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By Christian Geerkens

Increasing requirements on slab quality initiates SMS group in developing products with a high sophisticated level regarding production and process. These characteristics are represented by SMS group’s HD family. HD stands for High Definition or the improvement of product quality via higher precision of the casting processes. A deep look inside into casting process is realized by the use of fiber optical equipped HD mold. High definition casting process control is assured using the HD spray and HD size. For objective, environmentally friendly and highly informative analyze of the inner quality of the cast products the new HD scan is present.

Aug 16, 2017

By Rodrigo Perito Cardoso

Low-temperature nitriding of stainless steels is applied to obtain wear resistant surfaces without losing its corrosion resistance. The treatment consists in introducing nitrogen into the steel surface avoiding chromium nitride precipitation. The corrosion resistance of martensitic stainless steels is expected to be improved if the treatment parameters are correctly selected. It can be related to ?Fe2-3N and a'N phase formation on the treated surface. In the present work the influence of the pretreatment and treatment temperature on corrosion resistance of plasma nitrided AISI 420 steel samples is studied. Annealed, as-quenched and 400ºC-tempered samples were nitrided at 300, 350, 400, 450 and 500°C, for 6 h at 600 V. The pressure was 3 Torr and the gas mixture was composed of 70%N2, 20%H2 and 10%Ar, at a gas flow rate of 3.34×106 Nm3s-1. Plasma was generated using a square-wave pulsed DC power supply and the sample temperature was controlled by the duty cycle. The modified layers were characterized by optical microscopy, X-ray diffraction and microhardness measurement. The corrosion resistance was studied by electrochemical characterization, by means of Open circuit potential and Anodic polarization curves. The maximum surface hardness was achieved at 400°C. This temperature seems to be near the limit temperature for low-temperature treatment aiming to improve or at least to keep unaltered the corrosion resistance in relation to that verified for non-treated steel samples. Results confirm that the pretreatment and treatment temperature significantly affects the corrosion resistance of the treated surface.

Aug 8, 2018

By Konrad Krimpelstätter

The need for more effective and flexible roll-gap lubrication technologies in hot and cold rolling mills is steadily increasing due to ever-greater requirements placed on the rolling process and the final products. In particular, the rolling of high-strength steels poses enormous demands for both the rolling mill and the coolant/lubricant to be used. The presented paper focuses on two innovative technologies for highly efficient roll-gap lubrication for hot and cold rolling, which were developed utilizing extensive knowledge and expertise about the tribological interactions in the roll-gap. The advanced work-roll lubrication package (A-WRL) for hot rolling and ESP mills is using specially designed mixer-nozzle units to mix the water/oil emulsion very close to the nozzles to minimize the risk for contamination and clogging. The nozzles are quickly exchangeable and are optimized to ensure uniform lubricant distribution, high plateout efficiency and minimum oil consumption. This eco-friendly solution does not require any chemical additives or cleaning agents and significantly reduces electrical energy consumption and work-roll wear. The roll cooling system on mill entry and exit side remains switched-on, which is of vital importance especially for highperformance hot strip mills. Minimum Quantity Lubrication MQL® represents a new generation of roll-gap lubrication technologies for cold rolling, which applies minimum amounts of pure rolling oil finely atomized with pressurized air directly onto the work roll surface. This allows controlling the oil film thickness depending on actual process and product parameters, providing increased lubrication flexibility, significant improvement of strip surface cleanliness through reduction of strip wear. MQL® was successfully installed and tested on two industrial tandem cold rolling mills in Europe. Advanced WRL and MQL® represent Primetals’ latest technologies that feature a robust and reliable system comprising standardized interfaces and flexible communication options. Both packages can easily be integrated into existing or new hot strip mills, ESP lines or cold mills.

Aug 17, 2017

By Susanne Hahn

The Siemens VAI software model DynaPhase calculates thermodynamic properties depending on the chemical analysis of steel. It can be used online together with Siemens VAI’s secondary cooling model SIMETAL Dynacs 3D which is a unique feature. Offline it can be used to investigate the thermodynamic properties of steel grades and therefore supports the development of new grades. The core of DynaPhase is a substitutional solution model for the Gibbs free energy to calculate multi-component phase diagrams. The parameters of this model are determined by employing the CALPHAD approach. This model is combined with a microsegregation model to account for the interdendritic solidification process. New DSC (differential scanning calometry) measurements of the department of metallurgy of the Mining University of Leoben have been used to improve the DynaPhase database for high Al or Si concentrations. By comparing this experimental data to calculations it has been found that some of the widely used commercial software tools do not describe the ternary system FeAlC for high aluminum concentration correctly. In this paper we will show how thermal properties of high Al grades change with the optimized database and what impact this has on the secondary cooling of continuous casting, e.g. how the solidus point shifts on the strand. Moreover we will show that the online use of DynaPhase has many advantages for the production. Since DynaPhase uses the actual chemical analysis of the steel grade and not just concentration ranges or averaged concentrations it is possible to optimize the cooling strategy during casting for the actual chemical analysis of the actual heat.

Jul 30, 2018

By Vitor Guarnier Domiciano

Pre-shaped refractory burner blocks play an important role in reheating furnaces operation and melt shops production since they are responsible for heating the billets/plates so that they reach the temperature required for lamination. This paper presents the main characteristics and properties of a new refractory castable developed for pre-shaped burner blocks, which significantly improved the performance of reheating furnaces burner blocks. Tests carried out in 3 different melt shops have shown that the new refractory castable was able to extend the service life of the refractory burner blocks from 1 year (standard product) to more than 3 years (new castable), showing perfect conditions to continue operating for a longer period.

Oct 30, 2017

By Keulla Venya Urbano e Silva, Marcelo Quintão e Silva Marchetti, Rafael Silva Marcelino, Rafaella Bicalho da Rocha

Comparative study between standard and BigFLUX matrices for high intensity magnetic separation pre-concentration (WHIMS) stage for iron ore. The evaluation was carried out on GAUSTEC’s pilot equipment for samples from Viga Mine’s operation. Samples in different feed iron content on rougher stage were evaluated in 46 experiments with matrix variation. The analisys compared chemistry, mass recovery and metallurgical recovery results to define the most efficient matrix to use in a pre-concentration stage.

Oct 3, 2019

By Daniele Tolazzi

Electric Arc Furnaces keep evolving into highly powerful melting units, shrinking taptotap times by increasing the effectiveness of the energy sources and the material fluxes used in the process. Steelmakers are targeting to increase the efficiency of their injection package in order to reduce the overall conversion costs, seeking for technologies specifically designed to promote the metallurgical reactions in a predictable and reproducible process automatically controlled at the correct timing. Many technological enhancements have focused in the gas management, improving the burner design and the penetration capacity of oxygen injectors, dedicated to decarburization and the other exothermic reactions. Instead, lower evolution efforts have been addressed to engineered solutions for managing the addition of solid materials required in slag forming, although they are playing a key role in EAF process optimization, as well. The paper describes the latest solutions designed to manage efficiently the injection of fuel, oxygen and powdered materials in several EAFs and presents the operational results achieved. Accurate control of reliable additions of coal, lime and magnesia proved crucial for the control of the slag FeO and viscosity, generating stable foamy slag and producing cleaner steel.

Aug 17, 2017

By Uwe Wilhelm

Pittini Group has contracted Danieli in 2011 for the supply and replacement of the existing EAF at Ferriere Nord Plant in Osoppo. This was a very challenging project: giving the fact that the Meltshop was operating already under very high performance level, there were many elements involved for the project to improve (reduce the amount of charges, promote highest possible chemical energy utilization, allow best optimization on existing transformer power, modification on Drop Out box and Water Cooled Duct, Hydraulic System for EAF, Scrap Bucket design to fit to new EAF with existing loading and transport system, Automation System Review and Upgrade) as well as limitations of the existing installation (limited space, lifting capacity building and cranes and the required solutions for fast shell and roof exchange). All furnace parts, as well as installation engineering, were developed and discussed carefully with the Customer to either provide proven and reliable concepts, but also to define solutions for fast installation/maintenance access and quick exchange for offline turnaround. In the end, from disassembly of existing equipment up to the first heat of the new furnace, only 38 days were necessary. First heat was made on January 24th 2013, on the 6th production day 32 heats where produced at nominal design capacity and 28 days after start up 100,000 t liquid steel have already been produced.

Jul 30, 2018

By Henrique Dias Gatti Turrer, Marcelo Nazaro Silva, Henrique Lopes Martins Pereira, Claudio Luis Goulart

The Minas-Rio industrial complex uses a pipeline with extension of 529 Km to transport the iron ore concentrate to the filtering industrial complex and exporting port. Since project phase, bench lab tests have provided important information for the pumped slurry rheology control. Based in these tests results was possible to verify the effects of slurry stability, rheology controller type and particle size distribution in the regrinded concentrate yield stress and relative viscosity. Controlling some characteristics of pumped slurry, such as particle size distribution, pH and solids concentration guaranteed to achieve the necessary rheology properties for its safe pumping through pipeline and resulted in a performance improvement over the years.

Oct 3, 2019

By Jens Kempken

A competitive landscape pressurizes the steel producers business, zero defect requirements from customers forces the operators for additional efforts in process control and quality management. The so called quality related cost, which include also rework, cost for downgrading or even scabbing of material is already a remarkable lever in a plants profitability breakdown. The introduction of advanced state of the art grades in the product portfolio requires already a budgeting for the expenses for R&D and quality management. PQA has been developed as a process and quality management software solution next to existing level 2 or level 3 automation systems. It is focusing on the analysis of process data, equipment information, in line quality measurement devices and trend analysis to obtain an answer whether the process is according to definition and expectation and whether the intermediate or final product can be shipped for further processing as prime material. Advanced analytics which are linked to an expert know how based configuration identifies deficiencies in the production and processing process. An intelligent, state of the art quality rating system evaluates tolerable deviations. PQA comprises the software platform including the database, data configurator and collector from the different sources in the production process and units. The core element of the platform is the knowledge based expert know how package defining process and quality determining fundamentals. The paper describes the structure of the software package, it gives insights on the expert know how package, process and quality evaluation and points out the customer benefits, cost reduction, improvement yield, customer satisfaction increase. The link to recent operational references is given.

Oct 30, 2017

By Steven G. Jansto

Nearly one third of the globally produced structural flat and long structural products are in the 0.11 to 0.16% carbon range. By definition, numerous steelmakers globally define this approximate carbon range as peritectic in their melting grade family within their organization. The metallurgical consequence is the result of numerous global structural specifications which allow carbon to wide carbon ranges resulting in quality issues. For example, such specifications as ASTM A588 set no minimum carbon and a 0.15 to 0.19%C maximum depending on the specific grade designated within the specification. This peritectic region is specifically challenging in production compared to less than 0.10%C because of solidification issues and a higher propensity for slab or billet cracking during continuous casting. During hot rolling, rejects and/or deviates are increased as well. The relative steelmaking operational cost of production is compared between peritectic and non-peritectic carbon compositions for a given specification.

Aug 17, 2017

By Andrea Zanon

Slitting processes have been used for many years to increase the productivity of smaller diameter deformed bars, without making major investments in the rolling mill. This technology is used mainly for the production of reinforcing bars (7-20 mm diameter), but successful applications exist also for round bar production. The multi-slitting process enables to produce up to 5 bars starting from one billet, thus increasing the productivity of the smaller products. Danieli Morgårdshammar, world leader in the supply of rolling mills for long products, has been a front-runner in slitting technology since its first applications and has recently developed, first in the world, the technology to produce 5X8mm rebar. This process has been recently applied in BRSM steel, a company based in Bangladesh which is a worldwide benchmark for slitting technology performances. This paper presents the necessary modifications which need to be considered when developing a 5-strand slitting project (and multi-strand slitting projects in general), as well as the results obtained at BSRM Steel when the process was implemented in 2016, the first rolling mill in the world rolling 5X8 mm slit rebars.

Oct 30, 2017

By Patrícia Mundim Campos Faria

The process of particle size reduction by grinding is inherently inefficient and involves high capital and operating costs. In particular, ball milling is one of the important unit operations in the iron ore pelletizing process. The mill product, due to its physical properties, determines the efficiency of subsequent stages of classification, filtration and pelletizing, thus impacting the quality of iron ore pellets. The work demonstrates the application of the population balance model in the optimization of a full-scale ball mil circuit grinding pellet fines with the aim to evaluate the optimal solids concentration to improve iron ore pellet quality. Initially, detailed experimentation was carried out in a 25.4 cm diameter batch mill and a relationship for mill scale-up using a linear population balance model in wet grinding systems was established. The selection and breakage parameters and the specific selection functions were determined for pellet feed iron ore. It was possible to identify the non-normalizable nature of the breakage functions of the ore studied, which were modeled properly. Afterwards, as a result of incorporating the specific selection functions and breakage functions into the linear population balance model, it was possible to predict product size distributions in the pilot and plant scale mills (0.416 and 5.18 m diameter, respectively) from data obtained in the 25.4 cm diameter mill. Finally, with this scale-up procedure it was possible to appraise the plant scale optimization via laboratory scale grinding mill tests. The effects of changing percent solids were assessed in order to improve the industrial mill performance and the optimal value should be in the range from 76 to 80%.

Aug 1, 2018

By Salete Martins Alves

The future lubricants must be more environmentally adapted, with a higher level of performance lower total life cycle, cost than currently used lubricants. Environmental friendly, the biodegradable alternatives are available for a large variety of mineral oil based lubricants. Vegetable oils are the major source of these base fluids, although they have lower thermal and oxidation stability and even worse low-temperature behavior than mineral oil. These physical and chemical properties can be improved by chemical modification. The aim of this study was to evaluate physicochemical properties and film formation from modified vegetable oils. The vegetable oil was chemically modified by epoxidation reaction with acetic and formic acid using sunflower oils. Viscosity, iodine value, density, acidity value and thermal stability were determined for epoxidized oils. The film formation was analyzed using a HFRR tribometer. The results showed that epoxidized vegetable oils had excellent properties to be used as lubricant, and their tribological performance is higher than mineral oil.

Jul 31, 2018

By Osvaldo Guilherme Comineli

An extensive investigation into the role of low copper contents on the hot ductility of C-Mn-Al steels has been carried out in order to better understanding the problem of “hot shortness”. Previous work has suggested that this problem results from the build up of Cu that occurs at the surface of the steel as a consequence of the preferential oxidation of iron. This causes the formation of a Cu-rich film of low melting point. A nickel addition has been reported as a solution to the problem, since it increases the solubility of copper in the austenite. After hot tensile testing to failure, samples of Cu-containing steels have been examined using optical, scanning and transmission electron microscopes. Recently published results indicate that copper, in addition to precipitating out as CuS, also segregates to MnS inclusions forming a shell around them. This does not seem to impair the hot ductility under an inert atmosphere, but may have serious consequences under an oxidising environment and lead to “hot shortness”. The influence of nickel in improving the hot ductility seems to be due to it forming a higher melting point alloy with the segregated copper. Data from this incomplete work also suggests that Ni reduces the precipitation of CuS particles. Current investigation carried out using confocal microscopy still to be completed will improve the understanding of the role of copper and nickel on the problem of “hot shortness”.

Aug 8, 2018

By Henrique Silva Furtado

Concerning production of low phosphorus steel critical grades at ArcelorMittal Tubarão site, bottom blowing system plays a very important role. For those systems with independently controlled tuyeres, some non-uniform bottom blowing patterns seem to be promising in improving metal-slag mixing; however, based on computational fluid dynamics (CFD) results of ArcelorMittal Tubarão’s post oxygen bottom blowing, this may not be generalized. Also, from industrial trials it became clear that higher the bottom blowing flow rate, the closer were the end point P to the equilibrium. Despite this result an analysis of the apparent mass transfer coefficient has shown a week correlation with the classical power stir correlation suggesting a more complex kinetic limiting step for phosphorus removal.

Jul 30, 2018

By Anand Kumar Agrawal, Kinzel Klaus Peter, Lorenzo Micheletti, Cristiano Castagnola, Horst Kappes, Andre Oliveira, Björn Rösner, Philippe Bermes

Blast furnaces are widely employed today for iron production all around the world, with a total production of around 1.2 billion tons per year. Its operating principle, which relies on usage of coke to reduce the ore, to ensure the permeability in the reaction vessel, to maintain its flexibility of operation and acceptability for varying qualities of iron ores. The blast furnace route is widely considered as the most economic and efficient route of iron production, however it is based on fossil energy carriers. The blast furnace route has undergone significant developments in terms of energy efficiency in the last decades, which led to a substantial reduction in the use of fossil reduction materials. Being an energy intensive process, competitiveness and cost saving in the blast furnace plant was always strongly related to the saving of energy and hence reduction of CO2 emissions. In addition to this, EU emissions trading system (EU ETS) as a cornerstone of the EU's policy in response to climate change has set new “challenges” for iron production in Europe. Paul Wurth has always been deeply involved in the development of energy saving technologies for blast furnaces. In the following a review of energy saving achievements developed in the last decades will be presented and the potential of available CO2 saving technologies will be summarized. Additionally, an outlook about the potential of future technologies, concepts and their impact on the blast furnace and the steel plant’s energy balance will be discussed. Finally, the replacement of carbon by hydrogen as reduction agent in the steel plant will be reviewed, with special focus on a comparison of costs and incentives.

Oct 1, 2019

By Daniele Tolazzi

In today’s highly competitive market situation, it is of outmost importance for EAF steel makers to optimise their processes in order to reduce operating costs and to improve safety and reliability of the equipment. The laser based off-gas analysis technology, With laser units installed on the fix duct, downstream the combustion gap, uses the “Tuneable Diode Laser Absorption Spectroscopy” (TDLAS). The system performs real-time off-gas emissions measurements of CO, CO2, O2, H2O and temperature. A closed-loop operation is in place for dynamic control of the chemical energy package combustion/post-combustion of CO, H2 and CH4 gases into the EAF furnace shell. A statistical framework which builds on a data analysis engine, based on Danieli Automation Q3Intelligence technology, evaluates the “fingerprint” of the process represented by average and deviation trends of both gases and other process parameters. Process fingerprinting is conceived both for offline profile optimisation and on-line control of the refining process. This paper describes how the technology has been applied and the results achieved at ACCIAIERIE BERTOLI SAFAU (Italy) 100 t AC Electric Arc Furnace.

Aug 16, 2017

By Daniel Augusto Godinho de Carvalho

Since the beginning of BOF process, slag formation has been subjected to extensive development. During the initial stages of the blow, fast slag formation is primordial for the process performance. This is mainly to allow oxidizing reactions, and also to protect the refractory. A modeling of BOF process for the purpose of process optimization requires precise knowledge concerning the dissolution of CaO and MgO based materials. Using this knowledge, the optimal process conditions can be ensured by a controlling of the slag formation during the converter steelmaking process. Taking into account an application of large amount of different raw materials, as well as location-specific process conditions, the characterization of the dissolution behavior of different additives is an important key to improve the technological process. Thereby, in the frames of this project, an appropriate model for slag formation is established and compared to operational results for a 330t BOF, operating at ThyssenKrupp CSA, Santa Cruz, Brazil.

Aug 16, 2017

By Helênio Resende Silva Júnior

Arcelor Mittal Asturias coking plant at Gijon works, Spain, is undergoing a complete modernization of the whole coke making complex. In this context, Gijon has to be considered a brownfield project, where Paul Wurth has been awarded with the engineering, supply of key equipment as well as erection and commissioning supervision services for the rebuild of two coke oven batteries the modernization of the adjacent by-product and relevant waste water treatment plants. Main objective of this paper is to present the technological improvements introduced by Paul Wurth in the rebuild of a modern plant focusing on fulfilling all the recent environmental regulations.

Oct 30, 2017