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By M. Dadvand, G. Kipuros, A. Dadvand

"The ability to codeposit fillers within a nickel matrix has led to the production of a new generation of cermet coatings with properties useful for various applications. Hexagonal boron nitride (hBN) is a ceramic-type particulate matter with thermal conductivity, thermal stability, inertness, and lubricity properties that allow it to be codeposited. In this paper, a method was developed for modifying hBN surfaces to allow them to be uniformly dispersed in water-based solutions such as an electroless nickel plating bath. hBN surface modification improved wear performance of the electroless plated cermet due to enhanced interaction between the particulate and nickel matrix. RÉSUMÉ La capacité à effectuer un dépôt simultané de charges dans une matrice nickel a abouti à la production d’une nouvelle génération de revêtements cermet (une combinaison de céramique et de métal) dotés de propriétés très utiles pour diverses applications. Le nitrure de bore hexagonal (h-BN) est une matière particulaire de type céramique utilisée pour ses excellentes conductivité et stabilité thermiques, son inertie ainsi que son caractère lubrifiant, qui permettent son dépôt simultané. Cet article explore une méthode mise au point pour modifier les surfaces du h-BN de manière à ce qu’elles se répandent uniformément dans des solutions aqueuses telles qu’un bain de dépôt autocatalytique de nickel. La modification des surfaces du h-BN a amélioré la résistance à l’usure du placage autocatalytique du cermet en raison d’une interaction accrue entre la matière particulaire et la matrice nickel.INTRODUCTION Electroless nickel alloy coatings can be used for many applications; however, the need for improved tribological properties such as higher wear resistance and better lubricity has increased interest in incorporating particulates (fillers) into the nickel matrix by codepositing the particulates with nickel during the plating process. The selection of the particulate type depends on the desired properties (Sahoo & Das, 2011; Sudagar, Lian, & Sha, 2013). In terms of tribological applications, electroless nickel-based composites are categorized mainly into lubricating and wear-resistant composite coatings depending on the type of particles incorporated. The electroless nickel-phosphorus (Ni-P) composite coatings are composed of codeposited solid lubricants such as polytetrafluoroethylene (PTFE), graphite, WS2, MoS2, and hexagonal boron nitride (hBN) and, compared to nanocomposite electroless Ni-P coatings, they demonstrate a lower coefficient of friction. On the other hand, the nickel-phosphorus wear-resistant composite coatings are composed of hard particles such as silicon carbide (SiC), aluminum oxide (Al2O3), boron carbide (B4C), silicon nitride (Si3N4), diamond, tungsten carbide (WC), and zirconium oxide (ZrO2) and, compared to nanocomposite electroless Ni-P coatings, they have higher hardness and better wear resistance (Sahoo & Das, 2011; Sudagar et al., 2013; Parucker, Klein, Binder, Ristow, & Binder, 2014; Chakarova, Georgieva, Petrova, Dobreva, & Stoychev, 2016)."

Jan 1, 2018

By F. Chachula, A. Molinaro

"Sulphide mineral flotation operations continuously strive for a balance between mineralogy, mineral liberation, circuit conditions and reagent solutions to maximize the production rate and recovery of payable metals. The Taseko Gibraltar copper – molybdenum mill operations underwent an extensive project focusing on the fundamentals to identify the effects of process conditions and mineral liberation to improve the bulk circuit copper – molybdenum recovery efficiencies in the bulk flotation circuits. This discussion will provide process data that demonstrates; 1) fundamental relationship between mineral liberation to recovery and grade, 2) flotation circuit condition testing and optimization, 3) reagent combinations resulting in efficient/economical mineral recovery, and 4) the development of a xanthate free reagent solution. The data presented and discussed will also touch on flotation parameters including pH, retention time, kinetics and the effect on bulk circuit recovery performance.INTRODUCTION Taseko's is the owner (75%) and operator of the Gibraltar copper-molybdenum mine, located in south-central British Columbia, the second largest open pit copper mine in Canada and the largest employer in the Cariboo region. Taseko restarted Gibraltar in 2004. From 2006 until 2012, the company invested ~$700 million to expand and modernize the operation which was originally scheduled for demolition when the company acquired it in 1999. In the spring of 2011, construction commenced for Gibraltar Development Plan 3 (GDP3). GDP3 included the construction of a standalone 30,000 ton per day concentrator, built adjacent to the existing 55,000 ton per day facility. The new design capacity of Gibraltar was designed to be 85,000 tons per day. An integral part of the project was a new molybdenum recovery facility. In addition to the new concentrator, the mining fleet was upgraded with a new mining shovel, production drill and ten haul trucks (Taseko, May 2015). In May of 2015, the Company completed an updated mine plan for Gibraltar featuring a 50% decrease in strip ratio. This new mine plan was a result of a detailed, six-month engineering study and forms the basis of an updated NI 43-101 compliant reserve (Taseko Announces Improved Economics At Its Gibraltar Copper Mine, 2015). The new mine plan took into account lower milling costs as a result of the modernized processing facilities (Taseko, May 2015)."

Jan 1, 2018

Pilot plants for pressure hydrometallurgy represent special design and project execution challenges unique to the industry and to the pilot- and demonstration-scale. Pilot plant projects have different objectives and shorter timescales than commercial plant projects. Design considerations and strategies, and project execution methods that meet the special needs of pilot plant projects, are discussed. Specific guidance is given for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical process equipment, and for the selection of materials of construction for pilot-scale equipment. The balance between the need for process similarity with future commercial operations and the realities of pilot-scale equipment is also discussed.

Jan 1, 2004

By Egbert Burchardt

The challenge of "ore bodies getting steadily harder and lower in grade" was brought to light during the first oil crisis in the 70's. Shortly afterwards, HPGRs appeared on the scene with the promise of saving energy. This combined with developments in wear protection for the rolls ushered in a period of trade-off studies that considered the HPGR as an option to improve project economics or to even make projects feasible at all. Since then, applications of HPGRs at Cerro Verde (Freeport), PTFI Grasberg (Freeport), Mogalakwena (Anglo Platinum), Tarkwa (Goldfields), Boddington (Newmont), Penasquito (Goldcorp), and others have contributed to the creation of a formidable basket of operating experience. Collected through years of successful operation, this information has been used to validate design criteria, scale-up factors and establishing a clearer picture of what "to do" and what "not to do". This paper compares results from various mining operations using HPGRs in their processing plants. Some of the lessons learnt in different operating environments are reviewed in order to support proper implementation and operation of HPGR's. Some of the development programs that have been initiated to improve wear life of the tyres and to reduce overall operating costs are reviewed. It is timely to summarize today?s experience and analyse its implications for existing and new operations.

Jan 1, 2012

By Andrew D. Lapworth

The use of geological and grade models has been standard practice in mine design for many years now, with a wide range of software available to create and analyze the models. Although geotechnical parameters are also of vital importance for mine planning, there has been very little in the way of commercially available systems for integrating geotechnical data into the mine planning and design process. Sirovision is a new technology based on digital photography for automated, safe and accurate 3D mapping of geological and geotechnical features in rock faces. Datamine has integrated this capability into its product range so that Sirovision becomes an integral part of day-to-day face mapping, mine geology and geological / geotechnical modeling in both open pit and underground mines. This results in improved fragmentation for loading, hauling and processing, and for open pits local geotechnical conditions can be taken into account to improve slope design and control. This paper describes some of the ways that geotechnical modeling can be used to create more refined and cost effective mine designs and then discusses the role of Sirovision in enabling the raw data required for such modeling to be collected quickly, safely and reliably.

May 1, 2007

By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005

By K. Nagai

The Asian projects are now in their second terms after the five-year first terms. Ultrafined-grained steels were developed in lab-scale and/or in practical process. Basic approach has been performed to explore the evolution mechanisms of ultrafine-grained microstructures. There have been investigated two approaches to make the ultrafine grains: the "recrystallization route" and the transformation route. In the "recrystallization" route, heavy deformation at low temperature is necessary for the ultra-refinement. In the transformation route, making the high density of ferrite initiation sites in the deformed austenite, especially of the heavily compressed austenite structures, is essential for the ultra-refinement, and further hindering the ferrite growth is also inevitable to utilize the high initiation rate. Strength and toughness are dramatically improved by the ultra-refinement. Fatigue property is also excellent. The poor uniform elongation can be enhanced by the design of the second phase dispersion. At the same time the application has been also pursued from various viewpoints of engineering to take advantages of the ultrafine-grained steels. Bridge, ship, construction, automobile and other high strength parts are being attempted for the application.

Jan 1, 2004

By G. Q. Liu

"The application of oxygen-enriched cyanidation to three Canadian gold ore samples has been investigated. The results showed that the use of oxygen can improve gold dissolution kinetics, reduce grinding time, and lower cyanide and lime consumptions. To obtain the same gold extraction, the required cyanide leaching time was reduced from 48 hours in slurry containing 8 ppm O2 to 12 - 24 hours in 20 ppm O2 slurry. Reagent consumptions were reduced by 23 - 37% for cyanide and by 35 - 54% for lime. There was little advantage to further increasing the dissolved oxygen to 32 ppm from 20 ppm. Gold extraction from the +200 mesh fraction improved 4 - 14% in oxygen-enriched slurry. A general kinetic model derived from the cyanidation of three ore samples can be described by the following equation: <equation>where E is the gold extraction (%) at time t (hours), EI is the ultimate gold extraction (%) , and &apos;P and k are constants depending on cyanide concentration, level of dissolved oxygen, and the characteristics of the ore samples. Comparative studies of conventional carbon adsorption and carbon adsorption in oxygen-enriched slurry have also demonstrated that oxygen enrichment resulted in more favourable conditions for gold adsorption."

Jan 1, 1995

By K. Adham, C. Lee

The demand for nickel is continuing to exceed inventories, and producers are working vigorously to increase capacity. Many nickel processes utilize the fluidized bed technology for its fast heat and mass transfer, excellent temperature control and low maintenance. The following four nickel applications of the fluidized bed technology have been commercialized: I) Sulfide ore roasting; II) Nickel sulfide (matte) roasting; III) Nickel oxide reduction; IV) Nickel chloride pyrohydrolysis. This paper examines the issues surrounding the application of fluidization technology to the above processes, from the stand point of the engineer modeling the process and designing the key equipment, based on the historical success stories and the fundamental principles of flow sheet synthesis. Using the available data in open literature, typical flow diagrams (with convenient bases of 1 t/h feed or product) are developed to illustrate the relative flow rates and to highlight the key features of each application. In addition, some historical background information is provided for each process with supplemental notes with regards to our company&apos;s involvements.

Jan 1, 2005

By T. Navessin

Recent research activities in proton exchange membrane fuel cell (PEMFC) have significantly improved the performance per unit cost and its lifetime. These activities narrow the technology gaps, and thus, enable commercialization in some applications. One particular focus is in the development and understanding of proton conducting membrane materials. Many novel membranes are being developed which provide control and systematic understanding of complex relationships between chemical structure, morphology, physicochemical properties, and electrochemical kinetics. In this study, different classes of proton conducting membranes suitable for portable and automotive applications were evaluated in an operating PEMFC at the Institute for Fuel Cell Innovation, National Research Council. Analysis of these results may provide constructive feedbacks to the material researchers.

Jan 1, 2005

The integration of mining and mineral processing technologies into new advanced mining systems is considered to offer several benefits, including selective mining, reduction in waste, increased productivity, flexibility, and improved resource utilization. This paper focuses on underground hardrock mining and the integration of pre-concentration technologies into future mining systems as representing realistic, shorter-term integration options. Control of fragmentation to optimize grinding, pre-concentration of ores, in situ leaching, and modular mining/mineral processing systems are possible with existing technology. Current research is directed toward development of integrated underground systems that minimize surface activity and minimize or eliminate surface waste disposal. Results from a simulation model of an integrated underground pre-concentration system are presented.

Jan 1, 2002

By M. A. Nadar

Harsh and dynamic construction sites are generally equipped with cranes in order to rapidly and conveniently move heavy loads from one location to the other. If not properly inspected and managed, this operation can be very hazardous and lead to accidents. As such, a reliable and self-contained monitoring system that can update construction and safety personnel about the status of the crane, the weight of the load lifted, the location of the boom with respect to nearby buildings and other tower cranes, and the weather conditions under which the crane is operating, is deemed necessary. This can lead to significant time and cost savings as well as safety and productivity improvement due to the accuracy and immediacy of relevant on-site crane information delivery. This paper takes the initial steps and presents research targeted at evaluating the capability of wireless sensor networks (WSN) for monitoring tower crane operations in construction environments. A reliable long range WSN system is implemented and information is obtained from various special-purpose sensors (temperature, wind, proximity, etc.) mounted on special motes that relay data to and from each other and a central hub. The latter continuously monitors and manages network performance and relays incoming data to the host application. This application, in turn, displays the received data, and maps it onto a user-friendly visualization scheme, triggering alarms when a set of pre-programmed rules and safety conditions are crossed. The components of the proposed system have been tested through proof of concept experiments and preliminary results highlighted the potential of WSN systems for improving monitoring of tower cranes and reducing related accidents on construction sites, especially in Lebanon and the Middle East region where safety precautions are usually not properly implemented.

Aug 1, 2013

By P. Coulombe, J-F. Riverin, A. Gaboury

Cavity cleaning during anode change generates a material that consists of anode cover material and cryolite melts. This material is scooped and placed in bins for transport and further processing and recycling as fresh anode cover material. Typical processing methods in use involve cooling of the hot cavity bath in bins, with or without emission treatment systems, until it is adequate to be processed and grinded to the required particle size distribution. Handling of the hot and cooled cavity bath material can be labour intensive. It also generates significant air emissions which contain particulate and gaseous fluorides. With the advent of the Aluminerie Alouette smelter Phase II expansion, the hot cavity bath tonnage to be processed increased to 700 t/day and maintaining existing practices was not satisfactory. This article presents a novel process implemented at the Alouette smelter where cavity bath is processed as a hot material directly from the potlines ( 600-800°C range), sized, cooled and then processed in the existing cold bath treatment plant. The system is designed to process 36 t/h, is fully automated and requires limited monitoring from operations. Implementing this new system in a Browrifield environment imposed numerous constraints for space, interfaces with existing operations, commissioning and ramp-up. It is presently operating at approximately 80% availability and is easily meeting the requirements of the potlines. This system has significantly improved the workplace environment in the bath treatment area and reduced the overall particulate and gaseous fluorides emissions at Alouette. Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by

Jan 1, 2006

By Patrick Rennkamp, Wolf-Dieter Trodel, Andy Fearn

"The Jansen shafts are completed using purely mechanical excavation. This paper summarises the geology, a description of the shafts, the method used for excavation and the results achieved along with the challenges encountered and the solutions developed during the project. This experience is now being applied in the next generation machines and shaft sinking processes. This pioneering approach is changing shaft sinking in soft and medium to hard rock. INTRODUCTION The Jansen Mining project located approximately 150 km east of the city Saskatoon is the location of the BHP owned potash mine with an expected mining output of eight million tonnes annually upon completion. Mining contractors DMC Mining Services have used two Herrenknecht Shaft Boring Roadheaders (SBRs) to excavate the two blind shafts with an approximate excavation diameter of ten metres (inner diameter approximately 8.3 m) to depths of -975 and -1005 metres, respectively. The SBRs excavate the rock by a partial-face cutting method, using a transverse cutting drum mounted on a telescopic boom. The excavated rock is then conveyed away from the bench by an innovative pneumatic system and transferred into muck buckets to be hoisted to the surface. No drilling and blasting was done to keep to the BHP philosophy of using only mechanical excavation for this reference project. BHP VISION – MECHANICAL EXCAVATION BHP focused on mechanical excavation at Jansen due to the following perceived benefits: 1.No workers in the excavation chamber (shaft bottom), minimizing the exposure to traditional shaftsinking hazards associated with working in the shaft bottom. 2. Minimal damage to the rock fabric reducing the need for ground support and avoiding potential impact damage to freeze tubes located around the shaft. 3. Accurate excavation diameters with no overbreak, reducing volumes of rock to be removed and replaced with concrete lining."

Jan 1, 2019

By S. Khallouk, J. Zollinger, J. R. Kennedy, E. Bouzy, B. Rouat, D. Daloz

Titanium aluminides recently replaced Ni-based superalloys as turbine blades in the last LP stage of aircraft engines. To extend their range of use at higher temperature their properties need to be improved, either by alloying or processing. An efficient solution is to reduce the grain size during the solidification process. In the first part of the paper, an overview is given on the possibilities for grain refinement of such alloys, based on literature data and new results. The most efficient grain refinement is obtained with boron addition which leads to boride formations that are detrimental for in-use properties of turbine blades. In this work, the use of the high grain refinement potency of inoculation with non-brittle particles has been used by developing new refractory-based inoculants. The effect of one of these inoculants on grain refinement of an as-cast structure in a Ti-46Al is presented; resulting in a reduction of the grain size by a factor of 3.While less efficient compared to the potency of boron containing alloys, the grain refinement is effective and does not introduce any embrittling particles.

Jan 1, 2015

By D. Milne, G. Snell

"A new method to predict stope hangingwall failure in underground excavations is proposed. This method compares movement rate for stope hangingwalls, determined from changes in strain or deformation, with changing opening geometry. This geometry is represented by the effective radius factor (ERF), a measure of relative distance to supporting abutments from an opening surface point. This strain-ERF (SERF) approach is applied to an instrumentation program for Brunswick mine near Bathurst, New Brunswick. The SERF method for this case study predicted failure at an ERF of 13.9 m and hangingwall failure actually occurred at an approximate ERF of 12.4 m.RÉSUMÉ Cet article propose une nouvelle méthode permettant de prévoir la rupture de l’éponte supérieure des chambres d’abattage dans les excavations souterraines. Cette méthode compare la vitesse de mouvement des épontes supérieures des chambres d’abattage, déterminée à partir des changements aux niveaux des contraintes ou de la déformation, à la géométrie variable de l’ouverture au jour. Cette géométrie est représentée par le facteur du rayon effectif (ERF, de l’anglais Effective Radius Factor), une mesure de la distance relative jusqu’aux appuis latéraux de soutènement à partir d’un point de la surface d’ouverture au jour. Cette approche contraintes-ERF (SERF, de l’anglais strain-ERF) est appliquée à un programme d’instrumentation pour la mine Brunswick située près de Bathurst, dans le Nouveau-Brunswick. Pour cette étude de cas, la méthode SERF prévoyait une rupture à un ERF de 13,9 mètres (m); la rupture de l’éponte supérieure s’est effectivement produite à un ERF d’environ 12,4 m.INTRODUCTIONUnderground stope design can be improved with the installation of field instrumentation. The most commonly used instrumentation for monitoring rock mass behaviour around open stopes is extensometers. The y-axis of Figure 1 represents how the changing rate of movement, measured using either displacement- or stress-type instruments, can be observed over time. The magnitude of movement measured by extensometers can give an approximation of the load on installed support (Milne, Pakalnis, & Lunder, 1996) and a changing rate of movement can indicate approaching instability."

Jan 1, 2018

By J. Bednar, R. R. Rogers, W. Dingley

"Zinc is by far the most important metal used for protecting steel from the ravages of corrosion, and cadmium is also used extensively for this purpose. These metals are applied by electrodeposition in cyanide baths when a particularly good appearance and high throwing power are required. One great disadvantage in using these baths has been the decrease in cyanide concentration and the increase in carbonate concentration that takes place during the plating. Another disadvantage has been the development of serious embrittlement in high-strength steels. The present authors have developed new cyanide baths for electroplating both zinc and cadmium on steel. These baths are stable in composition during plating, they have not produced appreciable embrittlement in the high-strength steels that have been investigated up to the present time, and they permit the use of considerably higher plating current densities. In addition, they produce extremely fine grained coatings that are attractive and have excellent adherence and covering properties. Brighteners can be used in the plating baths if bright finishes are required."

Jan 1, 1967

By Anand Raman, Steve Dixon

"Industry practice for defining acid consumption is based on column tests. Freeport-McMoRan (FCX) has adopted a practice of leach operation using a defined pH or gpl acid in the raffinate based on the column test program. The acid consumption can be easily calculated using the leach operating parameters of SX-EW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate. The column leach test results and a column to heap efficiency factor are used to define the copper extraction. The maximum acid consumption will occur when zero acid is contained in the raffinate. The term Net Extracted Value (NEV) is to define the maximum extracted value relative to acid consumed.This paper presents the operating logic and method used to calculate acid consumption based on column tests and operating parameters.INTRODUCTIONIndustry practice for defining acid consumption is based on column tests. This may result in lower economic value if the tests are not designed to account for operating variables. A test program is described to assist in defining lift height and the influence of gangue on solution chemistry. A simple spreadsheet is presented that will use the leach operating parameters of SXEW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate to calculate the acid consumption for a proposed operation.A review of current leach operations solution chemistry will help to define acid consumption. This is recommended for all current leach operations.DISCUSSIONThe current practice at Freeport-McMoRan (FCX) is the use of column test results to define operating parameters. The monitoring of operational solution chemistry and copper production addresses any changes needed in operational parameters. This practice maximizes the value extracted from each tonne of ore leached."

Jan 1, 2008

By K. Fagerlund, L. Rosenback, T. Mäkinen, Y. Anjala

This paper deals with the nickel smelter and refinery concepts Outokumpu has applied at Harjavalta and several other plants. Also other process routes and modifications developed and tested by Outokumpu during the recent years are highlighted. Outokumpu started nickel production in Harjavalta in 1959. Until 1995 the Flash Smelting - Peirce-Smith (PS) converting route was applied. High grade nickel matte from the converting step was further refined by means of leaching and electrowinning to produce cathode nickel. In 1995 the nickel production capacity was increased from 17 000 t/a to 52 000 t/a based on the Direct Outokumpu Nickel Smelting Process (DON). In the DON process PS converting is eliminated and high grade nickel matte with low Fe-content is directly produced in the flash smelting furnace (FSF). Metal values from the smelting slag are recovered in the electric furnace (EF) as iron containing Ni-matte. The DON process can be operated with either two matte concept, where high grade FSF matte and EF matte are produced, or a single matte concept, where EF matte is recycled to the smelting furnace and thus only one type of high grade matte is obtained. The additional refinery capacity at Harjavalta is based on hydrogen reduction producing.

Jan 1, 2005

By A. B. Parsons, P. G. Howes

"This article discusses how recent changes in the federal and Quebec .income tax laws have contributed to an improved investment climate for mineral exploration in the Province of Quebec. Individual investors who are resident in Quebec and who are in the highest tax bracket (1984-60.4% marginal rate) may obtain tax benefits that result in only nine cents of each invested dollar being at risk.IntroductionIn a recent submission by the Mining Association of Canada to the Royal Commission on the Economic Union, it was stated that the mining industry ""is no longer discovering and opening new mines at rates sufficient to offset the depletion of existing orebodies and to maintain pre sent output"". With world metal prices still in a depressed state following the prolonged 1981-82 recession, moreover, the continuing success of Canadian mining in world markets will depend on this country&apos;s ability to compete in a new environment characterized by subsidized Third World production . For the most part, this new competitive environment will encourage the development of cost-efficient mines that are better equipped to withstand the troughs and valleys of international metals prices."

Jan 1, 1984