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By Robert M. Funk, James E. Lawver

The development of a laboratory and pilot-scale high-tension electrostatic flowsheet for the production of iron-ore super concentrates having silica contents in the range of 0.1% is presented, A variety of hematite and magnetite ores were tested with this flowsheet, and the pertinent metallurgical data are given. The applications and limitations of this process are brought out in terms of both practical and theoretical considerations. There have been many new developments in the past few years that have required mineral beneficiation engineers to consider new techniques for iron-ore concentration. Developments in iron powder metallurgy, and particularly the making of sheet metal directly from high-purity iron-ore concentrates, and the concept of using metallized pellets as a substitute for scrap in electric-furnace steelmaking have created demands for what is commonly referred to as iron-ore superconcen-trates. In most cases, specifications for superconcentrates are that they contain less than 0.1% total gangue, with some applications requiring less than 0.05% gangue. To produce these concentrates, new and modified processes are being developed, and the three methods receiving attention as the primary concentrating methods are: 1) Magnetic separation in which dry rotor-type equipment is used for magnetite and the high-intensity magnets are used for hematite. 2) Amine flotation. 3) "High-tension" electrostatic separation (or, elec-trodynamic concentration). This paper examines the high-tension electrostatic process in terms of its limitations and abilities for the production of iron-ore superconcentrates. A technically effective and simple flowsheet was developed through laboratory and 5 and 100-ton pilot-plant studies for the production of concentrates containing from 0.02 to 0.20% SiO, with iron recoveries between 85 and 90%. The process is also shown to be economically feasible. Laboratory Test Program Separation Characteristics: The suitability of the electrostatic high-tension method for iron-ore supercon-centration stems from the fundamental mechanism governing the process, i.e., particles are separated on the basis of differences in electrical conductivities. This conductivity is a characteristic property of minerals, and if the difference between the conductivities of two min- erals is great enough, then their separation can be performed by a high-tension machine. As shown in Figs. 1 and 2, the critical factor is the time necessary for the particle charge density, which is established by a corona discharge field, to decay to a level such that the centrifugal force acting on the particle exceeds its electrostatic, or image, force. At this point, the particle can leave the rotor at some trajectory and fall into an appropriate product receptacle. This decay time is directly proportional to electrical conductivity, and the process variables, such as feed rate, rotor speed, electrode configuration, and rotor composition, are selected to optimize the ability of the separator to resolve different conductivities. Table 1 lists the measured conductivities for some of the iron and gangue minerals used in developing the flowsheet. These results were obtained by using the conductivity cell described by Lawver and Wright.' The discharge curve of most minerals that lend themselves to super concentration by high-tension is so fast that the

Jan 1, 1971

By D. S. Flett, D. W. West

The solvent extraction of chromium 111 has been studied for the system Cr 111, H,SO., H,O/RNH/RNH., xylene, where the primary amine used was Primene JMT. Rate studies have shown that extremely long equilibrium times are required, ranging from 1 hr at 80°C to 20 days at room temperature. Heating the solution prior to extraction increases the rate of extraction. The variation in the amount of Cr 111 extracted is an inverse function of the acidity of the aqueous phase. Thus, the slow rates of extraction appear to be connected with the hydrolysis of the Cr I11 species. Extraction isotherms for the extraction of Cr 111 have been obtained for two sets of experimental conditions, namely at 60°C and for a heat-treated solution cooled to room temperature. The separation of Fe 111 from Cr 111 and Cr 111 from Cu 11 in sulfate solution by extraction with Primene JMT has been studied and shown to be feasible. A survey of the literature relating to the solvent extraction of chromium showed that, although many systems exist for extraction of Cr VI, only a very few reagents have been found to extract Cr 111. The extraction of Cr III by di-(2-ethyl hexyl) phosphoric acid has been reported by Kimura.' A straight-line dependence of slope —2 was observed between log D,, and the log mineral acid concentration at constant extractant concentration. Since the slope of this plot reflects the charge on the ion extracted, it must be concluded that a hydrolyzed species of Cr III is being extracted. Carboxylic acids generally do not form extractable complexes with Cr III but di-isopropyl salicylic acie does extract Cr 111. Simple acid backwashing of the organic phase, however, failed to remove the chromium. Similar difficulty in backwashing was found by Hellwege and Schweitzer8 in the extraction of Cr I11 with acetyl-acetone in chloroform. The extraction of Cr 111 from chloride solutions by alkyl amines has been reported4-' but the maximum amount of extraction achieved in these studies did not exceed 10%: From sulfate solutions, however, Ishimori" has shown that appreciable amounts of Cr I11 were extracted by amines. The amines used were tri-iso-octyl amine, Amberlite LA-1 (a secondary amine, Rohm & Haas) and Primene JMT (primary amine, Rohm & Haas). The efficiency of extraction with regard to amine type was primary>secondary> tertiary. Appreciable extraction of Cr I11 was recorded for Primene JMT as the aqueous phase acidity tended to zero. The major difficulty with Cr I11 in solvent extraction systems stems from the nonlabile nature of the ion in complex formation. This accounts for the slow rate of extraction generally experienced and the difficulty encountered in backwashing the Cr I11 from the organic phase in the case of liquid cation exchangers. Consequently, the possibility of extraction of Cr I11 as a complex anion is attractive since the backwashing problems should be minimized in this way. From published data, it appeared that the extraction of chromium from sulfate solutions of low acidity by primary amines afforded the best chance of success for a useful solvent extraction system for Cr iii This paper presents the results of a study of the extraction of Cr I11 from sulfate solution by Primene JMT and examines the application of such an extraction procedure for the recovery of chromium from liquors containing iron and copper. Experimental Chromium solutions were prepared from chrome alum in sulfuric acid and sodium sulfate so as to maintain a constant concentration of sulfate ion of 1.5 molar. Solutions of Primene JMT were prepared in xylene and the amine equilibrated with sulfuric acid/sodium sul-fate solutions, of the same acidity as the chromium solution, until there was no change in acidity between the initial and final aqueous phases. The solutions of Primene JMT conditioned in this way were then used for the equilibration experiments. Equilibrations at 25°C were carried out in stoppered conical flasks shaken in a thermostat; equilibrations at all other temperatures were carried out in stirred flasks in a thermostat. After equilibration, the phases were separated and analyzed for chromium. In the tests on the rate of extraction, small samples of equal volume of both phases were withdrawn from time to time and the chromium distribution determined. The chromium analyses were carried out either coloi-imetrically using diphenyl carbazide, or volu-metrically using addition of excess standard ferrous ammonium sulfate and back titration of the excess iron with potassium dichromate. The oxidation of Cr 111 to Cr VI in the case of the raffinate solution was effected by boiling with potassium persulfate in the presence of silver nitrate and, for the backwash solution, by boiling with sodium hydroxide and hydrogen peroxide. Results Preliminary experiments indicated that extraction results were effected by the age of the chromium solution, higher distribution coefficients being obtained with solutions which had been allowed to stand for some time. Consequently a stock solution of chrome alum, 10 m moles per 1 Cr I11 in 1.4 M Na,SO,/O.l M &SO,,

Jan 1, 1971

By A. Blake Caldwell

Northwest frontier is here defined as Alaska, the Yukon, the Northwest Territories and northern British Columbia. The mineral potential of this area is great and will unfold in the decade ahead but now the largest single producer is the Pine Point lead-zinc mine in the NWT about 1200 km north of Edmonton, Alta., close to the south shore of Great Slave Lake. The mill, initially designed for 4540 mtpd, was expanded to 7250 mtpd in 1969. This operation is described in detail in Mining and Concentrating of Lead and Zinc, Vol.1, Chapt. 17, SME/AIME in the article by W. H. R. Gibney.

Jan 1, 1971

By R. J. Lutton

Empirical data from 91 rock excavations have been used to construct a family of slope curves on a chart relating excavation height and inclination. The highest and steepest slopes from each excavation are plotted and connected by a line. The 31 1ines appear to establish one or two geometrical slope fields through which the curves are projected. The curves apparently represent a lumped eflect of many factors too complex to be considered individually. Important factors such as geological structure or ground-water conditions can dominate the picture, but where these factors do not overshadow others, the slope chart should be useful for estimating or checking optimum inclination. The U.S. Army Corps of Engineers (USAE) has been engaged since 1962 with the U.S. Atomic Energy Commission in a joint research program to develop nuclear excavation technology. The Corps is responsible for collecting the requisite data on engineering and construction problems associated with nuclear excavation. The ultimate objective is to develop a capability to use nuclear explosives as a construction tool on public works projects such as harbors and canals. The present study on empirical inclination-height curves for conventionally excavated slopes is an outgrowth of an investigation' sponsored by the USAE Nuclear Cratering Group on applicability of data from existing excavations in establishing guides for engineering judgment in crater excavation. Data were generously contributed by over 50 mining companies among other organizations. Inasmuch as several companies preferred that their contribution be anonymous, all data are treated so here. Some Factors Affecting Stability Many factors affect or are suspected of affecting the stability of excavated slopes, e.g., adverse structural orientation, degree of structural ordering, ground water, climatic conditions, mechanics of excavation, and plan-profile configuration. Such factors are lumped together in developing a slope chart. Obviously geological structure and ground water can overshadow all other factors. Where such is the case, the simplification of slope charts may give an erroneous picture (not conservative enough). A further complication results from the fact that the concept of stability may vary according to the use of the excavations. For example, slope adjustments that would be regarded as failure in a powerhouse excavation, might be tolerable in a mining operation. Mine slopes are continually being modified by further excavation, and instability that would develop in a similar permanent excavation slope over a period of years might not have time to develop in a mine. Inclination vs. Height Charts Charts of inclination vs. height for particular formations or conditions have been used in the past as an aid for designing excavation slopes. Some of these have been based upon empirical analyses of collections of data and experience. MacDonald" and Lane have presented slope tables and charts for excavated and natural slopes in relatively weak sandstone and shale. Coates' has shown an inclination-height chart for slopes in incompetent rock. Most organizations have developed slope design criteria which relate bench widths, heights, and inclinations to use in various rocks. Slope data collected in present studies can be similarly used to develop inclination-height charts; however, a plot of all slopes on such a chart shows very little because of the wide spread of the data. Reasons for the dispersion of points are: (1) many slopes are not carried at optimum inclination, particularly in mines where maintaining roadways and following irregularities of ore bodies are more important than achieving steep inclinations; (2) many engineers and geologists with varied backgrounds and viewpoints have been involved in designing these slopes; and (3) each slope is characterized by a unique combination of factors affecting stability and in turn optimum inclination. Significant curves can sometimes be constructed where the points can be grouped into related clusters from the same excavation. The essence of this approach appears when only two slopes from each excavation are considered—the highest slope and the steepest slope, connected by a line segment (Fig. 1). This reduces considerably the usable data because in many cases only one of these two slopes is available. Nevertheless, the concession seems justified. Construction of Slope Curves Ninety-one pairs of points and connecting line segments were assembled in this study. The line segments were assumed to approximate a geometrical slope field (Fig. 2), and a family of curves has been visually projected through to represent the slope field. It should be

Jan 1, 1971

By R. E. Rowlands, I. M. Daniel

An experimental study is discussed of the state of strain, deformation and fracture around lined and unlined cylindrical cavities in rock under biaxial compressive static loading. The specimens were limestone plates 36 in. high, 24 in. wide and 3 in. thick with a 4 in. diameter hole unlined or lined with hydrostone and aluminum liners. The ratio of horizontal to vertical applied stress was one-third. Experimental techniques used were strain gages, differential transformers and photoelastic coatings. Strain distributions were plotted along the horizontal axis of symmetry for various levels of applied stress. The agreement with theory was good at low stress levels but appreciable deviations occurred at higher levels and near the hole. The experimental strain concentration factor was nearly the same, slightly higher and appreciably higher than the theoretical value for the hydrostone-lined, unlined and aluminum-lined specimens, respectively. Failure modes were splitting along a vertical plane for the unlined and hydrostone-fined specimens, compressive (shear) failure for one unlined specimen and splitting with radial cracking for the aluminum-lined specimen. In the latter, a maximum tensile stress of more than three times the uniaxial tensile strength existed at the interface with the liner at the time of fracture,

Jan 1, 1971

By John V. Beall

On weekends things get pretty interesting out our way because the fleet is usually in. Our No. 2 son is now based at New London, which Isn't far from here, and he brings his friends home. No. 1 son is a re- cent Navy veteran, and he lives at home. It is just as well that the Pentagon can't hear what is said. This is all aside from the point except that last Friday evening, Dave Meinhard, a redheaded nukie (nuclear sub crewman) from Indiana, commented on our late arrival home In obvious need of a pick-me-up. "Just like my dad; but he has it rougher than you. We live in La Porte, Ind., and every day he drives 35 minutes to work at Bridgeman, Mich., and loses an hour on the time zone. It's really exhausting. You should see him." We feel very sympathetic. He should receive extra pay. However, extra pay benefits are hard to come by although the reverse comes relatively easy. For example Grass Valley, Calif., was such a nice place to live 25 years ago that they compensated for it by making an appropriate deduction for the s

Jan 1, 1971

Jan 1, 1971

By Wayne E. Glenn

A centennial meeting should be a time to take stock, to evaluate performance, to plan ahead. It is like a line in a televised commercial that goes, "You've come a long way to get where you've got to today." And no less should be said of the mining and energy industries. We have come a long way. A hundred years ago when AIME was founded, this country produced 23 million tons of bituminous coal and 5.2 million bbl of oil. The figures in 1970 were about 580 million tons of coal and 4.1 billion bbl of oil. In spite of such accomplishments, serious and compelling voices are heard in the land - doubting sincerity, questioning corporate structures, and challenging ethics. Those doubts are raised in one part of Washington at the same time that other sections of the Capitol are asking us to produce more energy in order to keep up with population growth, emerging nations, and new technologies. Those of us in the fuel or energy business frequently talk about the race for energy. The question is, can we develop enough energy fast enough to outdistance our present and increasing demands? Recently I heard of an incident that - in an odd way - caused me to think of the energy race. The incident involved a sky-diver who jumped from an airplane without a parachute. He was handed a chute in mid-air by a sky-diving companion. He put it on, opened it, and landed safely. In a way, it seems to me that our society is hurtling through space and that it needs some help from the energy industries to land safely. We're doing our best, but under some rather difficult conditions. Because of illegal strikes and work stoppages the coal parachute is snarled a bit. The cut in percentage depletion and other tax changes have put some holes in the oil parachute. And the gas ´'chute has been in trouble for some time because of unrealistic controls on producer prices. The irony of the situation is that some of the very people who have been taking potshots at the energy parachutes for a long time are the ones who are complaining loudest now because the 'chutes are not functioning the way they could. The safety of the entire nation can depend on the energy industries.

Jan 1, 1971

By Jack Fox

Last time there was a Take Five in these pages, it dealt largely with the matters considered by your Board of Directors at the meeting on October 20, 1970, in St. Louis, Mo. It was impossible to cover all the points worthy of discussion in the space available. So, at the end of the Take Five in the December issue of [i=], I promised to continue in the next installment. Unfortunately, I was unable to keep that promise. On December 2 your humble servant joined the ranks of those who have suffered a coronary occlusion. While I was away from the office, the very excellent SME staff team that we have built up over the years kept things going without bothering the "old man" unnecessarily. Assistant Executive Secretary, John V. Beall, Mrs. Lillian E. Donaldson, Assistant to the Executive Secretary, Mrs. Ruth Orologio, Administrative Assistant, and Mrs. Alice Ruiz exceeded even their usual dedicated efforts. As a result, the SME came up to the Centennial-Annual Meeting in great shape.

Jan 1, 1971

By John V. Beall

Our moment of truth is in the offing. When the SME Directory is published in this July issue of [8:] we will know how good or how bad our system is for this computerized Directory. At this writing we have not seen the printout. The SME Directory is designed for maximum utility by the membership but this, of necessity, makes the job complicated. In the alphabetical section, names are listed last name first, followed by codes indicating the class of membership, year of election and divisional interests of each Member. This information is followed by job title, company division, company name and address complete with zip code, or simply by the mailing address of the Member in cases where he either has no company or has not supplied the company information.

Jan 1, 1971

By James M. Winston

When I began my career (the first assignment was mucking the "drainage" ditch) an experienced miner told me, "Remember son, happiness is a journey, not a destination. . . ." If you missed the 100th Anniversary of AIME in New York this year, you are missing the journey. There are not enough superlatives to describe the event. Especially since New York is "known to have it all." An Indefinable Plus There was a little something different at this meeting. I cannot explain what, but there seemed to be more of everything. There were more wives there this year-what a pleasure to see all the lovely women mingling through the conference- which was reflected through our own attire and mannerisms. In fact, everyone looked so great, we checked to see if it really was a convention of miners. You wives keep coming to all of the events, because so much is added by your presence.

Jan 1, 1971

By S. Usui, I. Iwasaki

The effect of pH on the adsorption of dodecylamine at the mercury-aqueous solution interface was investigated by differential capacity and electrocapillary measurements. With dodecylammonium acetate, the differential capacity curves showed two desorption peaks in the cathodic branch with their relative intensities varying with the solution pH. With dodecyltrimethylammonium chloride, only one cathodic de-sorption peak was observed in the same pH range. Through thermodynamic analysis of the electrocapillary curves, the adsorption density of undissociated amine was evaluated separately from that of aminium ion. The adsorption densities of the un-dissociated amine and of the total amine increased with increasing pH. The ratio at the interface of undissociated amine to aminium ion was several orders of magnitude greater than the ratio in the solution and increased with increasing pH. The potential at the closest distance of approach of counter ions to the mercury surface was compared with values of zeta potential on quartz previously reported. The most important variable in the flotation separation of minerals is probably the pH of the pulp, and a number of theories have been proposed to explain its effect on the condition of the mineral surfaces, on the dissociation of collectors and of inorganic and organic species (accidentally present or intentionally added) in the pulp, and on the mineral-collector interaction. In the development of a theoretical background for oxide flotation systems, an experimental approach based on electrokinetic measurements has been of much value, although the effect of pH becomes confounded since it governs both the electrochemical conditions of the oxide surface and the dissociation of the collector. For investigation of the adsorption behavior of long-chain collectors on oxide minerals, however, electrokinetic potential measurements are the most widely used technique. Hydrogen and hydroxyl ions are found to be the potential determining species, thereby governing the interfacial electrical conditions. The electrostatic interaction between the charged mineral surfaces and ionized collectors is regarded as the driving force for the adsorption of the collectors. An association of alkylamine collectors adsorbed on quartz surfaces has been postulated from streaming potential measurements, and a term "hemi-micelles" has been proposed.' The possibilities of coad-sorption of undissociated amine along with aminium ion has been inferred from contact angle measurements? and from adsorption studies.~ Electrochemical titration as applied to silver sulfide provides a more quantitative approach to the analysis of the electrical double layer at an ionic solid-solution interfaceqG and the electrochemical evidence for the adsorption of amine at pH 4.7 indicates a specific affinity of dodecylammonium ion towards silver sulfide surfaces, whereas at pH 9.2 the adsorbed species might be free arnine." A combination of differential capacity and electrocapillary measurements on a dropping mercury electrode was reported to be a sensitive method of provid- ing reliable information on the adsorption behavior of dodecylammonium acetate (DAA) at a natural (near neutral) pH.? It was also shown that there were striking similarities in the properties of the double layer and in the adsorption behavior of the amine on mercury and on such ionic solids as quartz, silver sulfide, and silver iodide. The effect of pH on the differential capacity curves at a mercury-sodium fluoride solution interface has been investigated by Austin and Parsonss who reported that between pH 7 and pH 11 there was very little effect. In the present paper, the adsorption behavior of DAA was investigated as a function of pH through differential capacity and electrocapillary measurements and the information gathered was correlated with that available in literature on quartz and silver sulfide. Experimental The apparatus and the method used for determining the differential capacity and the electrocapillary curves were identical to those described previously.' The ionic strength of the supporting electrolyte was fixed at 0.1 M with potassium fluoride, and the pH of the solution with potassium hydroxide. Only the neutral to alkaline range was covered in order to avoid the dissolution of the glass vessel with hydrofluoric acid. Results In Fig. 1 the differential capacity has been plotted against the applied potential at a DAA concentration of 10-' M at three different pH values. The curves are characterized by one capacity peak in the anodic branch, by two capacity peaks in the cathodic branch, and by a marked depression in capacity between the peaks. The depression indicates an adsorption of the arnine in this potential range. One of the cathodic peaks appears at pH 7.3 near -1.4 v and decreases with increasing pH. The other appears at pH 8.9 near —1.2 v and increases with increasing pH. At pH 9.6 only the latter peak is observed. Beyond the cathodic peaks, all the curves tend to converge with the curve in the absence of DAA, implying that two different species are being desorbed in this potential region. The anodic peak near 0.0 v increases markedly with increasing pH. The well-defined anodic peaks at pH 8.9 and 9.6 were accompanied by an appreciable increase in the current flow (in excess of O.luA), and, therefore, is a "pseudo-capacity"'" due to a

Jan 1, 1971

By Edwin B. Wilson, Joseph W. Leonard, Richard W. Borio

preparation of specification coals for the utility industry is approached from the standpoint of a cooperative effort with the power company to assure that the shipped product will be a noncorrosive coal. Selective mining, coal preparation, the use of additives, and coal blending are mine-site techniques proposed as means for upgrading corrosion-retarding constituents of utility coals (CaO and MgO) while, at the same time, reducing the concentration of those constituents of coal (Na20 and K,O) which cause corrosion. Data obtained from large-scale boiler testing in combination with bench-scale physical and chemical tests are used as a basis for the formulation of mine-site procedures to improve coal combustion utilization. Electric power generation remains the greatest market for coal in the United States. A major reason for this strong market has been the ability of the coal industry to supply a superior product for combustion while maintaining competitive prices. Now that the coal industry is engaged in intensive competition with nuclear power for future energy demand, it becomes ever more imperative that superior coal products are produced. One important problem when burning some coals is a liquid phase corrosive attack on boiler tube metal in the superheater and reheater areas of the furnace where steam temperatures may exceed 1050°F. In addition to causing power outages and high maintenance costs, corrosion is a continuing barrier to the future development of more efficient steam cycles which permit lower generation costs when using coal. Research methods of the past which have been directed at finding solutions which could be applied at the power plant site have been only partially successful and are generally costly. This paper contains a suggested --method of corrosion control through investigation of the problem at the source of the trouble—the coal supplier facility. It is proposed that mine-site pre-ventative procedures be considered as an effective means of cooperative corrosion control between the power company and the coal supplier. Economic justification must be applied to the individual situation. This paper is based on recent work by Combustion Engineering, Inc. and the Coal Research Bureau of West Virginia University under a contract from the Department of the Interior Office of Coal Research.',' Results which are of importance to this discussion may be summarized as follows: 1) The alkali minerals of coal (Na2O and K2O), as measured by an acid leaching process, can be related to corrosion rate in utility boilers. As these constituents increase in a coal product, its corrosiveness can be expected to worsen. 2) The alkaline-earth minerals contained in coal, reported as total CaO and MgO reduce corrosiveness 2s their concentration increases. 3) Naturally occuring, alkaline-earth-bearing materials, such as limestone and dolomite, may be added to a coal to reduce its corrosiveness. 4) Coals with very low iron contents tend to be less corrosive. These results provide the groundwork for examination of the system of operations which occur at the supplier facility from the seam face where mining is begun to the point of loading for shipment. The Mining System Fig. 1 is a cross section of one of the typical coal seams (designated coal A) that was boiler tested during this research program. This seam is overlain by material which consists primarily of a gray-black shale. In the lower third of this seam, there exists a thin rock parting of less than 4 in. in thickness which is consistent throughout the seam. The floor material is fireclay. In order to examine mineral distribution throughout this particular seam, the Coal Research Bureau collected a

Jan 1, 1971

By John V. Beall

Ten years ago, upon coming home to New York, we had money in the bank, a portfolio of stocks, a rent- controlled apartment overlooking the Hudson and we didn't own an automobile. This was bliss! The just reward of industry and careful management of the fruits of our labor in the mines overseas. Although we kept up a delaying action, the family was pushing hard for a house in the suburbs. We were able to find something wrong with every house that came up but, finally, in a weak moment made the unlikely compromise of putting ten dollars down on a piece of property in Westchester County.

Jan 1, 1971

An Interstate Mining Commission organized in Raleigh, N. C., on April 27 still has no offices, no budget and only four members, but it could spell the beginning of the end for the state-to-state environmental control variations that have lately been con- founding the mining industry. Established by Kentucky, North Carolina, Oklahoma and Pennsylvania, the new organization is committed to protecting land, water and other resources through improved strip and other mining practices. In pursuit of this end, it has broad authority to study all mining activities affecting the environment and to recommend improvements in mining practices and in laws regulating the mining industry. The Startup The Commission was created under an interstate Mining Compact enacted in the 1960's by the legislatures of the four member states. According to the rules of this Compact, the Commissioners in the new organization are, ex officio, the governors of the member states-namely, Chairman Louie B. Nunn (Ky.), Vice Chairman Robert W. Scott (N.C.), David Hall (Okla.) and Milton J. Shapp (Pa.). Each Commissioner, however, must appoint an advisory body to counsel him in matters relating to Commission business and delegate one member of this body to act as his alternate. Each advisory body must include representatives of mining, conservation and other public and private interests.

Jan 1, 1971

By Claudio Guarnaschelli

Alteration of the electronic distribution of mineral surfaces by light irradiation has been used to modify the adsorption characteristics of flotation reagents. Energy of a few electron volts is suficient to cause the necessary transitions that either enhance or retard the adsorption phenomenon. The adsorption characteristics of potassium ethyl xanthate on galena and marmatite are presented as functions of the energy of illumination, type of semiconductor, and surface oxidation. In dilute solutions, the adsorption differences are readily detected by controlled kinetic measurements. The correlation between the electronic distribution and the adsorption and desorption phenomena at the solid surface is gaining more attention and acceptance. These interrelations have found a practical application in mineral processing since all of the sulfide minerals display semiconducting properties. By varying the ratio of free electron to electron vacancies, the separation of ilmenite from rutilel and zircon from pyrochlore" has been executed successfully. Plaksin et al.' indicate three possible ways of utilizing the semiconductor properties of a mineral. The first one involves the control of the oxidation-reduction potential of the liquid phase, the second one consists of allowing selected additives to diffuse through the mineral surface, while the third one entails a change in the adsorption and chemical activity of minerals by irradiating their surface. The aim of the present work is to consider the effect of irradiation on the adsorption-desorption characteristics of natural minerals. Since the effect of irradiation is to change the electronic distribution at the surface:

Jan 1, 1971

By Bruce A. Kennedy

Lufthansa flight 497 roared down the runway and climbed rapidly through the early morning mist hanging over Pudahuel airport and the city of Santiago, Chile, into the brilliant sunlight above the clouds. As the plane banked onto course for Lima, Peru, we got what was possibly our last look at the beautiful snowclad mountains that ring Santiago. To the northeast was the massive hump of Aconcagua, the highest mountain in the Southern Hemisphere, wreathed in clouds and virtually looming over Rio Blanco, the new mine put into production by Cerro de Pasco just one short year before. Almost a thousand miles to the north lay the massive open pits of Chuquicamata and Exotica, and a little closer to Santiago the El Salvador mine. Behind to the southeast, clinging to the steep slopes of the Andes, was the large and awe-inspiring El Teniente mine at Braden. These mines, once the bastions of such companies as Anaconda and Kennecott, had a new owner-the Government of Chile. On the plane were a number of people who had spent a large part of their lives in Chile operating these mines and plants, and who now were suddenly faced with the necessity of starting new lives somewhere else. To them, this was their last look at the country which not too long ago was their home, a bittersweet moment of reminiscence and a time for questioning what the future held.

Jan 1, 1971

By Nathaniel Arbiter

There is a history in all men's lives, Figuring the nature of the times deceas'd, The which observ'd, a man may prophesy, With a near aim, of the main chance of things. W. Shakespeare, Henry IV; Part 2 Introduction This nation's first century embraced two stages of the Industrial Revolution. During one, what had been a colonial agricultural economy began to industrialize; water power, then steam after 1794, were the energy sources; coal and iron were the essential ingredients. The second stage started after 1850; aided by rich and diverse mineral resources, the country began its transition from the Iron Age to the Age of Metals. Early civilizations had been built on stone, and fairly high levels were sustained on iron. But the spectacular advances in the past century in communication, in construction, in transportation by sea, rail, land and air, and in much that characterizes modern civilization have depended increasingly on the use of the complete metallic and nonmetallic resources of the earth's crust. Thus it was appropriate to define the Industrial Revolution as “the period during which man's relationship to natural resources became utterly changed”, 1 with minerals playing a major and indispensable role. But we are now becoming aware that the relationship of man to natural resources must change again. On every hand the dangers inherent in the contamination of land, sea and air by the wastes of civilization are becoming apparent. And from the growing realization that mineral wealth is finite must eventually come other far reaching changes in mineral use and distribution. For on the scale of centuries we cannot continue to exploit mineral resources even at present rates, let alone at expanded rates, without eventual depletion of the more abundant resources, and early exhaustion of the less abundant. In the past our problems were relatively easily met by the development of new and improved machinery and processes. But the future will

Jan 1, 1971

By J. D. Vincent

During the history of man, the term concentration has had many meanings. Early in history, it may have been construed to mean sorting and smelting. Not many years ago, its definition included only the physical beneficiation processes. Today, and in this article, the term concentration is taking on the meaning of beneficiation and chemical processing, or either separately. An alternate definition could be: concentration is the process of recovering and upgrading an element or nonmetallic mineral so that the product can be used or refined for the needs of man. For the purpose of this article, concentration will have the same connotation as it does in the mineral industry, which has come to include processing methods such as leaching and chlorinization under this heading. Usually, smelting techniques and electrorefining are excluded and classified under the heading of refining. Using the broad definition of concentration, the areas of mining processing include not only the physical beneficiation processes and flotation but also hydrometallurgy and vapor-metallurgy. These methods include sorting, sizing, crushing and grinding, gravity concentrating, magnetic processing and flotation as well as hydrometallurgy and vapor- metallurgical processing.

Jan 1, 1971

By W. R. Davison, C. A. Brown, J. P. Carstens

INTRODUCTION The phenomenon of heat-weakening of rock with 10.6 micron radiation from a continuous-wave C02 gas laser has been investigated in detail at the Massachusetts Institute of Technology for over 5 years. The programs at MIT have explored the basic nature of the heat-weakening phenomena and rock fracture caused by heating (e.g., Refs. 1 and 2), and have resulted in quantitative estimates of the relationship between the amount and parer level of heating and the resulting decrease in the modulus of rupture of a rock beam in a three-point bend test (Ref. 3). Results of the tests reported in Ref. 3 indicate a greater than 90% reduction in the modulus of rupture for granite beams heat-weakened by a laser. These results prompted the U. S. Department of Transportation to seek an assessment of the expected feasibility of employing the heat- weakening concept in a full-scale tunnel boring operation. Present- day continuous rock-tunneling machines have demonstrated tunneling time and cost savings over drill-and-blast methods, when used in rock types that are easily broken by the cutters. However, cutter bits have not yet been developed which can easily penetrate very hard rock

Jan 1, 1971