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By Vladimir J. Ovdenko, Sergey N. Lazarenko, Evgeny L. Schastlivtsev

The term sustainable development shortly appeared in international use in the run of UNO Environmental Protection Conference held in Rio de Janeim in 1992, bears the concept, that evolution process ( associated either with a region or society) should provide mutual interests concern in three aspects - environmental, economic and social ones, admitting as well the fact , that environmental protection should become an integral part of each process and cannot be regarded separately. In this connection it seems quite reasonable to employ the principal of sustainable development, while creating the model of industrial mastering the territory constraint lands viewing their future, for a example, in rich mineral deposit's development. In Kuznetsk coal basin in Russia ( west Siberia) the development of a big coal deposit Erunakovsky is now being underway. The major part of coal will be mined with open cast method, resulting the number of local environmental adverse impacts' occurrence. In such a situation mastering of sustainable development model is given the top priority, demonstrating the essential result of its application in a form of possibility to define the best correlation between economically expedient and environmentally tolerable loads during coal mining. The given paper is an attempt to work out the main principals to approach the creation of sustainable development model in regard of the definite region case. To simplify the presentation of employed approach's main idea, the given below accepts as its component only one of many actually existing environmental profiles, that define mining pro- cess impact on environmental situation -the size of infringed (de- graded) lithosphere surface. Basically, the actually existed correlation between spheres. grounding the model of sustainable development - economic, environmental and social- is given in a form of nomogram under Fig.1. On the presented graph the prognostic values of broken lands relative extent within Erunakovsky boundary ( to be compared with total region area taken as 100%) are arranged on axis x". Axis "y- demonstrates the main values associated with complete economic background, making the intrinsic part of the principal for sustainable development, i.e. annual coal output for the given area. It's top, used in assessment value relates to actual showings implied for the study region project and quantifies 60 min. tons. While regarding the social facet of principal for sustainable development, the applied mode to separate social issues into two types - one profiling a welfare standard of living and the other. pertaining the way environmental situation contributes to the degree of &ologica-1 comfort in people's living was defined as the most expedient and the most adequate in the matter of reflecting the actual terms of vital activity of the society. In accordance with the cited above the economic level showings are plotted on the graph on "-x” axis, while "-y" one obtains the values associated with the point of ecological comfort presented in conventional units. For the maximum possible conventional point of living (corresponding in nomogram to 1.0 value) a welfare level secured with industrial region economic activity revenue was assumed in case the top planned annual amount of coal is delivered ( 60 min. tons). While studying the index of public economic welfare, environmental conditions corresponding level in its original state i.e. prior to any industrial work carried in the region, was adopted as its top possible conventional rating (1.0). The given nomogram displays the integrity of x-f(y) type interrelations plotted on the basis of four separate dependencies, precisely a) the size (area) of infringed earth's surface as a function of coal output in the region; b) subordination of ecological comfort of people's living to the degree of lands infringement; c) interconnection of economic and environmental components of people living; d) interconnection of economic level of people's living and the amount of coal mined in the region. Linked to a single unit, these separate plain dependencies create, as seen from the graph, a more intricate system of bonds, that affords during defining or changing this or that system parameter to secure undergoing changes, that occur to other parameters of the system. The mentioned reason made it possible to consider and drive to mutual conformity ( as far as it is possible) all parameters values for the defined system's relations, that in their turn indicate the concern of other aspects of a sustainable development principal. According to the graph, in order to get not more than 50% of infringed land left after the deposit's mining, it is advisable to ex- tract not more than 40 min. tons of coal annually, gaining in this case the level of ecological comfort for living in the amount of not

Jan 1, 1996

By J. A. Cole

This paper discusses the modification of the cyanide tailings treatment method from ferrous sulfate to Caro's acid (peroxymonosulfuric acid). An examination of the operating parameters, costs, and chemistry describes how the decision was made to switch to this treatment method. Plant data collected from the last several months will be used, along with considerations from an operator's viewpoint.

Jan 1, 1996

By M. J. Gula

In the solvent extraction -electrowinning recovery of copper from oxide or sulfide ores there is a continuous transfer of iron and other impurities from the primary leach solution to the copper electrowinning electrolyte via chemical transfer or mechanical entrainment. Iron is the principal impurity that has to be controlled in the electrolyte by a "bleeding" of the electrowinning solution. This bleeding transfers copper and sulfuric acid back to the primary leach circuit along with the iron. Copper is recovered via the solvent extraction process and generally the sulfuric acid is used as a reagent in leaching. Unfortunately, cobalt, which is added to the electrowinning solution to modify the anodic process, is irreversibly lost through the bleeding operation. This cobalt loss represents a significant operating cost to SX-EW copper producers. DiphonixTM ion exchange resin contains diphosphonic acid and sulfonic acid functional groups on a polystyrene-divinyl benzene matrix. This resin has been found to strongly and selectively extract ferric ion from copper sulfate -sulfuric acid solutions containing cobalt. Thus, an ion exchange process using DiphonixTM resin for the control of iron has been developed to replace the conventional bleed stream process. The new process minimizes the loss of cobalt from the electrowinning circuit and strips the iron into a sulfate based solution suitable for leach solution makeup. In addition, this process can effect a lowering of the total iron concentration in the electrolyte circuit with an associated increase in current efficiency. In this paper, data on the loading and elution of iron are presented. Laboratory and pilot scale data will be discussed along with information on process design and comparative economics.

Jan 1, 1996

By Roy Norcross

For the past few years Caro's acid has been used for the treatment of cyanide containing slurry effluents, providing a feasible alter­ naive to other slurry treatment processes including !NCO SO2 / Arr and ferrous sulfate. Presently, mines using Caro's acid gen­erate their own Caro's acid onsite making a relatively low quali­ty product. It was at this point where we, at Degussa Corporation, decided to focus our efforts on engineering a Caro's acid genera­tor capable of cost effectively producing a high quality Caro's acid solution, thus reducing operating costs significantly. Caro's acid or peroxymonosulfuric acid is not a new chem­ical nor is it new to Degussa. The product was named after Heinrich Caro (1834-1910), a German chemist who first described its synthesis and its oxidizing properties in 1898. Degussa has been producing the potassium salt of Caro's acid as the triple salt, 2KHSO5 - 2KHSO4 - K2SO4, called Caroat®, for over 30 years. Caroat® is used for household and denture cleansers, as a bleaching agent in dish washing detergents, in printed circuit board etching and for cyanide destruction in the plating industry. From our experience in producing Caroat® Degussa developed its new Caro's acid based DegOX™ technology for the treat­ment of cyanide containing effluents from gold and silver mines.

Jan 1, 1996

By John D. Batty

With the emergence ofbiooxidation as a viable process for the pre treatment of refractory gold ores, so have the number of publica­tions on this topic increased dramatically. To a novice in the field of biooxidation, the infonnation presented is often confusing and sometimes even incorrect. Infonnation has also been published that is misleading in that it highlights a particular feature of a process that is either totally irrelevant or of no consequence to the ultimate goal viz. achieving the maximum economical gold recovery. To assist a potential user of biooxidation in evaluating the available published infonnation some guidelines or considera­tions for some of the more important aspects are given, as well as some extracts from publications that demonstrate the manner in which information has been presented.

Jan 1, 1996

By Doug Williams, Kent J. McGrew, Dr. Jack Murphy

For some time, selenate has eluded water treatment by conven­tional means such as precipitation and clarification. This has been due to the nearly universal solubility of all oxidized sele­nium species, the low levels required for surface discharge, and almost identical chemical behavior to all forms of oxidized sul­fur. The last characteristic makes selenate particularly difficult to deal with in acid mine waters where sulfate can easily be on the order of one gram per liter. Approaches such as ion exchange or reverse osmosis often tum into total demineraliza­tion schemes for the sake of removing a "trace" selenium species that may be present on the order of 108 sulfate/selenate. Reduction of selenate to selenite or elemental selenium by chemical means has been relatively unresearched. Some limit­ed success has been reported (Murphy, 1988) using ferrous hydroxide as a reducing agent; however, the reaction time as reported is too slow to be useful in a practical plant design. One significant difference between selenate and sulfate is that selenate has been discovered to be reducible in acid solution by elemental iron when catalyzed by soluble copper. Since the +4 or zero valence states of selenium are rather easy to deal with by coprecipitation with iron salts or alum, the elemental iron dis­solved in the process contributes to the overall process by pro­viding sludge upon raising the pH that can be separated by con­ventional clarification. Commercial production of selenium using copper catalyzed reduction of selenite to selenium metal via sulfur dioxide is well established, however, at the < 5 ppb requirements for surface discharge this reduction process equili­brates at levels far too high to be useful to low level selenate removal criteria. The reaction reported herein uses elemental iron for reduction of selenate with copper acting either as a cata­lyst or as a coprecipitation agent. This method, employed with conventional sludging, clarification and filtration can provide an economic method to achieve non detectable selenium (< 0.005 mg/I). Iron consumptions for the conditions tested have been on the order of 3 lbs/1,000 gallons treated. This represents as little as $0.06 or $2.00 per 1,000 gallons based on using a scrap source of iron or the purchase of electrolytic iron for the process.

Jan 1, 1996

By Robert W. Bartlett

Heap biooxidation of sulfidic refractory gold ore requires large amounts of oxygen, as shown in Figure 1. Bacteria, Thiobaci/lus ferrooxidans, are donnant at oxygen concentrations below about 3% in air (1 ppm in aqueous solution) because ofmonod kinet­ics. Hence, the maximum possible utilization is only about 75%, and it may be much less than that due to poor air sweep effi­ciency. At the maximum oxygen utilization, an ore containing two percent pyrite requires nearly 100 cubic meters of air per tonne (4,000 cubic feet per ton). The stoichiometric air require­ment to oxidize arsenopyrite is similar to that of pyrite. While the leaching solution percolating through the heap introduces some dissolved oxygen, the amount is insignificant because of the low solubility of oxygen in water, 7 to 8 ppm at atmospheric saturation. There are only three ways to provide oxygen to the heap: either air flow by natural convection, diffusion of oxygen from the surface (through stagnant air in the air-filled void space in the heap), or forced air ventilation of the heap. Each of these processes will be reviewed.

Jan 1, 1996

By Paul D. Chamberlin

In the author's selenium report of 1994 (1), the literature was culled for selenium removal technologies that had a chance of producing effluents with <10 ppb of total selenium. Very few processes could achieve such low concentrations. The EPA dictates such low concentrations. Discharges to fishery waters must be <5 ppb total selenium. The federal max­imum contaminant level ( MCL) for drinking water is 50 ppb. The EPA regulations are for total selenium, not for the species, perhaps because an approved EPA assay method is atomic absorption and it cannot distinguish between species.

Jan 1, 1996

By John J. Mancini

Elastomeric liner products have been used for over two decades in a wide variety of uses including pond liners, hazardous waste barriers, dam face rehabilitation and mining applications. Asphalt blended with polymers is enjoying renewed interest in the engineering community because of its durability, high yield attributes, fewer CQA steps due to seamless installation, and ease of installation and repair. As in other lining technologies, advancements in polymer chemistry and improvements in installation techniques have had dramatic impact on the quality of fluid-applied asphalt (FAA) membranes. Membrane 6, man­ufactured by Deery Oil, Inc. for over 16 years is a hot-applied polymer modified asphalt membrane that can be applied to a variety of substrates in a reinforced configuration or installed directly on an asphalt surface. By blending thermoplastic polymers with asphalt, very favorable stress/strain characteristics can be achieved (Chambers, 1980). Typically the membrane will yield under rel­atively low stress and also exhibit high elongation capability. In service applications where puncture resistance is a concern, fluid applied asphalt materials have the flexibility and com­pressive strength under heavy loading that leach pad designers may find attractive. Additional security is achieved if long term service life is important as in the case of radioactive waste con­tainment. The Department of Energy selected Membrane 6 over seamed liners for a surface barrier that must isolate and contain radioactive waste for 1000 years. Asphalt has a long history of use as a water-stop material and it is believed that this natural construction material combined with SBS polymers will per-form for a millennium. (Freeman, 1994) The process of installing Membrane 6 varies according to job size and the type of surface to be protected. Lining applica­tions on compacted substrates require the membrane to be applied to a scrim cloth (fig 1). Some early pioneers in FAA technology neglected this step and therefore never achieved per­formance levels that satisfied regulatory guidelines. The scrim provides a cohesive surface that promotes membrane flow while achieving high impermeability (2Xl0 '11).

Jan 1, 1996

By Douglas K. Maxwell

Critical components of any Carbon-In-Pulp or Carbon-In-Leach system are the carbon retention screens. One popular design of carbon retention screen is the "NKM" or "Nor-Kai" unit that was developed in South Africa based on units from there and Australia. OSNA Equipment has been manufacturing "NKM" style screens in North America since 1989. OSNA has sold approximately 200 individual NKM screens to date, equipping more than 20 gold leaching plants in the Americas and the Southwest Pacific.

Jan 1, 1996

By John G. Banker, Arthur L. Forrest

Titanium solves corrosion, maintenance and environmental problems in many reactor and autoclave applications. Titanium clad construction permits autoclave designers a great deal of flexibility combined with significant cost reduction. Titanium alloys can be selectively applied in specific regions of the auto­clave to accommodate local environmental conditions. Resistance to general corrosion, crevice corrosion, abrasion, and ignition conditions can be accomplished selectively and eco­nomically. Explosion clad pressure vessel fabrication and perfor­mance have been proven through three decades of experience.

Jan 1, 1996

By Fred W. De Vries

The history of mining-industry regulations on cyanide indicates a trend to set criteria based on generalized inferences related to its high toxicity. As toxic-inventory-motivated regulations are framed, material balances are expected to imply atmospheric releases of HCN as a major factor. A review of atmospheric data shows the probable triviality of any environmental impact of such releases, and suggests a very deliberate approach to any proposed regulations regarding these emissions.

Jan 1, 1996

By John W. Greene

ennec?tt's Bameys Canyon Mine personnel developed an mnovahve process to extract gold from a small (1.8 million tons) sulfide ore zone in an oxidized ore body located at the Bameys Canyon Mine. This approach consists of extracting the sulfides from the ore via flotation, shipping the concentrate to Kennecott's new smelter, and mixing the flotation tailings with the oxide ore, agglomerating the mixture, and stacking the resultin tailings/oxide ore combination on the heaps. Conventional heap leaching technology is utilized to recover the gold from the mixed materials. Overall, the total gold recovery from the sulfide ore is esti­mated to be 90%. This approximation is based on a smelter gold recovery of 98% from the concentrate and an 88% recovery from the tailings during heap leaching

Jan 1, 1996

By W. R. Mackenzie, C. A. MacDonald

Oxide copper was discovered in 1946 at Guelb Moghrein. Early work culminated in the construction in 1970, by a consortium headed by the Anglo American group, of a project producing copper concentrates from 1,000,000 tonnes per annum of oxide ore. The process used was the TORCO (Treatment Of Refractory Copper Ores) process, which reduced oxide copper minerals to elemental copper by roasting in fluidised beds at 800°C with salt and coal. The roaster product was then floated to yield a high grade smelter concentrate, which was exported. The project closed in 1976, due to low copper prices and increased energy prices, leaving an open pit, the old TORCO plant, a water pipeline, and more than 2,000,000 tonnes of tail­ings, which contained remnant copper, as well as an average of 3 git of gold. After several attempts to recommence operations at Akjoujt, recovery of gold from the old TORCO tailings was started in 1992 by a joint venture company known as MORAK (Mines d'Or d'Akjoujt). This company comprises General Gold Resources N.L. of Australia, who are the managing partner, SAMlN (La Societe Arabe des Mines d'Inchiri) and the International Finance Corporation. Because the tailings are high in copper (0.1-0.3% Cu), the project used the 'Hunt' process, which uses a combination of cyanide and ammonia to leach gold while suppressing copper extraction. The gold is recovered from leach liquor by carbon absorption.

Jan 1, 1996

By Bruno Sceresini

Prospectors and small scale mmmg companies have long expressed the wish for a highly mobile mineral processing plant. This is especially so in the case of gold mining as relatively small deposits can be highly profitable due to the relative ease of producing a marketable product when compared with the refming and marketing costs incurred with base metals. This paper will concentrate on gold ore treatment in fitting with the theme of the 1996 Randol Gold Forum but the principles may also be applied to base metal ores. The development and application of the Atomaer Filblast Gas Shear Reactor as a cyanidation tool has removed the con­straints of plant size in pulp cyanidation applications. KC Dodd and Associates, Consulting Engineers and Australian Mining Advisers, Pty Ltd, have designed a 1,000,000 and a 250,000 tpa fully modularised ore treatment plant. Various module configu­rations can be arranged to treat a wide variety of ores ranging from simple gold ores to gold-copper and base metal ores. This paper will limit the discussion to comparing the capital and operating costs of a conventional and a modularised 1 million tpa gold treatment employing a number ofnovel concepts which complement the compact, high capacity Filblast Cyanidation Process and the AARL pump Cell Adsorbers. The design described in the paper not only reduces equip­ment sizes and allows for rapid deployment of a sizeable capac­ity plant but also offers significant capital and operating cost benefits.

Jan 1, 1996

By Peter Mason, Chris Walker, Mike Costello

The Phase I electrowinning system at KCGM's Fimiston Operation utilised the well proven technology of electrowinning precious metal values onto steel wool followed by calcining and direct smelting to bullion. The above process, while reliable and successful, was to some extent labour intensive. The Williams Mine in Ontario, Canada had published conditions under which precious metal values are electrowon onto woven stainless steel and directly removed using high pressure sprays. The current paper describes the testwork which was carried out to check the applicability of the Williams criteria to KCGM eluates arising from the elution of highly loaded carbon from the calcine circuit and lowly loaded carbon from the float tails circuit. Information is also given on the commissioning and opera­tional experience which occurred.

Jan 1, 1996

By Mark William Johns

Carbon-in-pulp (CIP) is the preferred method of gold recovery om cyanided plp. However, other gold adsorbents (namely, ton-exchange resms) are being introduced to the industry as they are considered to have several advantages over carbon for the recoery of gold. A set of test methods have been developed by the industry to evaluate the quality of different carbons. owever, many ?f these tests are not applicable to evaluating ton-exchange resms. Hence, a need has arisen for a method to evaluate the different adsorbents. This paper introduces a philosophy to evaluate an adsorbent that results in an estimation of the capital cost and the operating cost associated with the adsorbent. Tests that have been devel­ oped to evaluate the ability of an adsorbent to adsorb gold (in­solutton . counter-current) and to evaluate the optimum adsorbent for a specific pulp (in-pulp batch) are introduced. A method of converting the test data into an economic dimension is present­ed. Case studies are presented to highlight the discussion.

Jan 1, 1996

By Marc E. Orman, Mark E. Smith

Regulatory and environmental concerns continue to broaden the range of mine wastes that must be capped with low permeabili­ty liner systems at closure. The mining industry has been a leader in developing liner technology for leach pads and tailings impoundments, but it is a newcomer to cap designs. Closure of waste piles, leach heaps and tailings require special design con­siderations. Factos such as differential settlement, surface ero­sion, veneer stability, vegetation and burrowing animals must be considered.

Jan 1, 1996

By Norbert Steiner, Roy Norcross

For the desulfurization of weak SO2 gas streams, Degussa developed a process using dilute H2SO4 solution containing H2O2 instead of conventional gas scrubbing with all solid absorbent medium (limestone, MgO). The process is based on fast reaction of H2O2 with SO2 yielding H2SO4 up to 70% strength, depending on off-gas tem­perature. Compared to the conventional systems with typically < 95% efficiency, independent on the raw gas SO2 concentra­tion, residual SO2 concentrations of less than 20 mg!Nm3 can be easily achieved, corresponding to nearly 100% removal. These features render the H2O2 process a very attractive, low capital cost technology to retrofit existing conventional desulfurization plants.

Jan 1, 1996

By Randy Clarkson

Sluiceboxes which are designed and operated as recommended from our recent research can provide much higher concentration ratios than most other gravity concentrators (up to 50,000: 1) at very high overall placer gold recoveries (95-99%). They are also very reliable, inexpensive and simple to operate. A sluice­box is a rectangular flume containing riffles on matting, through which a dilute slurry of water and gravel flows. However, sluiceboxes operating under ideal conditions are actually cen­trifugal concentrators whose riffles overturn ribbons of slurry to form vortices. At the bottom of these vortices, centrifugal and gravitational forces combine to drive gold particles into matting (figure 1).

Jan 1, 1996