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By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By M. Rebolledo, N. Mora, G. Zarate

For decades, the mining industry has been focussed to find an efficient and economically attractive process for the leaching of chalcopyrite. Jetti Resources has developed a novel hydrometallurgical alternative to extract metals of value from mineral ores that the mining industry has struggled to process. Jetti’s catalytic technology, whilst being especially advantaged for extracting copper from low-grade and highly refractory minerals, such as chalcopyrite, seamlessly integrates with existing heap leaching methods and downstream processing operations. The technology uses a catalyst which weakens the metal-sulfide bond in the crystalline structure of the chalcopyrite mineral and alters the structure of the passivation layer allowing the leaching process to continue. Metallurgical test work was conducted to examine the effect of ore variability, in terms of grade and copper deportment. The results presented in this study highlight the amenability of the technology and demonstrate that it is possible to enhance leaching performance of copper primary sulfides over a wide range of copper grades, from 0.1 to 2.2%. Further, it is concluded that despite the copper grade, the tests with increasing chalcopyrite content render copper recoveries up to 4 times higher compared to the tests under non-catalyzed conditions. Jetti’s catalytic technology is currently being evaluated at larger scales, namely a commercial dump leach operation and 50-tonne crib tests. The results obtained thus far are compared to the results from conventional sulfide heap leaching tests. INTRODUCTION For decades, the mining industry has been focussed to find an efficient and economically attractive process for the leaching of chalcopyrite. Chalcopyrite (CuFeS2) is the most abundant and recalcitrant of the copper sulfides (Singer, 2017). Owing to its abundance and economic importance, it is the most demandable natural source for copper worldwide. In fact, the projected demand for copper is further expected to rise much higher beyond the current demand by the year 2020 (Panda et al., 2015). Therefore, it becomes imperative to find low intensity hydrometallurgical technologies for the extraction of copper from chalcopyrite in ores of such low-grades that are un-economic to concentrate and to augment the supply by extracting copper from ores with complex mineralogy that cannot be concentrated (Watling, 2013).

Jan 1, 2019

By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By S. Bantubani, I. Mc Dougall, S. Arjun, H. Joubert, R. Hansraj

The requirements determining the design of the Söderberg electrode columns used in base metal applications are different to those of other industries. There is a strong trend to position the contact shoes above the furnace roof in order to reduce the risk of water leakages directly onto the furnace bath. Tenova Pyromet has adapted its proven electrode column design for application on base metal electric furnaces based on these requirements. The design modifications implemented as well as considerations regarding the overall electrode-roof-furnace arrangement are discussed. Equally important is the management of the Söderberg electrodes to prevent over or under baking. Tenova Pyromet has developed the AutoFurn™ furnace controller to not only optimise furnace operations, but to improve electrode management. An overview of the electrode management control philosophy implemented by AutoFurn™ is provided, focusing on intelligent electrode regulation, slipping and baking. INTRODUCTION Tenova Pyromet has developed an electrode system for use in base metal furnaces, which builds on the experience that Tenova has gained during the past 30 years with electrodes in the ferroalloy and base metals industries. In base metals applications, an important safety consideration is the minimization of water within the furnace and on the furnace roof. In addition, direct contact between copper equipment such as contact shoes and pressure rings and the contents of the furnace is discouraged. In a 3 phase AC furnace, three electrode columns transfer the electrical energy to the furnace bath. Both Söderberg and prebaked carbon or UHP graphite electrodes are in use in base metal furnaces. In each column, the electrode is held in position by a hydraulic slipping and regulating device, a pressure ring and contact shoes. The electrodes can operate in a submerged-arc or brush-arc configuration, where the electrode is immersed in the slag or a short distance above the slag (Mc Dougall 2013). The electrode equipment is divided into an upper and a lower electrode assembly. The self-baking Söderberg electrode is made from lengths of steel casings that are added to the top of the electrode column and welded into place. Carbon electrode paste is added to the inside of these casings and is baked to form a solid tip in the region of the contact shoes. The working platform that surrounds the area where new electrode casings are added, is electrically isolated from the building and each electrode is isolated from the others to ensure the safety of the personnel who perform the electrode casing additions.

Jan 1, 2019

Real time analysis of ore quality between the mine and mill provides major benefits to copper mining and processing operations. Prompt gamma neutron activation analysis (PGNAA) is a proven technique that has been successfully applied for real time conveyed flow multi-elemental measurement. The advantage of PGNAA is that it measures through the full conveyed cross section continuously and provides representative element measurement without the need to constantly sample coarse (primary crushed) conveyed flows. High specification PGNAA analyzers enable accurate measurement over time increments as short as thirty seconds. Elements such as copper can be measured to a precision of 0.02% copper which is sufficient for high confidence in decisions for bulk flow diversion. Increments of eight tonnes are being diverted through a bulk ore sorting application to remove batches of waste from mill feed as well as divert material to different stockpiles based on ore quality. Longer measurement increments of two to five minutes are suitable for blending control of ores to reduce feed quality variability and to control average ore quality within a target range. Feed blends can be adjusted as frequently as required but typically multiple measurement increments are composited to produce a rolling average ore quality. The paper details two case studies where analyzers have been successfully used to measure conveyed flows for blending and bulk diversion applications. The real time measurements of ore composition are also used for ore reconciliation, in metal accounting and providing process operators with advance warning of ore quality changes that may affect grinding performance and cause process upsets. Real time ore quality measurement has proven beneficial in improving copper processing performance through better utilising plant capacity in a leaching operation, optimising ore feed quality, and reducing unnecessary processing of waste. INTRODUCTION Representative real time elemental analysis of conveyed ore quality using fully penetrative technologies has been available to the minerals industry since the 1990s. The Prompt Gamma Neutron Activation Analysis (PGNAA) technique was developed into a conveyed material analyser and soon adopted by the cement and coal industries which recognised the benefits in real time quality management. These commodities were ideally suited to this measurement technique as operations generally involved conveying bulk material prior to processing. Measured quality was used to divert material to different destinations or used to control blending for improved quality consistency. Uptake in the minerals industry, however, has been slow until the last ten years, and particularly until the mid-2010s.

Jan 1, 2019

By F. F. Roberto

Sulfuric acid has been demonstrated to be an efficient lixiviant for in situ extraction of copper in the past. It has also been proposed that microbial production (by iron-oxidizing acidophilic bacteria) of acidic ferric solution either in situ or ex situ could provide an economic strategy to generate an effective lixiviant for secondary copper sulfides like chalcocite and covellite. Copper heap bioleaching also takes advantage of this approach. One of the major environmental challenges for in situ copper recovery projects is the containment of acidic solution within the ore deposit, and ultimate restoration of the depleted ore body to its original state. A perhaps overlooked aspect of projected site operations is the possibility that transient acidic conditions and pumping of solutions from surface reservoirs into the subsurface could stimulate the growth of iron- or sulfur-oxidizing species of acidophilic microbes in the ore body, leading to additional generation of sulfate, acid, and ferric iron. This outcome would benefit extraction of copper in mixed oxide/sulfide deposits in the near term, but could complicate restoration activities. Possible impacts of pumping acidic solutions into the subsurface on microbes resident in, or introduced into the extraction zone will be discussed in the context of our understanding of copper heap bioleaching and acid rock drainage. INTRODUCTION As high-grade deposits of metals such as copper continue to decline, conventional mining methods have evolved to mine and process larger and larger quantities of ore. What is currently defined as ore today often contains less metal than the tailings of past operations. The throughput of current-day mines also leads to tremendous amounts of waste rock and tailings that may threaten the environment and communities around the mines, as has recently been experienced by 3 major tailings disposal facility (TSF) dam failures in the past 5 years. Community acceptance of large mine operations thus becomes more difficult to achieve—loss of the social license to operate. In response, the mining industry urgently pursues innovations that can fundamentally change the way in which metals are mined. In situ recovery (ISR) of metals represents one approach to a more sustainable mining industry, by virtually eliminating the need for a pit or underground excavation, eliminating the excavation and transportation of ore to a process plant and the ensuing noise and dust that is generated, and any need for waste rock dumps or TSFs. An ISR mine could have very little visible footprint beyond a network of wells, pumps, and piping to transport pregnant solution to a recovery facility, such as a solvent extraction- electrowinning (SX-EW) plant for copper. Some solid waste streams and/or storage ponds may still be necessary to treat and store bleed streams, PLS and raffinate, or as part of groundwater restoration activities. Thus capital and operating investments would be potentially much lower than that required for a conventional mine. In theory production could also be controlled to adjust to subsurface ore grade and match market demand. A not insignificant challenge of in situ recovery is the requirement for an efficient, low-toxicity, and ideally selective lixiviant for the metal that is targeted.

Jan 1, 2019

By Arnfinn Prugger

"The construction of the new Scissors Creek shaft at the Rocanville mine, the first potash shaft successfully completed in Saskatchewan Canada since 1979, is summarized here. Located 15km from the existing Rocanville surface plant, this new 6 m inside-diameter, 1121 m deep service shaft was built for fresh-air ventilation and access. Shaft construction in the Saskatchewan sedimentary basin involves sinking through five different rock-types: glacial tills, shales, sandstones, carbonates and salts. The first four rock- types are all water-bearing, and the salts will dissolve in water. This results in five different sinking challenges and requires five different shaft lining designs. The upper 580 m of rock (the till – shale – sands sequence) was frozen before sinking, and grouting methods were used for water control through deeper carbonate levels. Challenges that were faced and overcome during shaft sinking are reviewed, and ideas that future operators working in sedimentary basin environments might consider in order to avoid these difficulties are discussed.INTRODUCTIONThe Nutrien Inc. (formerly Potash Corporation of Saskatchewan Inc. / PotashCorp) Rocanville potash mine in southeast Saskatchewan, Canada has been in continuous production since 1971. Devonian potash, formed approximately 380 Mybp, is mined in a sedimentary basin environment at approximately 1000 m depth below surface in this area of Saskatchewan. The predominant use for finished potash products is fertilizer: potash fertilizer is concentrated and nearly pure KCl (i.e. greater than 95% pure KCl). Currently 10 potash mines are in operation in Canada, all in Saskatchewan. In 2018 Saskatchewan mines produced ˜ 23 million tonnes of finished potash products, which is approximately 35% of World demand of ˜ 66 million tonnes for the year (e.g. Nutrien Inc., 2019).In November, 2007 it was announced that the Rocanville potash mine would be expanded to increase production from 3.0 Million tonnes per year (Mtpy) to approximately 6.0 Mtpy of finished potash products, requiring an increase in hoisting capability from approximately 9.0 Mtpy to over 18.0 Mtpy. The Rocanville potash mine has historically been accessed through two shafts: a production and ventilation exhaust shaft, and a service and ventilation fresh-air shaft located approximately 200 m from each other. All surface offices, processing facilities, etc. are situated near these original shafts.A very important part of the recent Rocanville expansion involved the construction of a new service shaft (6 m diameter, 1121 m deep) for fresh-air ventilation and access, approximately 15km west of the existing surface plant. Once this third shaft was completed in 2015, the historical service shaft was converted to a second exhaust and production shaft. Three shafts are now available for mine access, ventilation and ore hoisting at Rocanville. As of December 31, 2017, annual nameplate capacity for Rocanville was 6.5 million"

Jan 1, 2019

By R. K. Jonas

Many leading copper and other mineral processors have rapidly adopted advanced controls in last 5-10 years. Almost 600 multivariable predictive controls have been installed in mineral processing, and almost 50% of those are in copper concentrator plants. In most cases, mineral processors rely on 3rd party support to implement these advanced technologies. One challenge facing advanced control user is the selection providers and services for these technologies. The trend has been towards the use of multivariable predictive control and use of technology provider’s services. This paper will discuss status of advanced control, and the merging trends in the mining industry. A review will be presented of how advanced control is being applied in the mining industry over the last decade, and how user challenges are being overcome. Next the emerging uses of multivariable predictive control (such as multi/inter-unit optimization), focusing on the latest trends in concentrator plants. Finally, a review will be made of emerging technology advances in the that can be advantageous to mineral processors. INTRODUCTION Review of advanced control in mineral processing Advanced controls are serving an increasing role to improve processing plant operations and profitability. As advanced control is being installed into more mining processing plants such as copper concentrators, many of these plants are concerned about the selection technologies and vendors to support the installation and maintenance of these controls. In a study by Jonas and Craw (2011), they found that most new users have not had prior experience with advanced controls. It is the author’s experience of almost 30 years in advanced controls that most mineral processers considering advanced controls can benefit from better understanding of the technologies and their support requirements.

Jan 1, 2019

By B. D. H. Knights, N. B. du Preez

The recovery of the economy of the Democratic Republic of Congo has allowed for the rapid increase in production of copper from this region, while the increased price of cobalt continues to support the recovery of that country’s economy. This has enabled the modernization of the process technology used, particularly the change from direct electrowinning of copper to solvent extraction-electrowinning. With this change has come a variety of technical challenges in optimizing the recovery of cobalt from these sources. In this paper, we discuss aspects of the flowsheets for the production of cobalt from the ores of the DRC and Zambia, highlighting the technological improvements that have been made. Following this description of the practice, we assess the challenges of further improving the recovery and purity of cobalt from these sources. INTRODUCTION The African Copperbelt (Figure 1) is by far the biggest producer and holds the greatest reserves of cobalt (Sheed, 2015). However, the ores of this great mining region are extracted primarily for their copper content, and cobalt is a by-product. The ratio of copper-to-cobalt is between 6 and 20 to 1, with the ores from the DRC richer in cobalt than those from Zambia. The overall supply of cobalt, shown in Figure 2, is increasing due to an increase in demand for its use as a battery material. Cobalt is used in superalloys, hard metals, pigments, catalysts magnets, tyre adhesives, lithium-ion rechargeable batteries, and wear-resistant coatings, amongst others. Although these generic categories persist, Figure 3 shows how the relative usage of cobalt is changing due to the uptake of electric vehicles in China and Europe. Cobalt is a key element in lithium-ion batteries, and because it is widely anticipated that electric vehicles will be legislatively encouraged, it is anticipated that the demand for cobalt will rise. This anticipated increase in demand resulted in an increase in the price for cobalt, to which suppliers responded over-eagerly, and the price has dropped dramatically in the first few months of 2019, as shown in Figure 4. However, there is a clear cycle of price peaks in cobalt’s history.

Jan 1, 2019

By Ling Wu

The development of pyrometallurgical technologies has been focused on new smelting reactors, but the proposal for new converting reactors has been substantially lower. Up to today about 80% of copper matte is treated by the traditional P-S converters which have the weakness of pollutant fugitive emissions. Therefore, the continuously converting processes for treating molten matte have been studied and developed. In July 2017 the "oxygen-rich side blowing smelting + multi-lances top converting & fire refining" continuous copper treating process was commissioned. This process was designed by ENFI and YanTai GuoRun Copper Smelter. In this process, oxygen rich side blow technology is adopted for smelting, which is a new type of side blowing smelting furnace to produce high-grade copper matte. The converting adopts the horizontal multi-lances top-blowing continuously converting process, which eliminates the transportation of molten melt and the SO2 fugitive emission. The intermediate products of this process, copper matte and blister copper is fed into the furnaces respectively through launders. This new process is more advanced, more reliable and more environmentally friendly. Until now, this process in the GuoRun copper smelter is operating smoothly. An increasing number of projects which use this process are under design and construction in China. INTRODUCTION At present, there are many advanced smelting technologies for copper concentrate, such as oxygen bottom blowing smelting, flash smelting, top lance smelting (including ISA and Ausmelt furnaces smelting), side blowing smelting, Mitsubishi smelting, etc. At the same time, there are many copper matte converting technologies such as oxygen bottom blowing continuous converting, flash converting, Ausmelt top lance converting, horizontal multi-lances top blowing converting, Mitsubishi converting, P-S converter converting, etc. The final blister copper fire refining technology mostly adopts rotary anode furnace. Therefore, in the process of processing and extracting the copper from concentrate to produce anodes, there are dozens of technology combinations. Among them, the non-continuous converting technologies for molten or cold matte are often adopted in the converting process. The traditional P-S converting technology had been utilized for over one hundred years, with a mature, reliable and simple operation, also has advantages in the secondary scrap smelting of a wide range of quality. However, due to its batch operation, frequent roll in and out, poor sealing, considerable air infiltration, needs for ladles for molten phases transportation and other characteristics, the technology has a serious pollution problem due to fugitive SO2. At the same time, in the cold matte converting technology, the molten matte needs to be cooled and then processed. The sensible heat of the molten matte cannot be recovered, and the preparation process is needed in the process. Therefore, both energy consumption and investment are relatively higher.

Jan 1, 2019

By Euler De Souza, J. Daniel Stinnette, Julian Varaschin

"This paper outlines some of the factors that affect the airflow required for the ventilation of modern diesel-powered equipment and of electric equipment and examines how they can be applied in determining reasonable ventilation rates for Tier IV compliant diesel equipment and for electric equipment operating in mining environments. Airflow calculations for modern diesel-powered equipment and for electric equipment are more complex and must be based on a combination of factors that are unique to each mine. Methodologies for ventilation rate determinations for each case are proposed in this paper.INTRODUCTIONTraditionally, airflow requirements for production and support equipment operating in underground mines have been determined by multiplying the vehicle power by a ventilation rate that was either mandated by regulations or determined empirically from known quantities. However, in light of the drastic reductions to diesel equipment emissions mandated by the US EPA Tier IV and EURO Stage 4 regulations, there is still a great deal of uncertainty in the underground mining industry among those responsible for the ventilation of planned new mines or the expansion of current mines. The question remains, what ventilation rates should the ventilation system designer apply for modern diesel equipment?Also, given the ongoing development of grid/battery-electric equipment and active construction of fully electric mines, it has become critical to determine adequate airflow rates per brake kilowatt of electric engine power. One of the most important criteria for determining ventilation rates for electric equipment is the amount of heat they generate, as this is the most significant emission produced by electric equipment (which do not produce exhaust gases or particulates). Therefore, ventilation rates required to dissipate heat from electric equipment must be suitably determined for all electric vehicle fleets operating in underground mines."

Jan 1, 2019

By Joerg Hammerschmidt, Marcus Runkel, Steffen Haus

Given the limited number of new plant construction, focus is turning to the optimization of existing metallurgical roasting plants. To meet the goals of high process efficiency with limited capital expenditure, plant owners are looking for new strategies, including digitization and expert support. As a supplier for numerous roasting, gas cleaning and sulfuric acid plants, Outotec has intensified its effort in recent years to develop solutions to accommodate increasing customer need. This article presents a short review on how Outotec is applying advanced control tools for the fluidized bed industry. Focus will be given on how to transfer the existing technology (used in selected Zinc roasting plants for over a year now) to copper roasting. Outotec has developed the Pretium Roaster Optimizer, a system based on heat and mass-balanced simulation models. Direct experience with this technology will be shared and will highlight similarities to the Partial and Sulfate Copper roasting processes. Pretium detects equipment and plant bottlenecks and provides consistency in process development. The Pretium program combines 24/7 advanced online digitalization tools, along with expert personal support when required. INTRODUCTION Fluidized bed reactors have been used for commercial-scale zinc and copper roasting since the 1950s. While the principles of roasting remain unchanged, over time, the technology has advanced to improve process control of roasting plants. In the past, environmental and safety standards were the driving forces for improvement of equipment and plant design. Today, the emphasis is on plant efficiency and optimization. Another change has come in process control philosophy. While plant control and operation have traditionally been the responsibility of owner/operators, they have now shifted to include both integrated digital tools and specific know-how from engineering companies. This can be seen from the earliest design stages through commissioning and into production, as evidenced by zinc roasting plants in Mexico, Brazil and Turkey.

Jan 1, 2019

By G. G. Li

"A dynamic ventilation-modeling package, VREX, was used to simulate the mine activities through tracking the equipment movements in underground workings and determine the airflow demand for a new production scenario in a ventilation-on-demand (VOD) system. It incorporates the mine development data from a discrete event simulation and balances the ventilation network using the CANVENT ventilation solver. A case study was performed to demonstrate the capabilities of the software, evaluate the performance of the network and determine the potential energy savings for implementing VOD in a deep mine operation.INTRODUCTIONThe ventilation cost of an underground mine can be significant—up to 50% of the mine’s energy consumption could be used to run fans and provide heat/refrigeration to meet the specified production environment for workers and equipment. The VOD system has proven to be more efficient in operating the fans and supplying the amount of air corresponding to the mine activities taking place in underground workings (Hardcastle, Kocsis, & O’Connor, 2006). In order to properly solve and evaluate the VOD system, a dynamic ventilation modeling software VREX—the ventilation rules engine has been developed to simulate the mine activities and determine the airflow demand for each production scenario within an operation period (Dasys & Cameron, 2011).VREX is a decision support tool, backed by the CANVENT mine ventilation solver (Li, Kocsis, & Hardcastle, 2009), for determining the outcomes of network configuration changes over time. The software incorporates the mine development data with ventilation modeling through the discrete event simulation (DES) performed by SimMineTM. As it simulates the air requirements for different vehicles and activities, VREX can evaluate both the performance of the ventilation system and the potential economic benefits of making operational or technological changes (Pritchard, 2010). For example, the model can be used to assess the economic and environmental impacts arising from modifying regulations to support the use of electric or lower emission vehicles. The combination of DES and ventilation modeling provides a new technology to generate the production scenarios according to mine schedules and activities and to determine the potential benefits for various levels of ventilation control, such as time interval and work shift change."

Jan 1, 2019

By F. A. Auld

"Traditionally deep shaft sinking from the ground surface was carried out using drill and blast methods. Although large diameter blind shaft drilling has been carried out successfully on numerous occasions previously, including as early as 1852 in Germany (Auld, 1995), little attempt has been made until more recently to mechanise the shaft sinking excavation process using down-the-hole machines. This paper reviews the development of deep shaft sinking machines from the early 1970’s up to the present day. INTRODUCTION Mechanical excavation methods can significantly improve excavation performance, in order to access natural resources faster, and labour safety is increased compared to drill and blast operations. However, shaft sinking machines need to be capable of accommodating all the basic requirements for deep shaft sinking, namely: 1. Excavation and muck removal 2. Ground stability control 3. Groundwater ingress control 4. Temporary lining installation 5. Permanent lining installation and watertight sealing 6. Ventilation 7. Secondary means of egress for personnel In addition, how the machine operates in the shaft is an important factor, either slung on ropes from a surface headgear or on its own in the bottom of the shaft. An all-embracing machine which can deal with all of the above conditions is impossible but many of these requirements can be incorporated into a single machine. Deep shaft sinking also differs greatly from normal tunnel construction which employs the use of either a roadheader arm installed within a shield or a full-face tunnelling machine for excavation. Hydrostatic pressure and ground stability problems increase with depth, whereas in tunnelling the depth is normally relatively shallow and the aforementioned factors remain approximately constant along the tunnel length. DEEP SHAFT SINKING MACHINES All the shaft sinking carried out previously in the UK was by the traditional method of drill and blast. Elsewhere, in other parts of the world, attempts have been made to mechanise the process."

Jan 1, 2019

By T. Hidayat, D. Shishin, V. Prostakova, M. Shevchenko

The chemical compositions of copper feed streams are becoming increasingly complex following the growing demand for metals and corresponding shortages of primary sources. The optimisation of process conditions requires an accurate description of phase equilibria and thermodynamics. Integrated experimental and thermodynamic modelling research program on the characterisation of the complex, multi-component, multi-phase gas-slag-matte-speiss-metal-solids Cu2O-PbO-ZnO-Al2O3- CaO-MgO-FeO-Fe2O3-SiO2-S-(As-Bi-Ni-Sb-Sn-Ag-Au) system is being carried out to support companies undertaking the pyrometallurgical primary production and recycling of copper. The experiments involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of equilibrium phase compositions with quantitative microanalytical techniques, including electron probe X- ray microanalysis and Laser Ablation ICP-MS. The thermodynamic modelling is undertaken using FactSage computer package with advanced thermodynamic solution models. The continuing development of research methodologies has resulted in significant advances in research outcomes. Implementation of the results of these fundamental studies involves an ongoing collaboration of researchers and industry technologists. An overview of recent progress in research, implementation and applications in industrial practice are given in the paper. INTRODUCTION Rapidly developing technologies increase the demand for various metals in number and volumes. Modern technological devices such as mobile phones, computers, other electronic devices, have dozens of metals—all those metals have to be a) produced and b) recycled. The fast transition in mobility from fossil energy delivered through combustion to renewable energy first stored in bakeries and delivered through electric engines introduce a significant change in the metal demand in terms of both type and volume of metals. Pyrometallurgy is playing a key role in supporting these changes in our industrialised society.

Jan 1, 2019

By W. Dziurzynski, St. Wasilewski, T. Palka, A. Krach

"Air parameter monitoring systems, regardless of gasometrical protections, provide a significant number of measurement data. The obtained data broadens the knowledge on processes taking place in underground workings and shows the relationships and influence of machines and technological processes on the variability of ventilation parameters in the areas of longwalls. Nowadays, computer simulation methods are increasingly used to reproduce the flow of air and methane mixture in the area of longwalls equipped with shearers. The paper presents the results of a research experiment covering a long-term observation of a longwall area during mining with a shearer using sensors from the mine's monitoring system. Data from sensors for methane concentration, pressure and velocity were used and additional ventilation measurements were taken to determine the parameters characterising the air flow in the area. The influence of different machine cycles in the longwall on the changes of air parameters in the area of the longwall was shown. A numerical model of the ventilation area was developed and the computer program VentZroby was used for the calculations, which allows for the simulation of the process of ventilating the area of the active longwall during the extraction of coal with the use of a shearer and haulage of the run-of-mine. Computer simulation of the influence of the shearer's operation and the methane inflow associated with the distribution of the mixture of air and methane was carried out. The results of the simulation were compared with the data recorded by the monitoring system’s sensors during the measurement experiment. Comparison of the recorded methane concentration courses with the results of a computer simulation of the air and methane flow conditions in the mining area showed changes in the gassiness. INTRODUCTION Studies carried out in the Polish and global mining industry show that methane is an obvious factor in limiting mining production due to the loss of continuity in the operation of longwall complexes in hard coal mines under methane emission hazard (Schatzel et al., 2008). In addition, methane hazards have a significant impact on the safety of the operators of machinery in the longwall. The requirements of Polish regulations and the practice of safe operation of mining longwalls require correct determination of gas concentration, volume flow, as well as pressure and temperature of the flowing air. As part of the research undertaken in the Budryk (Wasilewski, 2010) and Bielszowice (Dziurzynski et al., 2009) mines to assess the methane hazard in the longwalls and workings in the vicinity of the longwall, research experiments were carried out, during which air parameters were recorded by the mine monitoring system and additional testing equipment in different cycles of shearer operation."

Jan 1, 2019

By Bradford C. Wesstrom, Ricardo Parra

The Freeport McMoRan El Paso Refinery uses co-generation to produce some of its electricity and all of its steam. This paper will cover the operation of the co-generation plant natural gas turbine at a fixed RPM for blade longevity and energy output. The by-product heat from the turbine passes through boilers with additional heat from a duct burner to produce steam for the Tank House and auxiliary operations. The steam demand varies dramatically throughout the day based on unloading activities in the Tank House. The use of an automated steam control system within the El Paso Refinery will help stabilize line pressure by incrementally controlling steam consumption based on electrolyte temperature. This will minimize steam line pressure fluctuations. INTRODUCTION In the mid 1920’s the Nichols Copper Company of Laurel Hill, New York recognized the need for a modern copper refining facility in the southwest. Due to the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the logical location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Energy costs (electrical and thermal) are critically important in the viability of modern copper electrorefineries. The El Paso Refinery produces electricity and steam through its cogeneration system. The El Paso cogeneration facility is a natural gas, 15-megawatt facility containing five turbine generators and associated waste heat recovery boilers. The facility is divided into two phases. Phase I consists of two Allison 2.2-megawatt turbine generators. Phase II consists of three Solar Taurus 3.5-megawatt turbine generators. Presently three units in Phase II are operated. The Phase I units were purchased and installed in 1986 and the Phase II units in 1992 (Solar 1991). The facility operated at full capacity until 2003 when steam demand was significantly reduced due to decrease in cathode production and closure of the copper sulfate and precious metal operations. Phase I units were taken out of service and put on care and maintenance status.

Jan 1, 2019

By S. Torres, J. Álvarez, R. Castillo, R. Fuentes, C. Sandoval, R. Parra, Myakalwar A. K., M. Velázquez, J. Yáñez, D. Sbarbaro

Rapid analytical assessment in copper mining industry is a limiting factor for operational purposes and for the improvement of processes. The present work aims to review the analytical assessment in the copper industry utilizing emerging spectrochemical techniques such as laser induced breakdown spectroscopy (LIBS) and UV-Vis-IR Hyperspectral Sensing. LIBS is a plasma based spectroscopic method where the sample surface is irradiated by high power laser. The light emitted from the plasma contains atomic -molecular spectral information and can be detected using a simple CCD based spectrometer. UV-Vis-IR Hyperspectral Sensing is produced by the reflection of light from the sample’s rough surface in all directions and it can be collected by using an ellipsoid or paraboloid mirror arrangement. The electromagnetic radiation emitted by the samples in the UV-Vis, NIR and MIR region can be used for molecular characterization. The spectrometer splits different wavelengths through a CCD arrangement in 2D spatial and spectral dimensions, thus a hyperspectral cube of data is generated. Chemometric techniques such as principal component analysis (PCA), K- nearest neighbors (KNN), support vector machine (SVM) among others, can be applied to LIBS and Hyperspectral data for better classification and quantification purposes in copper ores. Real- time determination of elemental and mineral species used for online processing control will help to achieve the copper industry 4.0. INTRODUCTION The demand for copper mineral resources is intensely growing with the increase in population, per capita GDP, the development of new technologies and the increase in global living standard. With the rise in consumption of copper, it is important to optimize mining and metallurgical processes tending to the copper industry 4.0 (Ge, Song, Ding, & Huang, 2017). The real-time analytical assessment in the mining and metallurgical processes is a crucial part for allowing the global improvement in mining industry. The features considered for better analytical assessment are the instrumental automation and interconnection, real time results, low cost, quality in terms of accuracy and precision. Furthermore, improving recovery (extraction), timing and quality of final products avoiding environmental impacts. Some elements such as Cu, Fe, Ag, Au, Mo, S, As, Pb, Zn are important to be determined in the process control. Additionally, rapid mineral identification of few species such as CuFeS2, Cu4FeS5, FeS2, CuS, Cu2S, MoS2, Cu3AsS4, FeAsS, among other can be challenging.

Jan 1, 2019

By G. A. Sutton

This paper, describes a case example from San Manuel mine, where in situ copper leaching of the supergene zone was done over a 14 year period (1986–1999) in conjunction with underground and open-pit mining operations of a copper porphyry deposit. In 1993–1994, testing of well fields was done to determine the amount of copper that would be recovered from in situ leaching of the supergene zone, which was composed primarily of chrysocolla and copper-clay minerals. It was determined that the leach fluid would reach 70% (‘sweep efficiency’) of the copper minerals and that 75% of them would be leached for a recovery of 52% of the acid soluble copper. However, the final results from Zone 6, which had the longest leach history, showed that approximately 42% of the acid soluble copper was recovered, indicating that the `sweep efficiency’ was closer to 55%. Comparison of drill-core assay data from two holes, one drilled before (ARM158) and the other after (SMO9607) leaching, also indicate that approximately 42% of the acid soluble copper was recovered. The discrepancy between the predicted (52%) and actual (42%) recovery is probably related to a combination of factors, including difficulty in maintaining fluid saturation, channeling effects and gypsum precipitation. INTRODUCTION In situ copper leaching at the San Manuel mine, Arizona, was initiated in 1986. It was recognized that some of the copper oxide resource was not going to be economically recoverable by conventional open pit and heap leach methods using solvent extraction and electrowinning (SXEW). A high stripping ratio would be required to access part of the resource. At the time, in situ leaching was becoming popular in the uranium industry but the approach was virtually unknown in the copper industry, especially not at a large scale.

Jan 1, 2019

By Xian Jian Guo, Lei Li, Hua Wang

Direct smelting of copper concentrate to blister copper has the advantages of energy saving and environmental protection. There has been a lot of effort invested in process development including test work and theoretic analysis in the past half century. However, the process has only been applied commercially to a few smelters that treat chalcocite types of copper concentrate. The main limitation to treating chalcopyrite types of copper concentrate is high copper content in smelting slag and low direct copper recovery. Thus intensive slag cleaning is needed. In this paper, the thermodynamic analysis was mainly carried out for the multiphase equilibrium of direct to blister copper smelting for both chalcopyrite and chalcocite concentrates. The practical problems in direct to blister copper smelting, which are mainly in copper content in slag, are clarified. The operational window of slag composition for different temperatures and oxygen partial pressure for the treatment of chalcocite type concentrates is identified. The process operation optimization for the blending of chalcocite, pyrite and chalcopyrite concentrates was done. INTRODUCTION The extractive metallurgy of copper can be divided into two broad groups of processes, namely, pyrometallurgy and hydrometallurgy, and the former is dominant. About 80% of copper in the world is produced by pyrometallurgy (Christopher et al., 2006). The first stage of conventional copper pyrometallurgy processing is to smelt copper concentrate to copper matte composed of FeS and Cu2S with slagging to remove a proportion of the iron (Gargul, Boryczko, & Bukowska, 2017). The smelting processes include bath and flash smelting. The second stage of the process is to convert copper matte to blister copper. In most cases, the copper matte is converted in Peirce Smith (P-S) converters, which are batch operations (Kubiszewski, 2015). The P-S converting can be divided into two periods, slagging and copper blowing. During slagging period, FeS in copper matte is oxidized to FeO, which reacts with silica flux forming slag. When the iron content in matte is less than 1%, copper begins to oxidize and reduce to form blister copper (Kucharski, Sak, Madej, Wędrychowicz, & Mróz, 2013).

Jan 1, 2019