Search Documents

By I. Iwasaki, R. Titi-Manyaka

Thermogravimetric analyses were used to formulate the chlorination and chloridization behaviors of such metals as iron, manganese, copper, tin, nickel, and zinc and their oxides; of lime and magnesia; and of such minerals as calcite, siderite, rhodochrosite, rhodonite, and apatite- all commonly encountered in ironmaking raw materials. Complexities of the reaction steps involved were indicated by plotting thermogravimetric analysis curves and the possible mechanisms were discussed based on the theoretical weight changes and thermodynamic considerations. The relative effectiveness of chlorine and hydrogen chloride as chloridizing agents was considered in the light of the experimental results.

Jan 1, 1973

By Owen S. Roberts

During the design phases of a conveyor system, the question arises regarding the type of drive required for each application. The paper shows that the correct drive for any particular application is the one that satisfies the criteria established for that application in the most economical manner consistent with such considerations as site location, availability of spare parts, area environmental conditions, power supplies available, etc. Following discussions of various mechanical arrangements for the drives, motor types and their characteristics are considered along with the control means of modifying these characteristics to satisfy individual requirements. These characteristics are all illustrated graphically. After selecting the motor and its starter, control accessories and interlocking arrangements as applied to material handling systems are discussed.

Jan 1, 1973

By L. F. Engle, M. A. Hewedi

SUMMARY Initial interest in using solutions of ammonium salts to leach native copper was documented in notes from an AIME meeting in 1871; By 1916-1917, application of the NH3-CO2-H2O system to recover nonferrous metals attained commercial significance, when it was used as a process for copper recovery by Kennecott Copper Corporation and Calumet & Hecla Mining Company. The Caron work in the early 1920s, Freeport Sulphur Company’s achievements leaching Cuban laterites during World War II, out- standing accomplishments in both eastern and western Canada, recovery of manganese related to the work of Dean -- all serve as landmarks as this One Century Review surveys a base for future technology. Current emphasis on compatibility of metals-producing systems with the need to meet environmental protection criteria provides special encouragement to researchers and engineers to find accept- able ways of recovering metals. The ever-present demand of management to design, build and operate facilities on a profitable basis provides additional impetus to apply information from the technical literature to that need. Examination of the general approach to this paper will reveal much that is firm and positive with respect to empirical results -- extractions, recoveries, amenability to familiar proven equipment and materials of construction common to the industry. Although there are many references, there are gaps in the basic scientific data that if filled could lead to even more usefulness; the paper attempts to indicate where further information is needed.

Jan 1, 1973

By W. A. Hockings, G. W. Lower, K. A. Smith

The kinetics of dissolution of metallic copper in aqueous cupric ammonium carbonate solutions were investigated. The major variables studied were temperature, agitation, and the cupric, cuprous, ammonia and carbonate concentrations. The rates of copper dissolution from rotating discs were determined by measuring the weight loss. The dissolution rate increased with the square root of the disc rpm and doubled when the temperature was increased from 20°c to 40°C.

Jan 1, 1973

By Kenneth W. Luke

A computer programing system has been devised to assist in open pit mine design planning. This system operates upon data generated for cross sections in the mine plan, and parallels present manual methods used in mine design, resulting in a minimal communications barrier between the mine planner and the computer. Input data for each cross section includes geologic interpretation and mine design parameters such as wall angles, bench heights, berm widths, and ramping system. The program will optimize the design of each cross section to give minimum stripping at any desired ore reserve level. This system is functional in the sense that it is easily adopted, changes in mine design parameters can be quickly evaluated, and each resultant design incorporates all recognized mining constraints.

Jan 1, 1973

By M. P. Nackowski, Armond H. Beers, W. T. Parry

Three hundred soil samples were collected on a one-mile grid in a 400-square mile area of the Oquirrh Mountains, Utah, including the Bingham-Lark, Ophir, Rush Valley, and Mercur mining districts. The soil samples were analyzed for copper, lead, zinc, silver, molybdenum, manganese, and iron by X-ray fluorescence using arsenic as an internal standard. Anomalies coincide in most cases with the mining districts. However, in the Mercur district no anomalies were detected. Also samples collected one mile from the Bingham mine barely reflect this major producer. No samples were collected within the Bingham mine area.

Jan 1, 1973

By O. Knacke, H. Barth, W. Gans

The rate of cementation was determined by measuring the time required to consume a thin electrodeposited layer of the cementating metal as indicated by a sudden increase in the electrical potential. The diffusion controlled cathodic current of the more positive metal was measured by conventional electrochemical techniques and compared with the cementation rate under the same experimental conditions. Micrographs revealed different types of crystal growth in different surroundings e.g. dendritic growth in acidic solutions.

Jan 1, 1973

By M. D. Everell

A study has been made of the relationships between grinding selection functions and physical properties of rocks, particularly the failure loads of irregular particles and the compressive and tensile strengths of large regular specimens. The rocks used were limestones of various structures and impurity contents, a carbonatite, and a high-purity crystallized calcite. The selection functions were obtained from carefully performed grinding experiments on selected narrow size ranges in various grinding machines-a laboratory batch ball mill, a Hard grove grindability machine, and a mill of the type suggested by Yang, Mempel, and Fuerstenau. The specific rates of breakage during milling and the failure loads of irregular specimens correlated well for the rocks studied. The testing of irregular particles is suggested as a means of predicting the behavior of commercial mills.

Jan 1, 1973

By Tadao Nagai, Masao Sato

Electrochemical measurements have been carried out in an auto- clave to investigate the electrochemistry of hydrogen precipitation of nickel from acetate buffered solution. After having previously obtained the rate equation for this reaction we have now made a concentrated effort to explain the rate equation electrochemically. A saturated NaC1-type Ag/AgC1 reference electrode has been improved so that it can be used in an autoclave. Polarization curves for the reaction, [H2=2H+ + 2e,] on nickel electrode were measured in solutions free from nickel ions at 185°C, and the parallel curves were obtained by changing PH2 and pH for normal and reverse reactions, respectively. Polarization curves in nickel solutions were complex, probably because the potential of hydrogen electrode is close to that of nickel and of the nickel surface altered during polarization. Then the nickel electrode potential and the reaction rate were measured simultaneously during pressure reduction at various hydrogen pressures and at various nickel concentrations. The reaction rates in terms of current density were plotted to obtain the local polarization curves for reactions Ni2+ + 2e ? Ni and H2 ?2H+ + 2e. The anodic and cathodic local polarization curves exhibit potential dependency. Therefore it is likely that the pres- sure reduction can be regarded as a coupled electrodes reaction.

Jan 1, 1973

By E. J. Freeh, W. E. Horst

Mathematical models of a continuous comminution process are developed as an extension of the batch grinding model. Pilot-scale experimental work is described and the results are used to demonstrate the capability of the comminution models to simulate observed behavior over a relatively wide range of process variables.

Jan 1, 1973

By I. H. Warren, E. A. Devuyst

The selective dissolution of pyrolusite (MnO2) in presence of goethite (FeO•OH) in aqueous ammoniacal ammonium carbamate solution has been investigated: various reducing agents were studied, in particular sodium sulfite (Na2SO3,) and hydrazine hydrate (N2H4•H2O). Sodium sulfite was found to be an unsatisfactory reducing agent for both goethite and pyrolusite, for the leaching rate decreased steadily with time to an impractical level because of the limited solubility of the reactions products. Hydrazine hydrate was an effective reducing agent for pyrolusite even at low temperature, whereas goethite required much higher temperatures for any appreciable dissolution. A 1-hr leach at 35°C dissolved 90% of the pyrolusite but only 0.1% of the goethite. An activation energy of 17.0 Kcal per mole was found for the dissolution of pyrolusite with hydrazine. A reaction mechanism for the leaching of pyrolusite with hydrazine is proposed in which a reduction reaction on the surface of the mineral is the rate-determining step. The application of ammonium carbamate to the beneficiation of ilmenite is briefly described.

Jan 1, 1973

By Klaus Schoenert

In the analysis of comminution processes, it is necessary to have a detailed knowledge of such subprocesses as: transportation of the particles to the zone where they are stressed; the stressing of particles to a level high enough for breakage; removal of the fragments that are smaller than the limit size from the grinding zone; and prevention of agglomeration of the fine fragments. Breakage phenomena of particles is the most difficult subprocess to understand. It can be understood only by applying the principles of fracture physics to obtain information about the stress-strain field in particles which are loaded either by compression or by impact, and by using this theoretical knowledge to interpret experimental results obtained from single particle crushing studies. Two important features of the "Science of Communition" are discussed: the fracture physics and crushing under controlled conditions with special reference to single particle crushing, packed bed crushing, measurement of energy needed for fracture, fragment size distribution, and new surface area produced. The important features of these aspects are detailed, namely, energy balance of a crack, influence of environment, specimen size problems, and energy utilization in single particle crushing.

Jan 1, 1973

By Allan D. Taylor, Robert S. Shoemaker

Adopting as a principle the phrase "the mill of yesterday should not be built with the high cost money of today," the authors have designed a hypothetical concentrator which could be built for a typical southwestern United States (or other similar area) copper ore. Many of the design features could also be used for other ores in other climates. Functional design, large equipment, and outdoor type of construction have been combined in a concentrator (which includes all ancilliary facilities such as truck and maintenance shops, offices, warehouse, nominal tailings disposal, and water supply) which could be built today for substantially less than the cost of comparable but conventional plants.

Jan 1, 1973

By John S. Sumner

The various electrode arrangements used in induced polarization (IP) surveying can be classified according to the geometry of the electric field being measured. The simplest geometry (Wenner, Schlumberger, gradient) is the parallel or plane-wave electric field, while the three-array and pole-dipole array measure the field about a point current electrode. In the dipole-dipole array the characteristics of a dipolar field are approximately measured. The drill hole arrays employ variations of these fundamental geometries, depending on the objectives of the survey. This report compares the relative advantages and disadvantages of each of the commonly used surface and drill hole IP electrode arrays. Factors of each array that are considered are signal-to-noise ratio, EM coupling rejection, speed and cost, and resolution of polarizable bodies. It is concluded that certain arrays are better suited for different exploration objectives and for different geological conditions. Also the type and capabilities of the IP surveying equipment and method limit the choice of arrays.

Jan 1, 1973

By Alan R. Grant

The Cascade Range of Washington can be considered metallogenetically to be primarily a copper province. Structural and chemical data compiled from examination of numerous copper occurrences in the Cascades indicate a marked parallel of physical conditions for sulfide deposition. In probable order of significance, the environmental criteria are as follows: 1) adjacent or subjacent, postregional metamorphism high-level intrusive activity, most commonly in the time range from 15 million years to 30 million years; 2) transverse northeast trending structural belts which obliquely cut the northwest regional trend of the range; 3) potassium-silica wall rock alteration; most important of the alteration suite of silicates are orthoclase secondary biotite and quartz; 4) the intersection of northwest trending and northeast trending structures. The varying geologic environments in the Washington Cascades present a complex setting for the sulfide deposits. The North Cascades are comprised of predominantly pre-Tertiary metamorphic rocks invaded by Tertiary calcalkaline intrustive rocks. The Central Cascades, lying south of the North Cascades, exhibit a younger, higher level geologic environment comprised of predominantly early to middle Tertiary volcanic rocks and subordinate sedimentary rocks which are intruded by Tertiary calc-alkaline igneous rocks. Although the Tertiary Cascade intrusions are dominantly quartz dioritic, copper mineralization is commonly found in rocks of quartz monzonite to granite composition. These acid rocks appear to be the product of late stage magmatic K alteration of the original quartz diorites. Sulfide concentrations are considered to be in part dependent on the degree of K-silicate activity and the intensity of transverse structural deformation.

Jan 1, 1973

By A. B. Johnson, J. S. Browning

The USBM has developed new and improved physical beneficiation techniques for economically recovering potash minerals from high-clay and low-grade ore from the Permian Basin of New Mexico. With the depletion of the high-grade ores a need for changes in industry's standard methods of recovery is a must. Technology may be improved in the beneficiation of the ore prior to mineral flotation and in brine clarification from the desliming phase to effect a reduction of losses of fine potash and brine in the disposal of the clay slimes. This report summarizes the results of these tests and demonstrates the feasibility of producing products that meet the requirements of the agriculture market, namely, 95% KCl equivalent to 60% K2O with recoveries ranging between 80 and 90%.

Jan 1, 1973

By Charles H. Jacoby

Solution-mined salt cavities are being used for storage of liquid petroleum gas, natural gas, and other hydrocarbons; waste disposal or storage; storage of radioactive wastes; and as a surge vessel for air compressed by an electric utility during off-peak hours. Examples of each use are given. Other contemplated uses of salt cavities are noted.

Jan 1, 1973

By Vernon E. Swanson, Tom G. Ging

Experiments indicate that simple addition of water to mixtures of untreated trona and otherwise insoluble leonardite yields a rich, black, slightly alkaline solution of concentrated humic substances. Prices of both trona from Wyoming and leonardite from South Dakota and Wyoming are very similar-$10-30 per ton. Leonardite is the term commonly given to naturally weathered, oxidized coal that is readily soluble in slightly alkaline water.1 Several tens of thousands of

Jan 1, 1973

By C. F. Kaiser, T. J. Roberts, I. A. Thomson

The Broken Hill Pty. Co. Ltd. grate-kiln pelletizing plant located at Whyalla, South Australia, produced a total of 250,000 tons of fluxed pellets during 1970. More than 180,000 tons were exported to Japan, while the remainder was used in B.H.P. Co. blast furnaces. The pellet plant treats high grade hematite ore fines and has a nominal capacity of 1.5 million tpy. The induration equipment includes a grate 12-ft 2-in. wide by 164-ft 1-in. long, a kiln 18-ft 6-in. diam by 118-ft 8-in. long, and a rotary cooler 50-ft mean diam by 7 ft wide. Operating problems encountered in the production of fluxed pellets are detailed. The most significant aspect of the trial was the increased production, from about 5100 tpd up to a maximum of 7100, brought about by the addition of artificial magnetite to the plant feed. Laboratory evaluation of fluxed pellets showed that pellets having a basicity ratio (CaO to SiO2) in excess of 1.2 have excellent physical qualities. Reducibility and compressive strength after reduction were both higher for these fluxed pellets than for normal acid pellets. Although it was not possible to publish blast furnace operating data, blast furnace trials on fluxed pellets indicated that production was higher and dust losses substantially lower, compared with similar operations on acid pellets.

Jan 1, 1973

By J. R. Ross, J. B. Rosenbaum

Bureau of Mines research has resulted in the development of fluid- bed ion-exchange columns for recovering uranium from slime pulps. In pilot plant tests, slime slurries containing up to 6 percent solids were processed at flow rates of 10 gallons per square foot per minute with high uranium recoveries and efficient resin loadings. Uranium was effectively eluted in a laboratory fluid-bed elution column at eluate-to-resin ratios of less than 5:1 and eluate flow rates of 3 gallons per square foot per minute. Construction costs of mills using these improved ion exchange techniques are estimated to be 25 percent less than for mills using solvent extraction of clear solutions. For mills having a capacity of 2,000 to 2,500 tons of ore per day, the saving would be in the range of $2.5 million. In addition, a saving of about $0.80 per ton of ore in total operating costs is indicated.

Jan 1, 1973