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By David De Klerk, Maximilian Richter, Thirunavukkarasu Pathmathas, Indresan Govender

We consider the average power dissipation distribution for dense granular flows of an idealised mono-sized charge (5 mm glass beads) in a 300 mm diameter tumbling mill operated in the cascading-to-cataracting Froude regime. By combining the inherent frictional nature of particles within a dense flow regime and noting that tumbling mills are typically characterised by collisional and turbulent stresses, we derive the power dissipation distribution for athermal boundary conditions. The input data to the model (velocity, solids concentration, pressure and flow depth) are obtained directly from non-invasive measurement using a nuclear imaging technique: Positron Emission Particle tracking (PEPT). The power dissipation due shear stresses is shown to be the dominant mode of dissipation in the tumbling mill with up to two orders of magnitude difference between pressure induced dissipation and shear.

Jan 1, 2014

By P. Zarate, M. Peart, T. Bhambhani, D. R. Nagaraj

More than 50% of all the molybdenum produced in the world is a by-product of copper production. A bulk Cu-Mo concentrate is first produced, which is subsequently separated into Cu and Mo concentrates. The Cu-Mo separation circuits rely on the use of inorganic Cu sulfide depressants such as NaSH, Na2S, and Nokes, which are hazardous, and sometimes require very large dosages for effective depression. Synthetic polymeric depressants are safer and more efficient, and are now being used on the plant-scale. Data presented in this paper demonstrates that these polymeric depressants can replace 50-90% of all the NaSH in Cu-Mo separation at a fraction of the NaSH dosage. In this paper we provide an overview of the mechanistic and practical aspects of the Cu-Mo separation with inorganic depressants and polymeric depressants. Important practical aspects include depression dynamics (related to conditioning time and rate of depression), optimum pH for effective separation, the role of pH modifiers such as lime and NaOH, and the effect of flotation gas on the efficacy of the separation. Using nitrogen as flotation gas, the NaSH consumption can be reduced by up to 95% by using a small amount of polymeric depressant. The experiments with conditioning time demonstrate that there is a significant rate component to the depression mechanism with NaSH, which is absent for the polymeric depressant system. This has important implications in the effective use and application of the depressant. It is also demonstrated that the pH modifier type (NaOH or Ca(OH)2) has no significant effect on separation efficiency and Mo recovery (i.e. Ca2+ ions do not depress MoS2 in the Cu-Mo separation).

Jan 1, 2014

By F. Z. Dong

The paper is mainly about a study on the techniques of separating iron from pyrite cinder of a certain sulfuric acid plant in Shandong province. The main components of the cinder are Fe2O3 and SiO2, and the degree of liberation of iron mineral and gangue is very high. So the iron concentrate with higher degree of iron and lower grade of silicon and sulfur can be achieved by reverse flotation. The iron grade of the concentrate reaches 63% and the recovery of iron is no less than 63%. And the most important influencing factor of the flotation is the temperature of the pulp. A better guideline can be achieved by magnetic separation. The cinder is magnetizing roasted for 15 minutes with temperature of 800?, and the concentrate with the iron grade 64%, sulfur grade 0.2% and iron recovery 85% can be obtained by two stage magnetic separation. A rotary kiln has been built to deal with the pyrite cinder, and the result of the industrial magnetizing experiment and magnetic separation is satisfying.

Jan 1, 2014

By Z. F. Hu

Tourmaline has the characteristics of piezoelectricity, thermoelectricity, spontaneous polarization and far-off infrared radiations. Ultra-fine powders of tourmaline have extensive applications in the fields of electron, chemical and environment protection, as well as health protection. The preparation technology of ultra-fine tourmaline powder is discussed. The key equipment of a pilot plant for producing ultra-fine tourmaline powder with jet mill and stirred ball mill is described. Using this pilot plant facility it is possible to produce tourmaline powder with particle size smaller than 100 nm, and a continuous production process can be realized. The final powder product has many superior performance such as high whiteness and large specific surface area, and it?s a negative ions emission can reach the value of 7190 ions per cubic centimeter.

Jan 1, 2014

By G. Unland

The sizing of crushers depends on the expected crushing forces. However, the crushing forces develop differently with every individual rock while it is compressed by the working surfaces of the crusher. For sizing, this compression process has to be characterized by the maximum crushing force. The maximum crushing force depends on the strength, shape and size of the rock, the amount and velocity of the imposed displacement of the working surfaces of the crusher on the rock and the conditions of the contact surfaces. From experience it is known that the strength of the material and, therefore, the crushing forces depend on the size of the specimen. This dependence is the so called size effect. The determination is based on compression tests. The force development is recorded during the compression of the specimen and for every individual test the maximum force is determined. The occurring maximum crushing forces of several rocks with the same diameter comminuted under the same conditions can be assessed by a mean value and a variance. The relationship between the mean values of the cross section related maximum crushing forces FAmax and the corresponding sizes d of the specimens can then be described by mathematical functions. They are derived from different approaches (phenomenological, statistical and statistical-physical methods). The phenomenological methods are subjective and yield functions depending on the assumptions of a person, whereas the statistical and statistical-physical methods are based on an evaluated function and the optimization of the parameters.

Jan 1, 2014

By S. J. Liu

The conventional collector for bauxite mineral is oleic acid, which is highly insoluble and must be used in high dosage in bauxite flotation operations, that is the great drawback of oleic acid in use. A series of hydroxamic acid were synthesized, and their collecting ability to certain minerals in bauxite: diaspore, kaolinite were studied. The collecting power of various reagents to diaspore in an incremental sequence were shown as follows: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<oleic acid<octylic hydroxamic acid; while the incremental sequence of the collecting power to kaolinite was like this: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<octylic hydroxamic acid<oleic acid. It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity, and octylic hydroxamic acid was chosen to use in the following experiments. Reduced zeta potential showed the adsorption of the anionic collector on the mineral. By the adsorptive capability and IR tests, the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption, which was greater than that of oleic acid, as it was physical absorption. Results of floatation experiments on manually mixed minerals indicated that the collectivity and selectivity of octylic hydroxamic acid were better than oleic acid.

Jan 1, 2014

Cenospheres is a sandlike hollow sphere component of the fly ash that is collected in coal-burning electric power generating plants. Metal coated particles have been widely used in industries. Magnetron sputtering method which was used to coat copper film on the surface of the cenospheres is a widely used coating technique in large surface metal coating. A newly designed equipment is used to make the fine particle coating can be carried out because the fine particle is hard to disperse and it must make the particle keep moving to let every direction of the particle be coated. The copper film coated is compact, smooth, even and without uncoated spots under the optical microscopy and SEM. The film has good affinity to the cenosphere surface. The film does not separate with cenoshpere surface even when the cenosphere is crushed. The XRD, SEM, XPS, SPM was used to study the copper film characteristic. It is shown that using this newly designed magnetic sputtering equipment can coat high quality copper nanofilm on the cenoshpere surface.

Jan 1, 2014

By D. M. R. Sekhar

Certain types of rock phosphates of sedimentary origin are applied to acidic soils as fertilizer directly. Recent research in India showed that high grade rock phosphate in fine size when used as a mix with organic manure works as efficiently as di-ammonium phosphate (DAP) in alkaline soils. The rock phosphate from Jhamarkotra, India (sedimentary origin), Egypt (sedimentary origin) and South Africa (volcanic origin) showed good agronomic efficiency when used as Phosphate Rich Organic Manure (PROM). Further PROM shows equal residual effect. The results of efficiency of PROM made using two grades (+ 24% P2O5 and 34% P2O5) of rock phosphate mineral from Jordan show that low grade rock phosphate slimes are as effective as high grade phosphate concentrate when used in PROM. Also PROM is very effective in the saline soil of Eshidiya desert where DAP is not at all effective.

Jan 1, 2014

By L. Y. Zhang

The metallic sulphides in Jinchuan Mine are relative friable and the gangue minerals suffer of wide secondary change, the overgrinding of metallic sulphides and sliming of gangue minerals are the main cause that makes the mineral separation indexes difficult to improve. So changing the process of grinding, and classification, and optimizing the particle size distribution of grinding product is the key improving the separation performance of Jinchuan nickel and copper ore.

Jan 1, 2014

By Sarthak Kaushik

Zeta potential measurements show that the isoelectric point of crandallite, in aqueous solution of 10-2 N sodium chloride is at about pH 5.5. Measurements of turbidity confirm the point of zero charge or crandallite. Calcium ions specifically adsorbed on the surface and thus changed the zeta potential and turbidity. From the measured data, it is confirmed that starch acts as a flocculent for crandallite. Oleic acid, which is a collector used in phosphate ore processing is weakly adsorbed on the surface of crandallite. This results in hydrophobic coagulation of particles resulting in a lower turbidity.

Sep 1, 2012

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei. These ores require mineral processing to remove the sub-strate/nuclei rock before smelting. This paper reviews experimental results of previous investigations. Observations and analysis of 10 samples from different localities were carried out and it was found that the liberation ratio of crushed product was high even at coarse size fraction, 0.5mm to 4mm. Experimental and calculated results in the smelting stage confirmed that the separation product satisfies the standards of the subsequent smelting process if the substrate/nuclei rock is removed from the 0.5mm to 4mm fraction with high separation efficiency. There was a density difference between the substrate/nuclei rock and the ferromanganese component. Thus the coarse sized sample was treated with gravity separation; air table separation was used as a dry method and jig separation as a wet method and high grade values with high recoveries were obtained by both kinds of gravity separation.

Jan 1, 2014

By S. Banisi, E. Arghavani, Gh. Parsapour, S. Mousavi

Maximization of water recovery in thickeners is an essential step in the mineral processing industries. The Gol-E-Gohar iorn ore processing plant uses a center pier thickener with a diameter of 38 m and depth of 4 m. The feed rate is 50 t/h solids with a concentration of 5% (w/w), and it has been designed to provide an underflow containing 50% solids. The performance of the thickener was not as expected judged by the overflow stream containing 0.6% solids and water loss of 52 m3/h in the underflow. A criterion called the index of flocculation incorporating the perimeter-based fractal dimension of flocs, floc size, and settling velocities was proposed and used to determine the optimum flocculant dosage which was found to be 20 g/t. The fractal dimension of flocs in a pulp containing 5% solids was found to be between 1.16 (no flocculant) and 1.56 (40 g/t flocculant) which indicated highly branched and loosely bound structures for the flocs as flocculant dosage increased. At these conditions, the size of the flocs which was recorded by a digital microscope increased from 93 µm to 403 µm. A new feedwell with a special design with the aim of preventing flocs breakage and maximizing energy dissipation of pulp was constructed and installed. These modifications led to an increase in the thickener drivehead torque from 5% to 18% of the rated torque, indicating a higher bed depth. Finally, installation of a PID controller reduced the drivehead torque relative oscillation from 52.0% to 12.7%. These changes increased the solids concentration of the underflow from 49.0% to 56.9%, decreased the overflow solids concentration from 0.6 % to values smaller than 0.01% and resulted in a reduction of 27% in water loss in the thickener underflow.

Jan 1, 2014

By Pat Turner, Abrie Schutte, Tim Olson, Roman van Ommen

The key to good cyclone circuit design and operation in primary grinding circuits will be discussed. Cyclone circuit design issues include individual cyclone design features such as cone angle or materials of construction, as well as orientation and manifold configuration. Cyclone performance issues as well as maintenance considerations will be detailed in an effort to achieve consistent cyclone operation with minimal coarse solids in the overflow. The new gMAXTM. cyclones will be introduced and evaluated using operating circuit data in closed circuit grinding applications

Jan 1, 2003

In this study, selective flocculating of diaspore using anion macromolecular reagent as flocculant was tested to separate diaspore from alum-silicate minerals. Firstly, the effect of pH on settling behavior of diaspore and kaolinite dispersions has been investigated. The results show that the maximum settling speed of diaspore and kaolinite appeared re-spectively at pH7 and pH3.33 which is close to the point of zero charge (PZC) of diaspore (6.8) and kaolinite(3.5). This result is in well agreement with the double electric layer theory. Secondly, the settling behavior of diaspore and kaolinite particles in different anion flocculant solution have been researched. The results indicate that flocculant solution concentration significantly affect the selectivity and the flocculating performance of anion molecular. In high concentration solution, both diaspore and kaolinite have faster settling rate compared to blank solution. How-ever, in low concentration solution, the anion macromolecular can enhance the settling rate of diaspore remarkably but has no apparent effect on the settling rate of kaolinite. This result suggests that the tested anion flocculant is a promising reagent for de-silica of diasporic bauxite. Lastly, FTIR method was employed to probe the adsorption mechanism of flocculant on diaspore and kaolinite. The results reveal that there are anion flocculant characteristic bands on the spectra of diaspore but no obvious characteristic bands of flocculant on the FTIR spectrum of kaolinite. This result is in good correspondence with settling test.

Jan 1, 2014

By M. L. Cao

In this study, a montmorillonite organo-intercalation compound (MOIC) was synthesized by using a Na-modified bentonite (NaB) as a matrix and hexadecyltrimethylammonium (HDTMA) bromide as an intercalating reagent under microwave irradiation. The synthesized products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), organic carbon content measurement, and adsorption density determination. The results show that, at 10% suspension concentration and 10 minutes irradiation in a 130-W microwave oven, the basal spacing d(001) of the synthesized MOIC increases to 2.209 nm from the original 1.218 nm of NaB. The MOIC has much higher adsorptive densities to nitrobenzene and aniline from aqueous solution than the NaB. The adsorption isotherm of nitrobenzene on the MOIC is linear, and the adsorption is mainly the result of nitrobenzene?s preferred partition in MOIC over aqueous solution due to MOIC?s hydrophobicity. The adsorption isotherm of aniline on MOIC follows the Freundlich equation and the increased adsorption is not only the result of aniline?s preferred partition in MOIC over aqueous solution but also that of the MOIC?s surface adsorptions.

Jan 1, 2014

By D. Kosior

Influence of frothers (a-terpineol and n-octanol) concentration on kinetics of a three phase contact (TPC) formation by a bubble colliding with a hydrophobic surface (Teflon) of different roughness was studied using a high-speed camera (1040 frames per second). It was found that the Teflon surface roughness and the frother concentration strongly affected time of the TPC formation (tTPC) and time of drainage (tD) of the liquid film separating the colliding bubble from the solid surfaces. With increasing Teflon surface roughness, from ca 1 to 80 µm, the time of the TPC formation was shortened by over the order of magnitude, from ca 100 to a few milliseconds only. At low a-terpineol and n-octanol concentrations, thetTPC values were shorter than in distilled water due to lowering the bubble velocity in the frother presence and diminished bouncing of the colliding bubble. However, at high frothers concentrations the tTPC values were prolonged, despite that the bubble velocity was similar. The prolongation of the tTPC at high frother concentrations indicates that air (micro- and/or nano-bubbles) was present at the Teflon surfaces of different roughness. The mechanism of the tTPCprolongation at high frother dosage is described.

Sep 1, 2012

By Andrzej Wieniewski, Cezary Regula, Bozena Skorupska, Krystian Cichy

"In this paper, experiences from Polish non-ferrous metals ores enrichment plants in the copper and blende concentrates quality improvement are discussed. The blende concentrate being produced in ZGH Boleslaw S.A., with Zn content of about 54,5% is characterized by the relatively high magnesium content reaching a level of 1% resulting from the dolomite presence, while for the zinc production by electrowinning a concentrate in which magnesium content should not exceed 0,3% is required. The implemented new technology for the quality improvement of blende concentrate is based on the leaching of zinc concentrate with sulfuric acid aimed at dissolving of the contained dolomite, and then flotation of the leached concentrate. It allows to obtain a concentrate with magnesium content below 0,1% at the simultaneously increased zinc content to about 57,5%. In the paper, laboratory tests results on the development of optimal flotation flowsheet for the gypsum removal and the industrial tests results concerning the process optimization of this flotation are discussed. In turn, the copper concentrate being produced in Polish copper ore enrichment plants KGHM PM S.A., is characterized by the increased organic carbon content - above 8%. It creates problems with the smelting of this concentrate because of difficulties with the heat removal derived from the combustion of organic carbon in the flash smelting process. The implementation of segregating flotation to the industrial practice allows the effective production of two concentrates with the differentiated chemical compositions - a concentrate with increased copper content and reduced organic carbon content for the flash smelting process, and a concentrate with lower copper content and increased organic carbon content for the shaft smelting process. In the paper, conditions of the segregating flotation and the achieved results are described."

Jan 1, 2014

By Dee Bradshaw

"Process mineralogy’ is a form of applied mineralogy which focuses on addressing problems associated with the processing of ores. ‘Mineralogy’ is the scientific study of minerals and ‘mineral processing’ is the production of concentrates from ores. ‘Process mineralogy,’ however can be defined as the practical study of minerals associated with the processing of ores, concentrates and smelter products for the development and optimisation of metallurgical flowsheets, including the waste and environmental management considerations. This hybrid discipline consists of teams that include geologists, mineralogists, samplers, mineral processors and often others, working together. The degree of cross-training, communication and trust dictates the potential capacity of the team and where an appropriate work dynamic is fostered, in which relationships flourish as much as does the ethic of technical excellence, it is possible to develop technical capabilities that surpass those of conventional teams. The world’s demand for metals is ever increasing and ore deposits available for extraction and processing are lower grade and more complex, often containing deleterious elements that require tailored treatment. Generally, in the past, the technical challenges only needed to be overcome and assessed economically to make an ore deposit viable; increasingly and in the future, a more sustainable approach including environmental and societal considerations is needed. Process mineralogical assessment is increasingly providing the critical information that stands between failure or collapse and survival or success of some mining operations. In this paper, selected case studies are used to demonstrate the valuable role of the process mineralogy tools being used to provide the platform for innovative technology development. Their common attributes are discussed and distilled, thus providing some insights and potential guidance for addressing some of the likely future challenges of the mining industry."

Jan 1, 2014

During incineration of municipal solid waste (MSW), various environmentally harmful elements and heavy metals are liberated partly into bottom ash, and partly carried away with the off-gases and subsequently trapped in fly-ash. If these waste incineration residues are not properly processed and immobilized, it can lead to secondary environmental pollution to the air, soil and water. The stricter environmental regulations require a higher immobilization efficiency of the waste incineration residues, which is the main objective of the present cooperation research. Within the present project, a systematic scientific research on various MSWI residues has been carried out, including sampling, low or high temperature processing and leaching tests. In the present paper, the major results have been summarized. The research results reveal that through appropriate combined pre-processing and high temperature vitrification, the bottom ash and fly ash can be efficiently stabilized. The results achieved provide a valuable alternative route to treat the solid residues from incinerators, and to make efficient recycling and safe utilization possible.

Jan 1, 2014

By F. Henríquez

Traditionally, the implementation of an automated control for a ball mill has been a challenging one. First, it must be capable of processing a variable SAG mill feed while at the same time avoiding to become a process bottle neck. Second thing is, it must deliver an adequate quality product (P80) to the process downstream. Then the ball mill itself and its associated classification equipment has problems of its own: it must maintain adequate control of cyclone?s pressure, density and pump-box level with often, less manipulated variables than needed, namely, variable pump speed and the opening/closing of cyclones. Thus, it becomes a non-linear multi-variable type of process with often too multiple and contradictory control objectives to satisfy simultaneously. On top of that, to extend cyclones availability and yet, maintaining their performance, is must both for process and maintenance purposes. Trying to solve the puzzle, Minera Los Pelambres implemented a novel and successful combination of MPC (Multivariable Predictive Control) and advanced control in two of its newest ball mills, reducing considerably process variability while maintaining high throughput and keeping the process well within constraints limits. Because of their differences in processing capacity, size and topology, two different stabilizing-control strategies were developed, tested and tuned. Hence, for both control approaches their implementation process, main results, areas of applicability, limitations and their key performance indicators are discussed further. This paper also discusses the need of such advance control technologies in the mining industry, including the impact of these technologies on best practices for their implementation, operation and long term sustainability

Sep 1, 2012