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This paper presents the development of a knowledge based integrated decision support system (E.X.I.S) for the extractive industries to provide information concerning the environmental impact of extractive operations on land quality, surface and ground waters, and the best solutions for the rehabilitation/revegetation of the waste disposal areas to the relevant target groups (extractive industries, regional authorities, national authorities, research institutes, public). GIS was integrated with the decision-making models for the rehabilitation and revegetation of mine spoil. The system design involves several steps including site selection ? mine type identification ? waste identification ? selection of rehabilitation (revegetation or other methods). The knowledge based model consists of two integral parts: the model base, in which the input data are processed and classified using special fuzzy algorithms and criteria and the knowledge model, which hosts the various decision algorithms concerning evaluation of vegetation covers, selection of trees and plant species, selection of rehabilitation and revegetation schemes and also economic analysis for each option. The system input will include parameters on site characteristics (climate, topography, geology, hydrology etc), waste type and properties (physical-geotechnical and geochemical data) as well as environmental parameters of the existing waste disposal area. Based on the values of the above parameters and the characteristics of the rehabilitation technologies developed worldwide, the system, using IF-THEN rules will define a list of appropriate techniques for the rehabilitation of the examined waste. Then, the model will involve the application of multi-criteria analysis (MCA), i.e. a structured system for ranking alternatives and making selections and decisions. Each technique shall be judged based on its behavior into four fields, i.e. financial, social, technical and environmental criteria. In turn these fields will be analyzed into a lower level of evaluation criteria.

Jan 1, 2006

By C. Vasilescu

Phytotechnologies use plants to remediate various media impacted with different types of contaminants. These technologies can be implemented either in situ or ex situ. The affected media in which phytotechnologies can be applied include soil, sediments, groundwater and surface water. They are best applied at sites with shallow contamination of organic, nutrient, or metal pollutants that are amenable to one of five treatment options: phytoextraction, phytotrans-formation, rhizosphere, bioremediation, phyto-stabilization or rhizofiltration. Phytoremediation can be used along or, in some cases, in place of mechanical cleanup methods. Phytoremediation can be used to clean up metals, pesticides, solvents, explosives, crude oil, polycyclic aromatic hydrocarbons and landfill leachates.

Jan 1, 2006

By Ch. Apostolaki

Eighty samples from Roman wall paintings from ancient Corinth were studied by means of optical and scanning electron microscopy coupled to an energy dispersive analyzer, X-ray diffraction and image analysis techniques. The goals of the study were the identification of the exact nature of the pigments and the technical features of paint application (binding medium, adherence to plaster, thickness of the pigment layer), which would provide evidence about the painting technique (fresco or secco). The main plaster is calcitic with secondary calcite as a cement binder to the primary calcite grains. All pigments, except Egyptian Blue, were naturally occurring ochres or pigment minerals, such as limonite, goethite, hematite for yellow, brown and red hues, cinnabar for red hues and celadonite for green color. The presence of specific elements such as Ni and Cr or minerals such as olivine, in the yellow, brown and red pigments, gave an indication about the provenance of the original pigments, which seems to be from Cyprus. The black color was represented using charcoal. It seems, finally, that for the pigment application the fresco technique was used, while secco is also apparent.

Jan 1, 2006

Bioleaching of solid wastes lithium ion battery industries was carried out in this investigation. A new method for recovery of cobalt, potentially the basis of an economic and environmentally friendly process was examined. The present study was conducted using chemolithotrophic and acidophilic bacteria Acidithiobacillus ferrooxidans and some mixed thiobacilli collected from abandoned mine drainage. These organisms were able to utilize sulfur and ferrous ion as energy source. Bio-dissolution of cobalt was found to be faster than lithium. The effect of initial Fe(II) concentration, initial pH and solid/liquid (w/v) ratio were studied in detail. With increase of time of leaching the dissolution of cobalt was found to be increased and this must be due to competitiveness of the mixed thiobacilli for utilizing the energy source among them. Since the bacteria are belonging to acidophilic group the higher pH studies revealed a decrease trend in metal dissolution. Higher solid/liquid ratio also found to be detrimental for the bacterial activity. It seems bacteria are not resistant to higher concentration of the metal. The optimized conditions for bio-dissolution were sol-id/liquid (w/v) ratio - 10 g/L, initial Fe(II) concentration - 5 g/L, elemental sulfur - 1% (w/v). In the optimized conditions, cobalt dissolution was observed to be about 75 % whereas that of lithium was 15% after 25 days.

Jan 1, 2006

By A. Geertsema

Introduction Gasification of coal has been practiced for many decades for the production of gas, fuels, chemicals and power. However it has only more recently started to get significant attention in the USA. In this review of the basics the features of gasification as compared with combustion is covered and the potential of increasing the conversion of coal via gasification is indicated. After dealing with the fundamentals of gasification a review of gasification technologies will be presented with an indication of the widespread international and more limited US use of this technology. In conclusion the attention will be directed at the future prospects of gasification.

Jan 1, 2006

By A. E. Koski

Two of the largest industries in northern Michigan, pulp and paper manufacturing and iron mining, formed a mutually beneficial partnership and collaborative research program to utilize paper mill residuals for waste rock stockpile reclamation. Historically, the majority of the paper industry’s residuals have been disposed of in landfills. The beneficial use of paper mill residuals for mine reclamation provides an environmentally sound recycling solution for the solids generated at northern Michigan paper mills and eliminates the need to strip additional overburden (glacial till) for final mine reclamation. Residuals offer a cost-effective source of organics and nutrients necessary for successful reclamation and waste rock stockpiles offer an economical and environmentally sound solution for disposal of residuals. The goal is to successfully pioneer technical development of paper mill residuals to accomplish vegetation of steep waste rock stockpile slopes and benches to establish a self-sustaining plant community that meets final reclamation requirements. Of the various types of iron mining wastes, rock stockpiles pose the greatest reclamation challenge. Success depends on incorporating sufficient organic matter into the rock stockpiles to produce a growth medium that can sustain vegetation without the need of overburden. This is an ongoing research program that is evolutionary in nature with numerous field trials, greenhouse studies, data collection and monitoring over multiple growing seasons. The program is a combination of innovative ideas and accepted reclamation practices that is proving to be a beneficial and economic approach to paper mill residual management and mine reclamation that will eventually lead from research to standardized reclamation procedures.

Jan 1, 2006

By L. J. Moore

Introduction Hydrometallurgical solvent extraction (SX) processes – featuring large quantities of combustible or flammable organic solvents - are common in the mining industry for recovering non-ferrous metals such as copper, nickel, cobalt, uranium, tungsten, iodine and lithium. Recent fire loss incidents and the widespread use of sub-grade tank farms and piping trenches, plastic piping, poor drainage, and closely spaced buildings demonstrate opportunities to improve the use of Inherent Safety (IS) in this industry. The mining industry has designed and constructed facilities with an emphasis on personnel safety, production efficiency and cost effectiveness. The use of IS to eliminate or minimize property fire exposures has not seen widespread practice. Lessons learned from the mainstream CPI have not been communicated or applied. As an example, copper SX plants have consistently used design of gravity flow as a cost and production-effective solution for transferring liquids and minerals through the process. In fact, Jergensen1 recommends to “utilize gravity to the fullest extent possible” in design of SX plants. This philosophy has been achieved by laying out SX plants with process equipment at different grade levels so that solutions can flow “downhill”. Because of the use of large quantities of flammable liquids and the potential for these liquids - if released – to flow unimpeded into other areas – gravity SX processes represent severe inherent fire consequences unless costly barriers, drainage and channeling are also provided. It appears that little thought has been given to the fire protection consequences and challenges of this design feature during the evolution of SX plants and most copper SX plants constructed today use some form of a sub-grade processing area (tank farm) and one-way gravity flow. While this layout is used to assure a cost effective operation it has resulted in significant exposures to high value production. The use of sub-grade production units is an inherently unsafe layout where flammable liquids are used and is a layout that would rarely if ever be used today by the mainstream CPI. Gravity-assist layout is only one example where copper SX plants have been designed and constructed without IS in mind. The use of combustible and frangible corrosion-resistant materials – such as glass, wood and plastic - for flammable liquid storage, processing and piping systems has significantly increased the hazards of these facilities. These materials of construction are not rigorous and allow for rapid failure and release of flammable contents during fire exposure. The use of combustible or frangible systems to handle or transport flammable liquids is not a practice seen today in the CPI.

Jan 1, 2006

The HB 2500 hydraulic breaker attachment from Atlas Copco Construction Tools features Krupp percussion technology and a service weight of 2,500 kg (5,512 lbs). This makes it ideal for demolition, tunneling, trenching, foundation work, rock mining and secondary breaking. Suitable for carriers in the 29-to 43-t (32-to 47-st) weight class, the HB 2500 accepts maximum hydraulic flow of 219 L/min (58 gpm) at 18 MPa (2,610 psi) of pressure, and delivers an impact rate of up to 550 blows per minute. The HB 2500 features PowerAdapt, a new system that automatically shuts down the breaker in the event that it receives excessive oil pressure from the carrier.

Jan 1, 2006

By M. J. Miller, N. Ripepi, M. Karmis, J. M. Conrad

Unmineable coal seams present an opportunity to sequester carbon dioxide emissions from power plants, while enhancing the recovery of coalbed methane. Injected carbon dioxide is adsorbed and stored on the coal surface while releasing methane that can be commercially recovered. Carbon sequestration, therefore, allows the utilization of unexploited mineral resources while reducing “greenhouse” gas emissions. This paper presents the feasibility, efficiency and enhanced recovery potential of coalbed methane production using carbon dioxide sequestration in the Central Appalachian Basin. The focus of research is on geological characterization of unmineable coal seams in Central Appalachia and the corresponding carbon dioxide storage capacity. Virginia Tech and Marshall Miller & Associates, Inc. conducted this research under the Department of Energy’s Southeast Regional Carbon Sequestration Partnership program.

Jan 1, 2006

By E. Baliktsis

PPC (Public Power Corporation) operates a new power plant at the South-West part of Crete. Recently the extension of the Power Plant started. ATHENA SA the main contractor of the project assigned to EXORIXI SA the implementation of a blast vibration monitoring program and prevention-evaluation of risks caused by construction blastings inside or very close to the operating part of the power station. The blasting parameters and characteristic elements that had been evaluated, the measures that had been taken and materialized, the overall risk management and the results of the whole program are presented in this paper.

Jan 1, 2006

By J. Nowak

Polish power industry is based on brown and hard coal combustion and transferring the heat into electric power. Over 99% of lignite is used as a fuel in power plants. Lignite is mined on in open pits. Therefore very deep (for example 300 m in Belchatow open pit) excavations having great volume are formed. Thus such type of mining has the impact on land degradation. In order to reduce this effect, at the earliest possible moment the cap rocks are dumped in the pit but at the safe distance from the mining face. Due to the big amounts of lignite delivered to the power plant, there are shortages of solids for filling the pit after completing the mining operations. Geotechnical properties of dumped combustion by-products depend on the lignite type, combustion technology and ashes haulage methods. The paper presents lignite combustion methods used in Poland and their impact on properties of ashes and methods of their transport determining the parameters of dumped wastes. Geotechnical, physical and chemical test results concerning transport and deposition of hydraulically active ashes from the Belchatów power plant are presented. The critical role of geotechnical properties in selecting the deposition technology and post mining management of open pit excavations was showed. The importance of filling the post-mining spaces for restoration the useful function of brown fields and for neutralization of negative effects of mining activity, was underlined.

Jan 1, 2006

By M. Stoica

Bioremediation is a complex process which involves mass transfer, chemical and biochemical phenomena. In particular, the adsorption kinetics of a substance by biomass may by model by taking into account: - Enzymatic kinetics type; - Combined kinetics - enzymatic kinetics at the same time with the Monod type biomass growth; - Chemical kinetics for substance adsorption according to Freundlich and Langmuir ad-sorption isotherms; - New empirical kinetics models based on experimental data. In this paper modelling of kinetics of bivalent lead ions on live vegetal biomass (aquatic plant Pistia stratiotes) as well as of hydrocarbons on dead vegetal biomass (pyrolysed nuts) is studied (Stoica, 2004). Modelling was carried out using experimental data and relative equations with an error of 5%.

Jan 1, 2006

By E. F. Schnitzer, C. Lidstone, D. Cramer, P. J. Wampler

The River Island mining site is located at approximately river mile (RM) 15 on the Clackamas River, a large gravel-bed river in northwest Oregon. During major flooding in February 1996, rapid channel change occurred. The natural process of meander cutoff, slowed for several years by dike construction, was accelerated by erosion into gravel extraction ponds on the inside of a meander bend during the flood. In a matter of hours, the river cut off a meander and began flowing through a series of gravel pits located on the inside of the meander bend. The cutoff resulted in a reduction in reach length of approximately 1,100 m. Erosion by bed lowering, knick point retreat and lateral erosion of upstream river banks occurred quickly. Within two days of the peak flow, 3.5 hectares of land and 105,500 m3 of gravel were eroded from the river bank just above the cutoff location. Much of this gravel moved a short distance downstream into the excavation. Reach slope increased from 0.0022 to approximately 0.0035 in the cutoff reach. Between 1996 and 2003, the knick point from the meander cutoff has migrated 2,290 m upstream, resulting in increased bed load transport, incision, and local lowering of the water table. In 1993, prior to the meander cutoff, transects were surveyed in the River Island reach upstream of the cutoff location. Resurvey of these transects and aerial photo analysis indicates that 96% of the knick point migration occurred during the first winter following meander cutoff. Connection of the flowing river to the off-channel ponds has had minimal effect on water temperatures in the mainstem Clackamas River. It is likely that this minimal change in temperature will decrease as ponds are isolated from active river flow by gravel bar deposition. Fish net-ting in spring 2002, suggests that salmonid use of the pond in the spring is minimal. The most abundant native species netted were large-scale sucker and northern pikeminnow. The most abundant non-native species netted was brown bullhead. Early regulation by state and federal agencies did not adequately evaluate potential impacts to the river and the floodplain; nor did it evaluate future impacts related to geomorphic processes and sediment transport. New permit evaluation methods, currently implemented by both Oregon and Washington, incorporate 1) river dynamism through historic river migration analysis; 2) stability of human structures in light of river dynamics; and 3) sediment transport and its impact on channel stability and dynamics. The gravel pit capture at River Island highlights the potential risks of mining in an active secondary channel of a large gravel-bed river. Mining deeper than the depth of the adjacent channel, within the active migration zone, may increase off-site impacts. In locations where multiple gravel excavations are present within the meander zone, a comprehensive reclamation and restoration plan should be developed which provides long-term channel stability within the natural variability of the entire river reach.

Jan 1, 2006

By I. Douni

The aim of this study is to synthesize hydrated compounds of calcium silicate (tobermorite) using as siliceous source perlite milling process wastes, containing more than 70% of SiO2. Calcium silicate hydrates are mainly used for construction of lightweight building materials, plasters, tiles and filters. The effect of temperature, time and particle size of perlite on the quality and composition of the solid product was studied. The solid products were characterized by X-ray Diffractometry, Differential Thermal Analysis and the amount of Acid Insoluble Residue. The synthesis of tobermorite was per-formed by the hydrothermal treatment of perlite waste with a saturated calcium hydroxide solution at a molar ratio CaO/SiO2 of 1, liquid to solid ratio 10 mL/g and 1% w.t. NaOH addition. Three experimental sets were performed. In the first series of experiments the synthesis temperature was kept constant at 205°C while the synthesis time varied from 0.5 h to 24 h. In the second experimental series the synthesis time was kept constant at 2 h while the temperature varied between 150°C and 245°C. In the third experimental set the temperature was 205°C and the reaction time was 2 hours and two perlite waste size fractions were used, a coarse (d50=18 µm) and a fine grained one (d50=8 µm). Reaction products consisted of semicrystalline calcium silicate hydrate (I) and crystalline Al-substituted tobermorite or a mixture of both. An isomorphic Si4+ ions substitution with Al3+ ions in the hydrated calcium silicate lattice was detected by thermal analysis. The experimental results show that good quality crystalline Al-tobermorite can be produced after 6 hours of autoclaving at 205°C or after 2 hours of hydro-thermal treatment at 225°C. Generally, the in-crease of synthesis temperature or time favors the crystallization of calcium silicate phases and enriches them in aluminum. The use of fine grain size perlite is more efficient for the hydrothermal synthesis of calcium silicate hydrates.

Jan 1, 2006

By E. H. Cho, B. Conner

Three sulfide minerals, chalcopyrite, sphalerite, and pyrite, were leached using a bioleaching mode and an electrobioleaching mode. The former mode was used to leach the minerals with the bacterium A. ferrooxidans in a bioreactor. In the latter mode, the leaching of the minerals was performed in a combination of a bioreactor and an electrochemical cell. In this set-up, the solution was circulated between the bioreactor and the cathode compartment, the two reactors were in series, and the cell was operated intermittently. The mechanism is such that an increase in Fe(II) concentration, which is a nutrient of the bacteria, by electrochemical reduction of Fe(III) would increase the bacterial population and in turn would accelerate the leaching of the mineral. It has been found that the electrobioleaching of chalcopyrite is an improvement over the bioleaching with respect to the fact that leaching conversion is higher and a high level of Fe(II) concentration can be maintained. However, the electrobioleaching of sphalerite does not show any improvement over bioleaching. The electrobioleaching of pyrite is similar to that of chalcopyrite, and this has potential to be used in applications such as coal desulfurization and pretreatment of refractory gold ore in heap leaching where fine gold particles are entrapped inside pyrite particles.

Jan 1, 2006

The residues produced during the incineration of leather scraps contain significant amount of chromium which can be recovered and reused in the tanning industry. The objective of this study is to develop a cost effective method for chromium recovery from leather ashes produced during the incineration of leather scraps using a fluidized bed incinerator. The entire process investigated involves fusion of leather ash with sodium carbonate in air to oxidise chromium to sodium chromate, leaching with distilled water to dissolve chromates, and chromium reduction from the hexavalent to trivalent state by sodium thiosulphate solution. The main factors affecting chromium extraction, such as temperature, reaction time, and sodium carbonate to leather ash ratio, were investigated. Based on the results obtained, almost 100% Cr extraction can be obtained at 700°C fusion temperature, sodium carbonate to ash weight ratio equal to 3 and retention time longer than 50 min.

Jan 1, 2006

By B. Stewart, J. R. Warneke

The productivity of underground mines has increased dramatically since the introduction of continuous miners. A variety of new hazards have developed as a result. In the spring of 2004, Mine Health and Safety Administration (MSHA) held a workshop to brainstorm ideas to decrease the number of injuries associated with continuous miners. One of the main areas of discussion at the workshop was “trailing cable-handling injuries.” The method of handling the power cables over the years has changed very little while the technology and uses of continuous miners has advanced dramatically. This paper will discuss the main ideas brainstormed at the MSHA continuous miner (CM) trailing cable handling workshop and the history and root causes of cable-handling injuries, as well as proposed ideas developed at the National Institute for Occupational Safety and Health (NIOSH) to alleviate some of the cable handling issues.

Jan 1, 2006

Iron removal using biologically produced organic acids was investigated as a treatment option for the production of refractory grade bauxite. A leaching solution containing 98mM oxalic and 67mM citric acid was prepared from a sucrose medium using for fermentation the fungus Aspergillus niger. The leaching capacity of the metabolic product was tested on a bauxite sample containing 16-19% iron (as Fe2O3). Aerobic and anaerobic leaching tests were carried out at pH 3, 50°C and in the absence of light. Results indicated that more than 80% of total Fe can be removed from the ore, when the sample is finely ground and applying a two stage treatment. The presence of oxygen was seen to affect adversely the kinetics of the process, suggesting that leaching follows a reductive mechanism. Experiments that were carried out with different particle size fractions indicated that for obtaining efficient removal of iron particles should be finer than 0.63mm. Reduction of the operating temperature from 50 to 30°C caused a decrease in the rate of iron removal by more than 10 times.

Jan 1, 2006

By Michel Grenier, David A. Young, Brent Rubeli, Mahe Gangal

This work forms part of a study being conducted into the feasibility of constructing a prototype Load Haul Dump (LHD) vehicle for operation in underground Canadian mines. A series of in-laboratory assessments were performed to determine the relative contributions of a Deutz F4L912W (54 HP- conventional vehicle engine) and a Deutz F2L 2011 (31 HP hybrid vehicle engine) to diesel emissions concentration during mine transient duty cycles and steady-state operating modes respectively. Results indicate significant reductions in the quantity of gaseous and particulate emissions with the application of the hybrid system and a high-efficiency ceramic element filter. This paper describes the engine test protocols and the results of this laboratory study.

Jan 1, 2006

By M. Kaya

The main purpose of this study was to design a modular/mobile coal preparation plant with a capacity of 300 t/h for Seyitömer B3 vein (almost 70% of the whole SLI deposit). Firstly, coal washing properties and washability curves were determined by sink and float tests. Then, equipment sizing, selection, flow sheet development, economic evaluation, investment and operating costs were determined for coarse (-150+18mm), fine (-18+0.5mm) and slime (-0.5+0.1mm) coals. Economic evaluation of the proposed flow sheet showed the feasibility and profitability of the investment.

Jan 1, 2006