Search Documents

By P. J. Oakley, W. M. Thomas, S. W. Kallee, D. G. Staines

A Friction stir welding (FSW) is now extensively used in aluminium industries for joining and material processing applications. The (FSW) technology has gained increasing interest and importance since its invention at TWI almost 15 years ago. The basic principle, recent applications and the continuing development of the FSW technology are described. The paper will introduce some of the variants of FSW, such as Dual-rotation, Twin-stir(TM), and the Stir-lock(TM) technique.

Jan 1, 2006

By B. Jago

From the perspective of metallurgical processing, gold ores can be classified into freemilling and refractory ores. Their extractive metallurgy is largely driven by mineralogical factors such as gold particle size, association with other minerals, coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of refractory gold minerals, and invisible gold in sulphide and sulpharsenide minerals. Gold process mineralogy helps address issues and problems related to gold ore processing. It is widely used as a predictive and trouble-shooting tool in gold ore processing, and provides useful information on process selection, flowsheet development, recovery improvement, and reagent consumption optimization. By combining classic mineralogical techniques, modern instrumental analysis, and diagnostic metallurgy, the mineralogist is able to balance the various types of gold occurrence in an ore.

Jan 1, 2006

By J. Petit

"In July 2004 workers at the ABI Smelter in Bécancour (Quebec, Canada) went on strike. Contingency plan were ready to face the situation and plan was done to operate one potline out of three. Two lines were stopped; keeping in mind the restart on cold metal after the strike was over. The subject to be presented and shared includes a summary of work organization including training, schedule of restart, pot cleaning, pot preparation, crash start method, follow up after crash start, safety and environment. This major project has been a very big challenge. It shows that people involvement is a must and the key success. It is then true to say : ""People who believe in success will work and act in order to get there"" and ""People who don't believe in success will act in such a way to fail"" Then both will prove they were right to think their own way ! Sharing such experience can be interesting because it's a true story and people like true stories."

Jan 1, 2006

By Ronald Molnar

"High demand for metals is driving the exploitation of lower grade and more complex orebodies. These projects are often the initiatives of junior mining companies with limited financial resources. In addition, existing operations seek to enhance revenue from their existing metal recovery operations, through the production of value-added by-product metals and chemicals. Typically, hydrometallurgical circuits, often with novel chemistry, are required to exploit these new ores, to produce the multiplicity of products that will make a marginal project economical, or to increase the product range of an existing operation. Often, the mineral processing engineer is given the task of coordinating the development of a back-end hydrometallurgical flowsheet for their mineral processing project. This paper discusses the objectives that companies have when they commission the operation of a hydrometallurgical pilot plant. The paper goes on to enumerate some of the principal differences between mineral processing and hydrometallurgical pilot plants and the effect these have on the design, operability and potential pilot plant outcomes. Important factors include working with chemically reactive solutions and pulps, elevated temperatures operation, changing rheological properties of slurries, the complexity of integrated circuit flowsheets with long hold-up times and multiple recycle streams, and the need in some cases for extreme attention to purity and cleanliness. Examples will be drawn from the extensive experience base of SGS Minerals Services at the Lakefield site, in piloting both mineral processing and hydrometallurgical process flowsheets.INTRODUCTIONWe are currently experiencing a period of strong growth in the demand for metals. This in turn is turning the spotlight on a great many smaller mining companies and mining promotion ventures trying to tap into the rising metal demand. Some of these companies want to develop their properties and recover metals while others want to develop to the point that a major company will take an interest, or in some cases buy them out completely.With the heightened interest in metals, many orebodies that have been known about for years are being reconsidered for exploitation. Often, the reason they have not been developed to date is because of difficult metallurgy and marginal grades leading to marginal economic viability. In both cases the key that unlocks the resources is often the application of a novel metallurgical flowsheet, often a hydrometallurgical flowsheet."

Jan 1, 2006

By Y. Okita

The Goro Nickel Process, developed over a ten-year period, uses a number of novel processing steps and treats two ore types, limonite and saprolite, together. Nickel and cobalt are solubilized using a 270°C pressure acid leach in sulphuric acid, which rejects the bulk of the Fe into the leach residue as hematite particles. The leach liquor, after CCD, is aerated to oxidize any ferrous iron to the ferric form and is neutralized with limestone to precipitate iron as hydroxides together with gypsum from the neutralization of the free acid. Further neutralization with lime, together with steps to remove suspended solids, reduces the iron to trace concentrations. Nickel and cobalt are directly recovered from the low-iron leach solution by primary solvent extraction using Cyanex 301® (SXl) in a high-strength hydrochloric acid solution. Nickel is subsequently separated from cobalt in a secondary solvent extraction circuit using tri-isooctylamine. A granular nickel oxide is made by pyrohydrolysis, and this allows the recycling of hydrochloric acid to SXl. The process is currently being commercialized to produce approximately 60,000 t/y of nickel as nickel oxide granules and approximately 5,400 t/y of cobalt as cobalt carbonate. This paper describes the process development to control the Fe concentration in the SX1 feed solution.

Jan 1, 2006

By Y. Chino

Cross-rolling, in which the roll axis is tilted by 7.5 degrees against the transverse direction, was carried out on a commercial magnesium alloy. The (0002) texture intensity of the cross-rolled specimen was lower than that of the unidirectionally rolled specimen. Also, the grain size of the cross-rolled specimen was smaller than that of the unidirectionally rolled specimen. As a result of the Erichsen tests at 433 ? 493 K, the press formability of the cross-rolled specimen was higher than that of the unidirectionally rolled specimen. The high formability of the cross-rolled specimen is attributed to both the reduction in (0002) texture intensity and the enhancement of grain refinement by the cross-rolling.

Jan 1, 2006

By J-F. Magnan, M-A. Thibault, R. Boulianne, C. Gauthier, J-P. Gagné, G. Dufour

During the production of aluminium in smelters, the anodes used in electrolysis cells have to be replaced frequently. Anode butts are usually placed on anode trays for transportation and cooling, a practice during which Hydrogen Fluoride (HF) is emitted in large quantities. Covers developed in 2000 by Alcoa Deschambault to fit on the anodes trays were implemented, resulting in significant reductions of HF emissions. However, the covers are expensive to maintain and use short-life consumable parts. In January 2004, STAS and Alcoa decided to develop a more efficient design of cover, with lower maintenance costs and no need for consumable materials (like soft cushions). This paper presents a summary of the work performed to develop the new design as well as a summary of the test results.

Jan 1, 2006

By H. A. Kishawy, S. Kannan, M. Balazinski

Metal Matrix Composites (MMCs) are new generation engineering materials that possess superior physical and mechanical properties compared to nonreinforced alloys. However, the presence of abrasive ceramic reinforcements in the ductile matrix causes severe tool wear and premature tool failure. Flank wear was found to be the dominant wear mode while the main wear mechanism was abrasion. Analysis of the cutting tools using scanning electron microscopy has shown that both two body and three body abrasion are operational during machining MMCs. A methodology for predicting the tool flank wear progression during bar turning ofMMCs was presented in an earlier paper [1]. In the proposed model, the wear volume due to two body and three body abrasion mechanisms was formulated. Then, the flank wear rate was quantified by considering the tool geometry in 3D turning. The main objective of this paper is to investigate the contribution of two body and three body abrasion towards the tool wear volume during cutting MMCs.

Jan 1, 2006

By Y. -B. Kang

New databases are being developed to provide the capability to evaluate the suitability of present and potential new Mg alloys for automotive applications through cost-effective calculations. An extensive and complete thermodynamic database is being prepared for Mg alloys formed from among 25 present and potential alloying elements. The database is being developed by critical evaluation, modeling and optimization of available phase equilibrium and thermodynamic data. It contains model parameters giving the thermodynamic properties as functions of temperature and composition. Using the FactSage thermodynamic software, users can access the database to calculate the amounts and compositions of all phases at equilibrium at any temperature and composition or to calculate any phase diagram section in multicomponent alloys, to follow the course of equilibrium or non-equilibrium cooling, to calculate corresponding heat effects, etc. A database of densities and lattice parameters of Mg alloys and intermetallics (as functions of temperature and composition) is also being developed in order to permit the calculation of volume changes during cooling and phase transformations, c/a ratios of the hcp phase, etc.

Jan 1, 2006

By M. Jahazi, J. Gholipour

Design and manufacturing of parts using hydroforming process require knowledge about material behaviour and tribological effects during hydroforming. Lubrication is one of the key issues in successfully hydroform the tubes. A Ni-based super alloy tube with 50.8 mm (2 inches) outer diameter and 0.9 mm (0.035 inches) thickness is considered for this research to study the effect of lubricants on the formability of the tubes. Hydroforming of a hollow compressor blade is considered for this project. A combination of press forming and hydroforming is employed to produce the part. LS-DYNA, an explicit dynamic finite element code, is used to model the experiments. Different lubricants are modeled using different coefficient of friction in the model. Predicted results for strain distribution at a critical section of the tube are extracted for each case to evaluate the effect of different lubricants on the process.

Jan 1, 2006

By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006

By H. R. Shakeri, R. Mayer, M. J. Worswick, A. Rahem

The current focus of research and development in transportation industry is to use lightweight materials such as aluminium alloys for more structural components. In this regard, maintaining safety of the passenger and vehicle is the most important; therefore crashworthiness of components made of lightweight materials must be evaluated prior to sizable application of these materials. The focus of the present study is to understand failure and damage mechanisms during the axial crushing of aluminium tubes made of A1Mg3.5Mn alloy of 2 and 3.5 mm thickness. Due mainly to complexity of the crushed tubes, a microstructural approach is considered. In this study optical, stereo as well as scanning electron microscopy techniques have been used to study damage and failure mechanisms in these types of tubes, which are essential energy absorbing components in passenger vehicles.

Jan 1, 2006

By Mohamed Ourriban, Yongjun Peng, Qi Liu, Denis Cotnoir

"In the flotation of fine particles, there are two difficulties in general: low recovery of valuable minerals and high recovery of gangue minerals. The low recovery of fine valuable minerals is attributed to low bubble-particle collision and attachment efficiencies, while high recovery of fine gangue minerals is attributed to mechanical entrainment through water films between gas bubbles. Over the last five years COREM has been actively developing fine particle flotation techniques with the objective of improving fine particle flotation separation efficiencies.The fine particle flotation techniques with both generation of micro bubbles and enlargement of sizes of fine particles have been developed to increase bubble-particle collision efficiency. For oxidized fine sulphide minerals, both physical and chemical techniques have been developed to modify the hydrophilic surfaces and therefore increase bubble-particle attachment efficiency. To reduce mechanical entrainment of fine gangue minerals, a new approach, polymeric depression and flocculation, has been developed. By selecting the high molecular weight polymeric depressants to make fine gangue minerals hydrophilic and also enlarge their sizes, entrainment can be minimized. By combining these techniques, we are able to improve both flotation recovery and selectivity in some fine ore flotation systems.INTRODUCTIONWith depleting mineral resources and their declining grades, ores leaving grinding circuit for froth flotation are becoming increasingly finer to achieve mineral liberation. Together with the increasing demand for minerals, ever-increasing tonnages of fines are being produced. Therefore, flotation of fine particles is an immense challenge to be tackled by researchers all over the world today."

Jan 1, 2006

By J. Jackman

North America has been aggressively pursuing approaches to improve the fuel efficiency of vehicles, and to develop alternatives to petroleum-based fuels used in automotive applications, for over ten years, Increasing energy demand due to emerging economies, coupled with probable peaking of conventional petroleum production in the coming decades are increasing the need to reduce dependence on petroleum-based fuels for transportation, Vehicle lightweighting is seen as an important strategy to improve fuel efficiency of conventional as well as highly innovative vehicles, Magnesium has recently emerged as a serious candidate for lightweighting, as a result of lower global prices, Automotive vehicles produced in North America currently use more Mg than vehicles produced elsewhere in the world, but the amounts per vehicle are very small in comparison to other materials such as steel, aluminum and plastics, The reasons, besides price, are primarily a less-developed state of technology for Mg in automotive transportation applications and lack of familiarity by the vehicle manufacturers with the material, This paper reviews the major government-funded research programs in the USA and Canada that are dedicated to advancing the state of Mg technology for automotive applications, It provides examples of research in the areas of high-pressure and other types of castings, corrosion solutions, sheet development and other wrought applications.

Jan 1, 2006

By D. Furrer, M. Dallaire

The arrival of Image analysis in the last 20 years has changed the world of quantitative metallography. Many standard measurement techniques which were previously manual can now be done with fully automated systems. This reduces subjectivity and operator fatigue and therefore enhances the quality of the statistical results. In many laboratories, Titanium Alloy microstructures continue to be evaluated by traditional methods, where quality of results is subject to operator fatigue and level of experience. Advances in Camera technology have tremendously improved image acquisition. One can often see clearly at 500x what can not be observed at 1000x, allowing for a larger area to be analyzed, without the inconveniences associated with very high magnification objectives. Powerful and versatile Image analysis software combined with a high precision motorized stage gives access to a multitude of applications, which were extremely challenging or impossible until now. Image Analysis tools such as Multilayer Grab, which reconstructs an uneven image into one plane of focus (ex. Observation at high magnification of texture resulting from etching) and Mosaic which builds an image from a number of fields of view (ex. Reconstruction of very large grains at low magnifications) expand even further the power and flexibility of IA systems. This presentation will describe how automated methods are applied to the point count method and grain size measurement. We will show how cameras and software work together to permit quantitative measurements of primary alpha and prior beta microstructures, as well as lamellar alpha plate thickness in titanium alloys.Automated and semi automated quantitative measurements of various Titanium microstrures have been assessed, using the Clemex Vision PE. Examples of the methods and steps used are presented.

Jan 1, 2006

By S. Kelebek

Batch flotation tests were carried out using samples from stockpiles that were up to 1.5 months old as well as fresh samples oxidized in the lab for up to six months. Head grades and size distributions of samples were equalized whenever possible. The samples from stockpiles and oxidation experiments produced inferior nickel grade-recovery compared to the fresh sample. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to complete flotation of pyrrhotite. Secondly, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite. Application of a high pH of 10 compared to the regular pH of 9.2 slowed down pyrrhotite flotation kinetics, but was not able to prevent complete flotation after 8 minutes. The samples oxidized in the lab did not match full characteristics of stockpile samples. They provided somewhat better selectivity for pentlandite. Some correlations were observed on a qualitative basis between surface characteristics such as elemental sulphur formation, activation and flotation behaviour. Oxidation conditions, which induce floatability on pyrrhotite while causing incremental loss in pentlandite floatability appear to be the root cause of difficulties in the processing of oxidized forms of these ores.

Jan 1, 2006

By A. G. Beer

The evolution of microstructure is examined during the annealing of hot worked magnesium alloy AZ31. The influences of deformation and annealing conditions on the developed microstructures are assessed. It is found that annealing at a low temperature (300 °C), after deformation at a low temperature and strain rate (300 °C and 0.001 5-1 respectively), results in the development of abnormally large grains. With increasing values of Z (lower temperatures, higher strain rates), static recrystallization of the dynamically recrystallised structure takes place; smaller annealed grain sizes are attained and the time at which coarsening begins is reduced. Whilst both the deformation and annealing conditions influence the time it takes to reach a stable annealed microstructure, the grain size attained is governed solely by the prior deformation conditions employed.

Jan 1, 2006

By M. R. Coffin

Since the plant startup in 1972, the leaching and jarosite precipitation circuits at the zinc plant of the Kidd Metallurgical Division have been reconfigured several times to improve overall performance, and/or to respond to market conditions. For the most part, the circuit changes have been driven by two market factors: the price of zinc and the price of silver. Until recently, circuit modifications undertaken to improve zinc extraction and recovery came at the expense of silver recovery, and vice versa. In 2004, the plant was modified once again to produce a precious metals-bearing residue, but additional leaching circuits were added to ensure that zinc extraction and recovery did not suffer as a consequence. The development of the zinc plant of the Kidd Metallurgical Division is updated in this paper, with a focus on the recent circuit modifications and associated control strategies that were implemented to maximize zinc and precious metals recoveries, and control the quality of the jarosite residue.

Jan 1, 2006

By Tim Hughes, A. H. (Sandy) Gray, Jennifer Abols

"The selective recovery of gold and silver from solutions containing other metals such as copper is possible using AuRIX®100 resin in conjunction with the Gekko Resin Column. Selectivity is driven by controlling the solution pH, which enables activities such as loading copper, gold and silver and then selectively stripping copper before gold and silver. Alternatively gold and silver can be loaded and the copper left in solution. The selective loading of gold while reducing the silver loading has also been demonstrated opening the possibility of producing high grade gold doré from high grade silver pregnant leach solutions. This paper reviews the AuRIX®100 resin and Gekko Resin Column Technologies, discusses the uses of AuRIX®100 in the recovery of gold and silver and the chemistry relating to several projects for which AuRIX®100 is being tested.INTRODUCTIONGekko SystemsGekko Systems specializes in the design, development and distribution of innovative mineral processing equipment and systems with a particular focus on gravity separation for the gold and diamond industries. The company, which has been around since 1996, has five main products: the InLine Pressure Jig, the InLine Spinner, the InLine Leach Reactor (ILR), Gekko Resin Column and Modular Systems.The InLine Leach Reactor is an intensive cyanidation reactor that uses high cyanide (0.5 – 2 % NaCN) and high oxidant (20 ppm dissolved oxygen as O2 or hydrogen peroxide) to dissolve gold from medium and high-grade gravity or flotation concentrates. The ILR, which typically replaces a shaking table in the gold room, is available in both batch and continuous models. There are 42 installations worldwide. Further details on this technology can be found in papers written by Gray et al (2003) and Longley, McCallum and Katsikaros (2003). By replacing a shaking table with an ILR, the overall gravity and plant recoveries can be increased significantly. Other advantages include reduced security risks, lower operating costs, reduced operator involvement due to the automatic process and increased safety for gold room operators."

Jan 1, 2006

By P. Leo

The hot deformation behavior of a Mg-9A1-1Zn alloy produced by high pressure die casting has been investigated by means of compression tests in the temperature and strain rate ranges of 125-300°C and 10-5-10-1 s-1 and torsion tests over 150-450°C and 5, 0.5, 0.05 5-1 . The compression samples were deformed in the die-cast state or after homogenization at 415°C for 2 h to evaluate improvements. A premature fracture at 45° with respect to the compression axis was observed in samples strained at low temperatures and high strain rates. The torsion specimens were tested as received or after a predeformation-homogenization treatment. In addition to constitutive analyses suitable for modeling previously published, the results are fitted to a relationship between strain rate normalized by diffusion coefficient and flow stress normalized by modulus. The results fit well with a set of published creep experiments that were conducted in the range of 70-150°C.

Jan 1, 2006