the East side of Manhattan Island, New York City (Figure 1). During construction of this station, several deep excavations were carried out adjacent to existing fragile buildings (Arksman et al. 2012, Grigson et al. 2016). These fragile buildings were typically four to five stories high, with a single rubble wall basement supported on timber piles or seated directly on the fill. The timber piles were often found to be in a poor condition and connections to the footings were compromised due to rotting of the timber within the zone of water table fluctuation. Several of these fragile buildings had to be strengthened and underpinned to improve the stability of the structures prior to commencement of excavation for the new subway station box (Trabold et al. 2012, Ho and Pena-Iguaran, 2013). The situation was most challenging at Ancillary Buildings 1 and 2 located at 93rd and 97th Street respectively, where secant pile walls were located merely 2 feet away from the adjacent property line, due to architectural space constraints. While mitigation of excavation induced ground movements can be controlled by the adoption of a stiff excavation support system, a more concerning factor was the uncertainty associated with the impact of the secant pile wall installation on the stability of the existing fragile buildings. This was particularly difficult at Ancillary 1 where the secant piles encountered highly variable rock levels that intruded into the excavation space. The following sections discuss the design and installation of the secant pile wall and contingency measures that were considered at Ancillary 1."

Jan 1, 2016

By G. Meschke

"This paper reports on computational and experimental research, performed at the Collaborative Research Center “Interaction Models for Mechanized Tunneling” at Ruhr-University Bochum, Germany. Research covers a broad spectrum of topics relevant for mechanized tunneling in soft soil conditions. This includes advances exploration methods and models for the characterization of the in-situ ground conditions, the interaction of the face support and the tail gap grouting with the porous soil, multi-scale models for the design of fiber reinforced segmental linings with enhanced robustness, computational methods for the numerical simulation of the tunnel advancement, the soil excavation and the material transport in the pressure chamber, logistics processes and risk analysis in urban tunneling.INTRODUCTIONMechanized Tunneling has proven itself as an economical and flexible construction method that continues to undergo a dynamic evolution process. Shield diameters continue to increase, and the application range of tunnel boring machines is being extended to an ever-increasing variety of geotechnical conditions. In order to maintain economic viability and to ensure an environmentally friendly construction process, realistic and reliable numerical models are required in order to make informed decisions during planning and construction. To provide a reliable numerical prognosis, it is necessary to accurately assess and understand the interactions between the components involved in mechanized tunneling with the surrounding site, the ground, and any pre-existing structures. Heterogeneous geological conditions and often only approximated ground parameters create, in contrast to other engineering projects, special demands. This necessitates new insights to new problems that can only be effectively solved through truly interdisciplinary research. To address these challenges, the German Research Foundation (DFG) has established the Collaborative Research Center “Interaction Models for Mechanized Tunneling” (SFB 837) at the Ruhr-University in Bochum in 2010. Collaborative Research Centers are interdisciplinary scientific research groups in which cooperative research is conducted under the umbrella of a central research theme. With a research budget of ca. 10 Million Euros for the second 4-year funding period, and a research team composed of 13 project leaders along with approximately 35 scientific assistants the SFB 837 is currently one of the largest research groups conducting fundamental research in tunneling related topics worldwide.RESEARCH TOPICSThe research topics of the SFB 837 encompass a number of relevant planning and construction related aspects in mechanized tunneling (Figure 1). These research themes are each supported by computational models and laboratory investigations and are all included in an SFB overarching Tunnel Information Model (TIM). Interaction groups integrate and combine the results of different submodels through prototypical cause-and-effect relationships, and through the analysis of the Wehrhahn metro line (WHL) project in Düsseldorf, which has been adopted as the reference project for the SFB 837."

Jan 1, 2016

By Jamey Rosen, Georgette Hlepas

"Bluestone Dam is a concrete gravity structure with an overall length of 2,060 feet and a maximum height of 165 feet above the streambed. Several major project modification designs have been implemented and additional modifications are currently in construction and design phases. Due to the various modifications since original construction was completed in 1948, detailed documentation with visualization of the project features is needed. A three-dimensional model of the internal and external features of Bluestone Dam was generated from LiDAR data, survey information, and other data sources. One of the key features of interest in this model is an accurate visualization of over 200 dam anchors based on downhole anchor surveys. The model is accessible in Microstation and Geographic Information Systems (GIS), allowing users to rotate the anchors in three dimensions; view them in the context of geology, internal dam structural features, historical construction records, site photographs, bathymetric data, and instrumentation data. Users can “click” on individual anchors to view associated construction details and open a comprehensive installation packages. The model will be used by the United States Army Corps of Engineers (USACE) as part of a larger Geospatial Data Management System as a historical accounting of the project construction data, and be a long-term living document for use by both design engineers and operations staff to assess dam safety risk and to design future project modifications.IntroductionDuring the life of any project, critical data concerning the construction and performance history are required to be collected and maintained. The data collected prior, during, and post-project construction help with the design process, ensure that the project is built to specifications and is performing as per design intent. During the Post-Implementation Evaluation (an evaluation performed after a major project modification), these data are used to visualize the repairs, verify the construction was performed per design intent, and document the history of the construction phases, associated test results, and overall effect on the project. The project described in this paper is the construction of a system of tools to effectively use these data.Data collected and maintained during the operations phase helps to ensure that the project is continuing to perform as per design and aids in advance warning of any potential failure or required maintenance. Dam Safety, Emergency Management (EM), and Operations and Maintenance personnel can use the system to verify the status of the project in preparation for a high flood event. For example, if there is repair work being performed on a critical feature of the project that would affect the operation of the dam structure during a flood event, Operations personnel would be responsible to update the status of the system such that Dam Safety and EM would be able to identify the feature that is out of service, its date of expected repair completion, and the implications during a flood. In addition, risk assessments typically require a full history of the project and its performance. Any concerns that arise concerning the safety or performance of a project will require a full documented history of the project and its components. Proper documentation and data management are key in this assessment process."

Jan 1, 2016

By Carl-Oscar Nilsson, Åke B. Nilsson

"The embankment dam at Storfinnforsen is 23 m high and was completed in 1954. The dam has an impervious zone with timber sheet piles and a support fill of glacial till. The pore water pressure in the downstream shoulder has during recent years increased due to deterioration in the sealing function of the timber sheet piling. There is a concern that the high pore water pressure in the glacial till will cause internal erosion initiating at a thin coarse transition layer between the glacial till and the rock fill along the downstream toe. As a remedial action in order to improvement of the leakage resistance a supporting berm of coarse rockfill against the downstream slope of the dam was constructed in year 2013. In addition a new impervious seal in the centre of the dam e.g. a diaphragm wall was considered. However, after further studies and a trial stretch of 40 drains each 20 m long and diameter 0.3 m an alternative with vertical drilled drains in the downstream support was selected. A contract has now started up to drill in a similar way to treat the full length of the dam with drains. The work is in the planning to be completed in 2016.Dam ConstructionStorfinnforsen Embankment Dam was put into operation in 1954. The dam is 330 m long and maximum height is approximately 23 m. The dam is constructed with a central core zone and supporting zones of earth and rockfill on the upstream and downstream sides giving an almost symmetrical cross-section about the dam axis, see Fig. 1. The upstream slope is 2H:1V down to el. 270 and 2.5H:1V below. On the downstream side the slope is 1.75H:1V down to +269 and 2H:1V below. The core zone consists of a timber sheet pile wall with a Zone 5 of glacial till, approximately 2 m wide, adjacent to the wall on the upstream side."

Jan 1, 2016

By Behzad Khorshidi

"The ultimate objectives of the post-tensioned strands are to connect the precast segments into a ring and provide pre-stress in the tunnel circumference. The method involves inserting the strand through the preliminary embedded duct in the precast concrete segments and then tensioning the strand by jack and fastening it. The post-tensioned strand eliminates the necessity of bolt connections between the segments and may reduce the labor cost and increase speed of lining construction. Pre-stressing of the segmental lining reduces the steel reinforcement or fiber volume in precast segments and/or thickness of the precast segments which would result in reducing the manufacturing cost of them. Pre-stressing would reduce cracking and increase water tightness, and would provide smooth intrados due to eliminated bolt joints and pockets in the tunnel lining. Pre-stressing would increase resistance to internal pressures as well. Further, this system could work very well structurally in tunnels with squeezing rock or tunnels with high seismic loadings. INTRODUCTION OF THE METHODPost-tensioning is commonly used in the construction of bridges, large buildings, nuclear power stations, and water tanks but its utilization in tunnels is still in its infancy.The precast pre-stressed concrete segmental lining can be used for shield tunnels. It provides a reinforced lining ring by the following construction stages and as shown in Figure 1:1) Segments to be assembled by TBM to complete a full ring2) Steel strand to be inserted through embedded duct (sheath) within the segments3) The strand to be tensioned by Jack after anchorage of the other end4) The strand to be fastened after reaching required tension load5) The horizontal strands (if necessary) to be installed, tensioned and fastened6) The recesses and gap between strand and duct to be filled by groutingFurther, Figure 2 shows an unbonded post-tensioning strand model; Figure 3 shows an anchor sample (Xanchor); Figure 4 shows a duct (sheath) and anchor within reinforcement; Figure 5 depicts the posttensioning of a strand by jack; and Figure 6 is an image of the Midorigaoka Trunk line tunnel in Sagamihara, Japan which was constructed using this system."

Jan 1, 2016

By Aditya Ayithi, William G. Ryan, Dean Herbst

"For rock socketed drilled shafts, it is a common practice not to include the frictional resistance of overburden soils into the nominal capacity estimation. The primary reason often being cited is “overburden soils resistance is negligible compared to that of rock socket resistance.” However, in certain geological conditions, where the rock layer is located at greater depths, friction resistance from overburden layers can be significant. In addition, at such great depths, shaft drilling becomes very complicated and expensive. In these situations, considering the resistance of the overburden layers can be an economic alternative.This paper presents a case study of an Osterberg cell (O-cell) load test conducted on a 161.8 feet long and 78-inch diameter instrumented test shaft. Based on initial designs, a 72-inch diameter rock socket of lengths 23 and 26 feet was required to provide a LRFD factored friction resistance of 3,200 kips. The load test results revealed that the material in the 72-inch diameter socket does not represent a true rock. However, the test results also proved that the factored friction resistance of overburden layers is greater than the required design resistance. Based on the load test results, it was decided to allow the overburden soils frictional resistance to be considered in the shaft design, resulting in significant economic savings.INTRODUCTIONRock socketed drill shaft design guidelines of various State Department of Transportation (DOTs) agencies allow friction and/or end bearing resistance of only the rock socket portion into the design capacity estimation. It is typical to neglect the frictional resistance of overburden soils. However, in certain geological conditions where the rock layer is at greater depths, friction resistance of the overburden soils can be significant. In this case the friction resistance of overburden soils was verified via the specified instrumented O-cell test program and then used as part of the design capacity.PROJECT DESCRIPTIONAs part of I-29 improvement project, Iowa Department of Transportation (Iowa DOT) planned to replace the dual four lane bridges that cross the Floyd River in Sioux City, Iowa with dual six lane bridges (Fig. 1). Expected benefits from this improvement include improved safety, traffic operations and roadway infrastructure conditions.BRIDGE SUBSTRUCTUREThe project consists of two individual bridges; a new south bound bridge and a new north bound bridge. The south bound bridge is 646-ft long and the north bound bridge is 644-ft long. Both are six-span, pretensioned and pre-stressed concrete beam bridges of varying width. Bridge foundations were designed such that the abutments of both bridges will be supported on driven steel piles and the bridge piers will be on drilled shaft foundations."

Jan 1, 2016

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy, E. D. Shepeta

This paper studies the features of known and newly synthesized dialkyldithiophosphates and reagents with thioamide groups when separating copper-containing and arsenic-containing minerals in the flotation of skarn-scheelite-sulphide ore at the Primorskaya concentration plant. The optimization of dialkyldithiophosphate collectors was based on the study of their surface activity at the liquid-gas interface and estimated hydrophobic abilities. The flotation experiments show that the selectivity of action of the reagent increases with an increase of its surface activity and a reduction of hydrophobic ability when separating chalcopyrite and arsenopyrite. IMA-225-5 was proposed as a more efficient dialkyldithiophosphate collector, which increases the recovery of copper by 2.8% compared to the industrially used collector IMA-I413. Selection of the optimal structure for reagents with thioamide groups (derivatives of thionocarbamate and thiourea) was carried out according to their acidity and the presence of hydrophilic particles in their structure. Calculations were performed depending on the pH of the solution of chalcopyrite to determine the optimum reagent sorption and to further optimize the structures of these reagents. The tests with reagents with thioamide groups show an increase in copper recovery by 3-4% together with a significant increase of arsenic content compared to IMA-225-5. As a stronger collector with thioamide groups, it was recommended to use sample 234, which belongs to the thiourea derivatives. IMA-225-5 was recommended for industrial tests at the Primorskaya concentration plant. Thus, this study has shown that using dialkyldithiophosphate is more appropriate if it is necessary to increase the selectivity of separation of copper-containing and arsenic-containing minerals, and using reagents with thioamide groups, or their combinations with dialkyldithiophosphates, is more appropriate if it is necessary to increase the recovery of copper or the quality of copper concentrate with less selectivity of the process.

Jan 1, 2016

By T. Ellis, J. Gagnon, L. Webb, M. Burr, D. Kakengela, D. Evans, A. Mirza

Lead-based alloys are used as the primary anodes for electrowinning from sulphate-based aqueous systems. Lead anode technology has evolved over the years, migrating from pure lead and lead-antimonial alloys to the present-day lead-calcium-tin alloys for copper electrowinning and leadsilver alloys for zinc electrowinning. Anode technology has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new alloys and production processes, the industry still has unresolved issues related to untimely corrosion, which limits anode life and may lead to higher contaminant levels in the metal being produced. Lead anodes corrode because of the difference in the chemical/electrochemical potential across the microstructural features of an anode. Given a very high purity material, we find that the grain boundary areas corrode significantly faster than the rest of the grain. A balance of alloying element selection and microstructural design allows the grain boundary area to be engineered, thus minimizing grain boundary corrosion. However, operational issues can lead to unexpected corrosion behaviours that we will discuss moving forward. The comments in this work, although directed toward copper electrowinning, can be extended to similar phenomena in other metals electrowon from sulphate media (i.e., zinc, nickel, cobalt, manganese). The life cycle of electrowinning anodes depends on tankhouse operating conditions and maintenance of the anodes, including cleaning and straightening. This paper will focus on the operational aspects of maximizing the utilization of lead anodes for base metals electrowinning.

Jan 1, 2016

By K. Swedburg, M. Samuels

"The New Afton concentrator was commissioned in June 2012, reaching the design milling rate in September 2012. By late 2013, through a campaign of optimization and de-bottlenecking, it was recognized that the installed plant was capable of greatly exceeding the design throughput of 11,700 tpd. Because the value of the metal contained (by increasing the plant feed rate) exceeded the offsetting losses of copper and gold recovery (as the operation moved to a coarser grind), the concentrator feed rate was strategically increased with support of New Gold, while the operations team was given a mandate to evaluate, and then implement, flow sheet options that could re-establish the original design criterion grind target and achieve the corresponding improved recovery. Broadly, the two options implemented were the addition of a tertiary grinding stage consisting of Metso Vertimill® prior to rougher flotation (in order to address the grinding required at increasing throughput by increasing the power), and the addition of three Woodgrove Staged Flotation Reactors (SFR) added to the cleaner circuit after regrind of the rougher concentrate (to address the increased mineral loading to the cleaner circuit). Through test work, it was anticipated that the SFRs would be capable of achieving final concentrate grade in a single pass without the integration of recirculating loads, a strategy sometimes referred to pre-cleaning. This paper describes the expectations generated for the Woodgrove SFR unit operation through pilot plant testing on site, and compares those results with the performance of the expanded circuit that exceeded the original design criterion of P80 160 µm, which was commissioned in the second quarter of 2015.INTRODUCTIONThe New Afton concentrator, located near Kamloops, BC Canada, commenced operation in June 2012. The mill achieved the design throughput of 11,000 tonnes per day average during the month of September 2012 and, following various operational optimization efforts (O’Hara et al, 2015), achieved the design p80 grind size of 160 µm at the design milling rate in July 2013.During August 2013, trials were carried out to determine the throughput rate limits of the mill circuits and to evaluate mill metallurgical performance at higher rates. Milling rates up to 15,500 dmt per 24 hours were achieved during this trial, demonstrating potential capability for sustained milling rates exceeding the nominal design capacity. As was expected, the higher milling rates resulted in a coarsening of the grinding circuit product size, and resulted in marginally lower recoveries in the rougher flotation circuit. Despite the lower recoveries, the higher milling rates resulted in higher metal production and the financial analysis favored running at rates of at least 13,000 tonnes per operating day, with the higher cash flow in the near term offsetting the value of metal production loss at the end of the mine life (due to the short term increase in the rate of reserve depletion). Milling rates were sustained above 13,000 tonnes per day through the second half of 2013, and increased above 14,000 tonnes per day by mid-2014 (Figure 1)."

Jan 1, 2016

By Guiqing Zhang, Liansheng Xiao, Zuoying Cao, Li Zeng

A new process of direct solvent extraction of nickel from sulfuric acid leach solutions of low grade and complicated nickel resources using a novel extractant HBL110 was proposed. The basic performance of new organic system was investigated and the continuous pilot plant and the industrial test were conducted. The results indicated that the extractant of HBL110 can be used to directly extract nickel selectively over iron, aluminum, manganese, magnesium, calcium and chromium from sulfuric acid leach solutions. The loaded organic solution can be easily stripped using dilute H2SO4 solutions. Both kinetics of extraction and stripping of nickel were fast. The continuous pilot plant test with the sulfuric acid leach solution of laterite containing 6.22g/L Ni2+, 14.1g/L Fe3+, 0.73g/L Fe2+, 33.9g/L Mg2+, 1.58g/L Al3+, 0.495g/L Ca2+, 0.97g/L Mn2+ and 0.5g/L Cr3+ as feed in mixer-settlers showed that the process had run stably with 98% recovery of nickel. The concentration of nickel in strip liquors reached as high as 50 g/L while the removals of Fe3+, Fe2+, Mg2+, Al3+, Ca2+, Mn2+ and Cr3+ were 98.5%, 91.5%, 99.95%, 99.8%, 99.1%, 98.6% and 99.5%, respectively. The industrial test with the sulfuric acid leach solution of electroplating sludge containing 11.5g/L Ni2+, 2.68g/L Fe3+, 7.54g/L Cr3+, 0.61g/L Mg2+, 2.09g/L Al3+, 0.68g/L Ca2+, 0.022g/L Mn2+ and 0.154g/L SiO2 as feed in mixer-settlers also showed that the process had operated successfully with 99.5% recovery of nickel. The concentration of nickel in strip liquors reached 42.7 g/L while the removals of Fe3+, Cr3+, Mg2+, Al3+, Ca2+, Mn2+ and SiO2 were 99.2%, 99.77%, 99.73%, 99.56%, 99.57%, 98.51% and 98.75%, respectively. The new process exhibited big advantages of short flow sheet, high recovery of nickel, high removal of impurities, low chemical reagent consumption and low cost. Application of this process in industry is expected to make important impact on the extraction of nickel from sulfuric acid leach solutions and to deliver good environmental and economical benefits.

Jan 1, 2016

By Jianhua Xin, Min Chen, Cuihuan Huang, Shan Yu, Xiaoao Li, Nan Wang, Guanghao Chen

Copper enrichment behavior in continuously cast slab induced by scale formation after continuous cooling in H2O vapor atmosphere and consecutively in air has been experimentally investigated by combining with SEM-EDS analysis, for the purpose to examine the effects of initial slab surface temperature and contents of copper and nickel. For Slab 1 with copper content of 0.1 percent, no visible copper enrichment is found at scale-substrate interface irrespective of the various scale microstructures formed at different initial slab surface temperatures. For Slab 2 with higher contents of copper and nickel, copper-rich phase accumulates and stays at scalesubstrate interface under the condition of lower initial slab surface temperature; while Cu-rich phase in the porous scale formed at higher initial slab surface temperature is noted with simultaneous Ni-enrichment appearing in front of the steel-scale interface. Both a porous scale and high nickel content work together to provide pores for copper-rich phase migration away from interface and occlude within the scale layer.

Jan 1, 2016

By cheng Peng-fei, TANG Hai-yan, guo Xiao-chen, LI Jing-she, Liang Yong-cang, Zhao Baojun

The origin and evolution of non-metallic inclusions for Al-killed casing steel during EAF-LFVD- CC process were studied by industrial tracer experiments. The formations of Al2O3 and MgO·Al2O3 micro- and macro-inclusions from ladle slag were analyzed by theoretical calculations. The results show that micro-inclusions were formed during deoxidation and temperature decreasing in the process of casting, most of the macro-inclusions come from entrapped ladle and mold slags. In addition, most of the Al2O3 formed were modified into 12CaO·7Al2O3 and 3CaO·Al2O3 inclusions which are liquid at steelmaking temperature. MnS cannot be fully modified to CaS and it was only wrapped outside the alumina or calcium aluminate in the form of (Ca,Mn)S with the amount of Ca-Si wire fed during the test.

Jan 1, 2016

By Pan Gu, Zhen Zhang, Jiang Diao, Bing Xie, Hongyi Li

Viscosities of FeO-SiO2-V2O3-CaO-P2O5 slags have been measured at the temperature range of 1673 K to 1773 K (1400°C to 1500°C). This investigated system represents the major components of basic vanadium slag that is an important intermediate product of a novel vanadium extracting process, in which removal of phosphorus and extraction of vanadium can be achieved from the vanadium-containing hot metal simultaneously. It was found that higher CaO/SiO2 ratio resulted in lower viscosity in the composition range of interest. Also, the viscosities increase with the increasing P2O5 concentration. The varying viscosities can be attributed to the modification in complexity and polymerization of the slag network. The variation of apparent activation energies are in tune with the viscosity measurements. The results of this work revealed the effect of CaO/SiO2 and P2O5 on the viscous properties of FeO-SiO2- V2O3-CaO-P2O5 slags and therefore provide the theoretical foundation for the control of the coupling de-P and V-extraction process.

Jan 1, 2016

By Xiancong Zhao, Hao Bai, Qi Shi, Zhancheng Guo

Reducing electricity cost is important for energy intensive industries such as the iron and steel industry. With the implementation of time-of-use (TOU) electricity price, plenty of attention has been paid to the optimal management of byproduct gases. The time-of-use (TOU) electricity price is the practice of implementing different prices for different times of use. It is possible to reduce electricity cost by adjusting the amount of product gases stored or used for power generation throughout the day. In this paper, a novel mixed integer linear programming (MILP) model concerning the TOU electricity price is proposed to optimize byproduct gas use. Compared with previous models, this model considers the optimal load shift between gasholders and boilers under TOU electricity price. The case study of a steel plant demonstrates that the electricity purchase cost can be reduced by more than 30% after optimization.

Jan 1, 2016

By Shengli Wu, Laixin Wang, Minyin Kou, Xinliang Liu, Weidong Zhuang, Yujue Wang

COREX process has obvious advantages in environment protection but still has some disadvantages, for example, it has a higher sulfur content of hot metal than blast furnace. In this paper, the thermodynamics and dynamics of desulfurization have been investigated to obtain the main operation parameters related to the mass fraction of sulfur in the hot metal. In addition, statistical analyses have been carried out to study the relationship between operating parameters and sulfur content of COREX hot metal based on actual plant data. It has been found that the mass fraction of sulfur in hot metal is significantly influenced by the C content in hot metal, MgO/Al2O3 in slag, the concentration of MgO in slag, the temperature of hot metal and binary basicity (R2).A linear model has been developed and subsequently used for reducing the mass fraction of sulfur in hot metal, improve the quality of hot metal and contribute to low carbon ironmaking.

Jan 1, 2016

By Sun Ying, Zhang Jing, Li Qiuju

A new process of enrichment Cu in molten copper slag under electric field is presented in this article. The experiments were carried out in the laboratory on a kilogram scale. The mobility of copper slag was improved by the technique of carbon reduction. The effects of temperature, electric field strength and intermittent feeding speed were investigated on Cu migration. The results showed that the best experimental conditions were the temperature at 1523K, electric field strength was 1.5V•cm-1 and feeding rates was 15 g•(10min)-1. The copper content of the slag decreased below 0.6wt%. The process was compared to the traditional electric furnace process of slag cleaning, there was reduced the energy consumption and heat loss, and also harmful gas emissions such as SO2 and CO2, accompanied by improved the efficiency of slag cleaning.

Jan 1, 2016

By Linfeng Zhou, Rong Sun, Guanghui Li, Zhiwei Peng, Tao Jiang

Dust, or airborne particulate matter, from metal smelting can be either mechanically or thermally generated and it negatively affects the indoor air quality as well as the fugitive emissions from the plant. The thermally generated dust is often referred to as fume and it is typically generated whenever liquid metal comes into contact with air. For practical reasons, such as vehicle access, etc. it is often difficult to collect 100% of the fume. It is therefore highly desirable to develop processes and optimize operational procedures so that fuming can be kept to a minimum. In this series of experiments, the mechanism of active oxidation and fume formation from liquid silicomanganese under an impinging air jet in the temperature range 1400-1600°C has been explored. Characteristic properties of the fume have been established; particle diameter, shape, size distribution, and elemental composition are reported. The oxidation process is described in terms of vaporization, oxidation and agglomeration. In the boundary layer, two competing mechanisms seem to be operative in parallel: a direct oxidation of Mn vapor, and a two-step oxidation of silicon. The thermodynamic and kinetic conditions governing the two mechanisms are discussed.

Jan 1, 2016

By Fangqing Yin, Qingyu Deng, Zhengfeng Qu, Mengjun Hu, Meilong Hu

Titanium bearing blast furnace slag, which contains 20%-30% TiO2, is a valuable secondary titanium resource. Based on the thermodynamics calculation effect of the temperature on the reduction of the slag in vacuum were studied at certain vacuum degrees. The results show that magnesium vapor and silicon monoxide vapor can be obtained at the condition of high temperature and low pressure. The purity of TiC increases with temperature increasing. When the temperature arrives at 1623K TiC can be obtained besides the reductant carbon. XRD result of the powder collected from the furnace cover show that magnesium and silicon in the titanium bearing BF slag leave the slag system during carbothermal reduction in vacuum. From the above it can be concluded that TiC can be obtained from the titanium bearing BF slag and silicon and titanium in the slag can be separated by carbothermal reduction in vacuum and acid leaching.

Jan 1, 2016

By Zhanjun Wang, Yongqi Sun, Mei Zhang, Zuotai Zhang, Min Guo

The role of fluorine on the viscous and crystallization behavior of CaO-SiO2-MgO-Al2O3-FetO-P2O5-(CaF2) slags were explored using the rotating cylinder method, non-isothermal differential scanning calorimeter (DSC), X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. It was found that the viscosity slightly decreased with increasing CaF2 content. It was also found that CaF2 addition can promote the primary phase transformed from MgFe2O4 spinel to Ca3(PO4)F, which was beneficial to the enrichment of phosphorus. Additionally, the structure of the slags explained by X-ray photoelectron spectroscopy (XPS) and magic angular spinning nuclear magnetic resonance (MAS-NMR) were further analyzed, which was well in accordance with the above analysis.

Jan 1, 2016