Search Documents

This monograph presents a unified theory of adsorption and desorption of aurocyanide on activated carbon. This theory has proved useful for CIP/CIL carbon adsorption and Zadra and AARL elution process and equipment design; in accounting for the effects of various water qualities and process temperatures; and in the development of reagents to improve these processes. The theory presented is based on rigorous fundamentals : Classical Eyring theory links initial first order kinetics with Langmuir isotherm equilibria, and this isotherm is demonstrated for the first time to be a consequence of the activated complex postulate of Eyring theory. Simple extension to Freundlich conditions at high solution tenors is possible, but not presented. Supporting entropy data determined by the author includes practically all the pioneering CIP plants built in South Africa and Australia in the early 1980s.

Jan 1, 1991

By Quast K. B, Newell R, Caterford J. H

The most common reason for gold-bearing deposits being refractory is the presence of sulphides; in many cases these interfering minerals contain arsenic, antimony, or other environmentally-sensitive elements. A number of processes have been proposed or developed for pre-oxidation of interfering minerals. In most cases developers have focussed on gold recovery and capital costs, with relatively little data on the deportment or form of these potentially harmful elements. This paper surveys recent work connected with pressure pre-oxidation processes. Data from pilot plant treatment of refractory gold materials, using the nitric acid Redox process, is discussed along with the attendant flowsheet and engineering implications. Four refractory gold-bearing materials have also been tested at the University of South Australia for arsenic and antimony deportments.

Jan 1, 1991

The epithermal Au-Ag deposits of the Hauraki Goldfield have formed in the convergent plate margin setting of the Coromandel Volcanic Zone (CVZ). The deposits form as siliceous lodes in the upper parts of geothermal systems associated with andesitic and rhyolitic volcanism. Two types of low sulphidation epithermal mineralisation are recognised in these volcanic terranes. Vein deposits within the rhyolitic terrane in the east and south of the CVZ (Whitianga Province) are typified by Chalcedonic Silica-Adularia-Illite type mineralisation. The veins are hosted by both rhyolite-dacite volcanic rocks and the underlying andesitic basement. The mineralisation formed by episodic violent decompressional boiling of deeply circulating meteoric water, with some magmatic fluid contribution; this boiling was associated with hydraulic fracturing and hydrothermal eruptions in geothermal systems where the piezometric surface of the deep geothermal reservoir lay near-surface. Such episodic boiling provides chalcedonic veining, banding and brecciation textures, adularia stability, bladed calcite, and extreme loss of H2S gas from the fluid to cause major gold deposition.   Crystalline Quartz-Illite-(Adularia-Kaolinite) type mineralisation is widespread in the andesitic terrane forming the northern and western portions of the CVZ (Kuaotunu Province). There is a spatial association with weak mineralisation of the high sulphidation (Vuggy Silica-Alunite-Kaolinite-Illite) epithermal type and porphyry eu-Au type. Crystalline Quartz mineralisation is probably formed by the mixing of shallow acidic groundwaters with the ascending deep geothermal fluid in geothermal systems beneath andesitic stratovolcanoes. The piezometric surface to the deep geothermal reservoir in these systems is likely to lie at considerable depth, with acidic gases rising from the geothermal reservoir condensing within the overlying vadose zone. The cooling effect, oxidation and pH decrease accompanying mixing apparently overcomes the dilution effect, and results in quartz deposition, illite (and locally kaolinite) alteration, and precipitation of gold. A high level of base-metal sulphide precipitation also enhances gold deposition. Violent boiling of the mixing fluids may occur at local structural dilation sites, producing high grade "bonanza" gold mineralisation.

Jan 1, 1991

By Lauha E. A

The Goldstrike Mine is in Eureka County, Nevada, U.S.A., approximately 23 miles northwest of the town of Carlin. The mine is at the north end of the Tuscarora Spur of the Tuscarora Mountains at elevations of 5,300 feet to 5,950 feet. It is part of the Bluestar/Goldstrike subdistrict of the Carlin Trend, a northwest alignment of sediment hosted, disseminated gold deposits. The Carlin Trend includes over 15 major gold deposits with production, reserves and geological resources of approximately 65 million ounces of gold (Figure 1). In the Bluestar/Goldstrike subdistrict, there are seven major deposits; Betze, Lower Post, Post, Genesis, Bluestar, Purple Vein and Deep Star, plus numerous smaller deposits (Figure 2). Production, reserves and resources for the subdistrict are approximately 40 million ounces. Betze and Purple Vein are located on property controlled by Bamck Goldstrike Mines and Bluestar and Genesis on Newmont Gold property. Post, Lower Post, and Deep Star occur both on Barrick and Newmont Property.

Jan 1, 1991

By Hayward N, Sutherland D, Wilkie G

A pilot plant study has been made of the liberation characteristics of a nickel ore under different milling conditions. A series of runs were made ranging from fully autogenous grinding to semi-autogenous grinding with a ball load of 8%. The mill products were sized and assayed then analysed by QEM4SEM. This enabled a full liberation analysis to be carried out to see whether the autogenous grinding leads to improved liberation by promoting selective breakage. Though it is frequently claimed that fully autogenous grinding yields superior liberation this could not be detected in the present study.

Jan 1, 1991

Sluice box operating practices in Papua New Guinea (PNG), and published work on sluice boxes are briefly reviewed. Some recent work on sediment entrainment mechanisms occurring in sluice boxes have also been described. In the light of this information, some drawbacks in the commonly adopted sluice box operating practices in PNG, and ways of overcoming them, are also highlighted.

Jan 1, 1991

Chlorination of organic matter by direct injection of chlorine gas or hypochlorite has been investigated metallurgically worldwide with little understanding of the basic chemistry of the passivation mechanisms in- volved. In this paper, chlorination of carbon is attributed to oxidation-reduc- tions, resulting in surface halogenation of graphitic or amorphous carbon. It is proposed that chlorine and carbon interact to form thin coatings of chioro-carbon complexes that block the adsorption of gold cyanide com- plexes, thus passivating the gold adsorption sites of carbonaceous matter. Analytical, spectrographic, microscopic and electron-optical methods have been applied to demonstrate the proposed mechanism of chlorine-carbon bonding, as well as to evaluate the advantages and limitations of chlorination in the pretreatment of refractory carbonaceous gold ores.

Jan 1, 1991

By Lewis PJ, Halfpenny R, Craighead GA

Exploration drilling by Joint Venture partners CRA Exploration Pty Ltd and Elders Mining PNG Pty Ltd has discovered a signif- icant copper and gold deposit at the Wafi River prospect, 60km WSW of Lae in Papua New Guinea. An indicated resource of 18Mt at 2.5g/t Au using a lg/t cutoff has been delineated in Zone A. No estimate has been determined for the separate copper occurr- ence at Rafferty's Zone but the copper will be significant to the project. Metallurgical studies on the gold indicate that the primary ore is refractory to direct cyanidation giving a highly variable and inadequate response. All conventional refractory ore oxidation techniques perform well on both ore and pyrite concentrate and oxidation occurs rapidly. No metallurgical studies on the copper mineralisation have been undertaken. Hypogene covellite and chalcocite copper mineralisation is associated with an intensely quartz-stockworked, and quartz and alunite-altered intrusive. Economically significant gold mineralisation occurs in distal subhorizontal lenses, within a sedimentary host, that plunge toward the intrusive. These lenses are sandwiched between overlying quartz and alunite-altered zones and underlying quartz and smectite zones in a mixed zone of quartz, dickite, kaolinite and illite alteration. The alteration and mineralisation is classified as a high sulphidation, epithermal style resulting from the influx of hot, acid magmatic fluids. Preliminary land ownership, road access, power supply and mine infrastructure studies are in progress. The project is currently at an advanced exploration stage.

Jan 1, 1991

By Rowley M, Bradford P

Plutonic Resources Limited (formerly known as Pioneer Mineral Exploration Limited) delineated, developed and operates the Plutonic Gold Mine located 180 kms northeast of Meekatharra, Western Australia. Gold mineralisation was discovered in the Marymia greenstone belt by Great Central Mines NL (GCM) in 1988. There was no previous, recorded gold mining activity in the area. In May 1989, Plutonic Resources Limited (PRL) entered into an agreement to acquire a 51 per cent interest in the three Mining Leases containing the Plutonic deposit from GCM. Subsequently in December 1989, PRL acquired the remaining 49 per cent interest in the Mining Leases. PRL and GCM are also involved in a 51:49 regional joint venture on extensive Exploration Licences in the vicinity of the Mining Leases. Following due diligence validation, reserve delineation and testwork, a feasibility study was undertaken in conjunction with JR Engineering Services, which led to the financing and development of the project for operation in August 1990.

Jan 1, 1991

By Rayner J. G, Leckie J. F, Moorehead C. F

The Coronation Hill gold-platinum-palladium prospect is located in the valley of the South Alligator River (latitude 13'35'S, longitude 132'36'E), about 80 kilometres east of Pine Creek in the Northern Territory. Coronation Hill was one of thirteen sites in the South Alligator Valley at which uranium was mined between 1955 and 1964 after initial discovery by the Bureau of Mineral Resources in 1953. Most of the mines were operated by United Uranium No Liability. The Sleisbeck mine 25 kilometres south of Coronation Hill was operated by North Australian Uranium Corporation and the group of mines at Rockhole about 20 kilometres to the north-west of Coronation Hill was operated by South Alligator Uranium No Liability. The uranium mine at Coronation Hill produced about 26000 tonnes of ore averaging 2.6 kg/t U308 with an estimated average gold grade of 10.4 g/ gold. Gold was commonly associated with the uranium mineralisation and was recovered at the gravity treatment plant at El Sherana. Gold was also recovered in 1986 by Pacific Gold Mines Limited by treating the tailings from the Moline and Rockhole uranium leach plants at a CIP plant at Moline. With the completion of uranium contracts in 1964 mining in the South Alligator Valley ceased. Exploration for uranium continued in the area during the 1960s and 1970s with no success. The Coronation Hill Joint Venture (BHP Gold Mines Limited 45 per cent, Pioneer Minerals (Gold) Pry Ltd 45 per cent, Notgold Limited 10 per cent)carried out the first exploration specifically targetted at gold in 1984 with the drilling of five vertical drill holes which indicated high potential for a substantial gold resource at Coronation Hill with no associated uranium. The Joint Venture has sub- sequently drilled about 25000 metres of diamond drill holes at Coronation Hill alone. Analytical results from 1985 drilling established that platinum and palladium were associated with gold. An indicated resource of 3.49Mt at 5.12g/t Au, 0.21g/t Pt and 0.56g/t Pd has been calculated using a lg/t Au cut off.

Jan 1, 1991

The optimisation of human resources provides the path to improving productivity. British Coal has the goal of competitiveness with a quality product in ensured supply. High class skilled professional management teams will analyse job definition and selection procedures for posts, as well as objectives for and delivery of effective management training.Some fundamental changes in attitudes towards training as a means of achievement may be by managers at all levels self-examining their abilities to improve their styles, and by moving training more into the world of high technology techniques. The resulting improvements to management and training with attendant cost benefits will be enjoyed by the companies responding most effectively to these challenges.

Jan 1, 1991

By Hendrix J. L, Nelson J. H

A study was conducted to examine how pretreatment of carbon-bearing gold ores with chlorine enhances gold recovery by cyanidation. It is hypothesized that metal species (including iron and copper) dissolved during chlorination adsorb on the carbon surface hindering the adsorption of dissolved gold. To test the hypothesis, samples of several sulfide minerals were subjected to reaction with sparged chlorine gas to determine which, if any, dissolve faster than gold under these conditions. Then, a synthetic carbonaceous refractory gold ore containing pyrite, chalcocite, activated carbon, and gold was subjected to gas sparging. The results of these experiments showed that chalcocite and arsenopyrite dissolve so that metal (copper and iron) is put into solution slightly faster than gold under the same chlorination conditions. Also, it was observed from the experiments that gold adsorbs on activated carbon during chlorination, but is replaced by copper and iron as the chlorination process dissolves more of the chalcocite and pyrite. The study concluded by investigating ferric chloride addition prior to chlorination to hinder gold adsorption on activated carbon.

Jan 1, 1991

In seeking to improve the economic performance of mines, the management or human aspects are usually seen to be quite seperate from, and more significant than, the technical aspects. There are obvious aspects of industrial relations, man-management, skills training and supervision that are currently the focus of efforts to improve the productivity and quality of the mining process. However technology also has a lot to offer. Analysis of the costs involved suggests that innovations leading to improvement in the productivity of the excavation and transport of overburden and the recovery of coal (both in the mine and preperation plant) can lead to improvements in the economic performance of a mine that may outstrip the obvious non-technical or management opportunities for improvement. While there are some innovations currently being investigated within the industry that relate to the design of mining equipment, the type of machinery being used in open cut mines has not changed dramatically over the last twenty five years. It is also likely that mining equipment will remain essentially of the same form in the forseeable future. If significant improvements to mining performance are to be achieved other than by futher increases in the scale of machinery, then we need to seek ways to operate these same types of machines in a more productive and controlled manner. This paper discusses the identification of mining processes the improvement of which is likely to have a significant effect on mining costs and performance. Some areas of current research are discussed and potentially fruitful areas for future development are identified.

Jan 1, 1991

By Meunier G, Davis J, Koperski G

The dry processing of mineral sands concentrates can result in the generation of significant amounts of airborne dust. The radioactive component of this dust has implications within the context of work environment health codes. The last four years have seen considerable investment in dry plant equipment enclosure and dust extraction systems, with resultant reductions in plant ambient dust levels. Simultaneously, an industry wide program was started to examine the origin, nature, mineralogy and radioactivity of the airborne dust. The major findings of this study have been: ò confirmation that monazite was the only significant source of dust radioactivity. ò recognition of two sources of dust: - agglomerates of finely divided ilmenite-rutile alteration products, which are formed by the removal of surface coatings and particles. - abraded mineral fragments, which reflect the mineralogy of the parent particles.

Jan 1, 1991

Experimentally determined and theoretically explained phenomenon of zonal disintegration of rock around the development working brings about the radical changes in existing ideas about the mechanism of interaction rock massive with engineering constructions.The essence of the phenomenon consists in the fact, that forming of non-elastic deformations zone goes on by way of more intensive deformation and destruction of rock simultaneously in several zones, covering partially or fully output circuit and divided by zones of destructed rock. Under the influence of change of massive strained-deformational condition of depositional rock an accidental deviation of zones of supplementary expansion and compression of rock from the previous positions take place. One can observe multiplicational change of the outline, size and form of all disintegration zones in the time within the area of the working influence at massive. This phenomenon was named "fluctuation of zonal disintegration of sedimentary rock around development working".

Jan 1, 1991

By Jaczkowski B. M, Cox T. J, Domfeh I. A, Stalker I

Mining and treatment of gold ore in the Ashanti region at Obuasi, Ghana has been continuous for more than 100 years. Earlier production from this world class deposit can be traced far into the history of West Africa's gold trade. As part of a general development and expansion program, Ashanti Goldfields Corporation (Ghana) recently undertook a program to heap leach oxidized near surface ore. Kappes, Cassiday & Associates was given a major role in the design, equipment supply, installation and start-up management of the 3000 tonne/day heap leach. Unusual conditions included a high annual rainfall and an ore which could be characterized as a soft, decomposed, water saturated schist. Production began in March 1990. Startup problems and their solutions are discussed.

Jan 1, 1991

By Ariti J

The mineralogy and extractive metallurgy of platinum and palladium in ores and residues is examined and the relative reactivity of Pt, Pd, PtS and PdS in cyanide and chloride media at 20¦C is discussed. Electrochemical measurements establish that Pd is readily leached in chloride media but more slowly in cyanide media due to a passivating PdO film. The passivating oxide film on Pt prevents leaching in either system at ambient temperatures. The results of leaching Au, Pd and Pt from an iron oxide residue obtained from the Sherritt Gordon Process using CN/air and Cl-/H202 are compared. It appears that passivation is overcome either by roasting at ?600¦ or by leaching at >_100¦C.

Jan 1, 1991

By Neill A, O&apos

The City of Kalgoorlie/Boulder is situated approximately 600 kilometres to the east of Perth (Fig. 1), and is the major regional centre of the Eastern Goldfields, supporting a population of approximately 25,000. The formation of Kalgoorlie Consolidated Gold Mines in 1989 brought the existing operat- ing entities adjacent to the city under common ownership and management. The Joint Venturers forming the management company are Homestake Gold of Australia and Gold Mines of Kalgoorlie (a Normandy/Poseidon com- pany). This traditional underground mining centre has been worked since 1893, yielding 40.8 million ounces of gold from ore with an average head grade of 10 grams per tonne. Historically the heart of the operation has been the famous Golden Mile located on the Eastern perimeter of the city, in the area known as Fimiston. The other significant operations that form KCGM are the Mt Percy Open Pit and the Mt Charlotte Underground Operation. KCGM's current production is 520,000 ounces per year, with the com- bined Fimiston operations (open cut and underground) contributing 400,000 ounces. The current expansion will increase production levels by a further 150,000 ounces. Traditionally 98 per cent of gold has been sourced from underground areas, however the recent upsurge of open cut operations is rapidly overturning this historical relationship.

Jan 1, 1991

By P C. Couper, P C. Keall, S J. Mathews, A Francis

An epithermal gold-silver deposit is presently being developed at the Golden Cross Mine in the Waitekauri Valley, 8 km northwest of Waihi, New Zealand. Highest grade mineralisation underground is mainly confined to an elongate zone of strongly banded quartz veining on the hangingwall. Footwall veining is irregular, flatter lying, and of lower grade. Hydrothermal breccias in the ore zone may have economic grades where clasts of vein quartz are present. Jigsaw breccias, shingle breccias, and layered breccias with sedimentary type structures such as layering, crossbedding, and graded bedding have been identified proximal to, and within, quartz veins. Mineralisation in the open pit occurs in and adjacent to stockwork quartz veining.   Three alteration zones are recognised: a central silicic zone enclosing Au-Ag bearing quartz veins, an argillic zone above the stockwork zone and in the footwall of the underground ore zone, and a propylitic zone which is gradational with argillic zone. Intense shearing is confined to the less competent argillic zone.   Precious metal mineralogy consists of electrum (65% Au; 35% Ag) and argentiferous tetrahedrite, polybasite, pyrargyrite, argentite, and native silver. Pyrite is the dominant sulphide mineral. Marcasite, arsenopyrite, and rare chalcopyrite and sphalerite also occur. Oxidation ranges from a few metres in the argillic western stockwork zone to 100 m in fractured rock in the footwall of the stockwork.   The open pit contains a proved and probable reserve of 2.1 million tonne grading 3.5 g/t Au and 17 g/t Ag. The underground mine will produce 2.7 million tonne grading 7.8g/t Au and 27g/t Ag.

Jan 1, 1991

By Leahy G. J, Moxon N. T, Nicol S. K

Experimental work is described in which extremely dilute aurocyanide liquors are treated with novel surface-active complexing agents to produce a hydrophobic aurocyanide species. Subsequent aeration of these liquors causes accumulation of such species at the air-water interface and the aurocyanide complex is transferred to a froth concentrate. A detailed performance assessment of this process is made and this knowledge used in the design of a pilot plant facility. Early results indicate the feasibility of the selective recovery of aurocyanide ions from reclaimed residue dam water (approximately 0.2ppm Au) with upgrade ratios of the order 180:1. A further study was made applying ion flotation to the recovery of gold from a carbon-in-pulp (CIL) feed liquor (approximately 1.0ppm Au). The probable economics of this process compared to conventional CIL processing is also described. Successful development of countercurrent ion flotation for concentrating solids-free gold solutions may offer a lower cost alternative to existing gold ore processing technologies, or in more secondary applications such as concentrating dilute gold solutions or heap leach runoff. The technology may also have more generalised applications to other heavy metal process- Ing.

Jan 1, 1991