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By X. Cao, B. S. Naik, D. L. Chen, P. Wanjara

AZ31B-H24 Mg alloy sheets with a thickness of 2 mm were friction stir lap welded (FSLWed) at two tool rotational rates of 1000 and 1500 rpm and two welding speeds of 10 and 20 mm/s. The tensile behavior of the FSLWed AZ31B-H24 Mg alloy was then evaluated at low (-40°C), room (25°C), and high (180°C) temperatures. It was observed that the failure load increased with decreasing tool rotational rate and increasing welding speed. The maximum failure load occurred at a tool rotational speed of 1000 rpm and a welding speed of 20 mm/s at all temperatures tested. It was also noticed that at the high test temperature, the samples failed along the sheet interface, i.e. shear fracture. At the low and room temperatures, the samples failed on the advancing side (AS) of the top sheet near the interface between thermo-mechanically affected zone (TMAZ) and stir zone (SZ). The different modes of fracture observed are associated with the hooking defect.

Jan 1, 2014

By N. Dobrin, R. Sheinman, Y. V. Kokotov, L. N. Braginsky

Increasing the production of a Mixer-Settler unit requires either increasing flow rates or increasing extractant concentration. The mixers still have to ensure complete emulsification and to maintain high values of specific interface surface area in order to provide a high rate of mass transfer. Theoretically, an increase in mixing intensity can support increased flow rates without reducing extraction efficiency. Unfortunately, conventional pump mixers and mixing systems create small droplets that do not separate easily. As pumping action and mixing intensities are increased, the quantity of small droplets increases. We describe the development and industrial application of a novel mixing system for efficient mass transfer without forming significant quantities of small droplets, targeting both high mass transfer rate and low entrainment values.

Jan 1, 2014

By I. M. London, G. P. Hatch

The Canadian Rare Earth Elements Network (CREEN) was formally launched at the Rare Earth Symposium at The Metallurgy and Materials Society of CIM (MetSoc) Conference of Metallurgists in October 2013. CREEN is an industry-led, multi-stakeholder network focused on providing collaborative solutions that will advance Canada’s REE sector to produce a significant proportion of the global production of separated critical rare earth products by 2018. The Network is industry driven by companies with REE projects under development and supported by universities, engineering firms, national and commercial laboratories, and government. CREEN aims to accelerate the development and delivery of timely solutions to technical and economic issues specifically facing Canada’s emerging rare earth sector. It will facilitate partnerships with other national and international organizations to leverage existing research initiatives. It will also support training and education to ensure that the needed qualified human resources are available to achieve the sector’s goals. CREEN membership spans the full rare earth supply chain and technical support organizations, from prospective producers, advanced project developers, national and commercial laboratories, engineering consultants, university researchers, and other innovators. This paper provides an update on CREEN's developing networking and project develop

Jan 1, 2014

By Y. -H. Cho, J. -M. Lee, J. -G. Jung

The effects of copper on the microstructure and mechanical properties of ultrasonic melt treated Al-xCu (x=0, 4) alloys were investigated. The densities of alloys were increased and their grain sizes were decreased by UST. The hardness and electrical resistivity measurements revealed that the amount of solute Cu within Al matrix was increased by UST. Both the yield and tensile strengths of Al-4Cu alloy were increased by UST. The improved mechanical properties of Al-4Cu alloy by UST were probably due to the reduced amount of casting defects (e.g. pore), grain refinement, and enhanced solid-solution hardening of Cu.

Jan 1, 2014

By H. Cay, J. Zachwieja, T. Esplin, R. Ravenelle, T. Olsen-Tank

Barrick Goldstrike mine utilizes a carbon-in-leach (CIL) circuit to simultaneously leach gold into solution with cyanide and adsorb the gold-cyanide complex onto activated carbon for further refinement. If the gold bearing ore contains a significant amount of native carbonaceous material, gold cyanide can be adsorbed at these sites instead of onto the desired activated carbon and the gold is effectively lost to tailings in a detrimental process known as "preg-robbing." The preg-rob effect is considerably reduced by treating the ore with a surfactant, which is hypothesized to adsorb to and passivate the native carbon surfaces. Past laboratory and pilot studies have consistently demonstrated significant gains in gold recovery after treating carbonaceous ore with surfactant. With success in bench and pilot scale testing, a plant trial was conducted at Barrick Goldstrike to evaluate the feasibility of using an alkoxylated fatty amine surfactant (Ethomeen T/12) to aid in the leaching of high preg-robbing ores. This paper analyzes the performance of the surfactant during the plant trial in addition to the problems that occurred during the trial period. Suggestions for improvement are also discussed.

Jan 1, 2014

By M. Connell, S. Bedrossian

Alkali cracking followed by chloride-based leaching is one of the prominent methods for rare earth element processing. Regeneration of the leach lixiviant, namely hydrochloric acid, is a critical operation in the process. A number of different process routes are available for recovery of hydrochloric acid from chloride solutions. The objective of this paper is to discuss various recovery routes and analyze the impact of several input variables on the variable operating cost.

Jan 1, 2014

By K. Halada

Current trend of the global flow of strategic metals are analyzed to discuss the strategy of the development of recycling technology and alternative technology. In many cases, each global flow of metal is changing from the trilateral structure of U.S., EU and Japan in the later 20th century into the convergence to China as the factory of the world. Scrap flows are also changing dynamically. A long term change of prices of metal has gotten changed since the entrance of this century. The estimation of metal consumption up to 2050, in which the author estimated that many kinds of metal will overshoot the reserve base line, is revised considering these change of current trends.

Jan 1, 2014

By G. Frithum

In the present paper a new and highly economic route for Fe-separation from HCl leaching processes in hydrometallurgical applications is described. In most ore leaching processes, Fe is involved and needs to be separated; HCl has become an interesting leaching agent, because it can be recycled. Usually a mix of Fe2+ and Fe3+ is obtained which can be hydrolyzed directly (in case only Fe3+) or roasted via pyrohydrolysis (in case of Fe2+) to ferric oxide. Economic oxidation of Fe2+ to Fe3+ is described, and potential technologies for regeneration of HCl with separation of Fe are shown and compared.

Jan 1, 2014

By Roger Payne, John R. Goode, Feng Gao, James Brown

The Eco Ridge deposit is located in the Elliot Lake mining camp in Northern Ontario, Canada. Between 1955 and 1996, the area produced more than 138,000 t (300 million pounds) of U3O8 and very significant amounts of thorium and heavy rare earths. Based on the NI 43-101 Preliminary Economic Assessment by Roscoe Postle Associates (RPA) dated June 2012, and the economic review by RPA as announced in Pele Mountains’ Press release dated September 12, 2013, the Eco Ridge Mine Project would extract and process 46 Mt of material to produce about 19,000 t (42 million pounds) of U3O8 and about 65,000 t of rare earth oxide (REO) over a 14-year life. This paper discusses process optimization studies including beneficiation and hydrometallurgical testwork. The proposed modified flowsheet includes the flotation and processing of 1) a pyrite concentrate, 2) a dominantly light rare earth elements (LREE) concentrate, 3) a concentrate containing most of the balance of the uranium and heavy rare earths (HREE), and 4) a relatively inert tailings.

Jan 1, 2014

By B. K. Mishra, Avijit Biswal, B. C. Tripathy, Abhijeet Singh, K. Sanjay, T. Subbaiah

We studied theeffect of anode substrates such as pure lead (Pb), lead antimony (Pb-Sb), and lead-silver (Pb-Ag) on the structural and electrochemical properties of electrolytic manganese dioxide (EMD). X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and chemical analyses were used to determine the structural and chemical characteristics of the EMD samples. The charge-discharge profile was studied in 9 M KOH using a galvanostatic charge-discharge unit. In all the substrates the current efficiencies were more than 99% except with Pb-Sb where it was 90%. Results revealed the nature of the substrate strongly affected the morphology of the deposited material which in turn affected the electrochemical properties of the EMD samples. XRD analyses revealed that the nature of the anode did not affect the crystal structure of the deposited EMD and all the samples were predominantly ?-MnO2, which is electrochemically active for energy storage applications. The EMD deposited on lead substrate showed superior discharge capacity of 245 mAhg-1 when compared with other substrates.

Jan 1, 2014

By Yan Qun, Chen Xiao-ming, Ma Pei-long, Luo Xian-ping, Luo Cai-gui, Feng Bo

The effect of leach promoting reagent LPF on the leaching process of a weathered crust elution-deposited rare earth ore has been investigated and the mechanism is discussed. The result shows that the leach promoting reagent LPF can enhance the leaching extraction of rare earth ore effectively. With the addition of LPF to the lixiviant at a concentration of 0.1%, the leaching extraction increased by more than 8%, the ammonium sulfate concentration could be decreased by 25%, and the leaching liquid/solid ratio reduced by 34%. The mechanism analysis shows that LPF can react with rare earth ions and form soluble coordination compounds, thus reducing the activity of the leached rare earth ions, increasing the concentration difference for ion diffusion, and promoting the rare earth leaching process. These results will hopefully help point to a new approach to making the leaching process of low-grade weathered crust elution-deposited rare earth ore more efficient and with lower lixiviant consumption.

Jan 1, 2014

By D. Auerswald, M. Kotze, V. Yahorava, T. Udayar

Uranium can be recovered from lower grade uranium ores (<800 mg/kg U3O8), leach residues, and waste dumps cost-effectively via resin-in-pulp (RIP). Using this technology, no solid/liquid separation or washing of the leach residues are required. Furthermore, the uranium recovery can be higher than with conventional methods. RIP technologies have, however, been perceived negatively due to concerns around potential resin fouling and losses. This paper highlights the advancements made in RIP and discusses a number of potential applications where the technology could deliver economic and consequential environmental benefits by reducing the uranium levels in the waste.

Jan 1, 2014

By Phillip J. Mackey, Gerardo R. F. Alvear F.

It is now 38 years since the publication of the first edition of "Extractive Metallurgy of Copper" by Professor W.G. Davenport and the late Professor A.K. Biswas. The text book would be issued in a total of five editions, soon became the standard for students and those in industry. Interestingly it was published at the onset of great change in the industry. This was a time when sulphur dioxide controls in the USA were introduced, and almost simultaneously, world oil shocks caused significant increases in the cost of fuel - all leading to efforts to adopt new technology and move away from the reverberatory furnace, which had no potential for sulfur capture and required large amounts of fuel. At the time of publication of the book, new processes such as the Noranda Process and the Mitsubishi Process were in their infancy, while flash smelting (which was first commercialized in 1949 at Harjavalta, Finland) had made significant in-roads in boosting copper output, with some 22 new flash smelters licensed by 1976. Computer technology and associated process control techniques were rudimentary compared to systems today, available physico-chemical data remained largely in tabulated format and needed to be manually entered into the main frame computers of the era, while modeling techniques common today had not yet been developed. The copper industry has therefore seen immense changes since the time of this textbook: world tonnage of smelted copper has risen from 7.34 million tonnes/year in 1976 to 16.7 million tonnes/year in 2012, over a two times increase. Technologies such as the El Teniente Process, or Top Submerged Lance technologies, typified by the ISASMELTTM, not commercialized at the time, now treat large tonnages of copper concentrate in a single furnace. Advanced heat and mass balance software and thermochemical modeling are now used extensively to examine chemical and physical characteristics for process design and to support process optimization. These changes in the industry have been chronicled in subsequent editions of the book. This paper looks at the issues and problems seen in 1976 and over the intervening years, and compares this with the challenges facing the industry with the available tools and technologies today. Some ideas looking into the future are also discussed in the paper.

Jan 1, 2014

By Claude Bazin, François Robichaud

The control of the operation of a semi autogenous grinding mill is mainly based on power and bearing pressure measurements. Image based sensors can provide on-line measurements of the size distribution of the ore feeding a SAG mill allowing the control of this variable that impacts the operation of this equipment. This paper investigates the potential of using the information from such type of sensor to maintain a SAG mill feed target size distribution by manipulating the speed of the ore extractors below an ore stockpile. A PID and adaptive predictive controller for the size distribution are studied using a simulator for a stockpile and the equipments used for ore withdrawing from the pile. The proposed controller is found to give a good performance while remaining easy to tune.

Jan 1, 2014

By H. Tokuichi, H. Ohta, K. Sato

A physical separation technique of tantalum capacitors from waste print circuit boards is in a development phase in Japan. A tantalum capacitor consists of an exterior coating of resin (epoxy resin) mixed with silica fillers and a sintered tantalum compact, the latter of which is impregnated with manganese dioxide (MnO2). In this study, we developed a process to recover tantalum oxide from tantalum capacitors by roasting, fluidized-bed separation, and hydrometallurgical treatments. Our aim was to recover tantalum oxide with high purity from waste tantalum capacitors. In this process, the exterior resin was selectively decomposed by roasting without oxidation and pulverization of the sintered tantalum compact at a proper temperature. Furthermore, the decomposed resin with silica filler on the surface of the sintered tantalum compact was mostly removed by fluidized-bed separation. The surface of the sintered tantalum compact was cleaned by ultrasonic irradiation in an acid solution to remove the MnO2 paste as well as residual Ag paste and silica filler. The impregnated MnO2 in the sintered tantalum compact was leached as Mn(II) ions using acid solutions via the reducing effect of tantalum metal to recover purified tantalum oxide.

Jan 1, 2014

By O. G. Olvera, E. Asselin, D. Rival

Particle concentration distributions in a leaching tank have been estimated using a novel experimental approach that takes advantage of the galvanic interactions that occur between pyrite (FeS2) particles and a Pt electrode. The collision of FeS2 particles with Pt changes the open circuit potential measured with the electrode due to galvanic interactions. To discern particle collisions with the Pt electrode from experimental noise a simple analytical procedure was first adopted although the use of techniques involving frequency domain analysis is also briefly presented and discussed. Although this method is still under development, it is simple to implement and can yield valuable information regarding the hydrodynamic behavior of solid particles in stirred tanks in very short times. Finally, the advantages and drawbacks of the technique are discussed.

Jan 1, 2014

By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014

By G. T. Lapidus, O. J. Solis-Marcial

Currently, ores with high-grades of copper oxides and secondary sulfides have become increasingly scarce, which has encouraged industry to look for alternative raw materials to obtain copper. The problem is that primary sulfides are difficult to dissolve at near ambient conditions. Proposed hydrometallurgical processes have not been implemented beyond a pilot or demonstration scale. One of the principal disadvantages is that the majority of these processes are not viable with ores that contain less than 4% copper. One of the more recently proposed techniques involves the use of organic solvents in the dissolution of copper concentrates with a chalcopyrite content of between 20 and 30%, which has shown high efficiency. The present research explores the ability of this process to leach copper from low grade chalcopyritic ores (<4% Cu) at different temperatures ranging from 20 to 50°C. It was found that depending on the temperature, high percentages of copper were extracted in 40 to 100 minutes, using different oxidants. Additionally, distinct leaching behavior was observed with each oxidizing agent. In some cases, the extraction kinetics adjusted to the diffusion controlled shrinking core model.

Jan 1, 2014

By Paivi Suikkanen, Kari Hietala, Kaarlo Haavanlammi

"Processing of high-magnesia concentrates, the recoveries of nickel and copper, as well as those of platinum group metals (PGM’s) and cobalt are key issues of the Nickel Smelting technologies. PGMs are typically found in association with each other, but also importantly with nickel and copper. A challenge of producing saleable concentrates at acceptable recovery degrees, an increasing focus on the sustainable use of metals and recent decreases in the value of nickel has increased the interest to find a reliable route from Cu-Ni-PGM bulk concentrates to product. According to studies, most efficient process for Ni-Cu-PGM concentrates is flash smelting using DON process20 years ago, in 1995, Outokumpu commenced at Harjavalta a new Nickel Flash Smelting technology based on the Direct Outotec Nickel (DON) Smelting Process. The DON process enables production of high-grade nickel matte with low Fe-content directly in the Flash Smelting Furnace (FSF) without subsequent converting. Metal values from the smelting slag are recovered in the Electric Furnace (EF) as iron containing Ni-matte. Matte refining is based on atmospheric pre-leaching and total pressure leaching. Nickel, cobalt and iron are leached leaving a leach residue containing small amount of gangue minerals and PGM’s. Iron is removed from the leach solution in and nickel will be recovered with standard methods. Overall > 95% metal recovery can be expected with low energy consumption and low environmental impact."

Jan 1, 2014

By H. Asgari, A. G. Odeshi, J. A. Szpunar

In the current research, the role of grain size on the texture formation and mechanical behavior of rolled AZ31B Mg alloy is investigated under shock loading conditions. The grain size of the original asrolled sample was 8 µm and different grain sizes, e.g. 25 and 46 µm, were produced by heat treatments at temperatures in the range of 400-500 °C. In order to evaluate the effect of grain size on the anisotropy of mechanical behavior, the samples were cut along the rolling direction (RD), transverse direction (TD) and normal direction (ND) and tested at strain rates of 900 and 1200 s-1 using Split Hopkinson Pressure Bar. Texture measurements showed that initial texture of the samples cut from the as-rolled sheet is a weak rtype texture. However, a stronger texture was observed for samples with large grains. After shock loading, a (00.2) basal texture developed in all samples and the intensity of the basal poles was higher in samples with coarser grains. This observation is corroborated by high twinning activity and possible activation of pyramidal <c+a> slip in coarse grained samples. Besides, the strength of basal texture increased with increase in the strain rate. Furthermore, the samples with larger grain size showed lower strength and higher ductility, and this was observed for all investigated strain rates.

Jan 1, 2014