Search Documents

By D E. Ralph, D-J Kim, G-J Ahn, Y-H Rhee

The amount of discarded dry batteries are presently found to be increasing globally and waste cathode active materials of the lithium ion battery industry are among them. Hydrometallurgical operations are being applied to recover the valuable metals from these waste batteries. To find an economic and environmentally friendly process, the bioleaching process was applied in the present investigation for recovery of valuable metals. Its principle is the microbial production of sulfuric acid and simultaneous leaching of metals. Bioleaching of spent lithium ion secondary batteries, containing LiCoO2, has been studied in this investigation. A new method for recovery of cobalt, potentially the basis of an economic and environmentally friendly process was examined. The present study has been carried out using chemolithotrophic and acidophilic bacteria Acidithiobacillus ferrooxidans, which utilises elemental sulfur and ferrous ion as the energy source to dissolve metals from spent batteries. Bio-dissolution of cobalt was found to be faster than lithium. The effect of initial Fe(II) concentration, initial pH and solid/liquid (w/v) ratio were studied in detail. Higher Fe(II) concentration showed a decrease in dissolution due to co-precipitation of Fe(III) with the metals in the residues. Similarly, at higher initial pH values and higher solid/liquid ratio (w/v) metal dissolution was found to be inhibited. The optimised conditions for bio-dissolution were solid/liquid (w/v) ratio û 10 g/L, initial Fe(II) concentration û 3 g/L, elemental sulfur û one per cent (w/v) and initial pH û 2.5. In the optimised conditions, cobalt dissolution was observed to be about 60 per cent, whereas that of lithium was ten per cent after 20 days. A first order kinetic model was derived to study the rate of dissolution of both the metals.

Jan 1, 2006

By D Mather

The Resources Boom of the 1960s in Australia provided a strong foundation for AustraliaÆs economic prosperity for the remainder of the twentieth century. In combination with sound economic management, our world-class minerals and energy sector has played a key role in the nationÆs competitiveness, and it has been the major source of our exports since the early 1970s. Even with the emergence since 1990 of major mineral provinces in Latin America and elsewhere, Australia has increased its percentage of world production of several minerals. Between 1990 and 2002, our share of iron ore production rose from 13 per cent to 20 per cent, nickel mine production from eight per cent to 17 per cent, copper mine production from four per cent to seven per cent and zinc mine production from 13 per cent to 17 per cent. Whether this situation will continue during the coming decades motivates the discussion of this reflective paper. The approach is to consider fundamental supply-side and demand-side issues in arriving at a view about the state of the world, the world minerals sector and the Australian resources sector in the coming decades. The argument draws from the experiences of other mature mineral producing countries such as Canada and the United States. In such nations, efficient producers have often sustained competitiveness for extended periods, despite falling grades and other challenging operating conditions. Yet several forces are changing the economic geography of the minerals industry in significant ways. These include the re-emergence of major global mining corporations, the revision of mineral policy in over 100 nations since 1985, the mobility of technology and more efficient transport both for mineral productions and mining professionals. Given these trends the paper argues that the Australian mining industry must continue to change and evolve significantly in the foreseeable future. Its leaders will need to be even more internationally focused if it is to maintain its strong competitive position.

Jan 1, 2006

As the mining sector increasingly embraces the sustainability agenda, and implements thorough environmental reporting in support of its case for a continued æsocial licence to operateÆ, there is a need for ever-clearer metrics for key areas of impact. It is clear that natural waters are both the predominant pathway and main recipient of the environmental impacts of mining. A new approach to summarising the impacts of mining operations on water quantity and quality is proposed, adapted from an existing generic framework, which is increasingly used to quantify the æwater footprintsÆ of cities and nations. This includes both direct water use and ævirtual waterÆ use, implicit in goods and services used by the mine. In contrast to the existing formulation of æwater footprintÆ, it is here argued that it makes hydrological sense to express the water footprints of mines in areal terms, as equivalent catchment areas. It is also important in the mining sector to capture systematic changes in the scale of impact, which can be anticipated and predictively quantified over the full life cycle. This includes the essentially infinite post-closure phase, during which æremanent water consumptionÆ occurs, either through physical water loss (eg by evaporation from pit lakes) or by ongoing contamination of sizeable flows of natural waters. Methods for assessing the water footprints of mines are now available, and the time is increasingly ripe for them to be applied in earnest in environmental reporting. An example application to a mine in a humid subtropical area of South America is presented. In that case, the mine site itself extended over 106 ha, whereas the maximum water footprint exceeded this by a factor of 27. Although the water footprint can be expected to decline by a factor of ten immediately after closure, sustained evaporation from pit lakes and tailings dams with water covers will gradually increase the remanent water consumption rate, such that the final post-closure water footprint remains about 25 per cent of that encountered during the peak of mining.

Jan 1, 2006

Australia is the dominant iron ore supplier to the Asian market, a position that began to emerge with the development of the Pilbara in the 1960s. Iron ore is now one of AustraliaÆs main commodity exports and is likely to remain so well into the future. The annual price negotiations are the focus of widespread comment and speculation by financial analysts, journalists and mining professionals. Much is written on the subject, but how much is understood? What is the process all about and what can mine managers learn from understanding the pricing mechanism? Every one of the major regional iron ore markets has its own characteristics. The focus here is Australian supply specifically to Asia, far and away the biggest and fastest-growing of these regional markets. The core of the paper reviews and explains the key elements and procedures that contribute to pricing iron ore in Asia, a market that has long been dominated by the Japanese steel mills (JSMs) and that is now feeling the full force generated by the rapid industrialisation of China. First, however, it is important to understand how this market has evolved over the past 40 years, and the key relationships that have shaped and continue to shape the iron ore price. A description of the essential technical and commercial factors follows. Each area is explained in some detail to provide an overall demonstration of the linkages and the importance of understanding the various influences on the pricing process.

Jan 1, 2006

By D C. Ibana

The use of electrostatic fields to effect phase dispersion and agitation in solvent extraction (SX) has demonstrated many advantages over conventional mechanical methods and is therefore a very real alternative. Despite this, an industrial application of the technique is yet to be developed. Here, the several variations of the technique that have been proposed are reviewed, the state-of-the-art assessed and key limitations to a commercial application outlined.

Jan 1, 2006

By T Berryman

The Fimiston reserve is being depleted at the rate of one million ounces per year; most of which is processed by the Fimiston plant, with the remainder being stockpiled. As for most other large open cut mines around the world, Fimiston has an excellent dispatch and tracking system. Reconciliation is used to determine how the various models used in mine planning (such as a reserve, budget and schedule models) are tracking against production. It is also used to gauge the performance of grade control estimation against production; however, analysing the results of this can be complicated and, at times, misleading. The reconciliation process involves adjusting the monthly production data to equal the mill reported tonnes and grade, plus the change in stockpiles. This adjusted number is then compared to the grade control reported tonnes and grade, the scheduled model (monthly planning model) tonnes and grade and against budget (Reserve) tonnes and grade. This paper includes explanations of all assumptions made in the reconciliation process, including the end of month closing stocks balance, the application of adjustment factors to the dispatch data to create a new balanced set of production data and the monthly sign off to comply with the Sarbanes-Oxley requirements of the North American owners. The reserve is reconciled by proved and probable classification. This tool is used to assess the robustness of the classification scheme utilised and identify any reconciliation issues as they arise. Within the Fimiston deposit there are still issues that are clouded by the assumptions made concerning the scale of observation, poor data support and the mining of the narrow lode areas of the deposit. The declared ore mined (DOM) number (which is defined in the paper) can be significantly affected by these assumptions, and these need to be clearly stated and understood when looking at the reconciliation data. The DOM tonnes and grade is a good indicator of real mine performance as it adjusts mined tonnes and grade to take into account the milled tonnes and grade each month, and prevents cumulative errors from building up in mine predicted dispatch numbers or end of period stockpiles. This number allows monthly monitoring of the mine to mill performance and allows valid comparisons to be made back to budgets and reserves over a period of time. KCGM uses three month rolling averages to monitor performance against reserve and budget models. This ensures that monthly distortions in the figures due to stockpiling issues or over mining in a particular period do not lead to false conclusions. Reconciliation performance over a longer period (12 - 18 months) is used to adjust reserve models should significant variance be observed. By closely monitoring the reconciliation performance at the Fimiston operation, fine tuning of all aspects of the grade estimation process from reserve through to grade control can be made. This allows the most accurate data to be used when planning from reserve data for the Life of Mine Plan through to grade control data for short-term mill feed.

Jan 1, 2006

By B Lavin, R Sanford

This paper examines the application of Lean Manufacturing in a mining environment, based on experience within the Rio Tinto entities: Rio Tinto Aluminium, Northparkes Mines and Hunter Valley Operations. The three applications have tested the flexibility of the Lean methodology. Within Rio Tinto, Rio Tinto Aluminium was the first group to introduce Lean. The rollout began in late 2004. It was introduced firstly at Boyne Smelters, Gladstone, as a model site with the initial application in the Carbon Bake Furnace area. It was later extended to other sites including the Weipa Bauxite Mine. LeanÆs successful application within Rio Tinto Aluminium was in part responsible for its recent adoption by other Australian-based Rio Tinto business units including Northparkes Mines, a copper mining operation in Central New South Wales, and Hunter Valley Operations, a group of four coal mines in the Hunter Valley region of New South Wales. Lean is also being adopted by Rio Tinto Iron Ore. Rio Tinto Aluminium introduced Lean Manufacturing to complement an existing Six Sigma business improvement program and to achieve continuous improvement activities at a workplace level. Lean provides a similar level of rigour and discipline to Six Sigma but its application is everyday and for everyone, everywhere in the workplace. It is a valuable management tool. In a short time, Lean has achieved good and sometimes spectacular results improving productivity and efficiency at all sites, including our mining site. Within Rio Tinto Aluminium, it has also had beneficial impacts on our ability to develop and retain employees.

Jan 1, 2006

Reverse sensitivity is a critical issue for all extractive activities. Extractive industries can only establish in the location of the particular resource sought to be extracted. Avoiding a location near sensitive activities (such as residential activities) may, therefore, be more difficult for extractive industries, than for other industry (such as dairy factories).   This paper focuses on the following matters: +        principles to be derived from case law, +       district and regional council approaches managing reverse sensitivity effects, and +        avoiding, remedying or mitigating reverse sensitivity effects in the future.

Jan 1, 2006

By M Haydon

How do you portray a large structurally and stratigraphically complex deposit to return a meaningful resource estimation, and produce a geological model that is useable for planning on a daily basis? The George Fisher Mine is located 22 km north of Mount Isa and forms part of XstrataÆs Zinc Group operations. It is currently a major producer of zinc, lead and silver in the region with an estimated total resource for all categories of 127 Mt at 100g/t Ag, 5.3 per cent Pb and 9.2 per cent Zn (June 2005). Production in 2005 totalled 2 647 492 wet tonnes for 317 699 kg Ag, 140 317 tonnes Pb and 230 331 tonnes Zn from underground operations. George Fisher (GF) consists of two deposits that are structurally complex on a mine scale, George Fisher North (GFN) and George Fisher South (GFS). Regional faulting has resulted in a 2 km long package of variably pyritic shale and siltstone that separates the deposits. This paper looks specifically at GFN. Distinct correlations exist between the two deposits based on stratigraphic matches; however, orebody characteristics, geometry and fault architectures differ significantly between the two. The deposits consist of multiple, sedimentary-hosted, stratiform orebodies from 2 to 25 m wide, separated by waste intervals of variable width. Each ore-waste interval is modelled as an individual geological domain. Structurally, George Fisher North (GFN) contains a series of major late-stage NE faults with dextral offset(s) of up to 130 m. Further complexity is added by NS, NW and NNE striking fault orientations that can produce either a loss or repeat of stratigraphy, local drag folding, orebody attenuation and block rotation. Due to this structural complexity and orebody offsets, domains at GFN are further divided into fault blocks (FB). The GFN model comprises eight FBs over a strike length of 1 km, all of which are modelled independently. As drilling progresses and additional resources are converted, further FBs will be added at major fault offsets to accommodate orebody and model expansion. This will be in addition to what is already a large and time-consuming data set to manage and update. For example, each FB has 18 domains each with two constraining wireframes (hanging wall and footwall). Each wireframe has several sets of point data depending on the type of data available, ie diamond drilling, mapping or interpretation points. This equates to over 1100 separate files to manage. Additional wireframes and files are also required for major structures, daily planning requirements and block model runs. In total some 1500 files are managed, updated and maintained for GFN alone. The ongoing need to expand as a business and optimise production in the current economic climate where there is a global demand for metal has led to an increase in production at GF. This has resulted in a rapidly growing data set and highlights the importance of practical and efficient modelling to achieve a meaningful resource estimate. This paper focuses on the geological modelling, modelling approaches and techniques employed for the GFN deposit.

Jan 1, 2006

By N Meadows, M Rodriguez

A 200 000 tpa heap leach demonstration plant was approved by the Murrin Murrin Joint Venture (MMJV) in December 2005 and engineering commenced in January 2006. The demonstration plant will utilise stockpiled ore reject material (æscatsÆ) and extract nickel and cobalt. Limited production from the demonstration plant is expected by the end of 2006. The demonstration plant will enable the company to fully investigate and understand all associated technical issues over the next 12 to 18 months, including the potential to expand the heap leaching operation to a commercial scale. In parallel, the MMJV will continue a research and development program to improve and expand the application of its heap leaching technology.

Jan 1, 2006

By R R. Lovel

In this paper, life cycle assessment methodology has been used to assess the variations in water use associated with different metal production and processing routes and provide insights into the value derived from water usage in the minerals sector. Using water consumption data derived from the literature it has been shown that the æcradle-to-gateÆ water consumption (or embodied water) for production of the various metals considered in the study ranged from 2.9 m3/t for steel up to 252 087 m3/t for gold. The results largely reflect the grade of the initial ore used to produce each metal, and can be approximated by the following equation:W = 167.7 G - 0.9039 where: W = embodied water (m3/t refined metal) G = grade of ore used to produce metal (per cent metal) The study showed that indirect water consumption in the metal production life cycle, in particular that due to electricity generation, can make a significant contribution to the embodied water value, eg aluminium production. When expressed in terms of m3/t ore, the results for all metals considered indicated that the embodied water is roughly, on average, three times the water consumption of the mining and concentration stage. It was also shown that the economic value per m3 of water consumed for the minerals industry exceeds that for the agricultural and industrial sectors, supporting the view that allocating water resources to the minerals industry has a strong underlying economic basis. Water reforms currently taking place in Australia aim to address issues such as competition for water access, reduced security of supply and increase in cost. Consequently the minerals industry, along with others, can be expected to come under increasing pressure to reduce fresh or raw water use and to integrate water use across sectors. While water recycling is an obvious candidate to help reduce water consumption in the minerals industry, issues such as water quality, among others, will influence the extent to which this can be achieved. In addition, wastewater volumes can be minimised using techniques such as pinch analysis to establish and use the minimum water requirement for the process. The use of dry or near-dry processing technologies, for which the demand for water is small or zero, may be a more radical solution to the water consumption problem; however, it is possible that the introduction of dry processing would bring with it a new set of problems, including dust.

Jan 1, 2006

By N Slade, D Kennedy

Optimal throughput is a key objective for the successful operation of any manufacturing or processing business. In the mining industry in particular, in order to obtain maximum return on the significant capital investment in the physical assets involved, ensuring continuous throughput is a major focus for the complete leadership team. Failure to meet throughput objectives becomes a major source of distraction for management which too often attempts to solve shortfalls by æforcingÆ and æenforcingÆ production targets. This focus on the short term and the lack of attention to addressing root causes frustrates operators who attempt to satisfy unattainable short-term targets and lose sight of the long-term goal. Mount Isa Copper Operations, Xstrata Copper, North Queensland, had ambitious plans to increase throughput volume by ten per cent within a four month period to allow budgets to be achieved within the financial year. To achieve this, the process had to overcome the interplay of a multi-node (æsiloedÆ) production system and its associated inventories, each node, of which on the face of it at least, had more than enough ænameplateÆ capacity to meet these plans. However, the actual volume achieved at the end point of the system was well below this nameplate capacity and the system operated with an extraordinarily high standard deviation. The key issues in terms of making or exceeding plan were: how to substantially reduce the variability of the system and managing the inventories between nodes, how to synchronise throughput between the production nodes, and how to improve the decision-making ability within the process. In this paper, the implementation team has shown that a revolutionary process view of the operation together with appropriate planning decisions allowed increased throughput to be achieved without further capital investment.

Jan 1, 2006

The selection and implementation of the right technology for a project is critical to the future development of the resource industry. It is essential for companies to ensure ongoing competitive viability that where practical new or alternative technology be adopted. Analysis of historical data relating to development of resource-based process plants provides an enlightening insight into the key factors which influence their success or failure. The adoption of new technology does not guarantee the success of a project. The outcomes of this analysis have been used to develop some general guidelines and principles the author believes are useful in the selection and implementation of new or alternative technology in resource projects. This paper is available as a PowerPoint presentation only.

Jan 1, 2006

George Fisher Mine, near Mount Isa in northwest Queensland, has been producing Pb-Zn-Ag ore since the late 1980s. It consists of two separate underground deposits, George Fisher South and George Fisher North. These two deposits are drilled and modelled separately but are crushed and hoisted as a single stream. The Pb-Zn concentrator in Mount Isa processes ore from George Fisher Mine and Black Star Open Cut, with production also from the Isa Lead Mine until January 2006. This paper outlines the steps involved in setting up a robust reconciliation system for George Fisher Mine, in conjunction with requirements of the Pb-Zn concentrator, Black Star Open Cut Mine and the Mount Isa Lead Mine. Good quality input data and commitment to training have contributed to establishing a robust and effective reconciliation system. Reconciliation data has highlighted several other continuous improvement opportunities.

Jan 1, 2006

By C Glassock, P Tilyard, T Sandeman

Computer simulation is a well accepted tool for modelling the behaviour of large and complex operating systems. It is a particularly useful technique in complex operations where there are multiple interactions between the inputs and outputs of various unit operations. It can be utilised during the early stages of a project as part of the business case definition phase or the early engineering phases, or alternatively to help understand the various options available in an upgrade or expansion. With the design of a new processing plant to handle a different ore type at Lihir Gold Limited (Lihir), there was concern that the existing conveying system could separately handle the increased tonnages. A simulation model was constructed which allowed Lihir to examine the impact on the conveying system of the new process plant, as well as investigate the effect of different trucking options. As is often the case, once the simulation model was built, further understanding of the downstream bottlenecks was able to be investigated, including the sizing of critical equipment.

Jan 1, 2006

By H Beucher

The uranium grade in roll front deposits is the result of successive processes that can be summarised in two steps. First a sedimentary phase, which gives the deposit support, then an oxidation-reduction phenomenon, which leads to the uranium deposit itself. In order to simulate such a deposit, it is important to mimic these different phases. The final aim of such a study is to localise the uranium itself and to reproduce the internal heterogeneity of the orebody in order to simulate the recovery process. The idea in this paper is not to reproduce a genetic approach but to consider the final image of the deposit. Three approaches are proposed. The first one consists of simulating the facies of the sedimentary deposit. The second approach reproduces the distribution of facies resulting from oxidation phenomenon (reduced or oxidised facies). The third approach consists of simulating the mineralisation at the interface of reduced and oxidised areas using the definition of a new data set determined by the grade values. At the end of each approach, the uranium grade could be simulated facies by facies according to the corresponding distribution characteristics. The plurigaussian method dedicated to random set simulations is well-suited for the facies simulations of deposits resulting from several sedimentary processes whether correlated or not. In this paper, the benefit of this method is demonstrated in an actual case study.

Jan 1, 2006

By B Mil, D P. Adhikary, M S. Craig, P Rutzou

As shallow coal reserves with easier mining conditions are exhausted, future deep coal mining with difficult mining conditions may face significant economic, technical and environmental challenges. Moreover, due to increased coal production capacity with the new generation longwall systems, predicting adverse mining conditions has become more important than ever before. The potential impact of these difficult conditions is an increase in mining risks and costs. Reliable prediction of rock mass deformation, mine stability and mine water inflow is not only essential for improving mine safety and reduction of coal production costs, but it is also important for the assessment and management of the environmental impact of mining. This paper briefly describes an integrated approach to mine groundwater simulation and prediction. Central to this integrated approach is a three-dimensional computer code called COSFLOW, developed by CSIRO of Australia in collaboration with NEDO and JCOAL of Japan to address the pressing issues of mine water management. COSFLOW incorporates unique features that make it ideal for the simulation of coal mining and examining the interaction between rock fracture, aquifer interference and water flow. This paper also presents an example of an application of the integrated approach and COSFLOW in water inflow prediction at Springvale Mine in New South Wales.

Jan 1, 2006

By D S. Perera, P Wal, D C. Southam, J L. Lowe

The Cooperative Research Centre for Sustainable Resource Processing (CSRP) is undertaking a large research project involving partners from industry, universities and government, which aims to develop the necessary chemical and structural understanding of geopolymer materials made from waste products for them to be used to capture a significant market share of the concrete business for a given industrial region. We are investigating the suitability of a range of soluble silica-bearing waste streams for use as geopolymer concrete feedstocks. In order to utilise a variety of waste streams, either singly or blended, an understanding of the role of secondary metal ions (Fe, Ca, Mg, Ti, etc) in the geopolymerisation process is essential. A range of experimental and analytical techniques is therefore being used to better understand the structure-chemistry-property relationships of geopolymers. Currently, we are investigating geopolymers made from a variety of waste streams (fly ash, kaolinite, red mud, etc) available in the Kwinana Industrial Region, Western Australia. This paper will detail how the basic scientific research underpinning the project is vital if waste streams of varying composition are to be successfully used in a commercial concrete product and the regional synergies required to develop geopolymers from waste streams.

Jan 1, 2006

By R Whittering, C Greet

High chrome grinding media has been used in the mining industry for quite some time, as it often proves economical on a wear basis. However, it is unusual for an operation to change to high chrome solely due to its metallurgical benefits. KagaraÆs Mount Garnet operation made the change from forged steel to high chrome media after laboratory testwork indicated that copper grades and recoveries would improve. The outcome was remarkable with positive changes in pulp chemistry throughout the circuit accompanied by marked improvements in copper, lead and zinc grades and recoveries. Reagent dosage rates were reduced, often by more than half, and the grinding media wear rate dropped to less than a third of the wear rate of the forged steel media. The economic analysis showed that out of the total increase of revenue and savings from metallurgical improvements and reagent and media consumption reductions the metallurgical improvements made up approximately 73 per cent, the reduced reagents saved 25 per cent and the savings through reduced media wear contributing by just over one per cent. This indicates that the popular view of high chrome media only being trialled in the plant for wear economics is outdated and the focus of operations should be shifted to using high chrome media for the metallurgical benefits.

Jan 1, 2006

By R Norris, M Dunne

Substantial efforts by the industry, as well as by process and equipment designers, have resulted in many innovative developments that provide cost effective reductions in water usage. This paper showcases four emerging best practices in industry including examples of recent installations. Belt press filters are a small fraction of the operating and capital cost of alternative ædryÆ tailings technologies. This gives operators who must ædryÆ their tailings a competitive advantage and makes such operations much more sustainable. The new generation of belt filter presses use less energy, produces lower cake moistures and better disposal stacking properties. The need for tailings storage facilities may be eliminated or in some cases high-grade tailings can be dewatered and sold as a low value product. Mining applications include sand tailings, sinter plant waste, coal tailings and power station fly ash. Flip-flow screening machines are proven worldwide in the dry classification of coal and other minerals, reducing the size of beneficiation plants, whilst reducing energy, water demand and media consumption. They also allow the screening of wet/sticky materials not able to be sized using conventional screens. Lamella separators are used for toxic water clarification and/or sludge thickening in many downstream metal industries with the underflow often dewatered in a belt filter press. Such low cost, high capacity thickeners could also be used instead of conventional thickeners at smaller mines. The simple and reliable continuous washing upward flow (CWUF) sand filters have been used for treatment of waste water from coal preparation plants and steel works as well as in the production of potable water. The filtered waste water from mining processes can then either be reused or discharged from site. Other installations include cleaning mine water to prevent the blocking of dust suppression spray nozzles.

Jan 1, 2006