Search Documents

By J Knoblauch, D, P J. J Strobos, C Foggo

The Sally Malay Project is located 120 km north of Halls Creek in the eastern Kimberley region. Since commissioning, ongoing improvements on the plant have resulted in recoveries now greatly exceeding the initial design targets. The continual optimisation endeavours of the Sally Malay metallurgy department included an automation project that was done in close collaboration with Mintek. In this team effort, several problem areas were addressed and the FloatStar advance control system was successfully commissioned to stabilise and optimise the flotation circuit. The remote location of the Kimberley Nickel Mines operation, fly-in, fly-out roster and the current mining boom makes the acquisition of experienced flotation staff difficult. The implementation of an automated flotation control system reduces this burden and contributes to the training of inexperienced staff. This paper illustrates not only the process control improvements achieved as a result of the installation of the FloatStarÖ advanced control system, but also how it has assisted operational personnel with their understanding of the process.

Jan 1, 2006

By S N SHEARD

The use of geophysics in mineral exploration in Australia, and overseas, has increased dramatically over this century. This paper shows that using simple equipment with clever interpretation that the foundations of modem geophysics were laid, using all the same principles. The plethora and diversity of mineral exploration geophysical techniques does not allow a full description of their evolution to be given in such a paper. To convey this evolution, however, the progress of two different geophysical methods, magnetics - a potential field (passive) method, and electromagnetics - an electrical (active) method, are described. Examples of magnetic survey data from the 1920s and more recent vehicle home and airborne surveys are given to show the increase in data quality through technological improvement. A set of four airborne electromagnetic data sets spanning three decades is used to indicate the improvement in electromagnetic techniques. It is argued, that considerable progress is still required in the electromagnetic field to increase its interpretability.

Jan 1, 1992

By Wright S, Rogers L. J, Precious T. H

Brown coal and its char were investigated as substitutes for petroleum coke in the manufacture of anodes for Hall-Heroult cells. The char, which had been densified by several techniques, was made into compacts with various binders and the anodic consumption determined during electrolysis. The results were an improvement on previous work, but the anodes still fell short of acceptability for use in aluminium smelters because of intractable microporosity. Some options for future development have been discounted.

Jan 1, 1986

The history of black coal as a fuel dates back in Europe more than 2,300 years, and possibly longer in China. Originally the mining of coal was done by underprivileged people, but with the industrial revolution and the dawn of mechanisation, the status of the coal miner improved. The improvement continued to the present day. Coal miners now take an important role in industrialised countries and enjoy a high standard of living. The miner is amongst the highest paid and best technologically served in any industrial activity. The abundance of coal relative to alternative fuels and its widespread occurrence, brings with it a prosperity much valued in those countries with significant resources such as Australia. Coal will play a major role in easing the world energy shortage. In addition to the conventional usage, throughout the world coal gasification plants are in various stages of development. Coal liquefaction plants are beyond the drawing board stage. Slurry pipelines to supply coal for direct burning in electric generating and other plants are planned. In the current atmosphere of environment consciousness, Australia has to contend with people with only marginal interest trying to influence coal mining activities to the detriment of the overall prosperity of Australia. Fortunately enlightened legislation is the greatest protector of the environment and in many instances great improvement to the environment ensues after mining has passed. With its vast resources of black coal Australia can look forward to a significant role in future supply of fuel. As a result of the trade and industry involved, Australia can become an even more influential country in world politics, trade, and the setting of high living standards.

Jan 1, 1975

By C P. de Jager, J J. Taljaard

Over the past 75 years, the mining of platinum has predominantly focused on the Merensky Reef horizon in the western Bushveld region of the Bushveld Igneous Complex (BIC) of South Africa (Figure 1). The orebody is relatively flat dipping at 10¦ to 25¦, narrow tabular in shape and has been mined to a maximum depth of some 1600 m within Anglo Platinum. This has resulted in the installation of up to four generations of shaft systems as mining progressed into reserves at greater depth. In recent years, with the improvement in processing technology and improved economics, in particular with the improved price of palladium, the mining of the UG2 Chromitite Reef is proving economically viable. The UG2 Chromitite Reef occurs below the Merensky Reef in the succession and the normal separation varies from 15 m to 400 m, with the largest separation between the reefs occurring in the eastern region of the BIC. The UG2 Chromitite Reef horizon is now being accessed from existing Merensky mining infrastructure by cross-cutting back through the stratigraphy where appropriate, or by establishing new decline cluster systems from surface, along the extensive strike length of the various mining properties. These declines are generally established utilising mechanised mining techniques. This paper gives an overview of the techno-economic approaches considered and evaluated for the selection of the optimum mining and shaft systems. More specifically, the paper reviews the design parameters used, techno-economics, conveyor versus haul alternatives, logistics simulations, capital costs, system performance, time to market or ramp-up success, important system differences and lessons learnt.

Jan 1, 2005

By G McSpadden

At September 2001 the beneficiation plant at BHP Billiton Iron OreÆs Mt Whaleback mine is set to treat 9.5 million tonnes per annum (Mtpa) of iron ore, 40 per cent better than original design. This paper describes the steps, decision-making processes and innovations used to increase capacity at minimum cost. The plant was designed in 1979 to operate at 1133 t/h for 6000 hours per annum, treating 6.8 Mtpa. Sufficient suitable contact ore was unavailable and feed was finer than planned. The plant was designed with minimum surge capacity between multiple process units. It had never reached design capacity. In 1993 a study by Fluor Daniel to treat increased tonnage resulted in modifications to improve plant operations. Efforts to expand production by increasing reliability did not achieve the desired capacity. NJ Morrow (Pty) Ltd (NJM) conducted a technical audit in 1996 with process evaluation by Mineral Processors. Replacement of operator interface and PLC logic in 1997 made plant operation and diagnosis easier. Involving operators in logic development enhanced their plant knowledge. Fluor Daniel Simulation developed a simulation model of the process. Mineral Processors and NJM reviewed the model findings, recommended metallurgical improvements and developed preliminary designs and costs. BHP Engineering produced a detailed design with a cost estimate of $A34 million. After analysis and revision of the design, a $A10.4 million upgrade to 8.5 Mtpa was carried out. Detailed modifications to the process units, particularly the HM drum plant, allowed significantly higher capacities and improved metallurgical performance. The target capacity was achieved in June 2001. Further modifications are progressing to treat lower-grade ores.

Jan 1, 2002

By Palmer C. G, Rowe P. G

Ore handling improvements at Mount Isa Mines Limited were necessary to keep abreast of technological advances in all phases of sublevel stoping practice.In the early 1930s an efficient ore handling system was in operation.However in 1936 excessive water encountered in deepening the hoisting shaft necessitated the sinking of a second hoisting shaft. Financial difficulties prevented abandoning the original shaft and surface ore handling and crushing facilities, so ore was transferred underground and underground crushing deferred. It was not until 1951 Jhat multilevel crushing permitted increased efficiency in the handling of ore from stopes. Ore was then hoisted in one shaft and transferred on the surface by conveyor belt to a new crushing plant.In 1956 a planned production increase from 5,000 to 11,000 tons per mining day made possible further improvements in ore handling. Larger equipment was installed and existing equipment modified to capacitate the handling of larger sized ore at increased daily tonnages.INTRODUCTIONThe intensive exploratory programme commenced in 1954 disclosed large reserves of both lead and copper ores and in 1956 an expansion programme was initiated to increase production from 5,000 to 11,000 tons per mining day. The increased tonnage would result in decreased costs per ton and further cost reductions would result from increased mechanisation underground. The combined effect would permit larger tonnages of lower grade ores to be included in ore reserves. To achieve both cost reduction and the scheduled production increase, improvement in ore handling was of vital importance.For efficient and low cost sublevel stoping it is necessary to maintain an economic balance between...

Jan 1, 1961

By J C. Koppe, L Vieira

One common problem for blasting in iron ore mines with significant weathering is the occurrence of large blocks of hard rock mixed with softer material. This situation causes a problem for blasting design and sometimes produces large boulders of rock that require a secondary blasting, as well as excavation difficulties. To minimise this situation, geophysical techniques were used to identify the hardest material amid the weathered material. To study the problem, seismic, ground penetrating radar (GPR), electrical resistivity and induced polarisation (IP) methods were used in an intensely weathered Brazilian iron ore deposit. The methods of GPR combined with IP, resistivity and seismic showed to be effective in modelling the contrast among hard, friable materials and soil. The results were used to improve the geological model and create more favourable conditions for the subsequent blast design. The blast design based on geophysical/geological models resulted in significant improvement in the fragmentation of the iron ore. This was achieved by the adoption of a specific drilling pattern for a given geological situation. With the new specialised blasting design the formation of boulders was eliminated.CITATION:Vieira, L and Koppe, J C, 2015. Geophysical techniques applied to blasting design, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 289–294 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By E K. Leeka

Process control limitations have led to suboptimal performance of the crushing section of Sishen MineÆs Jig Plant. The performance of the PID (proportional-integral-derivative) controller implemented during commissioning was hampered by the relatively small buffer capacity between the crushers and screens. The inability to maintain the tertiary crushing chamber under full choke conditions lead to inefficient crushing and reduced crusher product cubicity.Model predictive control (MPC) was implemented in the tertiary crusher plant in May 2012 and resulted in a throughput improvement of six per cent in its first month. The controller was further optimised and indicated a throughput improvement of 16 per cent during on/off testing in July 2012. The throughput improvement is attributable to the finer crusher product resulting from operating the crusher under full choke conditions and controlled feed rate to the tertiary crusher plant screens. The next step is to couple the model predictive controller, automated gap control system and an economic optimiser to ensure maximised throughput and value from the resource.CITATION:Leeka, E K, 2013. Performance of model predictive control on the crushing circuit at Sishen Mine, in Proceedings Iron Ore 2013 , pp 417-420 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

Over the longer term, the adoption of new technology is an essential component in the endless tasks of reducing mining costs, improving safety and improving environmental standards. However the choice of which of the many available new technologies to adopt and which not to adopt is not easy and the price of mistakes can be very high. The most important issue for mine developers faced with making such choices is knowing whether or not a new technology has been developed to the stage where the timing is right for its adoption. A system for categorising new mining technologies is provided. It provides a basis for more easily reaching common understandings about various new technologies and the background information supplied provides an understanding of what it takes to get new technologies to the proven stage and the risks of never getting there. Wherever possible, new full-scale mine developments should not rely on unproven technologies. Approaches to handling situations where a proposed new mine development is not feasible on the basis of proven technologies are also provided. If any commitment to the use of unproven technologies is made, a guarantee of high quality development support from the supplier of that technology is essential. Several case studies of successful and unsuccessful new technology development programs at BHP are Provided.

Jan 1, 1997

By N Currey, G Corder, G Becker

"The SUSOP« Framework is a new technique that helps incorporate sustainable development principles and objectives into the design and operation of businesses. Developed through the Co-operative Research Centre for Sustainable Resource Processing, it brings a design methodology to sustainability, similar to what hazard and risk techniques such as HAZOP did for safety.Metallica Minerals Limited (æMetallicaÆ) adopted the SUSOP« framework to help identify opportunities and risks that could directly improve or affect its flagship SCONI (nickel-cobalt and scandium) project. This project has the potential to become the worldÆs largest producer of scandium oxide (æscandiaÆ) which is used in solid oxide fuel cells and strengthens aluminium alloys. Located northwest of Townsville in Queensland, the plant site will be located within the previously mined and partially rehabilitated Greenvale Nickel Mine. By applying the SUSOP« framework through a series of multi-disciplinary workshops and offline analysis, Metallica was able to identify numerous sustainability opportunities and risks. Opportunities were clustered together to form concepts to develop a more holistic understanding of the projectÆs overall potential contribution to sustainable development as well as determine where key risks could be mitigated. Four key concepts were identified: Waste and Water Workforce Community and Enterprise Development Energy and Greenhouse Gases (GHG). Metallica was able to include a range of initiatives that could deliver enhanced environmental, social and community outcomes into their mine development plan. These included measures to reduce reliance on water, reduce the volume of waste, provide local opportunities for training and skilled employment and create support for local enterprise development. These measures also resulted in a significant reduction in the capital estimate of the project.This paper provides an overview of the SUSOP« framework, details its application to the SCONI project and discusses the outcomes that will help establish the projectÆs strong sustainable development credentials and improved business outcomes.CITATION:Corder, G, Currey, N and Becker, G, 2013. Sustainability, made easy - A business improvement case study, in Proceedings MetPlant 2013, pp 259-271 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 15, 2013

By H Hy÷tyniemi

In this paper multivariate data analysis performed on a new multi-camera system implemented to zinc flotation circuit of PyhSsalmi mine is presented. Image-analysis-based system was developed to take advantage of the commonly known fact that the changes in the flotation process are reflected to the visual appearance of the froth surface. Most often the changes are seen first in the froth and later in other process measurements. The image variables are already utilised in closed loop control and considerable savings are achieved with the current setting, but the results coming from the separate cells are used individually. This is clearly not the optimal way to take advantage of the many measurements coming from different locations of the process. A better approach would be for example to use the measurements coming from the early stages of the process to predict the behaviour (or improve the quality of measurements) in the later stages. The methods described in this paper are aimed to improving the situation in this sense.

Jan 1, 2005

By M Hilden, K Barbosa, M Yahyaei, C Ndimande, K Runge, V Jokovic

Classification devices provide a link between comminution and flotation. Basically, it determines which particles are diverted back for additional grinding and which ones pass to downstream flotation. Therefore, the classifiers play an important role in the performance of a mineral processing circuit. Hydrocyclones are the most common classifiers used in wet grinding, despite being associated with poor classification efficiency. Hydrocyclones are widely used due to advantages related to low maintenance as well as reduced capital and operating cost. Other classifiers, such as fine screens, have much better classification efficiency compared to hydrocyclones. The major challenge of using screens in an operation, however, is their large footprint and increased maintenance requirements relative to hydrocyclones. Some researchers have demonstrated that switching from hydrocyclones to screens, as the classifier device in a ball milling circuit, resulted in a 20 per cent increase in plant throughput and significant improvements in coarse particle recovery, resulting in a 6 per cent increase in overall flotation recovery. However, it is known that these benefits of improved classification are very much ore specific, ie depending on the ore response. Therefore, there is a need to estimate the benefits of improved classification in pilot scale testing before the plant could consider the potential classifier upgrade. This paper presents the results of two pilot-scale grinding tests where the ore sample was processed using different classifiers: a traditional hydrocyclone and hybrid classification involving the use of a semi-inverted hydrocyclone followed by a screen. The size specific energy and circulating load were used to compare the performance of the grinding circuit. The grinding product was subject to mineral liberation analysis and the impact of classification efficiency on the mineral liberation is discussed in the paper.

Aug 24, 2022

By M Darvall

Magnetite ore blending has yielded signifi cant performance improvements in OneSteel’s magnetite concentrator. The magnetite concentrator beneficiates magnetite ore from the Iron Magnet Deposit and produces concentrate, which is pelletised, then fed to the OneSteel Whyalla blast furnace. Concentrator feed variability severely detracts from the concentrator’s performance, affecting both concentrate yield and grade, which impacts on all downstream processing costs.A coordinated approach has integrated mine planning, geological modelling and grade control, to minimise concentrator feed variability, through effective ore blending throughout the mining and stockpiling process.Mine planning personnel design shots that extend the full width of the orebody and hence across the stratigraphic profi le. Based on geological information contained in block-outs and in consultation with Geology, the Grade Control team allocates material to each primary stockpile, potentially from every stratigraphic domane in the orebody. This ensures primary stockpiles are designed with maximum practical homogeneity and consistency.Using only primary movement, the allocated ore is stockpiled in a layer-cake fashion. The ore is pimple dumped across the width of the stockpile footprint and on completion of a layer, it is dozed flat with an access ramp that allows dumping to commence on the next lift. The primary stockpiles are reclaimed normal to build direction and the magnetite is crushed, all in, to a concentrator feed stockpile.The ore is sampled at the crusher from a falling stream cut. These assay data, are used for benchmarking and control charting the grade and variability of concentrator feed stockpiles. The concentrator feed stockpiles have demonstrated a statistically signifi cant reduction of within pile variation, between pile variation and pile to pile variation, primarily attributable to the development of ore blending. The concentrator has seen sustained, improved performance as a direct result, which translates into lower concentrate cost per tonne and improved yield and quality.

Jul 11, 2011

By W Potma, C Brauhart, S Halley, S Urbisinov, A Scogings

Truly integrated, quantitative, 3D GEOmetallurgical (or mineral system) characterisation, classification and 3D modelling should provide a cradle to grave unifying link across the exploration and mining value chain. All too often, spatially representative (quantitative) characterisation and modelling of a mineral system is delayed until feasibility stage, incurring a significant opportunity cost. The application of robust GEOmet characterisation methods early in the project lifecycle (at exploration stage) improves ground selection, exploration, and Mineral Resource estimation outcomes, long before there is a need for metallurgical test work. The value of this early provision of quantitative 3D mineralogy models is compounded at project feasibility stage, and continues to accrue over the entire project lifecycle, delivering cost savings, improved decision making and early warning of issues and opportunities.CITATION: Potma, W, Halley, S, Scogings, A, Urbisinov, S and Brauhart, C, 2018. Putting the ‘GEO’ back in front of GEOmetallurgy: importance of early implementation of quantitative mineral system characterisation, classification and modelling, in Proceedings Complex Orebodies Conference 2018, pp 55–57 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By C Moorhead, J Jones

A common problem in the mining industry is that company geologists can operate in relative isolation to the rest of the company (Jones and Moorhead, 2011). This may result in poor knowledge transfer and often priority conflicts with geology, operations and project departments. This problem is amplified by the acquisition of mineralogy capabilities and other metallurgical (met) test work undertaken by many companies in order to solve for complex orebody problems. Met data is often not located and viewed in 3D space so that geologists and engineers can create and work with geometallurgical (geomet) models (Bye, 2006). Visualisation of data in an interactive graphical 3D model provides a bridge enabling met professionals to collaborate with engineers and geologists to provide a common understanding of the relevance of geomet data.In recognition of this problem, Newcrest has undertaken an effective collaboration strategy to improve internal and external engagement through the use of large visualisation displays (Jones, 2009). The displays are underpinned by IT systems and information management practices that recognise the needs of underlying disciplines. Today it is generally understood within Newcrest that this is required to improve decision-making, deliver faster cycle times and improve governance.Collaboration in companies has been generally associated with the introduction of new IT functions (IBM, 2008). However, the science and engineering process that are used to structure modern IT-based collaboration systems and practices are now known to be simplistic compared to the long-standing practices associated with collaboration and knowledge management in disciplines such as geology and mining.CITATION:Jones, J and Moorhead, C, 2013. Geometallurgical communication as a distributed information system, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 133-138 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By J Harding, S Munro, R A. Bearman

Despite the importance of the primary crushing stage, performance optimisation is not well analysed with sufficient focus to give improvement opportunities. At the Newcrest owned Telfer operation, liner life plays an important part in scheduling planned maintenance. Major consideration is given to monitoring crusher performance, as the highly abrasive nature of the feed significantly impacts the liner wear life. A study was undertaken by the lead author which focused on establishing a strong baseline of accurate data pertaining to the performance of the crusher, in terms of, operating parameters, liner life and key machine design factors. As part of the study, mining feed materials were examined for a particular set of liners and this revealed that improved methods should be pursued. Due to the competitive nature of the mining industry, the business solution to complex problems with long shutdown cycles should be streamlined to incorporate a non-operational modelling approach that is significantly more efficient than traditional online trial and error methods. In order to dramatically reduce the time and business risks, it was decided to engage services to model and simulate the liner life by varying main operational and mechanical factors. The key to all simulation work is gathering high quality baseline data. Such data allowed deployment of the Kinematic Crusher Model and validation of the model against worn 2D wear liner profiles. The proven model was then successfully deployed to predict operational values that defined crusher performance. To enhance the study, further investigation into a set of mechanical and operational simulations generated a sensitivity matrix measuring key performance parameters throughout the wear life of the liners. The study revealed throughput as a highly sensitive parameter and a change in eccentric throw provided the greatest improvement in extending liner wear life.

Aug 24, 2022

By H Rossiter, A Maddever, J Market, P Jeanneau, A Virani

It is generally acknowledged that the head grade of the world’s copper resources is declining. Accordingly, there is an increase in the volume of resource material being mined and processed to maintain copper production. This has led to increases in cost base accompanied by reductions in Life of Mine (LOM) Net Present Value (NPV). The higher tonnages of material mined are driven by increased quantities of lower grade material required to satisfy the short term mine model. In turn, this has brought an increased focus on sampling and assay methods, since any error associated with estimating the grade of each block and determining its correct destination serves to magnify the losses that will occur. Presently most open-pit copper mining operations use blasthole sample assays to feed their shortterm model. The problematic nature of blasthole sampling is well documented (Engström, 2017), particularly the poor timeliness of the data and the significant errors that are inherent to the technique. Methods to improve grade control, such as drilling a separate grade control grid, have been proposed but come with their own cost, logistical, and accuracy shortcomings. A recent development in grade estimation is the Pulsed Fast and Thermal Neutron Activation (PFTNA) downhole logging probe. Deployed on an efficient semi-autonomous platform, PFTNA is being aggressively adopted in the Australian iron ore industry. The technology provides in-situ elemental analysis of the geological formation, delivering high accuracy, high efficiency, near realtime data from a sizeable measurement volume. In this paper we consider the application of the technology to copper. Whilst there are several operational components to such a value proposition, we focus on the benefits of improved gradeestimation. A simulated copper mine is used to model the quantum of improvement expected from a reduced grade-estimation error, which reduces the likelihood of misallocating material to the wrong destination, which in turn increases NPV.

Nov 10, 2020

By G Turner-Saad

An improvement to cut-off grade optimisation theory based on geometallurgy has been completed. The improvement fundamentally consisted of taking into account mineralogical and textural characteristics instead of grades. These characteristics are related to the spatial variability of mineral abundance, association, particle size and liberation properties. Additionally, the improve- ment considered the spatial variability of mineral processing liberation and selectivity properties associated with mineralogy and texture. The enhanced optimisation enables estimation of the economic value of mining operations based on an optimum cut-off policy attributed to liberated and selected ore minerals.The enhanced optimisation was developed as an essential component of a joint cut-and-fill mining and mineral processing methodology based on mixed integer mathematical programming. The formulation considers static and dynamic modifying factors that vary over the projected life of mining. The objective function of the mathematical formulation consists of maximising the realistic expected economic value of concentrates or products of liberated and selected ore minerals, whilst minimises liberated and selected gangue minerals. The optimal solution is obtained when the objective function is subject to geological, mining, processing, marketing, smelting, refining, environmental and financial constraints. The methodology accesses geometallurgical multivariate resource models, which integrate the spatial variability of mineralogical and textural characteristics and mineral processing liberation and selectivity properties.The geometallurgical process concurrently optimises stope geometries, ore reserves, mining sequences, and mining and mineral processing production based on the enhanced cut-off of liberated and selected ore minerals. In addition, the process considers additive and non-additive transfer functions associated to mutually exclusive geometallurgical spatial domains. The transfer functions also take into consideration the blending of mineralogical and textural characteristics with mineral processing liberation and selectivity properties.This contribution presents an example of cut-off grade optimisation via mineralogical and textural characteristic, and liberation and selectivity processing parameter optimisation for a spatially variable orebody.

Sep 5, 2011

Since 1960, the Dongchuan Copper Mining Bureau, Yunnan Province, China, has treated copper oxidised ores by sulphidisation - flotation technique only to recover copper. In order to improve the metallurgical performances and economics of flotation, extensive development work has been carried out during the past 30 years: several specific flotation flowsheets have evolved from the originally selected `stage - grinding and stage - flotation' flowsheet to suit various ores; the overall grinding size of the ores has been increased from 80 per cent - 200 mesh to 90 per cent - 200 mesh, resulting in significant increase in copper recovery; the substitution of CaS for NazS proved to be successful in sulphidisation of copper oxidised minerals, and also in avoiding the depressing effect of Na2S on copper sulphide minerals; the application of a number of activators of copper oxidised minerals, especially ethylene diamine phosphate, has considerably improved the flotation performance and decreased the consumptions of other reagents. Finally, the combined use of sodium hydroximate with butyl xanthate has been shown to be effective in enhancing the floatability of both copper oxidised and sulphide minerals.

Jan 1, 1993