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By Quan P. M

The great advances made in the application of solvent extraction to the recovery of copper from low grade ore sources over the past 15 to 20 years are well known. Solvent extraction is an essential step in the recovery and purification of copper from dilute sulphate leach solutions by which some one million tonnes of copper are now electrowon annually. A reagent is also available for the selective recovery of copper from chloride leach solutions and this may hold the key to the processing of complex sulphide ore concentrates. By comparison, the use of solvent extraction in the recovery and processing of zinc has as yet found little favour and is confined to only a few specific and comparatively small applications. This is despite the ready availability of a large number of low grade zinc sources and zinc-bearing wastes and residues. It is suggested that this difference is due in large part to the absence of suitable reagents having the particular features required to enable them to fit into a solvent extraction - electrowinning based process for zinc. Ideally, for the recovery of zinc from dilute sulphate solution, an extractant should operate on a proton exchange principle and be strong for zinc in the same way that o-hydroxyaryloxime reagents are strong towards copper. It should load efficiently with zinc at the pH of typical sulphate feed streams without the need for neutralisation and yet be stripped efficiently by spent zinc electrolyte. Another factor of major importance for many applications, however, is that it should be highly selective for zinc over ferric iron. These features have now been realised in a development extractant DS5846, which is a formulation of a novel class of reagent currently under investigation by Zeneca Specialties. The properties of this reagent are described with respect to selectivity, isotherms and how they compare with phosphoric and thiophosphoric acids that have been previously proposed for the extraction of zinc. For the recovery of zinc from concentrated chloride solutions a solvating or neutral donor type of extractant is required which again should ideally have high selectivity for zinc over a number of other metals, particularly iron. The new reagent Acorga ZNX50 is based on a formulation of a novel class of compound developed specifically for this purpose. It gives efficient extraction of zinc from feed solutions that are four to six molar in chloride ion but is readily stripped at 60 - 65¦C using either water, dilute brine, or spent zinc chloride electrolyte. The reagent is highly selective for zinc over iron and a range of other metals including cadmium, arsenic, lead and magnesium.

Jan 1, 1993

Zinc concentrates from the newer mines and from proposed developments provide both opportunities and processing challenges to the conventional roast-leach electrowin smelters. These concentrates are often characterised by low iron, elevated silica, possibly high manganese, and levels of elements such as germanium which may cause concern. In addition, environmental constraints on residue disposal are forcing significant changes to some smelter practices. Iron in concentrate, and the resulting environmental impact of residue disposal are now major questions. However, normal concentrate tariff structure provides a disincentive against smelters taking high grade concentrate and oxide fume. Processing technology to cope with these changes is reviewed, as is de-watering and materials handling of ultra-fine concentrate. Within a few years, such fine concentrates will account for up to 1 000 000 t/y of contained zinc. New processing technologies including novel transport methods, siliceous leach circuits, manganese removal cells and front-end smelting will become significant in zinc smelting.

Jan 1, 1993

By Hare G

The emphasis in Australia, until recently, has been on large scale mining methods with drive sizes in excess of 4.5 metres square and the acceptance of high dilution ratios, even when working in relatively narrow orebodies. The rising cost of extracting and treating the recovered ore and the lower prices available in the world markets has seen a growing trend to narrow mining methods.Traditionally narrow orebody mining has been carried out using hand held drilling methods and rail mounted boggers. Recent advances in mobile equipment now offers the operator of narrow method mines the opportunity to completely mechanise the mine from the drilling, through bogging to haulage, while maintaining minimal dilution in drive sizes to two metres wide or less.

Jan 1, 1993

By Dobias B

A new separation method based on a combination of coagulation and colum flotation was used to treat fine sphalerite in the range 90 per cent - 15 pm with a relative high superfical gas velocity and a thick froth layer. Minerals studied include sphalerite, calcite, kaolinite and baryte. A new developed sedimentometer was used for sedimentation analysis to characterise hetercoagulation of mixture and coagulation after addition of active ions or reagents. A comparison between use of selective frother and depressant (SHMP) was made to deactivate activated minerals. Selectivity of frother for sphalerite was found in flotation test. The depression function of Flotanol for activated minerals was confirmed in sedimentation alalysis. The use of small quantities of HPAM can improve the flotation of fine sized sphalerite particle and reduce recovery of activated gangue minerals in the neutral or alkaline pulp. A satisfactory separation of fine sphalerite from its gangue was achieved by using alkylpolyglycolether (Flotanol) and copolymer polyacrylamide (HPAM hydrolysed polyacrylamide) as frothing and flocculating agents Respectively.

Jan 1, 1993

By Ho-Tun E, Stewart PSB

The definition and recognition of silver minerals is very difficult. In general such minerals occur at low concentration and can be hard to identify and measure using conventional optical mineralogy. The present paper describes the use of the QEM*SEM system to tackle this problem and provide information of use to the metallurgist. Three aspects of QEM*SEM are used to special advantage in this application. Firstly the automated mode of operation is used to make a rapid search for the sparse phases. Secondly the X-ray capability is used to identify the mineral phases. Finally the image analysis programs quantify the distributions of the minerals which are found. The paper deals with the identification stage of the process and with the use of the data which can be derived. Silver minerals which covered a range of ore types and composition were collected and studied in detail. On the basis of these measurements and information received from a number of mining companies regarding the important minerals, a classification table was prepared. This table listed about 40 different silver mineral types which could be identified by QEM*SEM and which were of interest in silver recovery processes. Where the silver occurs in solid solution in concentrations greater than about one per cent, the silver content in the species was subdivided into ranges based on statistical intervals. The QEM*SEM system was programmed to recognise these as separate species. Examples are presented of the use of the system in defining the type and morphology of the silver mineralisation to assist in the assessment of batch flotation test Samples.

Jan 1, 1993

By Schofield N. A

The cross-sectional method of stope grade estimation at Cobar Mines has consistently had several shoneomings, me most imponant of which being mat stope grade is significantly overestimated in the high grade lenses.The use of mree-dimensional ore lens modelling improved the grade estimation and ore waste definition but significant overestimation still occurred in me high grade stopes, particularly those wim extremely variable grade distribution. The implementation of an indicalor kriging based method for mapping of me high grade copper mineralization has significantly improved the quality of copper grade estimates and provides a mineralisation geometry similar to that generated manually by me mine geologists. This paper presents the results of a test case study in the application of indicator kriging to the mapping of the copper grade in two stopes in the QTS North mineralisation. The results are encouraging in that they prov ide coofi rmation of the geometrical model developed by the geologists and much improved estimates of the grades of me stopes whencompared to me grade reponed from mining these stopes.

Jan 1, 1993

By Ault A. R

The recent modernisation program at the Risdon electrolytic zinc smelter of Pasminco Metals - EZ (PMEZ) inyolved significant changes to the composition of cell electrolytes. The most significant were increased acidity and sulphate level, a reduction in Co level, and the replacement of 2-naphthol in the additive mixture with licorice. In determining acceptable operating ranges, a relatively large number of industrial deposition tests under controlled conditions was required. The cathode zinc deposits so produced were examined in terms of overall appearance, crystal structure according to X-ray diffraction, and a micro-roughness parameter. Beginning with typical deposits produced in the presence of an excess of one of the addition agents glue or antimony or a mist suppressant (licorice or 2-naphthol), a simple classification system was developed. In this system, the deposits are divided into the following types: Doughy, Pinholed, Compact and Stressed. There was a weak correlation between deposit type and crystal orientation. In terms of ease of stripping, observations in plant operations showed that only Compact and Pinholed were consistently acceptable. Current efficiency was normally maximised by producing a Compact deposit. Process variables such as zinc concentration, temperature and the use of strontium carbonate were found to cause changes in deposit type if the reagent mixture used was unchanged. From the knowledge gained, guidelines were developed to allow glue and antimony additions to be altered to fit new circumstances. The simple classification system was first used to expedite recovery from undesirable morphologies and then to optimise individual cell units operated under substantially different conditions. It is believed that finer control could be exercised by determining the micro-roughness of Compact deposits. However, difficulties can arise if sudden, large deviations occur and go undetected. Suggestions are given for an improved additive control system. The classification system developed has been compared with published information in the literature, and good correspondence was noted suggesting a predictable relationship between short-term, laboratory deposition tests and observable phenomena in industrial electrowinning cells run under steady conditions.

Jan 1, 1993

Shear-flocculation is one of a munber of potential processes for upgrading deposits of finely-grained minerals and, more generally, for separating different types of particles suspended in a fluid.The smaller the particle the more likely it is to follow the fluid streamlines, or be entrained within turbulent eddies, and the less likely it is to deviate from the streamline and attach to bubbles (froth flotation), other particles (selective flocculation) or magnetic poles (wet magnetic separation). As shown in Figure I, a number of ingenious ideas have been proposed to overcome this effect. The suspended particles are assumed to be 1 - 10 µm.Thus, the efficiency of attaching ultrafme particles of the valuable component (solid circles) to air bubbles, as in process A, is poor. The efficiency may be improved by attaching the particles to oil droplets (Ralston, Kart and Newcombe, 1984) to form agglomerates that rise or sink (B), to magnetic particles (C) (Parsonage, 1988) to allow recovery in a magnetic separator (D), to other particles to form aggregates (E) that are then either attached to bubbles (F) or recovered by sedimentation (G) (Warren, 1992), and to pieces of polyethylene (Rubio and Baltar, 1991) that rise or sink (H).In A, C, E, F and H, the forces that are generally used to ensure collisions result in adhesion are hydrophobic forces, hydrodynamic forces and inertial forces (Warren, 1992). These drag particles from the streamlines to allow particle-particle adhesion. In B and E, soluble polymeric molecules have been added to bridge between particles as they approach closely during a collision.The second major consideration is selectivity. Selective adsorption of the hydrophobe or polymer onto the valuable particles is the key. Many subtle effects of surface chemistry are involved in obtaining adequate selectivity. A complication in real systems is that the initial suspension is often naturally coagulated and needs to be dispersed before being selectively flocculated.

Jan 1, 1993

By Oliveira JF

Thiourea is an alternative reagent for cyanide in gold leaching. The recovery of gold from acidic thiourea solutions by adsorption on activated carbon is based on methods similar to those applied for the extracting of gold from cyanide solutions, but the mechanism involved in the process is not completely understood. In the present work, studies were carried out to evaluate the adsorption of gold onto activated carbon. Experimental data showed good agreement with both the Freundlich and Langmuir isotherms. The adsorption of gold from acidic thiourea solutions proved to be an endothermic process, while the adsorption from cyanide is known to be exothermic. The isosteric heat of adsorption of -11.3 kcal/mol in the early stages of the adsorption is an indication of a process involving chemisorption. The effect of temperature was studied between 15¦C and 55¦C. An activation energy of 3.5 kcal/mol was determined by the Arrhenius plot, which indicates that the controlling step in the kinetics of adsorption is the diffusion onto the porous structure of the activated carbon.

Jan 1, 1993

By McConachy G. W, Wright J. V

During the 110 years since the discovery of the Broken Hill PbZnAg deposit six major mining companies have mined the ore body and explored the ore environment. Despite this activity, no new orebodies have been found at Broken Hill. The failure to discover large new resources cannot be attributed to a lack of activity because major companies have maintained substantial exploration commitments over many decades. This suggests that not only was a unique coincidence of conditions required to form the deposit but also that full recognition and definition of the critical parameters may not yet have been recognised. In an attempt to illuminate some of the more unusual and poorly studied characteristics of the ore environment some new areas of investigation are presented here which may contribute to understanding the ore deposit setting and focus exploration towards different and perhaps more productive targets. Sedimentological characteristics of the host succession of the Broken Hill deposit are apparently unique along the line of lode. An upward-coarsening megasequence reflected in the development of clastic psammites stratigraphically below the ore deposit is one important ingredient which has received little exploration focus. These psammites also host mineralisation and form part of a spectrum of quart-zrich rocks collectively referred to as gametiferous psammites, garnet quartzites and blue quartz lodes. Sedimentological data interpreted from outcrop, drill core and downhole geophysical well logs support a elastic origin for some of these rocks; an interpretation which is at variance with traditional interpretations favouring an exhalative origin. A clastic origin for many of the footwall psammites, and their close spatial association with the orebodies suggests their role in ore formation was important. It is interpreted as a critical part of the fluid flow architecture within the sedimentary basin, which focussed ore forming fluids into an unique environment favourable for trapping mineralisation. Detailed stratigraphic correlation near the deposit has also highlighted that quartzofeldspathic rocks (Potosi gneisses and lode pegmatites) have complex relationships with ore. Suites of stratabound quartzofeldspathic pegmatites have received limited study, but their distribution and voluminous development suggests they may be as important to ore formation as the psammitic lode rocks which host the orebodies. These associations are not in conflict with some recent ore forming models invoking deposition in a shallow water environments of deposition. The geochemistry of parts of the host sequence has been studied extensively in the past but this has not been merged with current stratigraphic subdivisions. A large drillhole data base now permits the geochemistry to be related to the sedimentary succession and reveals that a signature involving stratigraphic vectors best illustrated by changes in MnO, Na2O, Pb and Zn can be detected. This is interpreted to reflect sedimentary basin processes as opposed to a classical volcanic hydrothermal alteration pipe associated with seafloor venting. The stratigraphic setting together with characteristics of some of these poorly understood areas is discussed to emphasise that construction of sound models for exploration requires the total ore environment to be studied with attention directed to the geometry and setting of the full range of host rocks. Control of the greater portion of the line of lode by a single company, Pasminco Australia Limited, now permits disparate datasets and observations to be merged and presents new opportunities and encouragement for model refinement and exploration success.

Jan 1, 1993

By Gemmell J. B

Zinc-bearing massive sulphide deposits have been mined in Tasmania since 1900. The current major producers are Hellyer and Rosebery, with total resource tonnages (mined plus reserves) of 16 Mt (million tonnes) and 24.8 Mt respectively. These deposits belong to the class of seafloor volcanic-hosted massive sulphides (VHMS) and are located within the Mt Read Volcanics, a narrow belt of continental margin calcalkaline volcanics of Cambrian age. Compared to other Australian VHMS deposits, and world-wide MVT and Sedex deposits, the Tasmanian examples clearly stand-out due to their high metal grades, averaging over 17 per cent Pb+Zn. The deposits vary in morphology from mound style (Hellyer) to sheet style (Rosebery) with other combinations including stacked lenses (Que River) and disrupted cross-cutting bodies (Hercules). All deposits show the classic VHMS zonation from an Fe-Cu-bearing base to a Zn-Pb-Ba-rich top. Zinc, gold and silver tenor commonly increases toward the stratigraphic top of the deposits. The ores have been deformed during regional metamorphism, resulting in folding, shearing and recrystallisation of sulphide lenses. In addition to the major deposits, a number of small massive sulphide prospects occur throughout the volcanic belt and the potential for the discovery of further large, deeply buried deposits remains high.

Jan 1, 1993

By Schommarz KH, Dunne RC, Goodall CM

Column cells are widely used today for the recovery of base metals by flotation. Their use for the flotation of iron sulphides has not been as rapid. Australia has pioneered the use of large rougher flotation columns. During the last six years, seven rougher columns have been installed on gold mines treating iron sulphides and the technical viability of this technology has been demonstrated. Laboratory column testwork on a gold bearing iron sulphide ore demonstrated the effects of both physical and chemical parameters. In general the large commercial columns operate over a broad range of conditions depending on the downstream treatment of the flotation concentrate. The addition of wash water to commercial columns is not universally applied and there appears to be a need for a better wash water System.

Jan 1, 1993

From a personal view that encompasses both research and assessment of major projects the author outlines the two competitive pressures that will force more rather than less metallurgy viz the increasing difficulty in purchasing the latest overseas developments and environmental concerns. This paper then goes on to argue that Australian metallurgy or more precisely process engineering may be in a unique position to deliver the required results.

Jan 1, 1993

By Gurgenci H, Slifirski M

The Centre for Mining Technology and Equipment was established in 1991 to develop innovative technologies for the mining and processing industries, to introduce these technologies to the industry, and where appropriate, to co-operate with equipment manufacturers to transform these technologies into equipment products. It is an unincorporated joint venture between the University of Queensland, CSIRO and the Australian Minerals Industries Research Association. Base funding for the CMTE is provided by the Federal Government as a Co-operative Research Centre.

Jan 1, 1993

By Lo YC, Pate WT

In recent years there has been a great deal of interest in ways to optimise the performance of mineral processing plants. This paper describes a methodology developed for optimisation of autogenous and semiautogenous mills. The methodology involves plant sampling, batch testing, modelling, computer simulation, control strategy evaluation and implementation. The models have been tested in plant operations to verify the research findings and predictions. Two example applications of this approach to plant optimisation are presented. Benefits reported in these two examples are in the range of four - eight per cent increase in size reduction efficiency.

Jan 1, 1993

Some crystal chemical properties of several apatites from Brazilian deposits and occurrences were determined; the samples had different origins (igneous, metamorphic and sedimentary). The aim was to establish relationships to their froth flotabilities behaviour. Detailed X-ray diffraction studies were carried out, to determine precisely the unit cell parameters and the degrees of crystallinity of the apatite samples. A thorough chemical analysis of these minerals was also conducted. Microflotation studies were carried out, using sodium oleate and dodecylammonium chloride as collectors. The crystallinity levels were determined for all samples studied, with the establishment of a crystallinity index, which varied from 10.0 to 4.5, on a normalised scale. A marked dependence was observed between this crystallinity sequence and flotability; for both collectors, flotability dropped drastically for crystallinity indices lower than 8.0. Also, the low crystallinity apatites showed a decrease in floatability, for longer conditioning times.

Jan 1, 1993

By Rubisov DH

This paper is related to the problems of the mathematical modelling of vibrating screening process and to predicting the screening operation results. The authors propose a model of screening based on the interpretation of granular material segregation on a screen surface as an instantaneous process. Results show an agreement with laboratory and pilot plant tests. Derived formulae can be used for screen sizing and screening result estimating.

Jan 1, 1993

By Van Weert G

Ferrous chloride solution pyrohydrolysis is a successful IICI regeneration process which is carried out in either a spray roaster or a fluid bed. Pyrohydrolysis is not restricted to ferrous chloride only, every metal chloride can theoretically be hydrolysed. In practice, however, the conditions for ferrous chloride pyrohydrolysis differ from those of many non-ferrous metal chlorides eg zinc, lead and cadmium. Hence, a pyrohydrolyser could function as a ferrous/non-ferrous separator, eg an iron oxide and zinc chloride separator. Most pyrohydrolysers operate on solutions, in which case more than 50 per cent of the process energy is needed for heating and evaporating water. However, this disadvantage would be diminished by feeding a slurry to the reactor. Against this background it was decided to investigate the chloridisation of zinc ferrite which is an iron bearing solid with a non-ferrous impurity, and subject to processing and disposal problems. Synthetic zinc ferrite was chloridised in a tube furnace. The gas atmosphere in the tube furnace resembled that of a fluid bed pyrohydrolyser and consisted of HCI, 1120 and nitrogen. Gas composition, temperature, residence time and sample mass were varied. The experiments showed that complete (99.6 per cent) zinc extraction from synthetic zinc ferrite was possible in a simplified pyrohydrolyser atmosphere at 1100 K in four hours. The zinc ferrite was converted into gaseous zinc chloride, and hematite and magnetite solids. It was also found that zinc removal from the zinc ferrite lattice caused not only rccrystallisation of the zinc ferrite into hematite, but also hematite crystal

Jan 1, 1993

By McDonald K. J, Flann R. C

A liquid phase sintering (LPS) process for preparing basket anodes from nickel powder has been scaled-up and the innuence of compact green density and sulphur content, as well as sintering conditions (period and syngas now.rate) on the perfonnance of anodes has been evaluated. The product anodes have been tested in an industrial electroplating tank. It is concluded that if anode residues are to be minimised, then with a sintering temperature of 960"C, compact green density needs to be as high as economically achievable (85 - 87 per cent density of solid nickel) and the sintering period approximately 40 minutes. With these constraints, if residual sulphur contents of anodes are to be kept as low as those of commercial anodes, then the sulphur content of the green compacts would need to be less than 1670 ppm. At the same time, it is also found that residual sulphur concentrations as high as 2000 ppm are beneficial to anode pcrfonnancc and not detrimental to the quality of the electroplate. The ability of the LPS process to produce marketable nickel anodes for the electroplating industry is clearly demonstrated.

Jan 1, 1993

By Chapman G. J

Mining operations require detailed and precise methods and procedures for the optimum selection of ore from waste. A fundamental procedure applied to achieve this selection is accurate sampling. The key parameter to accurate sampling is an understanding of the degree of heterogeneity of the key element contained within a sampling mass. This paper will describe the methods applied for the calculation of the fundamental sampling error and the techniques used to achieve a representative sample in the Fimiston Open Pit, Kalgoorlie.The utilisation of Pierre Gy's sampling theory has optimised the blast hole sample quality and quantity for submission to the assay laboratory. This has resulted in reduced cost and optimised assay reliability in statistical terms. Similarly the analysis of exploration drill holes for resource definition has optimised drilling procedures in terms of the drilling method, sample length and sample quantity.

Jan 1, 1993